Alloys

Al–Mg–Si alloys are used in aircraft, train, and car manufacturing industries due to their advantages, which include non-corrosivity, low density, relatively low cost, high thermal and electrical conductivity, formability, and weldability. This study investigates the bulk mechanical properties of Al–Mg–Si alloys and the influence of the Si/Mg ratio on these properties. The Al cell was used as the starting structure, and then nine structures were modeled with varying percentages of aluminium, magnesium, and silicon. Elastic constant calculations were conducted using the stress–strain method as implemented in the quantum espresso code. This study found that the optimum properties obtained were a density of 2.762 g/cm³, a bulk modulus of 83.3 GPa, a shear modulus of 34.4 GPa, a Vickers hardness of 2.79 GPa, a Poisson’s ratio of 0.413, a Pugh’s ratio of 5.42, and a yield strength of 8.38 GPa. The optimum Si/Mg ratio was found to be 4.5 for most of the mechanical properties. The study successfully established that the Si/Mg ratio is a critical factor when dealing with the mechanical properties of the Al–Mg–Si alloys. The alloys with the optimum Si/Mg ratio can be used for industrial applications such as plane skins and mining equipment where these properties are required. Full article

The paper is a personal perspective on the design of metallic ultra-high temperature materials (UHTMs). Specifically, the alloy design “landscape” of metallic UHTMs was considered from the viewpoint of the alloy design methodology NICE. The concepts of synergy, entanglement and self-regulation and their significance for alloy design/development were discussed. The risks, ecological challenges and material-environment interactions associated with the development of metallic UHTMs were highlighted. The “landscape” showed that beneath the complexities of alloy design lies an elegant and powerful unity of specific parameters that link logically and that progress can be made by recognising those interrelationships between parameters that generate interesting, diverse, and complex alloys. Full article

Case-hardening steels are gaining increasing interest in the field of laser powder bed fusion (PBF-LB/M) due to their excellent weldability. In combination with post-process carburization heat treatment, the surface properties can be improved to generate high-strength products. When manufacturing larger products by means of PBF-LB/M, the in situ heat accumulation and the altered cooling rates affect the resulting material properties. Therefore, the fabrication of larger products requires an understanding on the influencing factors that affect the material properties. This work investigates the effect of different volumetric energy densities (VED) on the resulting microstructural and mechanical properties. It is found that the hardness decreases continuously along the build direction. The gradient depends on the applied energy and is stronger for higher energy inputs due to heat accumulation and lowered cooling rates. Furthermore, countering strategies are investigated to avoid process-specific hardness reduction along the build direction. This includes a reduced number of parts within the build job as well as a modified inter-layer time (ILT) between consecutive layers of the specimen. Applying a moderate inter-layer time helps to counter process-specific overheating, which is indicated by an almost homogeneous material hardness and melt pool size along the build direction. Full article

This article presents the results of studies of the self-propagating high-temperature synthesis (SHS) for obtaining zirconium alloys with niobium by the method of calcium-thermal reduction of nuclear-grade zirconium tetrafluoride in the presence of niobium powder. The optimal heating temperature of the initial charge and the methods of charge mixture with different calcium content were determined. The safety of the SHS process is ensured by the formation of an optimal combustion front of the mixture to remove the released high-pressure gases. A setup for the furnace reduction of zirconium alloys with charge preheating, discharge of molten products into molds of various designs, and control of the time and rate of slag and alloy crystallization has been tested. The required performance of the installation, the degree of transition of zirconium from salt into the alloy, and the purity, structure, and uniformity of the alloy were achieved. Full article

A systematic study of the phase composition of quenched binary titanium alloys with d-metals of groups 5–11 from periods four to six was carried out using the methods of X-ray diffraction analysis. It was found that the formation of the orthorhombic α″-phase depends on the position of the alloying metal in the periodic table. The formation of the α″-phase occurs only in the systems Ti-V, Ti-Nb, Ti-Mo, Ti-Ru, Ti-Ta, Ti-W, Ti-Re, Ti-Os and Ti-Ir, and in other systems, it does not occur. It was found that the critical parameter for the formation of the α″-phase is the difference in the size of titanium atoms and those of the alloying metal {(r_Ti − r_Me)/r_Ti 100%}. The formation of the α″-phase occurs only in systems where this value is lower than 9 at.%. Full article

