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Crystals, Volume 13, Issue 2

2023 February - 212 articles

Cover Story: Crystallization of struvite (MgNH4PO4·6H2O) to recover both N and P from municipal wastewater is challenging because of the need for low-cost magnesium sources. The required concentration of magnesium was provided by Mg(OH)2 (brucite)-obtained magnesite ore. The apparent order for the precipitation suggested that the dominant mechanism was surface diffusion, according to the polynuclear model. Brucite used in the form of slurry, as a magnesium source, gave significantly faster struvite precipitation in comparison with brucite-equilibrated solution. Simulated wastewater (SWW) inoculated with brucite crystals yielded an apparent rate constant for precipitation two orders of magnitude higher than the corresponding with solution equilibrated with brucite. P recovery from SWW reached 70%. View this paper
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Articles (212)

  • Feature Paper
  • Article
  • Open Access
10 Citations
3,580 Views
12 Pages

Micro-Nanoarchitectonics of Ga2O3/GaN Core-Shell Rod Arrays for High-Performance Broadband Ultraviolet Photodetection

  • Ruifan Tang,
  • Guanqi Li,
  • Xun Hu,
  • Na Gao,
  • Jinchai Li,
  • Kai Huang,
  • Junyong Kang and
  • Rong Zhang

20 February 2023

This study presents broadband ultraviolet photodetectors (BUV PDs) based on Ga2O3/GaN core-shell micro-nanorod arrays with excellent performance. Micro-Nanoarchitectonics of Ga2O3/GaN core-shell rod arrays were fabricated with high-temperature oxidiz...

  • Article
  • Open Access
2 Citations
2,320 Views
14 Pages

20 February 2023

The fracture and crack growth of materials can be practically and conveniently predicted through numerical analysis and linear elastics fracture mechanics. On this basis, the current study aims to present experimental work supported by a numerical te...

  • Article
  • Open Access
16 Citations
2,628 Views
15 Pages

Structural and Spectroscopic Effects of Li+ Substitution for Na+ in LixNa1−xCaLa0.5Er0.05Yb0.45(MoO4)3 Upconversion Scheelite-Type Phosphors

  • Chang Sung Lim,
  • Aleksandr Aleksandrovsky,
  • Maxim Molokeev,
  • Aleksandr Oreshonkov and
  • Victor Atuchin

20 February 2023

New triple molybdates LixNa1−xCaLa0.5(MoO4)3:Er3+0.05/Yb3+0.45 (x = 0, 0.05, 0.1, 0.2, 0.3) were manufactured successfully using the microwave-assisted sol-gel-based technique (MAS). Their room-temperature crystal structures were determined in...

  • Article
  • Open Access
13 Citations
2,399 Views
13 Pages

The Effect of Instability of KCl:Na Single Crystals

  • Kuanyshbek Shunkeyev,
  • Aizhan Tilep,
  • Shynar Sagimbayeva,
  • Zhiger Ubaev and
  • Aleksandr Lushchik

20 February 2023

For the first time, the stability of KCl single crystals doped with sodium impurity ions was analyzed via the optical absorption and luminescence methods. Using the characteristic bands of optical absorption, as well as of X-ray and tunnel luminescen...

  • Article
  • Open Access
9 Citations
3,648 Views
11 Pages

20 February 2023

Plasmonic hydrogen gas sensors have become widely used in recent years due to their low cost, reliability, safety, and measurement accuracy. In this paper, we designed, optimized, and fabricated a palladium (Pd)-coated nano-grating-based plasmonic hy...

  • Article
  • Open Access
11 Citations
3,279 Views
14 Pages

Effect of Few-Layer Graphene on the Properties of Mixed Polyolefin Waste Stream

  • S. M. Nourin Sultana,
  • Emna Helal,
  • Giovanna Gutiérrez,
  • Eric David,
  • Nima Moghimian and
  • Nicole R. Demarquette

19 February 2023

This work demonstrates how the addition of few-layer graphene (FLG) influences the processability and mechanical properties of the mixed polyolefin waste stream (R-(PE/PP)). Three different types of compounds were investigated: (1) R-(PE/PP) with FLG...

  • Article
  • Open Access
6 Citations
5,218 Views
14 Pages

19 February 2023

In this paper, a compact design and new structure of bowtie antenna with dual-band characteristics for the 5G and public safety bands in intelligent transport systems (ITS) is presented. The antenna consists of a double-sided bowtie radiating patch w...

  • Article
  • Open Access
2 Citations
3,145 Views
15 Pages

Predicting the Level of Background Current Noise in Graphene Biosensor through a Non-Covalent Functionalization Process

  • Chao-yi Zhu,
  • Zi-hong Lin,
  • Da-yong Zhang,
  • Jing-yuan Shi,
  • Song-ang Peng and
  • Zhi Jin

19 February 2023

The rapid worldwide spread of the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) has created a series of problems. Detection platforms based on graphene field-effect transistors (GFETs) have been proposed to achieve a rapid diagnosis of...

  • Article
  • Open Access
17 Citations
6,328 Views
20 Pages

Influence of Grain Size on Mechanical Properties of a Refractory High Entropy Alloy under Uniaxial Tension

  • Orlando Deluigi,
  • Felipe Valencia,
  • Diego R. Tramontina,
  • Nicolás Amigo,
  • Javier Rojas-Nunez and
  • Eduardo M. Bringa

19 February 2023

There is a growing interest in High Entropy Alloys (HEAs) due to their outstanding mechanical properties. Most simulation studies have focused on face-centered cubic (fcc) HEAs; however, bcc HEAs can offer a larger elastic modulus and plastic yieldin...

