114 Results Found

The paper presents the study of the corrosion resistance of electrodeposited Pd and its binary alloys with Pt, Rh, and Ru on a polycrystalline Au substrate. The corrosion resistance was tested in 0.5 M sulfuric acid at room temperature using potentio...

In polymer electrolyte membrane fuel cells (PEMFCs) for fuel cell electric vehicles, cell reversal (CR) at the anode side can occasionally occur—usually when hydrogen supply is interrupted—which results in degradation of the anode. To mit...

For direct formic acid fuel cells (DFAFC), palladium (Pd)-based alloy catalysts with competitive morphology and elemental composition are essential to boost the performance of the formic acid oxidation reaction (FAOR) in the anode zone. Herein, we de...

The structural and electrical properties of PtRu bimetallic alloy (BA) thin films prepared via atomic layer deposition (ALD) were systemically investigated according to the film composition, which was controlled at a deposition temperature of 340 &de...

The phase equilibria of the Ni–Al–Cr–Ru quaternary system were systematically investigated using the equilibrated alloy method combined with scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), and X-ray diffrac...

CoCrWReAl-xRu-TiC eutectic alloys (x = 0, 1, 2.5, and 5 wt.%) were fabricated in a tungsten arc furnace under a protective argon atmosphere using pure metals and amorphous graphite. We examined the phase composition and microstructure of the samples...

For large-scale and sustainable water electrolysis, it is of great significance to develop cheap and efficient electrocatalysts that can replace platinum. Currently, it is difficult for most catalysts to combine high activity and stability. To solve...

In order to provide further insights into the origin of Ru-Os-Ir alloys, this study presents new highly siderophile element (HSE: Re, Os, Ir, Ru, Pt, and Pd) abundance and ¹⁸⁷Re-¹⁸⁷Os and ¹⁹⁰Pt-¹⁸⁶Os isotope data for detrital grains of native Ru-Os-I...

Hydrogenation of levulinic acid (LA) represents a significant approach for producing the high-value biomass-based platform compound γ-valerolactone (GVL). In this study, an efficient RuIr alloy bimetallic catalyst supported on SiC was synthesiz...

Developing bi-functional electrocatalysts for both oxygen reduction reaction (ORR) and hydrogen evolution reaction (HER) is crucial for enhancing the energy transfer efficiency of metal–air batteries and fuel cells, as well as producing hydroge...

Ru is a key component of electrocatalysts for hydrogen evolution reaction (HER), especially in alkaline media. However, the catalytic activity and durability of Ru-based HER electrocatalysts are still far from satisfactory. Here we report a solvother...

With the development and wide application of nickel-based single-crystal superalloys, the effect of Ru on the microstructure stability and high-temperature properties of superalloys is becoming increasingly important. In this study, the effect of Ru...

The deformation and damage mechanisms of a single crystal nickel-based superalloy containing 6.0%Re/5.0%Ru were studied through creep performance tests at 800 °C/860–880 MPa, microstructure and morphology observation, and dislocation config...

The CO-tolerance mechanism of a carbon-supported Pt-Fe alloy catalyst with two atomic layers of stabilized Pt-skin (Pt_2AL–PtFe/C) was investigated, in comparison with commercial Pt₂Ru₃/C (c-Pt₂Ru₃/C), by in situ attenuated total reflection Fourier tr...

Since trace amounts of CO in H₂ gas produced by steam reforming of methane causes severe poisoning of Pt-based catalysts in polymer electrolyte membrane fuel cells (PEMFCs), research has been mainly devoted to exploring CO-tolerant catalysts. To test...

Electrodeposition of Cu-Ag films from acidic sulfate bath was conducted at n-Si(001) and polycrystalline Ru substrates. Significant nucleation overpotential of 0.4 V is observed with the Cu-Ag bath at n-Si(001) substrate, whereas the electrodepositio...

