Polysulfide plays an essential role in controlling various physiological activities in almost all organisms. We recently investigated the impact of polysulfide metabolic enzymes on the temporal dynamics of cellular polysulfide speciation and transcri...
Intracellular polysulfide could regulate the redox balance via its anti-oxidant activity. However, the existence of polysulfide in biological fluids still remains unknown. Recently, we developed a quantitative analytical method for polysulfide and di...
Lithium–sulfur batteries (LSBs), with a high energy density (2600
Lithium–sulfur battery (LSB) technology has tremendous prospects to substitute lithium-ion battery (LIB) technology due to its high energy density. However, the escaping of polysulfide intermediates (produced during the redox reaction process) from t...
Polysulfide-derived polymers with a controllable density and mechanical strength were designed and prepared successfully using bio-based cottonseed oil (CO) and its derivatives, including fatty acid of cottonseed oil (COF) and sodium soap of cottonse...
Excess sulfur has become a global problem in petrochemical industry. Inexpensive and easily available cottonseed oil (CSO) is still underutilized. To resolve these issues, bio-based polysulfide composites were prepared via inverse vulcanization of su...
Hydrogen sulfide (H2S) and inorganic polysulfides are important signaling molecules; however, little is known about their role in adipose tissue. We examined the effect of H2S and polysulfides on insulin sensitivity of the adipose tissue in rats. Pla...
The lithium-sulfur (Li-S) battery is one of the promising energy storage alternatives because of its high theoretical capacity and energy density. Factors governing the stability of polysulfide intermediates in Li-S batteries are complex and are stro...
Room-temperature sodium-sulfur batteries (RT-NaSBs) with high theoretical energy density and low cost are ideal candidates for next-generation stationary and large-scale energy storage. However, the dissolution of sodium polysulfide (NaPS) intermedia...
In this study, liquid polysulfide rubber was modified by silane coupling agent. New kinds of anti-corrosion coatings with salt spray resistance and strong adhesion to the steel substrate were obtained using the modified liquid polysulfide rubber, bim...
We have developed the continuous-flow synthesis of thioureas in a multicomponent reaction starting from isocyanides, amidines, or amines and sulfur. The aqueous polysulfide solution enabled the application of sulfur under homogeneous and mild conditi...
Li-S batteries still suffer from two of the major challenges: polysulfide shuttle and low inherent conductivity of sulfur. Here, we report a facile way to develop a bifunctional separator coated with fluorinated multiwalled carbon nanotubes. Mild flu...
In this study, the effects of curing temperature and curing time on the mechanical properties of polysulfide polymer concrete were investigated. For this purpose, several laboratory tests were conducted to measure the compressive, flexural, and bond...
Lithium–sulfur batteries are attractive candidates for next generation high energy applications, but more research works are needed to overcome their current challenges, namely: (a) the poor electronic conductivity of sulfur, and (b) the dissol...
The separators with high absorbability of polysulfides are essential for improving the electrochemical performance of lithium–sulfur (Li–S) batteries. Herein, the aramid fibers coated polyethylene (AF-PE) films are designed by roller coat...
Until 2021, experimental data on polysulfide groups in feldspathoids were limited to the properties of the S3•− chromophore center and the S2•− luminescence center in sodalite-group minerals. Interpretation of some spectroscopic...
Doxycycline (DOXY) is an antibiotic routinely prescribed in human and veterinary medicine for antibacterial treatment, but it has also numerous side effects that include oxidative stress, inflammation, cancer or hypoxia-induced injury. Endogenously p...
The potential involvement of polysulfide radical anions Sn•− is a recurring theme in discussions of the basic and applied chemistry of elemental sulfur. However, while the spectroscopic features for n = 2 and 3 are well-established, inform...
Though historically known as a toxic gas, hydrogen sulfide (H2S) has displayed a new face as the third endogenous gaseous signaling molecule after nitric oxide (NO) and carbon monoxide (CO). Here in this review, we survey the role and therapeutic pot...
There are many challenges for the Static lithium polysulfide semiliquid battery in its commercial application, such as poor stability of the cathode material and further amplification of the lithium polysulfide shuttle effect. Therefore, this manuscr...
We demonstrated the efficient coupling of BiFeO3 (BFO) ferroelectric material within the carbon–sulfur (C-S) composite cathode, where polysulfides are trapped in BFO mesh, reducing the polysulfide shuttle impact, and thus resulting in an improv...
Kinetic modeling and degradation study of liquid polysulfide (LPS)/clay nanocomposite is possible through Ozawa–Flynn–Wall (OFW) and Kissinger methods. Comparing the results of these models with experimental data leads to provide an accurate degradat...
To mitigate lithium dissolution and polysulfide shuttle effect phenomena in high-energy lithium sulfur batteries (LISBs), a conductive, flexible, and easily modified polymer composite layer was applied on the anode. The polymer composite layer includ...
Because of its considerable theoretical specific capacity and energy density, lithium–sulfur battery technology holds great potential to replace lithium-ion battery technology. However, a versatile, low-cost, and easily scalable bulk synthesis...
Li–S batteries are promising large-scale energy storage systems but currently suffer from performance issues; a major reason is the dissolution of polysulfides in electrolytes. To this end, we report a high-energy-density Lithium–Sulfur (...
Lithium-sulfur (Li-S) batteries are a promising option for energy storage due to their theoretical high energy density and the use of abundant, low-cost sulfur cathodes. Nevertheless, several obstacles remain, including the dissolution of lithium pol...
