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Inorganics, Volume 11, Issue 9

September 2023 - 28 articles

Cover Story: This work reports the synthesis and structural characterization of a series of quaternary lithium-alkaline earth metal alumo-silicides and alumo-germanides. The structures, despite their identical chemical formulae represented as A2LiAlTt2 (A = Ca, Sr, Ba; Tt = Si, Ge), are different, largely dependent on the nature of the alkaline earth metal. The calcium compounds are part of the TiNiSi family with the Pnma space group, the strontium compounds are isostructural with Na2LiAlP2 and have the Cmce space group, and the barium compounds crystallize with the PbFCl structure type in the P4/nmm space group. View this paper
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Articles (28)

  • Article
  • Open Access
3 Citations
3,658 Views
14 Pages

Manganese(I) Diamine Electrocatalysts: Electrochemical Carbon Dioxide Reduction to Carbon Monoxide

  • Badrinath Dhakal,
  • Brooke A. Corbin,
  • Alberto Sosa Parada,
  • Jonathan G. Sakai,
  • Emily A. Felton,
  • Lauren T. McDonald,
  • Anthony J. Gross,
  • Gary S. Nichol and
  • Greg A. N. Felton

21 September 2023

Novel organometallic complexes Mn(benzene-1,2-diamine)(CO)3Br, Mn-1, Mn(3-methylbenzene-1,2-diamine)(CO)3Br, Mn-2, and Re(benzene-1,2-diamine)(CO)3Cl, Re-1, have been synthesized and characterized by IR, UV/Vis, 1H-NMR, EA and HRMS. The structures of...

  • Article
  • Open Access
4 Citations
2,408 Views
16 Pages

The Analytical Application of Quenching Phenomena of CdTe Quantum Dot Nanoparticles

  • Petra Humajová,
  • Patrik Baliak,
  • Ivan Landry Yumdjo Youmbissi,
  • Alžběta Jebavá,
  • Lenka Řezáčová and
  • Přemysl Lubal

19 September 2023

This paper is devoted to the synthesis and application of CdTe quantum dot (QD) nanoparticles covered with organic ligands containing a thiol group, mostly mercaptopropionic acid (MPA) and glutathione (GSH). The simple one-step synthetic procedure wa...

  • Article
  • Open Access
2,232 Views
12 Pages

Organoruthenium Complexes Containing Phosphinodicarboxamide Ligands

  • Roberto Nolla-Saltiel,
  • Ana M. Geer,
  • Helen R. Sharpe,
  • Cameron D. Huke,
  • Laurence J. Taylor,
  • Thomas G. Linford-Wood,
  • Ashleigh James,
  • Jamie Allen,
  • William Lewis and
  • Alexander J. Blake
  • + 2 authors

19 September 2023

Ruthenium complexes of phosphinocarboxamide ligands, and their use to form metallacycles using halide abstraction/deprotonation reactions are reported. Thus, [Ru(p-cym){PPh2C(=O)NHR}Cl2; R = iPr (1), Ph (2), p-tol (3)] and [Ru(p-cym){PPh2C(=O)N(R)C(=...

  • Article
  • Open Access
5 Citations
2,462 Views
20 Pages

Structural, Morphological, and Optical Properties of Single and Mixed Ni-Co Aluminates Nanoparticles

  • Dana Gingasu,
  • Ovidiu Oprea,
  • Gabriela Marinescu,
  • Jose Maria Calderon Moreno,
  • Daniela C. Culita,
  • Silviu Preda and
  • Vasile-Adrian Surdu

16 September 2023

A series including single and mixed Ni-Co aluminates was obtained using the precursor method, with malic acid as a ligand. The malate precursors (polynuclear coordination compounds) were isolated and characterized by Fourier Transform Infrared (FTIR)...

