Clean Technologies

Diclofenac (DCF), a widely consumed non-steroidal anti-inflammatory drug, presents significant environmental challenges due to its persistence and toxicity in aquatic ecosystems. This study investigates the pH-dependent ozonation of DCF in aqueous media, focusing on degradation kinetics, transformation pathways, and effects on key water quality indicators. Ozonation experiments were conducted across a broad pH range (2.0–13.0), using a multi-scale analytical approach combining UV/Vis spectroscopy, colorimetry, turbidity, and aromaticity measurements. The results show that pH strongly influences DCF degradation efficiency: acidic conditions favor selective reactions with molecular ozone, while an alkaline pH enhances non-selective oxidation via hydroxyl radicals. Spectroscopic analyses revealed the progressive breakdown of aromatic structures, the transient formation of quinonoid and phenolic intermediates, and eventual mineralization to inorganic by-products such as nitrate. Low-pH conditions also induced turbidity due to precipitation of neutral DCF species. These findings underline the importance of pH control in optimizing ozonation performance and minimizing toxic by-products. Furthermore, this study proposes ozonation as a viable pre-treatment step within Nature-Based Solutions (NBSs), potentially improving the performance of downstream biological systems such as constructed wetlands. The results contribute to the development of integrated and sustainable water treatment strategies for pharmaceutical contaminant removal and water reuse. Full article

Lack of green spaces, citizen insecurity, and crime are the primary issues afflicting the Pueblo Libre district. This research aims to propose public spaces that revalue the cultural and historical landscape of Pueblo Libre. The methodology involves a literature review, urban analysis, and climate analysis, incorporating sustainability strategies supported by digital tools (AutoCAD, Revit, and Sketch-Up). The resulting design features an ecological park with vegetation capable of capturing carbon and emitting oxygen, absorbing up to 3544.99 kg of CO₂ annually. It also includes installing 26 solar-powered lights to illuminate necessary spaces efficiently and using eco-friendly materials. Additionally, the park incorporates an artificial wetland with a capacity to process 38,500 L of water using plants that remove toxic elements and capture nutrients. In conclusion, the ecological park seeks to revalue the cultural landscape and counteract environmental degradation by creating a green lung that purifies the air, fosters social connectivity, and integrates users with nature, enhancing their quality of life. Full article

The increasing demand for industrial enzymes calls for cost-effective and sustainable production strategies. This study investigates the potential of industrial wastewater as an alternative fermentation medium for enzyme synthesis, aligning with the principles of the circular bioeconomy. Four wastewater types from Québec, Canada—beverage wastewater (BW), pulp and paper mill activated sludge (PPMS), food industry wastewater (FIW), and starch industry wastewater (SIW)—were evaluated for their potential to support protease, amylase, and lipase production using Bacillus licheniformis, Bacillus amyloliquefaciens, and Bacillus megaterium. Initial screening identified SIW as optimal for amylase production with B. amyloliquefaciens, and PPMS for protease production with B. megaterium. Optimization using the Box–Behnken design was then performed, followed by scale-up experiments in 5 L bioreactors. B. amyloliquefaciens achieved 5.73 ± 0.01 U/mL of amylase at 48 h under 40 g/L total solids, 30 °C, and a 2% inoculum size, while B. megaterium produced the highest protease of 55.41 ± 3.54 U/mL at 24 h. Lipase production remained negligible across all media and strains. These findings demonstrate the feasibility of the potential of wastewater-based enzyme production, reducing reliance on expensive synthetic substrates, mitigating environmental burdens, and contributing to the transition to a circular bioeconomy. Full article

Carbon mineralization has attracted great interest as a promising strategy to achieve a decarbonized pathway by 2050. Despite the significant environmental and economic promise associated with using industrial solid waste for carbon mineralization, the scale-up application of this approach is limited due to its low reactivity and relatively high cost. A clear understanding of the detailed mechanisms governing various carbonation techniques is needed to achieve high CO₂ conversion efficiency. This review can provide valuable insight into carbon mineralization pathways, advantages and challenges, and potential feedstocks. Factors affecting reaction kinetics, and thereby carbonation efficiency, are also discussed. Then, we focus on the research progress of the most representative industrial solid wastes for CO₂ mineralization, process conditions, and their carbonation potential. Lastly, a market analysis of the precipitated carbonate products is provided to assess economic feasibility for practical applications. Full article