Although numerous research efforts have been made for the last two decades, the chronic problems of lithium-sulphur batteries (LSBs), i.e., polysulfide shuttling of active sulphur material and surface passivation of the lithium metal anode, still imp...
Lithium-sulfur (Li-S) batteries are regarded as one of the promising advanced energy storage systems due to their ultrahigh capacity and energy density. However, their practical applications are still hindered by the serious shuttle effect and sluggi...
Since the first description of hydrogen sulfide (H2S) as a toxic gas in 1713 by Bernardino Ramazzini, most studies on H2S have concentrated on its toxicity. In 1989, Warenycia et al. demonstrated the existence of endogenous H2S in the brain, suggesti...
The present article introduces a strategy for controlling oxidation and reduction reactions within polymer electrolyte membrane (PEM) networks as a means of enhancing storage capacity through the complexation of dissociated lithium cations with multi...
Metal–organic frameworks (MOFs) and their derivatives have emerged as promising candidates for separator engineering in lithium–sulfur batteries (LSBs). This is attributed to their structural tunability, high porosity, and chemical versat...
We have been studying the general aspects of the functions of H2S and polysulfides, and the enzymes involved in their biosynthesis, for more than 20 years. Our aim has been to elucidate novel physiological and pathological functions of H2S and polysu...
Two-dimensional metal-organic frameworks (MOFs) have shown great development po-tential in the field of lithium-sulfur (Li-S) batteries. In this theoretical research work, we propose a novel 3d transition metals (TM)-embedded rectangular tetracyanoqu...
Pathological examination of formalin-fixed paraffin-embedded (FFPE) needle-biopsied samples by certified pathologists represents the gold standard for differential diagnosis between ductal carcinoma in situ (DCIS) and invasive breast cancers (IBC), w...
Cystathionine γ-lyase (CSE) is an enzyme responsible for the biosynthesis of cysteine from cystathionine in the final step of the transsulfuration pathway. It also has β-lyase activity toward cystine, generating cysteine persulfide (Cys-SS...
Aqueous root extract from Acanthopanax senticosus (ASRE) has a wide range of medicinal effects. The present work was aimed at studying the influence of sulfide, cysteine and glutathione on the antioxidant properties of ASRE and some of its selected p...
For decades, reactive persulfide species including cysteine persulfide (CysSSH) have been known to exist endogenously in organisms. However, the physiological significance of endogenous persulfides remains poorly understood. That cystathionine β-synt...
Ischemia-reperfusion (I/R) injury refers to the exacerbation of tissue or organ damage upon the restoration of blood flow after an ischemic event. Despite its widespread clinical occurrence, therapeutic interventions for I/R injury remain limited in...
Improving the utilization efficiency of active materials and suppressing the dissolution of lithium polysulfides into the electrolyte are very critical for development of high-performance lithium-sulfur batteries. Herein, a novel strategy is proposed...
Lithium-sulfur batteries are anticipated to be the next generation of energy storage devices because of their high theoretical specific capacity. However, the polysulfide shuttle effect of lithium-sulfur batteries restricts their commercial applicati...
Hydrogen sulfide (H2S) and inorganic polysulfides are important signaling molecules; however, little is known about their role in the adipose tissue. We examined the effect of H2S and polysulfides on adipose tissue lipolysis. H2S and polysulfide prod...
Ionic liquids (ILs) based on hybrid anions have recently garnered attention as beguiling alternative electrolytes for energy storage devices. This attention stems from the potential of these asymmetric anions to reduce the melting point of ILs and im...
Protein tyrosine phosphatases (PTPs) can be regulated by several redox-dependent mechanisms and control growth factor-activated receptor tyrosine kinase phosphorylation cascades. Reversible oxidation of PTPs is counteracted by reductive enzymes, incl...
Non-aqueous redox flow batteries (NARFBs) using earth-abundant materials, such as sodium and sulfur, are promising long-duration energy storage technologies. NARFBs utilize organic solvents, which enable higher operating voltages and potentially high...
Polysulfides (H2Sx) represent a class of reactive sulfur species (RSS) which includes molecules such as H2S2, H2S3, H2S4, and H2S5, and whose presence and impact in biological systems, when compared to other sulfur compounds, has only recently attrac...
The Lithium sulfur (Li-S) battery has a great potential to replace lithium-ion batteries due to its high-energy density. However, the “shuttle effect” of polysulfide intermediates (Li2S8, Li2S6, Li2S4, etc.) from the cathode can lead to r...
Inhibiting the shuttle effect of soluble polysulfides and improving slow reaction kinetics are key factors for the future development of Li–S batteries. Herein, edelweiss shaped NiCo2O4 hollow nanospheres with a high surface area were prepared...
The development of long lifetime Li–S batteries requires new sulfur–carbon based composite materials that are able to suppress the shuttle effect—namely, the migration of soluble lithium polysulfides from the cathode to the anode of...
Background: Hydrogen sulfide (H2S) is an endogenous transmitter with the potential to regulate aqueous humor dynamics and protect retinal neurons from degeneration. The aim of the present study was two-fold: (a) to evaluate the release of H2S from tw...
Cisplatin, a widely used chemotherapy for the treatment of various tumors, is clinically limited due to its extensive nephrotoxicity. Inflammatory response in tubular cells is a driving force for cisplatin-induced nephrotoxicity. The plant-derived ag...
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