Laser materials processing includes rapid heating to possibly high temperatures and rapid cooling of the illuminated materials. The material reactions can show significant deviations from equilibrium processing. During processing of complex materials and material combinations, it is mainly unknown how the materials react and mix. However, it is important to know which chemical elements or compounds are present in the material to define the alloy. In addition, their distribution after rapid cooling needs to be better understood. Therefore, such alloy changes at rapid heating induced by laser illumination were created as pre-placed and pre-mixed powder nuggets. The energy input and the material ratio between the powder components were varied to identify characteristic responses. For the detection of reaction durations and mixing characteristics, the vapor plume content was assumed to contain the necessary information. Spectral measurements of the plume were used to identify indicators about process behaviors. It was seen that the spectral data give indications about the chemical reactions in the melt pool. The reactions of iron ore components with aluminum seem to require laser illumination to finish completely, although the thermite reaction should maintain the chemical reaction, likely due to the required melt mixing that enables the interaction of the reacting partners at all. Full article

Instead of a number of different approaches or a formal description of experimental data, a unified approach is proposed to consider failure and deformation as thermodynamic processes. Mathematical modeling of the processes is carried out using rheological models of the material. Parametric identification of structural models is carried out using minimal necessary experiments. Based on results of these experiments, the scope of applicability conditions for this material and test modes necessary for parametric identification of models are selected. One fracture criterion is used that formally corresponds to the achievement of a threshold concentration of micro-damage in any volume of the material. Calculations of durability under conditions of varying temperature and variable loads are based on the relationship of plastic flow and failure processes distributed over the volume of the material. They are performed numerically over time steps depending on the ratio of the rate of change of temperature and stresses. Full article

In this work, the influence of heat treatment on the corrosion resistance of shape memory stainless steel based on FeMnSiCrNiCo was evaluated. Deformed samples were annealed from 250 °C to 1050 °C for 1 h. Scanning electron microscopy (SEM-EDS) and a Vickers microhardness test were used to characterize the microstructure. Thermal analysis was performed to identify phase transformations. Corrosion resistance was evaluated in an electrochemical test in a 3.5% NaCl solution. FeMnSiCrNiCo in the deformed state had better corrosion resistance compared to other conditions. However, as the annealing temperature increased, the corrosion resistance decreased due to the formation of precipitates. Full article

Permanent magnets are becoming more and more relevant for modern society. As the most widely used permanent magnets contain rare-earth elements, the increased dependence on these strategic elements is worrisome, and the pursuit for rare-earth free alternatives has become a strategic goal in many countries. The metastable and ferromagnetic τ-phase that forms in the MnAl(C) system is one of the most promising alternatives, and since its discovery, major efforts have been made to improve its performance and realize its full potential. One major factor that has prevented a widespread commercialization of MnAl(C) permanent magnets is their relatively low coercivity. Here, we demonstrate that additive manufacturing, using laser powder bed fusion, can be used to produce MnAl in its high-temperature polymorph (ε, hcp), which can be subsequently transformed, through post-heat treatments to the ferromagnetic τ-phase. Although we successfully obtained a preferential orientation of the ε-phase with <001> parallel to the build direction, this did not translate into a strong preferential orientation in the τ-phase, thus indicating that the phase transformation occurs by the migration of incoherent interfaces. The MnAl(C) samples are characterized by a density of ≈4.4 g/cm³, a saturation magnetization of 39.3 Am²/kg, a coercivity of 168 kA/m, and a remanence of 17.5 Am²/kg. Full article

The microstructure and mechanical properties of as-homogenized Mg-xLi-3Al-2Zn-0.2Zr alloys (x = 5, 7, 8, 9, 11 wt.%) were studied. As the Li content increased from 5 wt.% to 11 wt.%, the alloy matrix changed from the α-Mg single-phase to α-Mg+β-Li dual-phase and then to the β-Li single-phase. Homogenized With the increase in Li content, the alloy strength decreased while the elongation increased, and the corresponding fracture mechanism changed from cleavage fracture to microvoid coalescence fracture. This is mainly attributed to the matrix changing from α-Mg with hcp structure to β-Li with bcc structure. Additionally, the increase in the AlLi softening phase led to the reduction of Al and Zn dissolved in the alloy matrix with increasing Li content, which is one of the reasons for the decrease in alloy strength. Full article

