Search Results (414)

04Cr13Ni5Mo martensitic stainless steel is extremely sensitive to forging temperature and is prone to generating extremely large cracks, which leads to the failure of forging. Therefore, high-temperature tensile tests were performed on 04Cr13Ni5Mo martensitic stainless steel using a Gleeble-1500D thermo-mechanical simulator to investigate its damage mechanisms. The tests covered a temperature range of 950–1200 °C and strain rates of 0.001–1 s⁻¹. The high-temperature damage behavior and tissue evolution law at high temperatures were studied by means of EBSD, TEM, etc. Secondly, two high-temperature damage models of 04Cr13Ni5Mo, namely Normalized Cockcroft and Latham (NCL) and Oyane, were established by combining optimization algorithm and finite element simulation. Then, the two high-temperature damage models were integrated into the Forge^®NxT 3.2 finite element software. Simulated thermal tensile tests were conducted on 04Cr13Ni5Mo at temperatures from 950 to 1200 °C, strain rates from 0.001 to 1 s⁻¹. A comparison was made between the predicted and experimentally measured fracture displacements of the tensile specimens. The calculated correlation coefficients (R) were 0.995 and 0.991, respectively. It was determined that the NCL model has better simulation accuracy for predicting the forging cracks of 04Cr13Ni5Mo. The reliability of the finite element method for predicting forging crack defects in 04Cr13Ni5Mo forgings was established. Full article

Carburizing is a cost-effective surface hardening process that significantly enhances the strength of components and is widely used in critical parts such as main transmission gears and cams. However, research on mathematical models for characterizing the strength of carburized layers remains underdeveloped, limiting the accurate assessment of the service strength of carburized workpieces. To address this issue, this study focuses on 20CrNiMo steel and proposes a novel composite strength method for the quantitative prediction of the tensile strength of carburized specimens. By establishing a continuous mapping function between microhardness measurements and tensile strength distribution, and developing an equivalent strength mathematical model for non-uniform carburized gradient structures, the proposed method successfully predicts the strength of specimens under different carburizing depths. This approach represents a departure from the conventional Voigt-based paradigm, which relies on layered discretization of the carburized zone for approximate estimation, leading to significant improvements in both predictive efficiency and accuracy. Based on experimental data, the proposed method achieves a reduction in prediction errors of over 41.8% compared to traditional multilayer methods. In summary, this study not only provides a reliable and efficient computational tool for the quantitative characterization of carburized steels, but also demonstrates strong potential for application in the strength assessment and design optimization of critical engineering components. Full article

Enhancing the surface mechanical properties and extending the service life of 45CrNiMoV mold steel are critical goals in mold development. To achieve these objectives, electron beam (EB) irradiation was employed to treat the 45CrNiMoV mold steel. This high-energy physical process enables precise modification of the surface microstructure. By meticulously controlling EB parameters, including energy, dose, and scanning mode, significant structural alterations occur in the surface layer. Consequently, the surface microhardness more than doubles, reaching 812.7 HV. This enhancement is attributed to grain refinement, increased dislocation density, and potential formation of new phases induced by EB irradiation. Beyond hardness improvement, the wear resistance of the treated specimen increases by 2.5-fold. Under standardized testing conditions, wear loss decreases markedly from 0.28 mg to 0.11 mg. This reduction in wear loss not only extends the mold’s operational lifespan but also minimizes maintenance and replacement requirements, thereby reducing production downtime and associated costs. This study transcends mere presentation of experimental data by comprehensively elucidating the intricate relationship between surface microstructure and the overall mechanical properties of 45CrNiMoV mold steel. Advanced characterization techniques, including scanning electron microscopy (SEM) and X-ray diffraction (XRD), were utilized to uncover the underlying mechanisms. The refined microstructure, characterized by fine grains and elevated dislocation density, impedes dislocation movement and crack propagation, thereby enhancing both hardness and wear resistance. Full article