Carbon nanotubes (CNTs) have been investigated in recent years as a catalyst support for proton exchange membrane fuel cells. Improved catalyst activities were observed and attributed to metal-support interactions. We report a study on the kinetics o...

Fullerenes were modified into fulleramines by the wet chemical method, and then a CoRu/CNB bimetallic catalyst with defect-rich carbon-coated CoRu alloy and Ru NPs anchored on N- and B-doped carbon, promoting full pH hydrogen evolution, was prepared...

Ruthenium (Ru) and its alloys exhibit high corrosion resistance in acidic environments; however, their corrosion behavior in supercritical acidic fluids remains unclear. In this study, the corrosion resistance of Ru–Mo–W and Ru–Mo&n...

Pulsed current has proven to be a promising alternative to direct current in electrochemical deposition, offering numerous advantages regarding deposit quality and properties. Concerning the electrodeposition of metal alloys, the role of pulsed curre...

Transition metal-ruthenium alloys are promising candidates for ultra-high-temperature structural applications. However, the mechanical and electronic characteristics of these alloys are not well understood in the literature. This study uses first-pri...

Pyrite ${\mathrm{FeS}}_2$ has become the focus of many researchers in thin-film photovoltaics because it has some possibilities in photovoltaics. In this manuscript, we present an experimental and a theoretical study of the electronic structure of pyrite ${\mathrm{FeS}}_2$ allo...

The selective electrooxidation of glycerol to value-added products is an effective method to address the surplus glycerol derived from biodiesel production. In this study, a series of carbon-supported non-precious metal-doped PtRu-based multicomponen...

Surface segregation in metal alloys critically determines their electrocatalytic performance, yet how chemisorbed oxygen alters segregation behavior under reaction conditions remains poorly understood. Using density functional theory, we quantify the...

We have prepared a multi-component nanoporous PtRuCuW (np-PtRuCuW) electrocatalyst via a combined chemical dealloying and mechanical alloying process. The X-ray diffraction (XRD), transmission electron microscopy (TEM) and electrochemical measuremen...

By testing the creep properties of a Re/Ru-containing single-crystal alloy specimen and examining the microstructural evolution of the allow at different stages of creep using scanning electron microscopy (SEM) and transmission electron microscopy (T...

NbRu has a potential as a high-temperature shape-memory alloy (HTSMA) because it has a martensitic transformation temperature above 1000 °C. However, its shape-memory properties could be improved for consideration in the aerospace and automotive...

Through room-temperature tensile testing, microstructural observation, and comparative analysis of dislocation configurations, this study investigates the deformation and damage behavior of a high-concentration Re/Ru single-crystal alloy. The results...

In this work, we developed 3D ionic liquid (IL) functionalized graphene assemblies (GAs) decorated by ultrafine RuCu alloy nanoparticles (RuCu-ANPs) via a one-step synthesis process, and integrated it into a microfluidic sensor chip for in situ elect...

The high-temperature stability of RuAl-based electrodes for application in microelectronic devices is analyzed for long-term duration. The electrodes are prepared on Ca₃TaGa₃Si₂O₁₄ (CTGS) substrates using SiO₂ and Al-N-O cover and barrier layers as o...

Hydrogen, with its high energy density and zero greenhouse gas emissions, is an exceptional energy vector, pivotal for a sustainable energy future. Ammonia, serving as a practical and cost-effective hydrogen carrier, offers a secure method for hydrog...

A series of PtRu/carbon black catalysts were prepared by means of deposition-precipitation and reduced by various reducing agents. NaBH₄, HCHO and NaH₂PO₂, respectively, were used as the reduction agents. Some of the samples were reduced by various a...

Carbon-supported Pt–Ru alloys with a Pt/Ru ratio of 1:1 were prepared by NaBH₄ reduction at room temperature. X-ray diffraction (XRD) measurements indicate that the as-prepared Pt–Ru nanoparticles had a face-centered cubic (fcc) structure. X-ray phot...

