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  • Article
  • Open Access
20 Citations
4,688 Views
9 Pages

Rhodamine B Removal of TiO2@SiO2 Core-Shell Nanocomposites Coated to Buildings

  • Dan Wang,
  • Zhi Geng,
  • Pengkun Hou,
  • Ping Yang,
  • Xin Cheng and
  • Shifeng Huang

31 January 2020

Surface application of photocatalyst in cement-based materials could endow it with photocatalytic properties, however, the weak adhesion between photocatalyst coatings and the substrates may result in poor durability in outdoor environments. In this...

(This article belongs to the Special Issue Cement-Based Composites: Advancements in Development and Characterization)
  • Article
  • Open Access
21 Citations
5,810 Views
25 Pages

Development and Upscaling of SiO2@TiO2 Core-Shell Nanoparticles for Methylene Blue Removal

  • Bárbara R. Gomes,
  • Joana L. Lopes,
  • Lorena Coelho,
  • Mattia Ligonzo,
  • Monica Rigoletto,
  • Giuliana Magnacca and
  • Francesca Deganello

8 August 2023

SiO2@TiO2 core-shell nanoparticles were successfully synthesized via a simple, reproducible, and low-cost method and tested for methylene blue adsorption and UV photodegradation, with a view to their application in wastewater treatment. The monodispe...

(This article belongs to the Section Environmental Nanoscience and Nanotechnology)
  • Article
  • Open Access
29 Citations
5,639 Views
17 Pages

30 April 2023

TiO2 and core–shell SiO2@TiO2 nanoparticles were synthesized by sol-gel process at different calcination temperatures. Mesoporous hollow TiO2 composites were prepared by etching SiO2 from SiO2@TiO2 nanoparticles with alkali solution. X-ray diff...

(This article belongs to the Special Issue New Developments of Protective Coatings, Organic Polymers, and Surface Analysis)
  • Article
  • Open Access
67 Citations
21,218 Views
14 Pages

Application of Turkevich Method for Gold Nanoparticles Synthesis to Fabrication of SiO2@Au and TiO2@Au Core-Shell Nanostructures

  • Paulina Dobrowolska,
  • Aleksandra Krajewska,
  • Magdalena Gajda-Rączka,
  • Bartosz Bartosewicz,
  • Piotr Nyga and
  • Bartłomiej J. Jankiewicz

26 May 2015

The Turkevich synthesis method of Au nanoparticles (AuNPs) was adopted for direct fabrication of SiO2@Au and TiO2@Au core-shell nanostructures. In this method, chloroauric acid was reduced with trisodium citrate in the presence of amine-functionalize...

(This article belongs to the Special Issue Plasmonic Materials)
  • Article
  • Open Access
29 Citations
4,714 Views
12 Pages

25 January 2021

Dielectric elastomer (DE) is one type of promising field-activated electroactive polymer. However, its significant electromechanical actuated properties are always obtained under a giant electric voltage, which greatly restricts the potential applica...

(This article belongs to the Section Polymer Composites and Nanocomposites)
  • Article
  • Open Access
6 Citations
4,222 Views
14 Pages

Core/Shell ZnO/TiO2, SiO2/TiO2, Al2O3/TiO2, and Al1.9Co0.1O3/TiO2 Nanoparticles for the Photodecomposition of Brilliant Blue E-4BA

  • Mahboubeh Dolatyari,
  • Mehdi Tahmasebi,
  • Sudabeh Dolatyari,
  • Ali Rostami,
  • Armin Zarghami,
  • Ashish Yadav and
  • Axel Klein

30 October 2024

The synthesis and characterization of ZnO/TiO2, SiO2/TiO2, Al2O3/TiO2, and Al1.9Co0.1O3/TiO2 core/shell nanoparticles (NPs) is reported. The NPs were used for photocatalytic degradation of brilliant blue E-4BA under UV and visible light irradiation,...

(This article belongs to the Special Issue New Advances into Nanostructured Oxides, 2nd Edition)
  • Article
  • Open Access
13 Citations
4,091 Views
17 Pages

4 February 2023

A nitrogen-doped TiO2@SiO2 core/shell nano-photocatalyst (N-TiO2@SiO2) was used as an additive in photocatalytic paint and applied for the photocatalytic degradation of gaseous acetaldehyde under light-emitting diode (LED) visible light irradiation....