Nickel–tungsten carbide (Ni/WC) multi-pass fused cladding layers with different cerium (IV) oxide (CeO₂) contents were applied to Cr12MoV cold work tool steel surfaces using the coaxial powder feeding method for laser cladding. Scanning electron microscopy, energy spectrum analysis, X-ray diffraction, and wear experiments were conducted to study how adding CeO₂ to change the properties of WC-reinforced Ni-base composite coatings in turn alters the microstructure and properties of Cr12MoV cold work tool steel. The results show that laser cladding is effective when the process parameters are as follows: a power of 1500 W, a 24 mm defocusing distance, a 6 mm/s scanning speed, a 5 mm spot diameter, and a powder delivery of 0.1 g/s. Laser-fused cladding coatings are mainly composed of dendrites, crystalline cells, strips, and bulk microstructures. The addition of CeO₂ is effective at improving the microstructure and morphology of the coating—the size and distribution of the reinforcing phase change very significantly, and the shape changes from irregular and lumpy to spherical. With a 2% CeO₂ content, the enhanced phase, now spherical and white, is more diffusely distributed in the tissue. The maximum microhardness of the composite-coated specimen after the addition of CeO₂ is about 986 HV, which is approximately 20% higher than the hardness of the composite coating with no CeO₂ added. Full article

In addition to the minerals naturally present in grapes, wine can acquire additional minerals during its production and storage from materials that come into contact with it, including bottling materials. This study aimed to evaluate the concentration of a wide range of elements in white wine samples packaged in 0.75 L green glass bottles sealed with two different closure systems: natural cork stoppers and metal screw caps with a plastic liner. No statistically significant differences were observed between the two closure types for most elements (Li, Be, Fe, Co, Ni, Zn, Se, Rb, Sr, Mo, Sb, Cs, Ba, and Tl). For V, Cr, Mn, Cu, As, Cd, and Pb, some differences were observed, but without a clear pattern. However, the concentration of Sn was significantly higher in wines packaged in bottles sealed with metal screw caps plus plastic liner. Elemental analysis of the original, unused liners showed negligible content of Sn and other studied elements, suggesting that the Sn in the wine comes from the Sn-plated steel screw cap, despite the presence of the plastic liner. Although the changes in the natural elemental composition under these bottling conditions are not very high and unlikely to pose a health risk to consumers, they may still influence wine stability and sensory attributes. Understanding these effects is important for both wine producers and consumers to ensure optimal wine quality and preservation. Full article

Deep cryogenic treatment (DC) is widely applied to martensitic stainless steels to suppress the presence of metastable retained austenite (RA), which may otherwise transform into brittle martensite under deformation and degrade mechanical performance. In this study, a low-carbon 13Cr-2Ni-2Mo martensitic stainless steel was subjected to deep cryogenic treatment for 2 h, followed by tempering at 200–600 °C to investigate carbide evolution and its correlation with mechanical response. At 200 °C, undissolved M₂₃C₆ was observed, accompanied by an RA volume fraction of 8.43% which exhibited a hardness of 543.3 ± 5.1 Hv. When tempered at 400 °C, M₃C became predominant, corresponding to a hardness of 524.5 ± 5.1 Hv. At 500 °C, the simultaneous precipitation of M₃C, M₇C₃, and M₂₃C₆ carbides induced pronounced secondary hardening, which promoted the peak hardness of 559 ± 5.6 Hv. Further tempering at 600 °C resulted in carbide spheroidization M₂₃C₆, which resulted in a hardness reduction to 392.2 ± 3.9 Hv while enhancing ductility. These findings reveal that the tempering temperature plays a decisive role in controlling the carbide precipitation sequence and the stability of retained austenite, thereby enabling the design of an optimal strength–ductility balance in deep cryogenically treated martensitic stainless steels. Full article