Cork processing generates significant by-products that pose environmental challenges and waste management concerns. This study investigates the potential of utilizing cork residues—finishing powders, grinding powders, and sawdust—for biomass pellet production, emphasizing compliance with ENplus^® A1, A2, and B standards. Physical, chemical, and calorimetric analyses reveal that sawdust is the only material capable of independently meeting ENplus^® requirements, due to its low nitrogen (0.19%) and ash (0.22%) contents. However, its low net heating value necessitates blending with cork residues for improved energy performance. Finishing powders, despite a high net heating value (17.36 MJ/kg) and low ash content (0.37%), are restricted by their elevated nitrogen levels (1.59%). Grinding powders, with net heating values ranging from 16.25 to 17.78 MJ/kg, offer limited suitability due to high ash and nitrogen contents. For Class A1, mixtures require 85–87% sawdust, limiting cork residue incorporation to 15%. For Class A2, sawdust inclusion drops to 65–70%, allowing for greater use of cork residues and boosting net heating values to 16.74 MJ/kg. Class B mixtures achieve the highest incorporation of cork residues (up to 65%), with net heating values reaching 16.92 MJ/kg, suitable for industrial applications. These results highlight blending strategies as essential for balancing regulatory compliance, energy efficiency, and waste valorization. Future research should focus on pretreatment methods, alternative biomass sources, and lifecycle assessments to enhance compliance and scalability, promoting sustainable energy solutions and circular economy goals. Full article

This study utilizes a zero-dimensional, constant-pressure, perfectly stirred reactor (PSR) model within the Cantera framework to examine the combustion characteristics of hydrogen, methane, methanol, and propane, both singly and in hydrogen-enriched mixtures. The impact of the equivalence ratio (ϕ = 0.75, 1.0, 1.5), fuel composition, and residence duration on temperature increase, heat release, ignition delay, and emissions (NO_x and CO₂) is methodically assessed. The simulations are performed under steady-state settings to emulate the ignition and flame propagation processes within pre-chambers and primary combustion zones of internal combustion engines. The results demonstrate that hydrogen significantly improves combustion reactivity, decreasing ignition delay and increasing peak flame temperature, especially at short residence times. The incorporation of hydrogen into hydrocarbon fuels, such as methane and methanol, enhances ignition speed, improves thermal efficiency, and stabilizes lean combustion. Nevertheless, elevated hydrogen concentrations result in increased NO_x emissions, particularly at stoichiometric equivalence ratios, due to higher flame temperatures. The examination of fuel mixtures at varying hydrogen concentrations (10–50% by mole) indicates that thermal performance is optimal under stoichiometric settings and diminishes in both fuel-lean and fuel-rich environments. A thermodynamic model was created utilizing classical combustion theory to validate the heat release estimates based on Cantera. The model computes the heat release per unit volume (MJ/m³) by utilizing stoichiometric oxygen demand, nitrogen dilution, fuel mole fraction, and higher heating values (HHVs). The thermodynamic estimates—3.61 MJ/m³ for H₂–CH₃OH, 3.43 MJ/m³ for H₂–CH₄, and 3.35 MJ/m³ for H₂–C₃H₈—exhibit strong concordance with the Cantera results (2.82–3.02 MJ), thereby validating the physical consistency of the numerical methodology. This comparison substantiates the Cantera model for the precise simulation of hydrogen-blended combustion, endorsing its use in the design and development of advanced low-emission engines. Full article

