You are currently on the new version of our website. Access the old version .

58 Results Found

  • Article
  • Open Access
10 Citations
2,910 Views
15 Pages

Perspective Compounds for Immobilization of Spent Electrolyte from Pyrochemical Processing of Spent Nuclear Fuel

  • Svetlana A. Kulikova,
  • Sergey S. Danilov,
  • Anna V. Matveenko,
  • Anna V. Frolova,
  • Kseniya Y. Belova,
  • Vladimir G. Petrov,
  • Sergey E. Vinokurov and
  • Boris F. Myasoedov

25 November 2021

Immobilization of spent electrolyte–radioactive waste (RW) generated during the pyrochemical processing of mixed nitride uranium–plutonium spent nuclear fuel is an acute task for further development of the closed nuclear fuel cycle with f...

  • Article
  • Open Access
6 Citations
7,731 Views
28 Pages

Analyzing Organic Electrolyte Solvents from Spent Lithium-Ion Batteries as a Basis for Distillative Value Component Recovery

  • Martin Wolke,
  • Kai Schröder,
  • Konstantin Arnold,
  • Pamina Mozumder,
  • Till Beuerle,
  • Katharina Jasch and
  • Stephan Scholl

5 February 2025

The rapid expansion of lithium-ion batteries (LIBs), largely driven by the rising demand for electric vehicles, will lead to a significant increase in end-of-life (EOL) batteries, necessitating efficient recycling processes, which must be accompanied...

  • Article
  • Open Access
16 Citations
3,451 Views
11 Pages

Conditioning of Spent Electrolyte Surrogate LiCl-KCl-CsCl Using Magnesium Potassium Phosphate Compound

  • Svetlana A. Kulikova,
  • Kseniya Yu. Belova,
  • Ekaterina A. Tyupina and
  • Sergey E. Vinokurov

16 April 2020

The current work was aimed at developing a new conditioning method of spent electrolyte-radioactive waste (RW) generated during the pyrochemical reprocessing of mixed nitride uranium-plutonium spent nuclear fuel. Magnesium potassium phosphate (MPP) c...

  • Communication
  • Open Access
12 Citations
4,147 Views
13 Pages

31 May 2019

By utilizing thermodynamic calculations, the possible removal path of spent lead-acid battery electrolytes was modeled. The process was divided into precipitation and carbonation processes. In the carbonation process, two scenarios were discussed, na...

  • Article
  • Open Access
11 Citations
12,132 Views
13 Pages

The archival value of this paper is the investigation of novel methods to recover lead (II) ions from spent lead acid battery electrodes to be used directly as electrolyte for a soluble lead flow battery. The methods involved heating electrodes of sp...

  • Article
  • Open Access
3 Citations
2,592 Views
15 Pages

Capacitive deionization (CDI) based on LSC-957 resin/carbon composite electrodes was used to remove Fe impurity ions from a spent vanadium electrolyte, which enabled simple and efficient regeneration of the electrolyte. The experiments conducted in t...

  • Article
  • Open Access
2 Citations
1,955 Views
12 Pages

1 September 2023

Among the many radiochemical problems, the search for new materials and technologies for the immobilization of radioactive waste remains relevant, and the range continues to change and expand. The possibility of immobilizing the spent chloride electr...

  • Article
  • Open Access
1,359 Views
14 Pages

28 January 2025

The molten-salt electrolytic method was employed to recycle spent SCR catalyst to prepare TiC compound. A systematic investigation has been carried out through thermodynamic calculation and experimental analysis. The effects of graphite content, cell...

  • Article
  • Open Access
1 Citations
1,168 Views
14 Pages

Electrosynthesis of Titanium Alloys from Spent SCR Catalysts

  • Long Zheng,
  • Jiahao Jin,
  • Zongying Cai,
  • Xiangpeng Li,
  • Qi Zhu and
  • Weigang Cao

16 January 2025

Spent selective catalytic reduction (SCR) catalysts are hazardous wastes containing many valuable metals whose improper disposal can cause environmental pollution and resource waste. Therefore, it is significant to recover valuable metals from spent...