This study reviews and experimentally investigates critical logistics and transport models in stainless-steel (SS) fluid storage tanks, focusing on stainless steel grades 316 and 304L. Conceptual vessel schematics emphasize hygienic drainability, refill uniformity, and thermal control, supported by representative 316L properties for heat-transfer, stress, and fluid–structure analyses. At the logistics scale, modelling integrates component-level simulations, computational fluid dynamics (CFD), and Finite Element Method (FEM) with network-level approaches, such as Continuous Approximation, to address facility location, refilling schedules, and demand variability. Experimental characterization using EDS and XRF confirmed the expected Cr/Ni backbone and grade-consistent Mo in 316, while unexpected C, Mn, and Cu readings were attributed to instrumental limits or statistical variance. Unexpected detection of Europium in 304L highlights the need for further mechanical testing. Overall, combining simulation, logistics modelling, and compositional verification offers a coherent framework for safe, efficient, and thermally reliable stainless-steel tank design. Full article

Temperature and strain rate play a crucial role in determining the mechanical properties of metals. These critical parameters are typically assessed using the split Hopkinson pressure bar (SHPB) test. However, previous studies have seldom considered the coupled influence of temperature and strain rate on dynamic mechanical behavior, thereby reducing the accuracy of constitutive models. To accurately characterize the dynamic mechanical behavior of 34CrNi3MoA low-alloy steel, a new constitutive model combining temperature and strain rate was developed. Firstly, SHPB experiments under varying temperatures and strain rates were designed to obtain actual stress–strain curves. The results indicate that the mechanical properties of 34CrNi3MoA low-alloy steel are significantly influenced by both temperature and strain rate. True stress has a significant temperature-softening effect within the temperature range of 25 °C to 600 °C, while the flow stress in the yield stage increases with rising strain rate. Secondly, a novel constitutive model was established by integrating a correction function. The model comprises three components: a strain rate-strengthening function influenced by temperature, a temperature-softening function influenced by strain rate, and a strain-hardening correction function accounting for the coupling of temperature and strain rate. Comparing the mean relative error, the new model significantly improves accuracy compared to the original Johnson–Cook (J-C) model. Full article

To address the synergistic degradation mechanisms in engineering service environments, we propose a boron microalloying strategy to enhance the multifunctional surface performance of AlCoCrFeNiMo-based high-entropy alloys. AlCoCrFeNiMoTiBx coatings (x = 0, 0.5, 1, and 1.5) were fabricated on Q235 steel substrates using laser cladding. The microstructure of the coatings was characterized using scanning electron microscope (SEM) and energy dispersive spectrometer (EDS), while their wear and corrosion resistance were evaluated through tribological and electrochemical tests. The key findings indicate that boron addition preserves the original body-centered cubic (BCC) and σ phases in the coating while promoting the in situ formation of TiB₂, leading to lattice distortion. With increasing B content, the BCC phase becomes refined, and both the fraction and size of TiB₂ particles increase. Boron incorporation improves the coating’s microhardness and wear resistance, with the highest wear resistance achieved at x = 1, where abrasive and oxidative wear predominate. At lower content (x = 0.5), B enhances the stability of the passive film and thereby improves corrosion resistance. In contrast, excessive formation of large TiB₂ particles introduces defects into the passive film, accelerating its degradation. Full article

This study utilizes the Standard k-ε turbulence model and ANSYS CFX software to tackle silt erosion in the top cover clearances of guide vane of the Francis turbine at Genda Power Station (Minjiang River Basin section, 103°17′ E and 31°06′ N) under sediment-laden flow conditions. A numerical simulation of a solid–liquid two-phase flow along the whole flow route was performed under rated operating circumstances to examine the impact of varying guide vane end clearance heights (0.3 mm, 0.5 mm, and 1.0 mm) on internal flow patterns and sediment erosion characteristics. The simulation parameters employed an average sediment concentration of 2.9 kg/m³ and a median particle size of 0.058 mm, indicative of the flood season. The findings demonstrate that augmenting the clearance height intensifies leaky flow and secondary flow, resulting in a 0.49% reduction in efficiency. As the gap expanded from 0.3 mm to 1.0 mm, the leakage flow velocity notably increased to 40 m/s, exacerbating flow separation, enlarging the vortex structures in the vaneless space, and augmenting the sediment velocity gradient and concentration, consequently heightening the risk of erosion. An experimental setup was devised based on the numerical results, and the dynamic resemblance between the constructed test section and the prototype turbine was confirmed for flow velocity, concentration, and Reynolds number. Tests on sediment erosion revealed that the erosion resistance of the anti-sediment erosion material 04Cr13Ni5Mo markedly exceeded that of the base cast steel, especially in high-velocity areas. This study delivers a systematic, quantitative analysis of clearance effects on flow and erosion, along with an experimental wear model specifically for the Gengda Power Station, thereby providing direct theoretical support and engineering guidance for its wear protection strategy and maintenance planning. Full article