Mining activities have a significant impact on the quality of river water in the Roșia Montană area. This region, known for its gold and other precious metal mining, serves as an example of the interaction between anthropogenic activities and the natural environment. Water from mine drainage is metal-rich and contaminates the environment, inhibiting the growth and reproduction of aquatic plants and animals, while also having corrosive effects on infrastructure. As part of the study, parameters such as pH, dissolved oxygen, biochemical oxygen demand, chemical oxygen demand, sulfates, and heavy metals were monitored for the rivers in the area (Roșia Montană, Săliște, Corna, Abrud, and Arieș). Roșia Montană river shows a decrease in pH to highly acidic values (2.69–3.95), especially in the downstream sections. Sulfate concentrations exceed 3600 mg/L, and heavy metal concentrations (Fe, Zn, As, Mn) increase significantly, indicating severe pollution, primarily originating from the Gura Mine gallery. These frequently exceed the thresholds corresponding to water quality classes I and II, and in some cases even surpass the limits of class V (the most polluted). The presence of As (27.60 µg/L) in Roșia Montană River indicates a significant ecotoxicological risk. In an attempt to treat the acid mine drainage from Roșia Montană, a natural zeolite was used at different doses. The results obtained show good efficiency of zeolite in removing the metal ions (Fe, Zn, and Mn). The results provide valuable information on the quality of river waters in the mining area of Roșia Montană and suggest that zeolite can be used effectively to decontaminate mine waters. Full article

Elevated fluoride levels in drinking water pose a significant health risk for communities relying on groundwater in the Ethiopian Central Rift Valley. This study aims at characterizing real groundwater samples from the Ethiopian Central Rift Valley and evaluating the performance of an integrated membrane process based on reverse osmosis (RO) and membrane crystallization (MCr) for fluoride removal and its recovery as mixed fluoride salts. Groundwater analysis revealed fluoride concentrations of 20.8 mgL⁻¹ at the Meki-01 site and 22.7 mgL⁻¹ at the Meki-02 site, both exceeding the WHO guideline of 1.5 mgL⁻¹. In addition, total dissolved solids exceeded 1000 mgL⁻¹ at both sites, classifying the water as brackish. A commercial RO membrane demonstrated excellent fluoride and ion rejection, with fluoride removal rates exceeding 99%. The total dissolved solids (TDS) removal efficiency reached 89%. The mean water permeability of the membrane was 4.52 Lm⁻²h⁻¹bar⁻¹. The retentate produced in the RO unit reached a concentration of 70 mgL⁻¹, which was then treated using osmotic membrane distillation–crystallization (OMD-Cr) and/or vacuum membrane crystallization (VM-Cr). This process facilitated the recovery of mixed salts while achieving an almost zero-liquid discharge. The study confirms the successful removal of fluoride and its recovery as mixed salt, along with the recovery of water in an environmentally friendly and manageable way. Full article

Chlorine gas and hydrogen chloride are highly reactive chemicals that pose a significant hazard to living organisms upon direct contact. Also, chlorine-containing gases are often by-products of industrial chemical synthesis and can be released into the air as a result of accidents. This can lead to great pollution of the environment. To remove toxic gases, various filter systems can be used. Filters based on carbon nanomaterials can be suitable for capturing gaseous chlorine-containing substances, preventing their spread into the air. In this work, the sorption activity of various carbon-based nanomaterials (graphene oxide, modified graphene oxide, reduced graphene oxide, multi-walled carbon nanotubes, carbon black) in relation to gaseous chlorine and hydrogen chloride was investigated for the first time. It has been shown that employed carbon nanomaterials have an excellent ability to remove chlorine and hydrogen chloride from the air, exceeding the performance of activated carbon. Modified graphene oxide with an increased surface area showed the highest sorption capacity of 73.1 mL HCl and 200.0 mL Cl₂ per gram of the sorbent, that is almost two and five times, respectively, higher than that of activated carbon. The results show that carbon nanomaterials could potentially be used for industrial filters and membrane fabrication. Full article

The volume or mass throughput of a mechanical treatment plant for commercial waste represents a key performance parameter. This measurement parameter is often unavailable, as the sensor technology required is often expensive or does not provide accurate data. The first process stage is usually a shredding machine, converting the waste into a transportable and separable fraction size. Here, a methodical approach is pursued which enables an indirect estimation of the volume throughput capacity based on further machine parameters, such as the drum speed and the drum torque. Based on 32 test data sets, two models were developed to approximate the volume throughput rate. The two models developed are the regression model and the displacement model. Furthermore, two reference models were defined to evaluate the accuracy of the two approaches developed: the so-called mean value model and the ANOVA model. When looking at the 80th percentile of the sign-adjusted relative deviation, the results show that the regression model, with ±40%, followed by the displacement model, with ±42%, enable significantly more accurate estimates of the volumetric throughput performance than the two reference models, with ±63% and ±71%, respectively. Full article