The grain boundaries and dislocations play an important role in understanding the deformation behavior in polycrystalline materials. In this paper, the deformation mechanism of Cu, Ni, and equimolar Cu-Ni alloy was investigated using molecular dynamic simulation. The interaction between dislocations and grain boundary motion during the deformation was monitored using the dislocation extraction algorithm. Moreover, the effect of stacking fault formation and atomic band structure on the deformation behavior was discussed. Results indicate that dislocations nucleate around the grain boundary in copper, the deformation in nickel changes from planar slip bands to wavy bands, and high density of dislocation accumulation as well as numerous kink and jog formations were observed for the equimolar Cu-Ni alloy. The highest density of the Shockley dislocation and stacking faults was formed in the equimolar Cu-Ni alloy which results in the appearance of a huge gliding stage in the stress–strain curve. The grain boundaries act as a sinking source for vacancy annihilation in Ni and Cu; however, this effect was not observed in an equimolar Cu-Ni alloy. Finally, radial distribution function was used to evaluate atom segregation in grain boundaries. Full article

One of the main challenges encountered in the Laser-based Powder Bed Fusion (L-PBF) Additive Manufacturing (AM) process is the fabrication of defect-free parts. The presence of defects severely degrades the mechanical performance of AM parts and especially their fatigue strength. The most popular and reliable method to assess the ability of the employed process parameters for the fabrication of full-density parts is the process windows map, also known as printability map. However, the experimental procedure for the design of the printability maps and the identification of the optimum-density process parameters is usually time-consuming and expensive. In the present work, a modelling framework is presented for the determination of a printability map and the optimization of the L-PBF process based on the prediction and characterization of melt-pool geometric features and the prediction of porosity of small samples of 316L SS and Ti-6Al-4V metal alloys. The results are compared with available experimental data and present a good correlation, verifying the modelling methodology. The suitability of the employed defect criteria for each material and the effect of the hatch-spacing process parameter on the optimum-density parameters are also presented. Full article

High entropy alloys present many promising properties, such as high hardness or thermal stability, and can be candidates for many applications. Powder metallurgy techniques enable the production of bulk alloys with fine microstructures. This study aimed to investigate powder metallurgy preparation, i.e., mechanical alloying and sintering, non-equiatomic high entropy alloy from the Al-Cr-Fe-Mn-Mo system. The structural and microstructural investigations were performed on powders and the bulk sample. The indentation was carried out on the bulk sample. The mechanically alloyed powder consists of two bcc phases, one of which is significantly predominant. The annealed powder and the sample sintered at 950 °C for 1 h consist of a predominantly bcc phase (71 ± 2 vol.%), an intermetallic χ phase (26 ± 2 vol.%), and a small volume fraction of multielement carbides—M₆C and M₂₃C₆. The presence of carbides results from carbon contamination from the balls and vial during mechanical alloying and the graphite die during sintering. The density of the sintered sample is 6.71 g/cm³ (98.4% relative density). The alloy presents a very high hardness of 948 ± 34 HV_1N and Young’s modulus of 245 ± 8 GPa. This study showed the possibility of preparing ultra-hard multicomponent material reinforced by the intermetallic χ phase. The research on this system presented new knowledge on phase formation in multicomponent systems. Moreover, strengthening the solid solution matrix via hard intermetallic phases could be interesting for many industrial applications. Full article

Nowadays, great efforts are being made to develop bcc-superalloys for medium- and high-temperature applications. However, the high brittle-to-ductile transition temperatures (BDTT) have restricted their application. Therefore, designing hot-processing routes to obtain a refined grain in these new superalloys is required. Particularly in the Fe-10Al-12V (at%) alloy, we have recently tested the BDTT shifting and, using physical models, it was indicated that a combination of L2₁-precipitate sizes with small grain sizes could shift the BDTT below room temperature. Here, we will present the study that allowed us to design the processing route for grain refinement in the tested superalloy. Molds of different geometry and with metallic and sand walls were used to test two different types of casting. Carbide conditioning treatments for improving the sizes and distribution were studied. The recrystallization process was explored first by hot rolling and post-annealing in stepped geometry samples with two different columnar grain orientations. Finally, we analyzed the grain microstructure obtained along a hot processing route consisting of carbide conditioning treatment, forging into a squared bar, and hot rolling up to a 2.8 mm thickness strip. Full article

Nickel is an important and widely used alloying element in carbon steels. Some of its prominent metallurgical effects in these steels are moderate solid solution strengthening, mild hardenability and, importantly, a strong promotion of toughness, especially at low temperatures. The first uses of nickel as an alloying element in commercial steel production date back to the early 20th century. The aim of the current review is to give the reader a thorough and concise overview of nickel functionalities relevant to modern carbon steel production. The interaction of nickel with other alloying elements and processing conditions is also considered. Examples will be given demonstrating the advantages of nickel alloying in selected steel grades and applications. Full article