Nickel–ruthenium–phosphorus, Ni–Ru–P, alloy coatings were fabricated by magnetron dual-gun co-sputtering from Ni–P alloy and Ru source targets. The composition variation and related microstructure evolution of the coatin...

As an important raw material for organic synthesis, the 1,6-hexanediol (HDOL) is synthesized by the complicated two-step process traditionally. The hydrogenation of adipic acid (AA) is a potential way to prepare 1,6-hexanediol. At present, amorphous...

In this work, the effect of the Ru element on the γ′-phase evolution and deformation mechanism in the fourth-generation Ni-based single-crystal superalloy was investigated. Results show that the Ru element alters the distribution coeffici...

RuAl thin films possess a high potential as a high temperature stable metallization for surface acoustic wave devices. During the annealing process of the Ru-Al films, Al ${}_2$ O ${}_3$ is formed at the surface of the films even under high vacu...

We report the results of a mineralogical investigation of placer samples from the upper reaches of the Sisim watershed, near Krasnoyarsk, in Eastern Sayans, Russia. The placer grains are predominantly Os–Ir–(Ru) alloys (80%) that host var...

The Ta-Ru binary phase diagram has not been fully investigated, but shows potential for a two-phase region of A2 + B2. Given the high melting points of both Ta and Ru, such an alloy would have the potential for high temperature strength. A Ta₇₂Ru₂₈ a...

We describe assemblages of platinum-group minerals (PGM) and associated PGE–Au phases found in alluvium along the River Bolshoy Khailyk, in the western Sayans, Russia. The river drains the Aktovrakskiy ophiolitic complex, part of the Kurtushibi...

We discuss the suitability of laser-based resonant ultrasound spectroscopy (RUS) for the characterization of soft shearing modes in single crystals of shape memory alloys that are close to the transition temperatures. We show, using a numerical simul...

Ruthenium addition inhibits the formation of the topologically close-packed phases in Ni-based superalloys and improves the solid solution strength of Ni–Ti shape memory alloys. Therefore, the Ni–Ti–Ru phase stability is a very valu...

Refractory superalloys (RSAs) are promising candidates for high-temperature, high-strength applications. Two-phase RSAs containing body-centered cubic (BCC) and ordered B2 phases are among the more promising candidates. Systems containing Ru-based B2...

The effects of Ru on Re segregation and low-cycle fatigue (LCF) behavior were investigated in two model single-crystal superalloys, Ni-8.5Al-4Re and Ni-8.5Al-4Re-2Ru (wt.%). Microstructural morphology, elemental distribution, fatigue deformation beha...

Pt₂RuMo/C catalysts were synthesized by the modified polyol method in the presence and absence of Li(C₂H₅)₃BH (LBH), annealed at 600 °C under H₂ atmosphere to improve the reduction of Pt and Ru to provide stronger interactions between Mo and anot...

The platinum-group minerals (PGM) in placer deposits provide important information on the types of their primary source rocks and ores and formation and alteration conditions. The article shows for the first time the results of a study of placer plat...

Two structural forms of a ternary alloy PtRuIr/C catalyst, one amorphous and one highly crystalline, were synthesized and compared to determine the effect of their respective structures on their activity and stability as anodic catalysts in methanol...

In the field of orthopedic or dental implants, titanium and its alloys are most commonly used because of their excellent mechanical and corrosion properties and good biocompatibility. After implantation into the patient’s body, there is a high...

The aim of this study was to systematically analyze the influence of potential and the Co(II)–Ru(III) molar ratio on the electrochemical behavior of the Co–Ru system during codeposition from acidic chloride electrolytes. The equilibrium s...

Thin-film ruthenium (Ru) and copper (Cu) binary alloys have been prepared on a Teflon™ backing layer by cosputtering of the precious and nonprecious metals, respectively. Alloys were then selectively dealloyed by sulfuric acid as an etchant, and thei...