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Crystals, Volume 9, Issue 3

2019 March - 61 articles

Cover Story: Cover story: In this paper, we present a study on the evolution of crystal mosaicity during dendritic solidification of single-crystal nickel-based superalloys prepared by seeded Bridgman processing. The work was performed in the frame of the Collaborative Research Center SFB/TR 103 “From Atoms to Turbine Blades—a Scientific Basis for a New Generation of Single-Crystal Superalloys”. In this center, scientists from the Ruhr-Universität Bochum (RUB), Friedrich–Alexander Universität Erlangen–Nürnberg (FAU), Max-Planck-Institut für Eisenforschung (MPIE), Forschungszentrum Jülich (FZ Jülich), and German Aerospace Center (DLR) focus on various important research objectives related to single-crystal nickel-based superalloys. Today, these superalloys are considered the key material for modern gas turbines. This research activity is funded by the Deutsche Forschungsgemeinschaft (DFG). View Paper here.
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Articles (61)

  • Article
  • Open Access
3 Citations
4,632 Views
8 Pages

Deep Etched Gallium Nitride Waveguide for Raman Spectroscopic Applications

  • Yu-Li Hsieh,
  • Wen-Shao Chen,
  • Liann-Be Chang,
  • Lee Chow,
  • Samuel Borges,
  • Alfons Schulte,
  • Shiang-Fu Huang,
  • Ming-Jer Jeng and
  • Chih-Jen Yu

26 March 2019

Gallium nitride (GaN) materials with a high chemical stability and biocompatibility are well suited for bio-sensing applications and evanescent wave spectroscopy. However, GaN poses challenges for processing, especially for deep etching using convent...

  • Article
  • Open Access
9 Citations
8,482 Views
14 Pages

Fab Fragment of VHH-Based Antibody Netakimab: Crystal Structure and Modeling Interaction with Cytokine IL-17A

  • Olga Kostareva,
  • Ilya Kolyadenko,
  • Andrey Ulitin,
  • Victoria Ekimova,
  • Stanislav Evdokimov,
  • Maria Garber,
  • Svetlana Tishchenko and
  • Azat Gabdulkhakov

26 March 2019

Interleukin 17A (IL-17A) is a proinflammatory cytokine produced by Th17 cells. Antibody BCD-085 (netakimab) against human IL-17A is one of the new inhibitors of this cytokine. In netakimab, the VH domain is replaced by the VHH domain of Lama glama po...

  • Article
  • Open Access
7 Citations
4,608 Views
16 Pages

Study of Liquid Crystals Showing Two Isotropic Phases by 1H NMR Diffusometry and 1H NMR Relaxometry

  • Anton Gradišek,
  • Mario Cifelli,
  • Michal Wojcik,
  • Tomaž Apih,
  • Sergey V. Dvinskikh,
  • Ewa Gorecka and
  • Valentina Domenici

26 March 2019

In this work, we report a study of two thermotropic liquid crystalline samples showing a not common mesophase behavior. The samples, namely a di-benzyloxy biphenyl derivative labelled 9/2 RS/RS, and a bimesogenic liquid crystal labelled L1, show a di...

  • Review
  • Open Access
41 Citations
6,439 Views
12 Pages

26 March 2019

Piezoelectric ceramics is a functional material that can convert mechanical energy into electrical energy and vice versa. It can find wide applications ranging from our daily life to high-end techniques and dominates a billion-dollar market. For half...

  • Article
  • Open Access
5 Citations
5,926 Views
15 Pages

26 March 2019

In drug development, it is extremely important to evaluate the solubility and stability of solid states and to immediately determine the potential for development. Salt screening is a standard and useful method for obtaining drug candidates with good...

  • Article
  • Open Access
6 Citations
3,732 Views
13 Pages

25 March 2019

A three-dimensional model of a circular casting mold with a vibrating nucleus generator was established, and the characteristics of temperature and flow fields during the solidification process of ferritic stainless steel Cr17 in the casting mold wer...