Recent literature reports have shown that individual HEAs, especially those of the AlCoCrFeNi composition system alloyed with appropriately selected elements, exhibit excellent mechanical properties and corrosion resistance, making them promising candidates for replacing conventional materials such as austenitic steels in corrosive environments. Therefore, in the present study, the high-entropy alloy AlCoCrFeNiMo_0.25 was examined and compared with AISI 304L steel and the reference alloy AlCoCrFeNi. The HEA was produced by arc melting in vacuum. The effect of molybdenum addition (5% at.) on the structure, mechanical properties, and corrosion resistance was evaluated. Potentiodynamic polarization and electrochemical impedance spectroscopy tests were carried out in a 3.5% NaCl solution in a three-electrode electrochemical system. The addition of molybdenum to AlCoCrFeNiMo_x alloy additionally caused, along with the BCC phase, the formation of σ phase and FCC phase (less than 1%), as well as changes in the microstructure, leading to the fragmentation of grains and the formation of a mosaic structure. On the basis of nanoindentation tests, it was established that the addition of Mo increases hardness and elastic modulus and improves nanoindentation coefficients H/E and H³/E², as well as an increase in the elastic recovery index while decreasing plasticity index (vs. the reference equiatomic HEA). This indicates the improvement of anti-wear properties with impact loading resistance. In turn, electrochemical tests have shown that the addition of Mo improves corrosion resistance. Corrosion pitting develops in Al- and Ni-rich areas of HEA alloys, as a result of galvanic microcorrosion related to Cr chemical segregation. In general, the addition of 5% Mo results in a fine-grained mosaic structure, which primarily translates into favorable nanoindentation and corrosion properties of the AlCoCrFeNiMo_0.25 alloy. Full article

The increase in electrification and desire for greater electrical motor efficiency under a range of operating conditions for different products (e.g., household appliances, automotive and aerospace) is driving innovative motor designs and demands for higher performing electrical steels. Improvements in the magnetic, electrical and/or mechanical properties of electrical steels are required for high-volume electric motors and recent advances include steels with increased silicon (Si) content (from <3.5 wt% Si up to 6.5 wt%). Whilst the 6.5 wt% Si steels provide increased motor performance at high frequencies, the formation of a brittle BCC B2/D03 phase means that they cannot be cold-rolled, and therefore the production route involves siliconization after the required thickness strip is produced. The advances in computationally driven alloy design, coupled with physical metallurgical understanding, allow for more adventurous alloy design for electrical steels, outside the traditional predominantly Fe-Si compositional space. Two alloys representing a new alloy family called HiPPES (High-Performing and Processable Electrical Steel), based on low cost commonly used steel alloying elements, have been developed, cast, rolled, heat-treated, and both magnetically and mechanically tested. These alloys (with nominal compositions of Fe-3.2Mn-3.61Si-0.63Ni-0.75Cr-0.15Al-0.4Mo and Fe-2Mn-4.5Si-0.4Ni-0.75Cr-0.09Al) offer improvements compared to current ≈3 wt% Si grades: in magnetic performance (>25% magnetic loss reduction at >1 kHz), and in tensile strength (>33% increase in tensile strength with similar elongation value). Most importantly, they are maintaining processability to allow for full-scale commercial production using traditional continuous casting, hot and cold rolling, and annealing. The new alloys also showed improved resilience to grain size, with the HiPPES materials showing a <5% variance in loss at frequencies greater than 400 Hz for grain sizes between 55 and 180 µm. Comparatively, a commercial M250-35A material showed a 40% increase in loss for the same range. The paper reports on the alloy design approach used, the microstructures, and the mechanical, electrical and magnetic properties of the developed novel electrical steels compared to conventional ≈3 wt% Si and 6.5 wt% Si material. Full article