  • Article
  • Open Access
1 Citations
2,358 Views
13 Pages

Behavior of Glass-like and Mineral-like Phosphate Compounds with an Immobilized Chloride Mixture in Hydrogen Peroxide Solutions

  • Anna V. Frolova,
  • Svetlana A. Kulikova,
  • Kseniya Y. Belova,
  • Sergey S. Danilov and
  • Sergey E. Vinokurov

5 September 2022

A new type of high-level waste (HLW) is generated during pyrochemical reprocessing of mixed nitride spent uranium–plutonium nuclear fuel. Such waste is a spent electrolyte, which is a mixture of chloride salts containing approximately 25.7 wt.%...

  • Communication
  • Open Access
17 Citations
4,674 Views
11 Pages

10 February 2020

Spent electrolyte from lead-acid battery contains high concentrations of sulfate acid and heavy metals; therefore without proper handling, they might cause severe environmental pollution. A relatively high concentration of sulfate ions (approximately...

  • Article
  • Open Access
8 Citations
2,046 Views
12 Pages

Effect of pH Hydrolysis on the Recovery of Antimony from Spent Electrolytes from Copper Production

  • Eduardo Díaz Gutiérrez,
  • José Antonio Maldonado Calvo,
  • José María Gallardo Fuentes and
  • Antonio Paúl Escolano

23 May 2023

This study examined how pH hydrolysis affects the recovery process for antimony extracted from spent electrolytes. Various OH− reagents were used to adjust the pH levels. The findings reveal that pH plays a crucial role in determining the optim...

  • Article
  • Open Access
1 Citations
1,258 Views
15 Pages

Investigation on the Recovery of Rare Earth Fluorides from Spent Rare Earth Molten Electrolytic Slag by Vacuum Distillation

  • Ziyan Yang,
  • Faxin Xiao,
  • Shuchen Sun,
  • Ganfeng Tu,
  • Zhentao Zhou,
  • Jingyi Chen,
  • Xin Hong,
  • Wei He,
  • Chengfu Sui and
  • Kuopei Yu

28 March 2025

Spent rare earth molten salt electrolytic slag (REMES) needs to be recovered not only because of its economic value of rare earth elements (REEs), lithium, and fluorine, but also for the environmental benefits. Vacuum distillation has many advantages...

  • Article
  • Open Access
11 Citations
3,015 Views
17 Pages

18 November 2022

A single production of nitrogen-doped graphene nanosheets was developed in this present work from a spent Zn-C primary battery. The electrochemically exfoliated nitrogen-doped graphene nanosheets (EC-N-GNS) was applied in supercapacitor symmetric dev...

  • Article
  • Open Access
6 Citations
2,008 Views
16 Pages

Effects of Ultrasonic Pretreatment on the Discharge for Better Recycling of Spent Lithium-Ion Batteries

  • Weichen Yang,
  • Zheng Tong,
  • Hezhan Wan,
  • Shuangyin Jiang,
  • Xiangning Bu and
  • Lisha Dong

2 February 2025

Discharge treatment is a vital process in the pretreatment of spent lithium-ion batteries (LIBs). This paper focuses on the effects of ultrasonic pretreatment on the discharge of spent LIBs from the perspective of electrolyte concentration and ultras...

  • Article
  • Open Access
1 Citations
1,532 Views
20 Pages

15 May 2025

Recycling the positive electrode materials of spent Li-ion batteries is critical for environmental sustainability and resource security. To facilitate the attainment of the goal, this study presents a novel approach for recovering valuable metals fro...

  • Article
  • Open Access
2,651 Views
16 Pages

Electrochemical Oxidation of Phenol Released from Spent Coordination Polymer Impregnated with Ionic Liquid

  • Nicoleta Plesu,
  • Bianca Maranescu,
  • Milica Tara-Lunga Mihali and
  • Aurelia Visa

7 December 2023

Coordination polymer (CP)-type adsorbents impregnated with ionic liquids that are used to remove phenol from wastewater must be regenerated. A simple washing of the adsorbent releases about 70% from the spent adsorbent. In order to increase and study...