  • Article
  • Open Access
12 Citations
4,698 Views
12 Pages

Synthesis, Structures and Co-Crystallizations of Perfluorophenyl Substituted β-Diketone and Triketone Compounds

  • Takumi Kusakawa,
  • Shunichiro Sakai,
  • Kyosuke Nakajima,
  • Hidetaka Yuge,
  • Izabela I. Rzeznicka and
  • Akiko Hori

25 March 2019

Perfluorophenyl-substituted compounds, 3-hydroxy-1,3-bis(pentafluorophenyl)-2- propen-1-one (H1) and 1,5-dihydroxy-1,5-bis(pentafluorophenyl)-1,4-pentadien-3-one (H22), were prepared in 56 and 30% yields, respectively, and only the enol forms were pr...

  • Article
  • Open Access
14 Citations
3,678 Views
13 Pages

Impact of Weak Nanoparticle Induced Disorder on Nematic Ordering

  • Dejvid Črešnar,
  • Christina Kyrou,
  • Ioannis Lelidis,
  • Aleksandra Drozd-Rzoska,
  • Szymon Starzonek,
  • Sylwester Janusz Rzoska,
  • Zdravko Kutnjak and
  • Samo Kralj

24 March 2019

Dilute mixtures of nanoparticles (NPs) and nematic liquid crystals (LCs) are considered. We focus on cases where NPs enforce a relatively weak disorder to the LC host. We use a Lebwohl-Lasher semi-microscopic-type modeling where we assume that NPs ef...

  • Communication
  • Open Access
5 Citations
3,613 Views
11 Pages

Effect of High-Density Nanoparticles on Recrystallization and Texture Evolution in Ferritic Alloys

  • Eda Aydogan,
  • Connor J. Rietema,
  • Ursula Carvajal-Nunez,
  • Sven C. Vogel,
  • Meimei Li and
  • Stuart A. Maloy

24 March 2019

Ferritic alloys are important for nuclear reactor applications due to their microstructural stability, corrosion resistance, and favorable mechanical properties. Nanostructured ferritic alloys having a high density of Y-Ti-O rich nano-oxides (NOs <...

  • Article
  • Open Access
2 Citations
4,266 Views
6 Pages

Diode-Pumped Actively Q-Switched Nd:YVO4/RTP Intracavity Raman Laser at 1.49 µm

  • Yue Jiao,
  • Zhaojun Liu,
  • Xingyu Zhang,
  • Feilong Gao,
  • Chenyang Jia,
  • Xiaohan Chen and
  • Zhenhua Cong

22 March 2019

For the first time, a diode-pumped actively Q-switched Nd:YVO4/RbTiOPO4 (RTP) intracavity Raman laser at 1.49 µm was demonstrated to the best of our knowledge. Experimentally, a dual-end diffusion-bonded YVO4–Nd:YVO4–YVO4 crystal wa...

  • Article
  • Open Access
6 Citations
3,719 Views
13 Pages

22 March 2019

For requiring high communication rate and high-quality illumination, multi-color light-emitting diodes (LEDs) have been utilized in visible light communication (VLC) systems and attracted substantial research interests. It should be noted that multip...

  • Article
  • Open Access
5 Citations
3,489 Views
9 Pages

Optical Characterization and Photovoltaic Performance Evaluation of GaAs p-i-n Solar Cells with Various Metal Grid Spacings

  • Jenq-Shinn Wu,
  • Der-Yuh Lin,
  • Yun-Guang Li,
  • Hung-Pin Hsu,
  • Ming-Cheng Kao and
  • Hone-Zern Chen

22 March 2019

GaAs p-i-n solar cells are studied using electroreflectance (ER) spectroscopy, light beam induced current (LBIC) mapping and photovoltaic characterization. Using ER measurements, the electric field across the pn junction of a wafer can be evaluated,...

  • Article
  • Open Access
120 Citations
5,918 Views
15 Pages

21 March 2019

Quantum mechanics, through the Hellmann–Feynman theorem and the Schrödinger equation, show that noncovalent interactions are classically Coulombic in nature, which includes polarization as well as electrostatics. In the great majority of t...