With the rapid development of mechanical components, increasingly stringent demands are placed on steel properties—particularly tensile strength and rotating bending fatigue resistance. This study systematically investigates the effects of the electropulsing-assisted ultrasonic surface rolling process (EUSRP) on the surface microstructure and fatigue performance of 30CrNi2Mo steel. A fine-grained surface layer (depth: 80 μm) was formed. Lath martensite width decreased significantly from 7 μm to 4 μm after EUSRP treatment, which was significantly refined after electropulsing treatment and an ultrasonic surface-rolling process. Under identical stress amplitudes, the rotating bending fatigue life of EUSRP-treated specimens substantially exceeded that of the as-machined state. Fatigue cracks in the as-machined state consistently initiated at the surface, coalesced, and propagated into large cracks, leading to premature fracture. In EUSRP-treated samples, crack initiation shifted to subsurface regions, delaying failure and extending fatigue life. Full article

The study investigates the influence of post-weld heat treatment (PWHT) on the microstructure and hardness of hardfacing layers applied to hot forging tools. The research focuses on three tool steels (55NiCrMoV7, X37CrMoV5-1, and a modified X38CrMoV5-3) and uses robotized gas metal arc welding (GMAW) with DO015 filler material. It examines the structural and mechanical differences in the hardfaced layers before and after heat treatment involving quenching and tempering. The findings reveal that PWHT significantly improves microstructural homogeneity and hardness distribution, especially in the heat-affected zone (HAZ), mitigating the risk of crack initiation and tool failure. The study shows that untempered as-welded layers exhibit microstructural inhomogeneity and extreme hardness gradients, which negatively impact tool durability. PWHT leads to tempered martensite formation, grain refinement, and a more stable hardness profile across the joint. These improvements are critical for extending the service life of forging tools. The results underscore the importance of customizing PWHT parameters according to the specific material and application to optimize tool performance. Full article

The induction quenching–tempering process typically enhances the surface strength and core toughness of alloy steels by utilizing the skin effect. However, the impact of parameters like quenching current and heating time on the microstructure and mechanical property of 34CrNiMo6 steel crankshafts remains unclear. In this work, the microstructure of 34CrNiMo6 steel after induction quenching exhibits three distinct zones: a martensite hardened layer; a transition zone of martensite and tempered sorbite; and a matrix of tempered sorbite. As the induction current (400, 500, and 600 mA) and heating time (3, 5, and 7 s) increase, the hardened layer thickness enhances (up to 3.21 mm). Under the 600 mA and 7 s, the hardened layer reaches peak hardness and residual stress values of 521.48 HV and −330.12 MPa, showing a decreasing trend from surface to core. After tempering at 330 °C for 2 h, the hardened layer mainly consists of tempered martensite, and the surface hardness and residual stress decrease to 417.94 HV and −12.33 MPa. The temperature gradient from quenching balances after tempering, with martensitic phase transformation and stress redistribution reducing hardness and residual stress. Furthermore, the induction quenching–tempering process enhances the toughness of 34CrNiMo6 steel when compared to the untreated specimen, boosting its tensile yield strength, elongation, and tensile strength by 15.3%, 14.9%, and 19.5%, respectively. This work deepens the understanding of induction quenching–tempering process and provides valuable insights for designing alloy steels with excellent mechanical properties. Full article