  • Article
  • Open Access
1 Citations
3,053 Views
14 Pages

Electrolytic Regeneration of Spent Caustic Soda from CO2 Capture Systems

  • Hossein Mohammadpour,
  • Almantas Pivrikas,
  • Ka Yu Cheng and
  • Goen Ho

2 April 2024

The traditional electrochemical caustic soda recovery system uses the generated pH gradient across the ion exchange membrane for the regeneration of spent alkaline absorbent from CO2 capture. This electrochemical CO2 capture system releases the by-pr...

  • Article
  • Open Access
3 Citations
2,534 Views
13 Pages

Natural Clay Minerals as a Starting Material for Matrices for the Immobilization of Radioactive Waste from Pyrochemical Processing of SNF

  • Anna V. Matveenko,
  • Andrey P. Varlakov,
  • Alexander A. Zherebtsov,
  • Alexander V. Germanov,
  • Ivan V. Mikheev,
  • Stepan N. Kalmykov and
  • Vladimir G. Petrov

28 September 2021

Pyrochemistry is a promising technology that can provide benefits for the safe reprocessing of relatively fresh spent nuclear fuel with a short storage time (3–5 years). The radioactive waste emanating from this process is an electrolyte (LiCl–KCl) m...

  • Article
  • Open Access
1 Citations
1,240 Views
13 Pages

3 October 2024

Utilizing spent refractory material (SRM), generated after the overhaul of aluminum electrolytic cells, as a raw material for producing Al-Si alloys presents an efficient approach towards achieving full resource utilization of SRM. However, a bottlen...

  • Article
  • Open Access
3 Citations
2,949 Views
15 Pages

Towards Understanding the Cathode Process Mechanism and Kinetics in Molten LiF–AlF3 during the Treatment of Spent Pt/Al2O3 Catalysts

  • Andrey Yasinskiy,
  • Sai Krishna Padamata,
  • Srecko Stopic,
  • Dominic Feldhaus,
  • Dmitriy Varyukhin,
  • Bernd Friedrich and
  • Peter Polyakov

10 September 2021

Electrochemical decomposition of spent catalyst dissolved in molten salts is a promising approach for the extraction of precious metals from them. This article reports the results of the study of aluminum electrowinning from the xLiF–(1-x)AlF3 melt (...

  • Article
  • Open Access
34 Citations
5,972 Views
11 Pages

Accelerated H2 Evolution during Microbial Electrosynthesis with Sporomusa ovata

  • Pier-Luc Tremblay,
  • Neda Faraghiparapari and
  • Tian Zhang

8 February 2019

Microbial electrosynthesis (MES) is a process where bacteria acquire electrons from a cathode to convert CO2 into multicarbon compounds or methane. In MES with Sporomusa ovata as the microbial catalyst, cathode potential has often been used as a benc...

  • Feature Paper
  • Review
  • Open Access
1,074 Views
15 Pages

16 September 2025

Waste lithium-ion batteries (LIBs), which usually contain dangerous organic electrolytes and transition metals, including nickel, cobalt, iron, and manganese, can hurt the environment and human health. Substantial advancements have been achieved in e...

  • Article
  • Open Access
3 Citations
3,219 Views
13 Pages

Ethylene carbonate is, among other applications, used in Li-ion batteries as an electrolyte solvent to dissociate Li-salt. Supercritical CO2 extraction is a promising method for the recycling of electrolyte solvents from spent batteries. To design an...

  • Review
  • Open Access
64 Citations
25,626 Views
28 Pages

The consistency in capacity degradation in a multi-cell pack (>100 cells) is critical for ensuring long service life for propulsion applications. As the first step of optimizing a battery system design, academic publications regarding the capacity...

  • Article
  • Open Access
4 Citations
3,262 Views
10 Pages

This study assesses the status of hydration and the acid-base balance in female handball players in the Polish Second League before and after simulated matches in both indoor (hall) and beach (outdoor) conditions. The values of biochemical indicators...