Ultrasound-assisted extraction (UAE) using water as a green solvent is a promising non-thermal technique for the extraction of total dietary fiber (TDF) and betaine from red beetroot (Beta vulgaris L.) peel. Compared to conventional thermal extraction (CE), UAE has proven to be a more efficient alternative method for the extraction of TDF and betaine. The pretreatment of beet was carried out using pulsed electric field (PEF) technology, with the specific energy of the PEF treatment set at 1.6 kJ/kg. To achieve the maximum betaine concentration of 24.80 µg/mL, the optimum UAE parameters were 50% amplitude with an extraction time of 3 min using distilled water as extraction solvent. The optimum TDF yield of 44.07% was achieved at 75% amplitude, 6 min treatment time and 50% ethanol solution as extraction solvent. These conditions can effectively supplement UAE, especially in the extraction of bioactive compounds from red beetroot peel. However, the TDF obtained in the residue must be evaporated for further use, which increases energy consumption. Ethanol concentration had no statistically significant effect (p > 0.05) on the TDF results, suggesting that distilled water could replace ethanol as a solvent in UAE. This substitution offers environmental and economic advantages, as water is more environmentally friendly and less expensive than ethanol. In addition, the use of distilled water eliminates the need to evaporate ethanol, which is particularly advantageous when the extracted material is intended for fortification or improvement of the technological and functional properties of food products. Full article

Transitioning to clean energy in off-grid remote locations is essential to reducing fossil-fuel-generated greenhouse gas emissions and supporting renewable energy growth. While hybrid renewable energy systems (HRES), including multiple renewable energy (RE) sources and energy storage systems are instrumental, it requires technical reliability with economic efficiency. This study examines the feasibility of an HRES incorporating solar, wind, hydrogen, and biofuel energy at a remote location in Australia. An electric vehicle charging load alongside a residential load is considered to lower transportation-based emissions. Additionally, the input data (load profile and solar data) is validated through statistical analysis, ensuring data reliability. HOMER Pro software is used to assess the techno-economic and environmental performance of the hybrid systems. Results indicate that the optimal HRES comprising of photovoltaic, wind turbines, fuel cell, battery, and biodiesel generators provides a net present cost of AUD 9.46 million and a cost of energy of AUD 0.183, outperforming diesel generator-inclusive systems. Hydrogen energy-based FC offered the major backup supply, indicating the potential role of hydrogen energy in maintaining reliability in off-grid hybrid systems. Sensitivity analysis observes the effect of variations in biodiesel price and electric load on the system performance. Environmentally, the proposed system is highly beneficial, offering zero carbon dioxide and sulfur dioxide emissions, contributing to the global net-zero target. The implications of this research highlight the necessity of a regional clean energy policy facilitating energy planning and implementation, skill development to nurture technology-intensive energy projects, and active community engagement for a smooth energy transition. Potentially, the research outcome advances the understanding of HRES feasibility for remote locations and offers a practical roadmap for sustainable energy solutions. Full article

The occurrence of heavy metals in aquatic ecosystems is a serious environmental hazard, and their effective removal is imperative. In this regard, the feasibility of living microalga Chlorella vulgaris (C. vulgaris) to remove heavy metals (Ni, Pb, Zn, Cd, and Cu) is investigated by using 1, 5, and 10 ppm concentrations of single- and multiple-metal-treated (MT) cultures. Experiments were performed in controlled laboratory conditions, and metal removal analysis was performed through atomic absorption spectroscopy (AAS). The cultures were also examined by means of optical microscopy, UV-Vis spectrophotometry, and Fourier transform infrared (FTIR) spectroscopy to follow the cultures’ pigment content, cell population, and functional group changes during cultivation. The removal efficiency results of both single and multiple MT cultures were evaluated using the Langmuir isotherm model. The results indicate that C. vulgaris presents potential for heavy metal bioremediation, even towards multi-MT conditions, despite the influence of a competitive uptake in multi-MT cultures. In mono-MT cultures, the removal efficiency of C. vulgaris presents values of 65–99% on Day 3 and 72–99% on Day 7 of cultivation, while the results for the multi-MT cultures are 49–99% and 62–99% for Days 3 and 7 of cultivation, respectively. The research illustrates the potential for C. vulgaris as a promising biosorbent for heavy metal remediation along with its post-treatment use in applications supporting the green circular economy. Full article