(This article belongs to the Special Issue Novel Photo(electro)catalysts for Energy and Environmental Applications)
  • Feature Paper
  • Article
  • Open Access
38 Citations
6,204 Views
19 Pages

Rapid Microwave-Assisted Synthesis of Fe3O4/SiO2/TiO2 Core-2-Layer-Shell Nanocomposite for Photocatalytic Degradation of Ciprofloxacin

  • Ivana Gabelica,
  • Lidija Ćurković,
  • Vilko Mandić,
  • Ivana Panžić,
  • Davor Ljubas and
  • Krešo Zadro

22 September 2021

In this work, magnetic nanoparticles based on magnetite were successfully prepared via rapid microwave-assisted synthesis. In order to obtain the ternary core–shell Fe3O4/SiO2/TiO2 nanocomposite, first magnetite (Fe3O4) nanoparticles were coated with...

(This article belongs to the Special Issue Photocatalytic Activity of TiO2 and Its Applications)
  • Article
  • Open Access
73 Citations
8,759 Views
19 Pages

Design and Application of Magnetic Photocatalysts for Water Treatment. The Effect of Particle Charge on Surface Functionality

  • Anna Zielińska-Jurek,
  • Zuzanna Bielan,
  • Szymon Dudziak,
  • Izabela Wolak,
  • Zuzanna Sobczak,
  • Tomasz Klimczuk,
  • Grzegorz Nowaczyk and
  • Jan Hupka

27 November 2017

Core-interlayer-shell Fe3O4/SiO2/TiO2, CoFe2O4/SiO2/TiO2 and BaFe12O19/SiO2/TiO2 magnetic photocatalysts were obtained. A water-in-oil microemulsion system with suitable surfactants was used for functionalization of the magnetic core with silica inte...

(This article belongs to the Special Issue Magnetic Nanocatalysts)
  • Article
  • Open Access
17 Citations
11,881 Views
17 Pages

Efficient Method for the Concentration Determination of Fmoc Groups Incorporated in the Core-Shell Materials by Fmoc–Glycine

  • Elżbieta Szczepańska,
  • Beata Grobelna,
  • Jacek Ryl,
  • Amanda Kulpa,
  • Tadeusz Ossowski and
  • Paweł Niedziałkowski

1 September 2020

In this paper, we described the synthesis procedure of TiO2@SiO2 core-shell modified with 3-(aminopropyl)trimethoxysilane (APTMS). The chemical attachment of Fmoc–glycine (Fmoc–Gly–OH) at the surface of the core-shell structure was...

(This article belongs to the Section Electrochemistry)
  • Article
  • Open Access
11 Citations
2,161 Views
19 Pages

Tailored Magnetic Fe3O4-Based Core–Shell Nanoparticles Coated with TiO2 and SiO2 via Co-Precipitation: Structure–Property Correlation for Medical Imaging Applications

  • Elena Emanuela Herbei,
  • Daniela Laura Buruiana,
  • Alina Crina Muresan,
  • Viorica Ghisman,
  • Nicoleta Lucica Bogatu,
  • Vasile Basliu,
  • Claudiu-Ionut Vasile and
  • Lucian Barbu-Tudoran

Background/Objectives: Magnetic nanoparticles, particularly iron oxide-based materials, such as magnetite (Fe3O4), have gained significant attention as contrast agents in medical imaging This study aimsto syntheze and characterize Fe3O4-based core&nd...

(This article belongs to the Section Medical Imaging and Theranostics)
  • Article
  • Open Access
1 Citations
2,887 Views
14 Pages

Europium(III) Complex-Functionalized SiO2@mTiO2 Nanospheres for Al3+-Modulated Multicolor Emission

  • Chao Bai,
  • Shi He,
  • Huai-Ming Hu,
  • Hui Zeng,
  • Feng Zou and
  • Ji-Jiang Wang

28 October 2021

A europium(III) hybrid material Eu(tta)3bpdc-SiO2@mTiO2 (Htta = 2-thenoyltrifluoroacetone, H2bpdc = 2,2′-bipyridine-3,3′-dicarboxylic acid) was successfully designed and synthesized by the covalent grafting complex Eu(tta)3bpdc to SiO2@mTiO2 core–she...