  • Article
  • Open Access
14 Citations
14,628 Views
15 Pages

12 November 2021

The recovery of platinum group metals (PGMs) from waste materials involves dissolving the waste in an aqueous solution. However, since PGMs are precious metals, their dissolution requires strong oxidizing agents such as chlorine gas and aqua regia. I...

  • Article
  • Open Access
9 Citations
12,476 Views
16 Pages

Hypochlorite Generation from a Water Softener Spent Brine

  • Daniela Sánchez-Aldana,
  • Noe Ortega-Corral,
  • Beatriz A. Rocha-Gutiérrez,
  • Lourdes Ballinas-Casarrubias,
  • Eneidy J. Pérez-Domínguez,
  • Guadalupe Virginia Nevárez-Moorillon,
  • Luis A. Soto-Salcido,
  • Salvador Ortega-Hernández,
  • Guadalupe Cardenas-Félix and
  • Guillermo González-Sánchez

26 November 2018

Industries that require water with low hardness consume large amounts of NaCl for water softening. In this work, water softener spent brines were recovered and used as raw material in an electrolysis cell with cationic exchange membrane (CEM) to yiel...

  • Article
  • Open Access
8 Citations
3,090 Views
16 Pages

‘In-Situ’ Preparation of Carbonaceous Conductive Composite Materials Based on PEDOT and Biowaste for Flexible Pseudocapacitor Application

  • Francisco J. González,
  • Andreina Montesinos,
  • Javier Araujo-Morera,
  • Raquel Verdejo and
  • Mario Hoyos

Composite materials of poly(3,4-ethylenedioxythiophene) (PEDOT)/activated carbon (AC) were prepared by ‘in-situ’ polymerization and subsequently deposited by spray-coating onto a flexible electrolyte prepared in our laboratories. Two acti...

  • Article
  • Open Access
8 Citations
3,382 Views
13 Pages

High-Temperature Corrosion Behavior of Al-Coated Ni-Base Alloys in Lithium Molten Salt for Electroreduction

  • Wan-Bae Kim,
  • Woo-Seok Choi,
  • Kyu-Seok Lim,
  • Soo-Haeng Cho and
  • Jong-Hyeon Lee

13 March 2021

The electrolytic reduction of a spent oxide fuel involves the liberation of oxygen in a molten salt LiCl–Li2O electrolyte, which creates a corrosive environment for typical structural materials. In this study, the corrosion behaviors of Al–Y-coated s...

  • Article
  • Open Access
4 Citations
2,815 Views
13 Pages

Study of the Functionalities of a Biochar Electrode Combined with a Photoelectrochemical Cell

  • Spyridon Giannakopoulos,
  • John Vakros,
  • Ioannis D. Manariotis,
  • Dionissios Mantzavinos and
  • Panagiotis Lianos

21 December 2022

Biochar has been obtained by pyrolysis of spent malt rootlets under limited oxygen supply and further activated by mixing with KOH and pyrolyzed again at high temperature. The total specific surface area of such activated biochar was 1148 m2 g−...

  • Article
  • Open Access
17 Citations
3,938 Views
13 Pages

Biochar from Spent Malt Rootlets and Its Application to an Energy Conversion and Storage Device

  • John Vakros,
  • Ioannis D. Manariotis,
  • Vassilios Dracopoulos,
  • Dionissios Mantzavinos and
  • Panagiotis Lianos

Activated carbon obtained from biomass wastes was presently studied in order to evaluate its applicability in an energy storage device. Biochar was obtained by the carbonization of spent malt rootlets and was further processed by mild treatment in Na...

  • Review
  • Open Access
24 Citations
14,543 Views
20 Pages

Direct Recycling Technology for Spent Lithium-Ion Batteries: Limitations of Current Implementation

  • Anna Pražanová,
  • Zbyněk Plachý,
  • Jan Kočí,
  • Michael Fridrich and
  • Vaclav Knap

28 February 2024

The significant deployment of lithium-ion batteries (LIBs) within a wide application field covering small consumer electronics, light and heavy means of transport, such as e-bikes, e-scooters, and electric vehicles (EVs), or energy storage stationary...