  • Article
  • Open Access
14 Citations
5,289 Views
10 Pages

21 March 2019

Three 2D new coordination polymers Co2(L1)2(1,10-Phenanthroline)2(DMF)0.5(H2O) (1), (H2L1 = Pyridine-3,5-dicarboxylic acid) Co(L1)(2,2-bipyridine) (2), and Co(L2)(2,2-bipyridine) (DMF) (3) (H2L2 = Pyridine-3,4-dicarboxylic acid) were synthesized thro...

  • Article
  • Open Access
24 Citations
3,865 Views
20 Pages

Stimulated Raman Scattering in Alkali-Earth Tungstate and Molybdate Crystals at Both Stretching and Bending Raman Modes under Synchronous Picosecond Pumping with Multiple Pulse Shortening Down to 1 ps

  • Milan Frank,
  • Sergei N. Smetanin,
  • Michal Jelínek,
  • David Vyhlídal,
  • Vladislav E. Shukshin,
  • Lyudmila I. Ivleva,
  • Elizaveta E. Dunaeva,
  • Irina S. Voronina,
  • Petr G. Zverev and
  • Václav Kubeček

21 March 2019

Comparative investigation of characteristics of spontaneous and stimulated Raman scattering (SRS) in different alkali-earth tungstate and molybdate crystals at both high and low frequency anionic group vibrations is presented. It has been found that,...

  • Article
  • Open Access
14 Citations
5,835 Views
14 Pages

20 March 2019

This paper discloses six polymorphs of famoxadone obtained from polymorph screening, which were characterized by XRPD, DSC, and SEM. A study of solvent-mediated polymorphic transformation (SMPT) of famoxadone from the metastable Form II to the stable...

  • Review
  • Open Access
12 Citations
4,799 Views
27 Pages

Liquid-Crystalline Dispersions of Double-Stranded DNA

  • Yuri Yevdokimov,
  • Sergey Skuridin,
  • Viktor Salyanov,
  • Sergey Semenov and
  • Efim Kats

20 March 2019

In this review, we compare the circular dichroism (CD) spectra of liquid-crystalline dispersion (LCD) particles formed in PEG-containing aqueous-salt solutions with the purpose of determining the packing of ds DNA molecules in these particles. Depend...

  • Review
  • Open Access
30 Citations
8,202 Views
51 Pages

Surface-Controlled Photocatalysis and Chemical Sensing of TiO2, α-Fe2O3, and Cu2O Nanocrystals

  • Anna Kusior,
  • Milena Synowiec,
  • Katarzyna Zakrzewska and
  • Marta Radecka

20 March 2019

A relatively new approach to the design of photocatalytic and gas sensing materials is to use the shape-controlled nanocrystals with well-defined facets exposed to light or gas molecules. An abrupt increase in a number of papers on the synthesis and...

  • Review
  • Open Access
8 Citations
4,620 Views
17 Pages

19 March 2019

Nematic phases are some of the most common phases among the lyotropic liquid crystalline structures. They have been widely investigated during last decades. In early studies, two uniaxial nematic phases (discotic, ND, and calamitic, NC) were identifi...

  • Article
  • Open Access
3,872 Views
11 Pages

A Preview of a Construction of a Crystal Lattice Based on Intermolecular Interactions

  • Vladimír Hejtmánek,
  • Martin Dračínský and
  • Jan Sýkora

19 March 2019

A general procedure of crystal packing reconstruction using a certain number of intermolecular interactions is introduced and demonstrated on the crystal structure of l-histidine·HCl·H2O. Geometric restrictions based on intermolecular i...

  • Article
  • Open Access
13 Citations
6,025 Views
14 Pages

19 March 2019

Adding crowding agents such as polyethylene glycol (PEG) to lyotropic chromonic liquid crystals (LCLCs) formed by water dispersions of materials such as disodium cromoglicate (DSCG) leads to a phase separation of the isotropic phase and the ordered p...

  • Communication
  • Open Access
10 Citations
5,012 Views
8 Pages

Hybrid Biomimetic Materials from Silica/Carbonate Biomorphs

  • Julian Opel,
  • Niklas Unglaube,
  • Melissa Wörner,
  • Matthias Kellermeier,
  • Helmut Cölfen and
  • Juan-Manuel García-Ruiz

18 March 2019

The formation of a polymer protection layer around fragile mineral architectures ensures that structures stay intact even after treatments that would normally destroy them going along with a total loss of textural information. Here we present a strat...