Adsorption represents an effective strategy for water remediation applications, particularly when utilising eco-friendly materials in a circular economy framework. This approach offers significant advantages, including low cost, material availability, ease of operation, and high efficiency. Herein, the performance of cadmium ion adsorption onto hydroxyapatites, derived through a calcination-free process from shells of two mollusc species, Queen Scallop (Aequipecten opercularis) and Pacific Oyster (Magallana gigas), is examined. The phase and morphology of the synthesised adsorbents were investigated. The results showed that hydroxyapatites obtained from mollusc shells are characterised by high efficiency regarding cadmium removal from water, exhibiting rapid kinetics with equilibrium achieved within 5 min and high adsorption capacities up to 334.9 mg g⁻¹, much higher than many waste-based adsorbents reported in literature. Structural investigation revealed the presence of Cadmium Hydrogen Phosphate Hydrate in the hydroxyapatite derived from oyster shells loaded with Cd, indicating the formation of a solid solution. This finding suggests that the material not only has the capability to decontaminate but also to immobilise and store Cd. Overall, the results indicate that hydroxyapatites prepared via a synthetic route in mild conditions from waste shells are an economical and efficient sorbent for heavy metals encountered in wastewater. Full article

This study investigates the size effect on the Seebeck coefficient (SC) in cement composites incorporating silicon carbide (SiC). Two specimen shapes, cubic (50 × 50 × 50 mm³) and beam (40 × 40 × 160 mm³), were analyzed with varying SiC substitution ratios (0%, 50%, and 100%) for fine aggregates. Thermal and electrical conductivities were measured to assess their influence on the SC. The results showed that a higher SiC content increased porosity, which reduced mechanical strength but significantly improved thermal and electrical conductivities. Thermal conductivity increased from 1.88 W/mK (0% substitution) to 11.89 W/mK (100% substitution), while electrical conductivity showed an improvement from 0.0056 S/m to 0.065 S/m. Cubic specimens exhibited higher SC values compared to beam specimens, with a maximum SC of 1374 μV/K at 100% SiC substitution, attributed to shorter thermal diffusion distances. The findings suggest that optimizing member size and SiC content can significantly improve the thermoelectric performance of cement composites, potentially enhancing energy efficiency in construction applications. Full article

The expansion of fisheries and aquaculture in recent decades has led to a substantial increase in fish by-products. This study investigates the extraction and characterization of calcium phosphates from the by-products of representative species in these industries, aiming to identify potential sources for biotechnological and pharmaceutical applications. Clean bones obtained by enzyme hydrolysis from the heads, central skeletons, and/or tails of Atlantic horse mackerel, blue whiting, hake, mackerel, and farmed turbot were subjected to calcination to obtain calcium phosphates. The clean bone content in terms of nitrogen, lipids, organic matter, total protein, and amino acids was evaluated together with the chemical bonds, structures, and elemental composition of calcium phosphates. Results indicated a significantly higher yield of wet bone recovery (23%, p < 0.05) for the central skeleton of Atlantic horse mackerel and the highest mineral fraction for the heads of Atlantic horse mackerel (73.2%), followed by that of blue whiting (72.6%). Hake and turbot presented the lowest mineral fractions and, therefore, the highest protein content (27–31%, p < 0.05), with significant levels of collagen-related amino acids (p < 0.05). X-ray diffraction (XRD) and Fourier-transform Raman spectroscopy (FT-Raman) confirmed the biphasic calcium phosphate composition for most samples based on hydroxyapatite with contributions of whitlockite/β-tricalcium phosphate. The highest contribution to the non-apatite phase was made by the central skeletons of both mackerel and Atlantic horse mackerel. Full article