FeSiCr alloys are used as soft magnetic materials for power multilayer inductors. The alloys are typically annealed at intermediate temperatures in air during inductor fabrication to form an insulating chromium oxide layer around the alloy particles. The variation of the annealing temperature between 700 °C and 900 °C in air, and, for the first time, the variation of the oxygen partial pressure during annealing at 900 °C are studied, and their effects on the alloy’s oxidation behavior, phase formation, insulation resistance, and permeability are demonstrated. The chromium oxide content increases up to about 12 wt% with annealing temperature in air, whereas it decreases to 8.2 wt% after annealing at 900 °C and 0.001% O₂. The observed mass changes during annealing confirm the various tendencies towards oxidation. This oxidation behavior is reflected in an increase in the insulation resistance with annealing temperature or in a resistance reduction with decreasing oxygen partial pressure. The permeability decreases from µ = 22 after annealing at 700 °C to µ = 18.5 at 900 °C in air. The reduction of p_O2 during annealing at 900 °C leads to an increase in permeability up to µ = 22.5 at p_O2 = 0.001% O₂. The results can be used to design cofiring strategies using reduced oxygen partial pressure for new composite multilayer inductive components consisting of FeSiCr- and ferrite layers in combination with silver metallization. Full article

The demand for high-strength aluminum alloys for the laser powder bed fusion (LPBF) process is still growing. However, to date, the crack susceptibility of conventional alloys as well as the high prices for specially developed alloys are the main obstacles for the use of high-strength aluminum alloys for LPBF. In this paper, crack-free LPBF samples with a relative density >99.9% were processed from AlMgSi1Zr (6182 series alloy) powder, to which 0.5 wt.-% Zr and 0.5 wt.-% Ti were added via mechanical mixing. No hot cracks were found in the µCT scans. Moreover, a fully equiaxed microstructure with a mean size of the α-Al grains of 1.2 µm was observed in the as-built parts. Al₃(Zr,Ti) particles were observed, acting as efficient heterogeneous grain refiners for α-Al by building a semi-coherent interface. Unmolten Ti and Zr particles with sizes up to 80 µm were found in the α-Al phase. The resulting fine-grained microstructure led to a tensile strength of 329 ± 4 MPa and a total elongation at a break of 11.4 ± 0.9% after solution heat treatment, quenching in water, and subsequent artificial ageing. Full article

Additive manufacturing (AM) techniques such as laser powder bed fusion (L-PBF) are rapidly growing due to the inherent design freedom and possibilities to produce components not available with other techniques. This could be utilized in, e.g., the design of new types of heat exchangers in ferritic stainless steels often used for high-temperature applications. Ferritic stainless steels are, however, difficult to weld and could therefore imply obstacles when produced by AM. When establishing the AM-produced alloy in new applications, it is therefore important to increase the understanding of the mechanical properties and high-temperature creep resistance in relation to the unique microstructure and printability. In this study, we have investigated the microstructure of Cr-rich SS446 ferritic stainless steel produced by L-PBF by microscopical and crystallographic techniques. The properties were compared to the conventionally produced tubes. The rapid cooling and reheating during the application of the subsequent powder layers during L-PBF introduces an intriguing microstructure consisting of a ferritic matrix with precipitation of austenite showing a Kurdjumov–Sachs orientation relationship. Characteristic dislocation networks were observed in the L-PBF samples and contributed to the good mechanical properties in the as-built state (more than twice the yield strength of the conventionally produced tube). Furthermore, the creep resistance at 800 °C was superior to the conventionally produced component, suggesting that L-PBF-produced SS446 possesses many advantages regarding production as compared to the conventional route. Full article

In this work, the structural, magnetic, thermal, and transport properties of the arc-melted polycrystalline Heusler alloy Co₂Ti_1.5Sn_0.5 are investigated. The alloy crystallizes in an L2₁ structure with a space group of Fm-3m. The magnetic properties of the alloy depict its antiferromagnetic nature and the alloy exhibits magnetic ordering around Neel Temperature T_N = 8.5 K. The effective magnetic moment value obtained from the Curie –Weiss law suggests that the cobalt atom in the alloy is in the low-spin state. From the heat capacity studies, the Sommerfeld coefficient and Debye temperature were determined. In addition, electrical resistivity shows a linear response with increasing temperature, indicating the metallic nature of the alloy. Full article