  • Article
  • Open Access
29 Citations
3,515 Views
25 Pages

Probe-Sonicated Synthesis of CuO–ZnO Hybrid Nanocomposite for Photocatalytic and Supercapacitor Applications

  • Amal BaQais,
  • Mir Waqas Alam,
  • Mohd Farhan,
  • Ghazala Muteeb,
  • Nassiba Allag and
  • Shehla Mushtaq

16 September 2023

An ultrasound-assisted probe sonication route effectively prepared pure CuO and two-dimensional CuO-ZnO nanocomposites (NCs) for different ratios of CuO and ZnO, and the experimental and theoretical methods investigated the structural, photocatalytic...

  • Article
  • Open Access
7 Citations
2,903 Views
14 Pages

Synthesis of High-Crystallinity Mg-Al Hydrotalcite with a Nanoflake Morphology and Its Adsorption Properties for Cu2+ from an Aqueous Solution

  • Nai-Cai Xu,
  • Dan-Dan Shi,
  • Ying Zhang,
  • Kai-Peng Zhong,
  • Jing Liu,
  • Qi Zhao,
  • Qiang Gao and
  • Shao-Ju Bian

15 September 2023

A magnesium–aluminum-layered double hydroxide (Mg-Al LDH) with a nano-lamellar morphology was prepared by using a homogeneous precipitation and hydrothermal method, and a calcination product (Mg-Al LDO) of the Mg-Al LDH was also obtained in thi...

  • Article
  • Open Access
14 Citations
5,779 Views
12 Pages

Effects of Coloration of Spinel CoAl2O4 Cobalt Blue Pigments: Composition, Structure, and Cation Distribution

  • Weiran Zhang,
  • Ziyu Li,
  • Guohua Wu,
  • Wei Wu,
  • Hailan Zeng,
  • Haiyun Jiang,
  • Weili Zhang,
  • Ruomei Wu and
  • Qiong Xue

14 September 2023

Cobalt blue ceramic pigments mainly consisting of CoAl2O4 are subject to the difficulty of color control. Here, a perspective is reported regarding research on the reasons for color change based on the control of the heat treatment and ratio of compo...

  • Article
  • Open Access
8 Citations
3,511 Views
18 Pages

Copper(I)/Triphenylphosphine Complexes Containing Naphthoquinone Ligands as Potential Anticancer Agents

  • Celisnolia M. Leite,
  • João H. Araujo-Neto,
  • Adriana P. M. Guedes,
  • Analu R. Costa,
  • Felipe C. Demidoff,
  • Chaquip D. Netto,
  • Eduardo E. Castellano,
  • Otaciro R. Nascimento and
  • Alzir A. Batista

9 September 2023

Four new Cu/PPh3/naphtoquinone complexes were synthesized, characterized (IR, UV/visible, 1D/2D NMR, mass spectrometry, elemental analysis, and X-ray diffraction), and evaluated as anticancer agents. We also investigated the reactive oxygen species (...

  • Article
  • Open Access
5 Citations
2,067 Views
12 Pages

9 September 2023

Soluble noble metal salts are widely used for loading noble metals as nano-catalysts in many applications. In this paper, Pt-SnO2 composite nanoceramics were prepared from SnO2 nanoparticles and H2PtCl6 using two Pt loading methods separately: for th...

  • Article
  • Open Access
2,136 Views
11 Pages

Dibromo- and Dichlorotriphenylphosphino N-Acyclic Carbene Complexes of Platinum(II)—Synthesis and Cytotoxicity

  • Anna Farasat,
  • Luca Labella,
  • Maria Luisa Di Paolo,
  • Lisa Dalla Via and
  • Simona Samaritani

8 September 2023

Some new dichloro- and dibromotriphenylphosphino isonitrile and N-acyclic (NAC) carbene complexes of platinum(II) were synthesized, starting from suitable dinuclear precursors. The reaction of cyclohexylisonitrile with trans-[Pt(μ-X)X(PPh3)]2, fol...

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Inorganics - ISSN 2304-6740