  • Article
  • Open Access
10 Citations
4,785 Views
11 Pages

Growth of Ga2O3 Nanowires via Cu-As-Ga Ternary Phase Diagram

  • Hang Wang,
  • Ying Wang,
  • Shuyan Gong,
  • Xinyuan Zhou,
  • Zaixing Yang,
  • Jun Yang,
  • Ning Han and
  • Yunfa Chen

15 March 2019

Currently, it is challenging to develop new catalysts for semiconductor nanowires (NWs) growth in a complementary-metal-oxide-semiconductor (CMOS) compatible manner via a vapor-liquid-solid (VLS) mechanism. In this study, chemically synthesized Cu2O...

  • Article
  • Open Access
13 Citations
4,203 Views
10 Pages

15 March 2019

Orbital angular momentum (OAM) mode-division multiplexing (MDM) has recently been under intense investigations as a new way to increase the capacity of fiber communication. In this paper, a two-layer Erbium-doped fiber amplifier (EDFA) for an OAM mul...

  • Article
  • Open Access
15 Citations
5,694 Views
9 Pages

Impact of Delay Time before Annealing MAI-PbI2-DMSO Intermediate Phase on Perovskite Film Quality and Photo-Physical Properties

  • Yujun Yao,
  • Xiaoping Zou,
  • Jin Cheng,
  • Dan Chen,
  • Chuangchuang Chang,
  • Tao Ling and
  • Haiyan Ren

14 March 2019

High-performance perovskite solar cells are strongly dependent on the quality of the perovskite layer. Two-step sequential deposition of CH3NH3PbI3 (MAPbI3) films is widely used to fabricate perovskite solar cells and many factors influence the quali...

  • Article
  • Open Access
17 Citations
8,492 Views
11 Pages

Luminescent Layered Double Hydroxides Intercalated with an Anionic Photosensitizer via the Memory Effect

  • Alexandre C. Teixeira,
  • Alysson F. Morais,
  • Ivan G.N. Silva,
  • Eric Breynaert and
  • Danilo Mustafa

14 March 2019

Layered double hydroxides (LDHs) containing Eu3+ activators were synthesized by coprecipitation of Zn2+, Al3+, and Eu3+ in alkaline NO3-rich aqueous solution. Upon calcination, these materials transform into a crystalline ZnO solid solution co...

  • Article
  • Open Access
1 Citations
2,696 Views
11 Pages

14 March 2019

Evaluation and correlation of global quantities, i.e., normal and tangential hardness, at scratch testing in the context of a representative stress description was investigated. In particular, verification based on experimental results is at issue. I...

  • Article
  • Open Access
6 Citations
3,733 Views
10 Pages

13 March 2019

New technologies and materials with superior characteristics impel great development of functional devices in the terahertz field. The dynamically tunable plasmon-induced transparency (PIT) based on radiative–radiative-coupling in terahertz hybrid me...

  • Communication
  • Open Access
3 Citations
3,333 Views
10 Pages

13 March 2019

The management of irradiation defects is one of key challenges for structural materials in current and future reactor systems. To develop radiation tolerant alloys for service in extreme irradiation environments, the Fe self-ion radiation response of...

  • Article
  • Open Access
8 Citations
4,060 Views
13 Pages

Radio-, Thermo- and Photoluminescence Properties of Lu2O3:Eu and Lu2O3:Tb Nanopowder and Film Scintillators

  • P. Popielarski,
  • J. Zeler,
  • P. Bolek,
  • T. Zorenko,
  • K. Paprocki,
  • E. Zych and
  • Yu. Zorenko

13 March 2019

This work is dedicated to the preparation and characterization of the radio-, thermo-, and photoluminescent properties of Lu2O3:Eu and Lu2O3:Tb nanopowder (NPs) scintillators, prepared by means of hydrothermal processing, and their film analogues mad...