  • Article
  • Open Access
7 Citations
2,959 Views
12 Pages

Rheological Behavior of Oil Well Cement Slurries with Addition of Core/Shell TiO2@SiO2 Nanoparticles—Effect of Superplasticizer and Temperature

  • Giovanni dos Santos Batista,
  • Francisca Puertas,
  • Antonio Shigueaki Takimi,
  • Eleani Maria da Costa and
  • Marta Palacios

8 January 2025

This study investigates the rheological behavior of oil well cement pastes (OWCPs) modified with core/shell TiO2@SiO2 (nTS) nanoparticles and polycarboxylate-ether (PCE) superplasticizers at different temperatures (25, 45, and 60 °C). Results sho...

(This article belongs to the Special Issue Effect of Additives/Admixtures on the Properties of Concretes and Cementitious Composites)
  • Article
  • Open Access
24 Citations
5,318 Views
11 Pages

TiO2-Coated Silicon Nanoparticle Core-Shell Structure for High-Capacity Lithium-Ion Battery Anode Materials

  • Jinbao Li,
  • Sha Fan,
  • Huijuan Xiu,
  • Haiwei Wu,
  • Shaoyan Huang,
  • Simin Wang,
  • Dingwen Yin,
  • Zili Deng and
  • Chuanyin Xiong

23 March 2023

Silicon-based anode materials are considered one of the highly promising anode materials due to their high theoretical energy density; however, problems such as volume effects and solid electrolyte interface film (SEI) instability limit the practical...

(This article belongs to the Special Issue Nanomaterials and Nanotechnology for Energy Conversion and Storage)
  • Article
  • Open Access
5 Citations
2,613 Views
18 Pages

Fabrication of Fe3O4 core-TiO2/mesoSiO2 and Fe3O4 core-mesoSiO2/TiO2 Double Shell Nanoparticles for Methylene Blue Adsorption: Kinetic, Isotherms and Thermodynamic Characterization

  • Ahmed Mohamed El-Toni,
  • Mohamed A. Habila,
  • Mohamed Sheikh,
  • Mohamed El-Mahrouky,
  • Abdulrhman S. Al-Awadi,
  • Joselito P. Labis and
  • Zeid A. ALOthman

12 September 2023

Herein, Fe3O4 core-TiO2/mesoSiO2 and Fe3O4 core-mesoSiO2/TiO2 double shell nanoparticles were prepared by first (R1) and second (R2) routes and applied for the removal of methylene blue. The reported adsorption capacities for R1-0.2, R1-0.4 and R2 sa...

(This article belongs to the Section Environmental Nanoscience and Nanotechnology)
  • Article
  • Open Access
1 Citations
2,936 Views
11 Pages

Metal-Supported TiO2/SiO2 Core-Shell Nanosphere Photocatalyst for Efficient Sunlight-Driven Methanol Degradation

  • M. R. Karimi Estahbanati,
  • Thuy-Dung Vu,
  • Trong-On Do,
  • Zahra Nayernia and
  • Maria C. Iliuta

The development of novel and active photocatalysts to industrialize photocatalysis technology is still a challenging task. In this work, a novel method is presented to prepare TiO2/SiO2 NSs by covering SiO2 nanospheres (NSs) with titanate-nanodiscs (...

  • Article
  • Open Access
12 Citations
3,247 Views
13 Pages

17 May 2022

The concept of localized surface plasmon resonance has been applied to increase the absorption efficiency of dye-sensitive solar cells (DSSCs) by using various photoanode structures. A three-dimensional model for a photoanode of the DSSC based on com...

(This article belongs to the Special Issue Liquid Metals, Alloys, Salts, Oxides, and Their Coexistence and Interaction with Solid Phases)
  • Review
  • Open Access
31 Citations
9,310 Views
31 Pages

9 July 2021

Uses of novel technologies for improving the durability and lifespan of the construction materials have emerged as viable solutions toward the sustainable future wherein the coating industry plays a significant role in economy growth and better livel...