  • Article
  • Open Access
28 Citations
7,840 Views
14 Pages

The Efficiency of Black Mass Preparation by Discharge and Alkaline Leaching for LIB Recycling

  • Tiaan Punt,
  • Steven M. Bradshaw,
  • Petrie van Wyk and
  • Guven Akdogan

14 June 2022

Lithium-ion batteries (LIBs) are dangerous to recycle, as they pose a fire hazard when cut and contain various chemical hazards. If recycled safely, LIBs provide a rich secondary source for metals such as lithium and cobalt, while reducing the enviro...

  • Article
  • Open Access
6 Citations
5,994 Views
11 Pages

Waste Zinc–Carbon Battery Recycling: Focus on Total Material Recovery

  • Anatoliy Ranskiy,
  • Olga Gordienko and
  • Vitalii Ishchenko

21 September 2024

Currently, less attention is paid to zinc–carbon batteries, although they are still widely used and are among the major types of batteries collected and recycled. The recycling technologies currently in use do not allow the complete recovery of...

  • Article
  • Open Access
42 Citations
5,557 Views
14 Pages

14 April 2019

Tantalum is a critical metal that is widely used in electronic products. The demand for tantalum is increasing, but the supply is limited. As tantalum waste products have increased in Taiwan in recent years, the treatment of spent tantalum capacitors...

  • Article
  • Open Access
13 Citations
5,111 Views
20 Pages

Recycled Cobalt from Spent Li-ion Batteries as a Superhydrophobic Coating for Corrosion Protection of Plain Carbon Steel

  • Ali Rafsanjani-Abbasi,
  • Ehsan Rahimi,
  • Hossein Shalchian,
  • Jalil Vahdati-Khaki,
  • Abolfazl Babakhani,
  • Saman Hosseinpour and
  • Ali Davoodi

27 December 2018

A new recycling and film formation scheme is developed for spent Li-ion batteries, which involves the combination of ascorbic-assisted sulfuric leaching and electrodeposition to fabricate a corrosion resistance superhydrophobic coating. The idea behi...

  • Article
  • Open Access
29 Citations
6,521 Views
17 Pages

15 April 2022

This work investigates the comprehensive recycling of graphite and cathode active materials (LiNi0.6Mn0.2Co0.2O2, abbreviated as NMC) from spent lithium-ion batteries via pretreatment and flotation. Specific analytical methods (SPME-GC-MS and Py-GC-M...

  • Article
  • Open Access
60 Citations
8,575 Views
16 Pages

24 July 2018

Recycling of Li-Ion Batteries (LIBs) is still a topic of scientific interest. Commonly, spent LIBs are pretreated by mechanical and/or thermal processing. Valuable elements are then recycled via pyrometallurgy and/or hydrometallurgy. Among the therma...

  • Feature Paper
  • Article
  • Open Access
6 Citations
2,985 Views
13 Pages

13 December 2022

In this paper, the results of an experimental study on hydrogen production at a tungsten discharge electrode with negative polarity in the DC electrolysis of a typical 10 wt% Na2CO3 aqueous solution in three operational regimes (the Faradaic, transit...

  • Review
  • Open Access
39 Citations
25,728 Views
25 Pages

27 October 2022

Lithium, a silver-white alkali metal, with significantly high energy density, has been exploited for making rechargeable lithium-ion batteries (LiBs). They have become one of the main energy storage solutions in modern electric cars (EVs). Cobalt, ni...

  • Article
  • Open Access
24 Citations
3,165 Views
9 Pages

22 November 2020

Spent Pot Lining First Cut (shortened to SPL-1cut) is a solid waste discharged from a primary aluminum electrolytic production process. SPL-1cut is classified as hazardous waste in China because it contains large amounts of soluble sodium fluoride an...

  • Article
  • Open Access
8 Citations
2,687 Views
15 Pages

14 May 2023

Molten LiCl-KCl salt and liquid cadmium are proposed as the electrolyte and the reactive cathode for the electrorefining of spent nuclear fuels, but they can be corrosive to the structural alloys. The down-selection of existing materials through corr...