  • Article
  • Open Access
47 Citations
8,108 Views
19 Pages

On Crystal Mosaicity in Single Crystal Ni-Based Superalloys

  • Philipp Hallensleben,
  • Felicitas Scholz,
  • Pascal Thome,
  • Helge Schaar,
  • Ingo Steinbach,
  • Gunther Eggeler and
  • Jan Frenzel

13 March 2019

In the present work, we investigate the evolution of mosaicity during seeded Bridgman processing of technical Ni-based single crystal superalloys (SXs). For this purpose, we combine solidification experiments performed at different withdrawal rates b...

  • Article
  • Open Access
10 Citations
4,721 Views
13 Pages

Preparation of Few-Layer Graphene by Pulsed Discharge in Graphite Micro-Flake Suspension

  • Xin Gao,
  • Naoaki Yokota,
  • Hayato Oda,
  • Shigeru Tanaka,
  • Kazuyuki Hokamoto,
  • Pengwan Chen and
  • Meng Xu

13 March 2019

Few-layer graphene nanosheets were produced by pulsed discharge in graphite micro-flake suspension at room temperature. In this study, the discharging current and voltage data were recorded for the analysis of the pulsed discharge processes. The as-p...

  • Article
  • Open Access
5 Citations
3,926 Views
14 Pages

12 March 2019

α,ω-diperfluorohexylquaterthiophene (DFH-4T) has been an attractive n-type material employed in the development of high-mobility organic field-effect transistors. This paper presents a systematic study of the relationship between DFH-4T t...

  • Article
  • Open Access
12 Citations
5,016 Views
15 Pages

12 March 2019

The effect of cold rolling on the recrystallization behavior of Al-free and Al-added 15Cr-oxide dispersion strengthened (ODS) ferritic steels was investigated. The recrystallization of both steels are enhanced by cold rolling. The Al-free ODS steel w...

  • Article
  • Open Access
17 Citations
6,817 Views
14 Pages

10 March 2019

The time-dependence of electrochemical reduction current, which was observed during the one-dimensional (1-D) crystal growth of ferromagnetic cobalt nanowire arrays, was analyzed by Johnson–Mehl–Avrami–Kolmogorov (JMAK) theory. Text...

  • Article
  • Open Access
15 Citations
3,901 Views
11 Pages

10 March 2019

Many nanoparticle-based chiral liquid crystals are composed of polydisperse rod-shaped particles with considerable spread in size or shape, affecting the mesoscale chiral properties in, as yet, unknown ways. Using an algebraic interpretation of Onsag...

  • Article
  • Open Access
5 Citations
3,374 Views
10 Pages

8 March 2019

How many strong C−I⋯N halogen bonds can one 1,3,5-trifluoro-2,4,6-triiodobenzene molecule form in a crystal structure? To answer this question, we investigated in detail the noncovalent interactions between 1,3,5-trifluoro-2,4,6-triiodobenzene...

  • Article
  • Open Access
12 Citations
5,984 Views
10 Pages

A Light Guide Plate That Uses Asymmetric Intensity Distribution of Mini-LEDs for the Planar Illuminator

  • Zhi-Ting Ye,
  • Yung-Min Pai,
  • Cheng-Huan Chen,
  • Hao-Chung Kuo and
  • Lung-Chien Chen

8 March 2019

Traditional backlights are designed with new dot patterns, and then injection molding, laser beam fabrication, or UV (Ultraviolet) roll-to-plate imprinting is used to apply dot patterns to a light guide plate—the process consumes considerable t...

  • Article
  • Open Access
8 Citations
3,764 Views
9 Pages

7 March 2019

As the most promising materials for phase-change data storage, the pseudobinary mGeTe•nSb2Te3 (GST) chalcogenides have been widely investigated. Nevertheless, an in-depth understanding of the thermal-transport property of GST is still lacking, w...

  • Article
  • Open Access
13 Citations
4,828 Views
13 Pages

Photonic Topological States in a Two-Dimensional Gyrotropic Photonic Crystal

  • Xiao-Chen Sun,
  • Cheng He,
  • Xiao-Ping Liu,
  • Yi Zou,
  • Ming-Hui Lu,
  • Xiao Hu and
  • Yan-Feng Chen

7 March 2019

Time-reversal symmetry (TRS) of electrons is associated with an anti-unitary operator with T 2 = 1 , which induces Kramers degeneracy and plays an important role in realizing the quantum spin Hall effect (QSHE). By contrast, TRS of p...