(This article belongs to the Section Microscale Materials Science)
  • Article
  • Open Access
63 Citations
13,150 Views
13 Pages

Synthesis Characterization and Photocatalytic Studies of Cobalt Ferrite-Silica-Titania Nanocomposites

  • David Greene,
  • Raquel Serrano-Garcia,
  • Joseph Govan and
  • Yurii K. Gun'ko

23 April 2014

In this work, CoFe2O4@SiO2@TiO2 core-shell magnetic nanostructures have been prepared by coating of cobalt ferrite nanoparticles with the double SiO2/TiO2 layer using metallorganic precursors. The Transmission Electron Microscopy (TEM), Energy Disper...

(This article belongs to the Special Issue Magnetic Nanomaterials)
  • Article
  • Open Access
7 Citations
2,273 Views
24 Pages

“Core/Shell” Nanocomposites as Photocatalysts for the Degradation of the Water Pollutants Malachite Green and Rhodamine B

  • Joana Zaharieva,
  • Martin Tsvetkov,
  • Milena Georgieva,
  • Dimitar Tzankov and
  • Maria Milanova

“Core/shell” composites are based on a ferrite core coated by two layers with different properties, one of them is an isolator, SiO2, and the other is a semiconductor, TiO2. These composites are attracting interest because of their struct...

(This article belongs to the Section Materials Science)
  • Article
  • Open Access
6 Citations
3,488 Views
13 Pages

New Core-Shell Nanostructures for FRET Studies: Synthesis, Characterization, and Quantitative Analysis

  • Anna Synak,
  • Elżbieta Adamska,
  • Leszek Kułak,
  • Beata Grobelna,
  • Paweł Niedziałkowski and
  • Piotr Bojarski

This work describes the synthesis and characterization of new core-shell material designed for Förster resonance energy transfer (FRET) studies. Synthesis, structural and optical properties of core-shell nanostructures with a large number of two...

(This article belongs to the Topic Nanoarchitectonics with Molecular and Materials Science: Functional Materials for Energy, Environment, Bio and Others)
  • Article
  • Open Access
51 Citations
8,754 Views
15 Pages

8 September 2018

In this study, Ag@SiO2 nanoparticles were synthesized by a modified Stöber method for preparing the TiO2 mesoporous layer of carbon counter electrode-based perovskite solar cells (PSCs) without a hole transporting layer. Compared with normal PSC...

  • Article
  • Open Access
9 Citations
1,949 Views
14 Pages

Preparation of Fe3O4@SiO2@N-TiO2 and Its Application for Photocatalytic Degradation of Methyl Orange in Na2SO4 Solution

  • Li Sun,
  • Xingyu Ouyang,
  • Zilong Li,
  • Zhigang Yuan,
  • Wenbang Gong,
  • Zhen Chen,
  • Shunqi Mei,
  • Ying Liu and
  • Quan Zhou

14 June 2024

In this paper, Fe3O4@SiO2@TiO2 and N-doped Fe3O4@SiO2@N-TiO2 photocatalysts with magnetic core-shell structures were prepared using a multi-step synthesis method. The materials were analyzed using various techniques, such as X-ray diffraction (XRD),...

  • Feature Paper
  • Article
  • Open Access
9 Citations
5,874 Views
16 Pages

29 January 2019

The type of metal oxide affects the activity and selectivity of Fe2O3–SiO2–MeO2–Pt (Me = Ti, Sn, Ce) catalysts on the hydrogenation of cinnamaldehyde. The double shell structure design is thought to protect the magnetic Fe2O3 cores,...

(This article belongs to the Special Issue Heterogeneous Catalysts Synthesis and Characterization)
  • Feature Paper
  • Article
  • Open Access
14 Citations
4,546 Views
15 Pages

11 May 2020

This work proposes to use core-shell structured spheres to evaluate whether it allows to individually optimize bulk and surface effects of a packing material, in order to optimize conversion and energy efficiency. Different core-shell materials have...

(This article belongs to the Special Issue Plasma-Catalysis for Environmental and Energy-Related Applications)
  • Article
  • Open Access
5 Citations
6,679 Views
13 Pages

17 December 2016

A method to prepare novel organic-inorganic hydrophobic nanocomposite films was proposed by a site-specific polymerization process. The inorganic part, the core of the nanocomposite, is a ternary SiO2–Al2O3–TiO2 nanoparticles, which is grafted with m...