This study investigates the drying behavior and rheological properties of dehydrated sewage sludge from various wastewater treatment plants in the Liege region (Belgium). Emphasizing the characterization of key parameters to enhance sludge management strategies, a series of experiments were conducted, including total solid content (TSC) determination, volatile solid content (VSC) analysis, texture profile analysis (TPA), penetrometry, and oscillatory rheology tests. Results showed no significant trends between specific evaporation capacity and the analyzed variables, cohesiveness, TSC, VSC, hardness, yield, and flow point. However, a clear trend indicated that higher G′ values are associated with improved drying rates. This aligns with the existing literature, suggesting that the viscoelastic properties of sludge, represented by G′, could potentially predict drying performance. A strong correlation between G′ and cohesiveness was also observed, recommending the use of G′ as the primary parameter due to the standardization and reliability of rheological tests. Despite the limited sample size, the study provides a valuable starting point for future research. Further investigations with larger sample sizes and controlled laboratory conditions are recommended to validate these findings and establish ranges within which the studied properties can be useful for future calculations and analyses. These efforts will contribute to optimizing sludge drying processes and promoting sustainable wastewater treatment practices. Full article

The ammonia adsorption capacity of lignin-rich biomass solids was tested for the first time at low partial pressures (<1.5 kPa) and 20 °C. The biomass samples included untreated tree barks, husks, and peats, as well as the biochars produced by their slow pyrolysis. Proximate and ultimate analyses, lignin content, and metal content are also presented. The untreated biosolids had higher VM/FC ratios, molar H/C, and O/C than the treated biosolids (biochars and treated biochars). A novel methodology is described for the safe generation of gaseous ammonia at predictable low partial pressures from tabletop-scale batch reaction experiments of NaOH with (NH₄)₂SO₄ in aqueous solution, leading to the determination of ammonia adsorption capacities from low-cost experiments. Statistically significantly larger NH₃ adsorption capacities were obtained for the untreated biosolids than for their biochars (p < 0.001). In contrast, the biochars were found to be poor NH₃ adsorbers without further treatment. The NH₃ adsorption capacities from this study’s biosolids were compared with those of common adsorbent types in the same conditions using the existing literature through equilibrium model interpolation (Dubinin–Astakhov, Toth, and Freundlich) or cubic spline fit from graphical isotherms. Controls consisting of commercially sourced activated carbons (AC) had low adsorption capacities, close to those derived from the literature in the same conditions for similar materials, confirming the methodology’s robustness. The untreated biosolids’ NH₃ adsorption capacities were in the same range as those reported for silica, gamma-alumina, and some of the treated or doped ACs. They also performed better than the undoped, untreated ACs. The work suggests lignin-rich untreated biosolids such as barks and peats are competent low-cost ammonia adsorbents. Full article

Chert gravel, a byproduct of sand quarrying, remains an underutilized material in construction due to its low microwave (MW) absorption and high mechanical strength. The present study deals with the potential of MW irradiation as a novel, energy-efficient method for processing chert gravel into high-quality aggregates, reducing reliance on virgin materials. The research systematically examines MW exposure duration (1–2.5 min), rock size (150–800 g), moisture conditions, and cooling methods (air vs. water quenching) to optimize fragmentation. Experimental results indicate that larger rock sizes (600–800 g) yield coarser, less uniform aggregates, while prolonged MW exposure (>2 min) induces extensive micro-fracturing, producing finer, well-graded particles. Water quenching significantly intensifies fragmentation, generating irregular but highly fragmented aggregates, whereas pre-wetted samples exhibit finer and more uniform breakage than dry samples. The findings introduce a novel approach for optimizing chert gravel fragmentation, a material previously considered unsuitable for MW treatment. The study proposed a customizable methodology for tailoring aggregate properties through precise control of MW parameters, offering a sustainable alternative to conventional crushing. The results contribute to resource conservation, reduced energy consumption, and climate change mitigation, paving the way for more sustainable construction practices. Full article