  • Article
  • Open Access
1 Citations
2,377 Views
9 Pages

Investigation of Y2.1Er0.9(ScxGa1−x)5O12 Matrix Components on the Spectral Properties around 3.0 μm by Micro-Pulling-Down Method

  • Zhijiang Che,
  • Jian Zhang,
  • Baiyi Wu,
  • Qiangqiang Hu,
  • Wenxiang Mu,
  • Yanru Yin and
  • Zhitai Jia

7 March 2019

Single crystal fibers of 30% Er3+-doped compound of Y3(ScxGa1−x)5O12 have been grown by using the micro-pulling down (μ-PD) technique successfully. Our main purpose is to tune the fluorescence properties by adjusting the ratios of Sc3+ and G...

  • Article
  • Open Access
2 Citations
3,491 Views
11 Pages

Bird-Wing Optical-Reflector Design with Photocatalyst for Low-Glare Mosquito Trapping System with Light-Emitting Diodes

  • Wei-Hsiung Tseng,
  • Diana Juan,
  • Wei-Cheng Hsiao,
  • Yi Chian Chen,
  • Cheng-Han Chan,
  • Hsin-Yi Ma and
  • Hsiao-Yi Lee

7 March 2019

Dengue fever is the most serious vector-borne disease in Asia. There are still no dengue vaccines or therapeutic drugs, and vector-mosquito control is the main prevention and treatment method. The prevention and control of dengue-fever vector mosquit...

  • Article
  • Open Access
4 Citations
4,137 Views
6 Pages

Determination of Diffusion Coefficient of Copper in ZnO (001) Single Crystals at 1000 °C

  • Primavera López-Salazar,
  • Gabriel Juárez-Díaz,
  • Javier Martínez-Juárez,
  • José A. Luna-López,
  • Ramón Peña Sierra,
  • Yuri Koudriavtsev,
  • Carlos Palomino-Jiménez and
  • Angel. P. Rodríguez-Victoria

6 March 2019

Copper from a solid source was diffused into undoped n-type bulk ZnO (001) single crystals at 1000 °C under a nitrogen atmosphere at different diffusion times. The Cu diffusion profiles were obtained by Secondary ion mass spectroscopy (SIMS), and...

  • Article
  • Open Access
36 Citations
3,760 Views
14 Pages

6 March 2019

Four new series of laterally methyl-substituted hydrogen-bonded supramolecular complexes were prepared. The prepared complexes were thermally investigated by differential scanning calorimetry (DSC) and phases identified by polarized light microscopy...

  • Article
  • Open Access
9 Citations
4,292 Views
14 Pages

Optimal Sr-Doped Free TiO2@SrTiO3 Heterostructured Nanowire Arrays for High-Efficiency Self-Powered Photoelectrochemical UV Photodetector Applications

  • Shiming Ni,
  • Fengyun Guo,
  • Dongbo Wang,
  • Shujie Jiao,
  • Jinzhong Wang,
  • Yong Zhang,
  • Bao Wang and
  • Liancheng Zhao

6 March 2019

Due to their high performance, photoelectrochemical ultraviolet (UV) photodetectors have attracted much attention, but the recombination of photogenerated electrons at the interface of photoanode/electrolyte limited further improvement of photoelectr...

  • Article
  • Open Access
2,911 Views
13 Pages

Crystal Structure of a Cationic Bile Salt Derivative ([3β,5β,7α,12α]-3-(2-naphthyloylamino)-7,12-dihydroxycholan-24-triethylammonium iodide)

  • Francisco Meijide,
  • María Pilar Vázquez-Tato,
  • Julio A. Seijas,
  • Santiago de Frutos,
  • Juan V. Trillo Novo,
  • Victor H. Soto and
  • José Vázquez Tato

6 March 2019

The crystal structure of the iodide salt of a quaternary ammonium derivative of cholic acid having a naphthalene group attached to the 3rd position of the steroid nucleus through an amide bond ([3β,5β,7α,12α]-3-(2-naphthyloylamino)-7,12-dihydroxychol...

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Crystals - ISSN 2073-4352