(This article belongs to the Special Issue Green Nanotechnology)
  • Feature Paper
  • Article
  • Open Access
32 Citations
5,022 Views
15 Pages

Synthesis of LiDAR-Detectable True Black Core/Shell Nanomaterial and Its Practical Use in LiDAR Applications

  • Suk Jekal,
  • Jiwon Kim,
  • Dong-Hyun Kim,
  • Jungchul Noh,
  • Min-Jeong Kim,
  • Ha-Yeong Kim,
  • Min-Sang Kim,
  • Won-Chun Oh and
  • Chang-Min Yoon

20 October 2022

Light detection and ranging (LiDAR) sensors utilize a near-infrared (NIR) laser with a wavelength of 905 nm. However, LiDAR sensors have weakness in detecting black or dark-tone materials with light-absorbing properties. In this study, SiO2/black TiO...

(This article belongs to the Special Issue Multifunctional Materials and Applications: Basic Nanomaterials, Catalysis, Composite, Electronic and Biomaterials)
  • Article
  • Open Access
21 Citations
3,216 Views
10 Pages

Effect of Ti Atoms on Néel Relaxation Mechanism at Magnetic Heating Performance of Iron Oxide Nanoparticles

  • Musa Mutlu Can,
  • Chasan Bairam,
  • Seda Aksoy,
  • Dürdane Serap Kuruca,
  • Satoru Kaneko,
  • Zerrin Aktaş and
  • Mustafa Oral Öncül

2 April 2022

The study was based on understanding the relationship between titanium (Ti) doping amount and magnetic heating performance of magnetite (Fe3O4). Superparamagnetic nanosized Ti-doped magnetite ((Fe1−x,Tix)3O4; x = 0.02, 0.03 and 0.05) particles...

(This article belongs to the Special Issue Functional Oxide Thin Films and Nanostructures: Growth, Properties, and Applications)
  • Article
  • Open Access
7 Citations
3,399 Views
13 Pages

Application of Biobased Substances in the Synthesis of Nanostructured Magnetic Core-Shell Materials

  • Marcos E. Peralta,
  • Alejandro Koffman-Frischknecht,
  • M. Sergio Moreno,
  • Daniel O. Mártire and
  • Luciano Carlos

We propose here a novel green synthesis route of core-shell magnetic nanomaterials based on the polyol method, which uses bio-based substances (BBS) derived from biowaste, as stabilizer and directing agent. First, we studied the effect of BBS concent...

(This article belongs to the Special Issue New Advances into Nanostructured Oxides)
  • Communication
  • Open Access
3 Citations
1,636 Views
9 Pages

18 December 2024

TiC provides a promising potential for high-temperature microwave absorbers due to its unique combination of thermal stability, high electrical conductivity, and robust structural integrity. C@TiC/SiO2 composites were successfully fabricated using a...

(This article belongs to the Special Issue Functional Polymer and Ceramic Nanocomposites)
  • Article
  • Open Access
571 Views
16 Pages

High-Temperature Energy Storage Performance of Polyimide Nanocomposites Enhanced by Core–Shell BT-BMT@SiO2

  • Zunpeng Feng,
  • Xingyu Hou,
  • Sitian Ren,
  • Xinyao Zhuang,
  • Wei Chen,
  • Haoran Liu,
  • Chaoqiong Zhu,
  • Ziming Cai and
  • Peizhong Feng

21 July 2026

Advanced electrical and electronic systems are placing increasingly stringent demands on high-temperature dielectric capacitors. Polyimide (PI) possesses excellent thermal stability, but its low dielectric constant and breakdown strength limit its en...

(This article belongs to the Section Polymer Composites and Nanocomposites)
  • Communication
  • Open Access
8 Citations
3,581 Views
12 Pages

Effect of Various Metal Oxide Insulating Layers on the Magnetic Properties of Fe-Si-Cr Systems

  • Zhenyi Huang,
  • Huaqin Huang,
  • Hao He,
  • Zhaoyang Wu,
  • Xuesong Wang and
  • Rui Wang

20 April 2023

Iron-based soft magnetic composites (SMCs) are the key components of high-frequency electromagnetic systems. Selecting a suitable insulating oxide layer and ensuring the integrity and homogeneity of the heterogeneous core–shell structure of SMC...