  • Article
  • Open Access
8 Citations
3,066 Views
9 Pages

16 January 2022

Electronic products are ever growing in popularity, and tantalum capacitors are heavily used in small electronic products. Spent epoxy-coated solid electrolyte tantalum capacitors, containing about 22 wt.% of tantalum and 8 wt.% of manganese, were tr...

  • Feature Paper
  • Article
  • Open Access
5 Citations
2,954 Views
16 Pages

Self-Standing Hierarchical Porous Nickel-Iron Phosphide/Nickel Foam for Long-Term Overall Water Splitting

  • Qixian Han,
  • Hongmei Wu,
  • Feng Li,
  • Jing Liu,
  • Liping Zhao,
  • Peng Zhang and
  • Lian Gao

26 August 2023

Electrolytic water splitting is a promising path for the production of clean hydrogen when combined with green electric power, such as photovoltaic and wind power; however, the high current water electrolysis is mainly dependent on the utilization of...

  • Article
  • Open Access
1,870 Views
13 Pages

Cyclic Voltammetry of C.I. Disperse Orange 62 in an Aqueous Electrolyte

  • Thomas Bechtold,
  • Noemí Aguiló-Aguayo and
  • Tung Pham

27 October 2023

Disperse dyes are an important group of colorants for dyeing polyester fibers. Approximately 30.000 tons of disperse dyes are released into the waste water annually from spent dyebaths. Therefore, methods for decolorizing such dyes are of general int...

  • Article
  • Open Access
5 Citations
4,103 Views
20 Pages

Effect of the Heating Rate to Prevent the Generation of Iron Oxides during the Hydrothermal Synthesis of LiFePO4

  • Francisco Ruiz-Jorge,
  • Almudena Benítez,
  • M. Belén García-Jarana,
  • Jezabel Sánchez-Oneto,
  • Juan R. Portela and
  • Enrique J. Martínez de la Ossa

16 September 2021

Lithium-ion batteries (LIBs) have gained much interest in recent years because of the increasing energy demand and the relentless progression of climate change. About 30% of the manufacturing cost for LIBs is spent on cathode materials, and its level...

  • Article
  • Open Access
8 Citations
2,955 Views
20 Pages

Effect of N-Doped Carbon on the Morphology and Oxygen Reduction Reaction (ORR) Activity of a Xerogel-Derived Mn(II)O Electrocatalyst

  • Shaik Gouse Peera,
  • Ravindranadh Koutavarapu,
  • P. Siva Prasada Reddy,
  • Ganesh Koyyada,
  • Abdullah N. Alodhayb,
  • Saravanan Pandiaraj,
  • Seung Won Kim and
  • Mohan Rao Tamtam

6 November 2024

This work synthesizes a xerogel from a sol–gel synthesis strategy and supports it on N-doped carbon support from spent coffee biomass (Mn(II)O/N-CC, hereafter MnO) as an efficient oxygen reduction reaction (ORR) catalyst in alkaline electrolyte...

  • Article
  • Open Access
15 Citations
5,373 Views
12 Pages

Recovery of Rare Earth Elements from Spent NdFeB Magnets: Metal Extraction by Molten Salt Electrolysis (Third Part)

  • Hanwen Chung,
  • Laras Prasakti,
  • Srecko R. Stopic,
  • Dominic Feldhaus,
  • Vesna S. Cvetković and
  • Bernd Friedrich

10 March 2023

The results obtained from the work on a concept of a recycling process for NdFeB magnets to recover rare earth elements for remanufacturing similar magnets are presented. This paper investigates the viability of extracting rare earth metals from magn...

  • Article
  • Open Access
277 Views
16 Pages

24 December 2025

The Bayer process is used to extract alumina from bauxite, resulting in the formation of a highly alkaline solid residue known as bauxite residue (BR). However, such residue contains insufficient iron (<35% Fe) and complex impurity composition for...

of 2