(This article belongs to the Section Ceramic Coatings and Engineering Technology)
  • Article
  • Open Access
17 Citations
5,149 Views
2 Pages

Τhe photocatalytic activity in the range of visible light wavelengths and the thermal stability of the structure were significantly enhanced in Si, N co-doped nano-sized TiO2, and synthesized through high-energy mechanical milling of TiO2 and SiO...

  • Review
  • Open Access
24 Citations
11,181 Views
32 Pages

10 March 2018

Functional core-shell-structured particles have attracted considerable attention recently. This paper reviews the synthetic methods and morphologies of various electro-stimuli responsive polyaniline (PANI)-coated core-shell-type microspheres, includi...

(This article belongs to the Special Issue Stimuli Responsive Polymers)
  • Article
  • Open Access
18 Citations
4,567 Views
15 Pages

19 July 2023

The development of pulse power systems and electric power transmission systems urgently require the innovation of dielectric materials possessing high-temperature durability, high energy storage density, and efficient charge–discharge performan...

(This article belongs to the Special Issue Electric Properties, Characterization, and Simulation of Polymer Composites)
  • Article
  • Open Access
6 Citations
1,919 Views
19 Pages

Preparation of Magnetic Photocatalyst Fe3O4@SiO2@Fe-TiO2 and Photocatalytic Degradation Performance of Methyl Orange in Na2SO4 Solution

  • Li Sun,
  • Zilong Li,
  • Zhigang Yuan,
  • Ying Liu,
  • Shunqi Mei,
  • Fanhe Meng,
  • Xingyu Ouyang,
  • Yi Xiong,
  • Ke Zhang and
  • Zhen Chen

30 March 2025

In this study, Fe3O4@SiO2@TiO2 (FS-FT (0 g)) photocatalysts, featuring a magnetic core–shell structure, and Fe-doped Fe3O4@SiO2@Fe-TiO2 (FS-FT (x g)) photocatalysts, were fabricated via the sol–gel method. Structural and compositional ana...

  • Article
  • Open Access
4 Citations
6,914 Views
12 Pages

Rapid Synthesis and Formation Mechanism of Core-Shell-Structured La-Doped SrTiO3 with a Nb-Doped Shell

  • Nam-Hee Park,
  • Takafumi Akamatsu,
  • Toshio Itoh,
  • Noriya Izu and
  • Woosuck Shin

2 July 2015

To provide a convenient and practical synthesis process for metal ion doping on the surface of nanoparticles in an assembled nanostructure, core-shell-structured La-doped SrTiO3 nanocubes with a Nb-doped surface layer were synthesized via a rapid syn...

(This article belongs to the Special Issue Low-Dimensional Anisotropic Thermoelectrics)
  • Feature Paper
  • Article
  • Open Access
7 Citations
3,326 Views
16 Pages

29 September 2019

We analyze the microscopic mechanism of the improvement of solar cell efficiency by plasmons in metallic components embedded in active optical medium of a cell. We focus on the explanation of the observed new channel of plasmon photovoltaic effect re...

(This article belongs to the Section Energy Materials)
  • Article
  • Open Access
6 Citations
3,618 Views
16 Pages

2 March 2023

The application domain of deep learning (DL) has been extended into the realm of nanomaterials, photochemistry, and optoelectronics research. Here, we used the combination of a computer vision technique, namely convolutional neural network (CNN), wit...

  • Article
  • Open Access
11 Citations
3,069 Views
11 Pages

30 September 2021

Dielectric nanocomposites with high energy storage density (Ue) have a strong attraction to high-pulse film energy-storage capacitors. Nevertheless, low breakdown strengths (Eb) and electric displacement difference (Dmax-Drem) values of nanocomposite...

(This article belongs to the Section Polymeric Membranes)
  • Article
  • Open Access
5 Citations
2,618 Views
12 Pages

Optimising Hollow-Structured Silicon Nanoparticles for Lithium-Ion Batteries

  • Chenghao Yue,
  • Yao Liu,
  • Shaoliang Guan,
  • Alireza Fereydooni,
  • Yuexi Zeng,
  • Zhijie Wei,
  • Yonggang Wang and
  • Yimin Chao

28 August 2023

Silicon has been proven to be one of the most promising anode materials for the next generation of lithium-ion batteries for application in batteries, the Si anode should have high capacity and must be industrially scalable. In this study, we designe...

(This article belongs to the Section Advanced Nanomaterials and Nanotechnology)