  • Article
  • Open Access
3 Citations
3,572 Views
12 Pages

19 February 2023

Titanium oxyfluoride (TiOF2) is a metastable product that can be obtained in a fluorine-rich environment. This material can also be a valuable precursor in the synthesis of titanium(IV) oxide (TiO2). However, the effect of TiOF2 morphology on the phy...

  • Article
  • Open Access
5 Citations
2,913 Views
17 Pages

In Situ Observation of Retained Austenite Transformation in Low-Carbon Micro-Alloyed Q&P Steels

  • Xiaoyu Ye,
  • Haoqing Zheng,
  • Gongting Zhang,
  • Zhiyuan Chang,
  • Zhiwang Zheng,
  • Zhenyi Huang,
  • Xiuhua Gao and
  • Guanqiao Su

18 February 2023

Retained austenite (RA) transformation and its role in the mechanical properties of three low-carbon micro-alloyed quenching and partitioning (Q&P) steels was investigated utilizing in situ tensile tests and electron microscopy. Meanwhile, RA&rsq...

  • Article
  • Open Access
2,327 Views
13 Pages

Ion-Beam Synthesis of Structure-Oriented Iron Nanoparticles in Single-Crystalline Rutile TiO2

  • Iskander R. Vakhitov,
  • Nikolay M. Lyadov,
  • Vladimir I. Vdovin,
  • Anton K. Gutakovskii,
  • Vladimir I. Nuzhdin,
  • Lenar R. Tagirov and
  • Rustam I. Khaibullin

18 February 2023

Magnetic nanoparticles embedded into semiconductors have current perspectives for use in semiconducting spintronics. In this work, 40 keV Fe+ ions were implanted in high fluences of (0.5 ÷ 1.5) × 1017 ion/cm2 into an oxide semiconductor...

  • Article
  • Open Access
31 Citations
3,743 Views
17 Pages

18 February 2023

The aim of the current work is to investigate the effect of SiC particle weight percent and rolling passes on Al/Cu/SiC laminated composites, fabricated by accumulative roll-bonding (ARB) and cross-accumulative roll-bonding (CARB) processes. The opti...

  • Feature Paper
  • Article
  • Open Access
6 Citations
3,016 Views
15 Pages

Dependence of Charpy Impact Properties of Fe-30Mn-0.05C Steel on Microstructure

  • Jianchao Xiong,
  • Heng Li,
  • Ling Kong,
  • Xiaodan Zhang,
  • Wenquan Cao and
  • Yuhui Wang

18 February 2023

Fe-30Mn-0.05C steel specimens with cold-rolled, partially recrystallized, fine-grained, and coarse-grained microstructures were fabricated by means of 80% cold rolling followed by annealing at 550–1000 °C. The initial and deformed microstru...

  • Feature Paper
  • Article
  • Open Access
5 Citations
2,878 Views
12 Pages

Textile Functionalization by Porous Protein Crystal Conjugation and Guest Molecule Loading

  • Luke F. Hartje,
  • David A. Andales,
  • Lucas P. Gintner,
  • Lucas B. Johnson,
  • Yan V. Li and
  • Christopher D. Snow

18 February 2023

Protein crystals are versatile nanostructured materials that can be readily engineered for applications in nanomedicine and nanobiotechnology. Despite their versatility, the small size of typical individual protein crystals (less than one cubic mm) p...

  • Article
  • Open Access
4 Citations
2,997 Views
17 Pages

Effect of Mn+2 Doping and Vacancy on the Ferromagnetic Cubic 3C-SiC Structure Using First Principles Calculations

  • Najib M. Sultan,
  • Thar M. Badri Albarody,
  • Kingsley Onyebuchi Obodo and
  • Masri B. Baharom

17 February 2023

Wide bandgap semiconductors doped with transition metals are attracting significant attention in the fabrication of dilute magnetic semiconductor devices (DMSs). The working principle of DMSs is based on the manipulation of the electron spin, which i...

  • Article
  • Open Access
14 Citations
3,335 Views
12 Pages

First-Principles Study of the Structural, Mechanical and Thermodynamic Properties of Al11RE3 in Aluminum Alloys

  • Touwen Fan,
  • Lan Lin,
  • Houjiang Liang,
  • Yuhong Ma,
  • Yuwei Tang,
  • Te Hu,
  • Zixiong Ruan,
  • Dongchu Chen and
  • Yuanzhi Wu

17 February 2023

The stability and mechanical and thermodynamic properties of Al11RE3 intermetallics (RE = Sc, Y and lanthanide La-Lu) have been investigated by combining first-principles and Debye model calculations. It was found that the formation enthalpies of the...

  • Article
  • Open Access
1,879 Views
9 Pages

17 February 2023

The reaction of the Ni/X interfaces (X = Si or Cr) with O2+ ions at low energy (3 keV) was studied using X-ray photoelectron spectroscopy (XPS) and factor analysis (FA). It was found that low ion doses lead to the formation of a NiO thin film on the...

  • Article
  • Open Access
1 Citations
2,360 Views
14 Pages

Synthesis, Supramolecular Structural Investigations of Co(II) and Cu(II) Azido Complexes with Pyridine-Type Ligands

  • Mezna Saleh Altowyan,
  • Jörg H. Albering,
  • Assem Barakat,
  • Saied M. Soliman and
  • Morsy A. M. Abu-Youssef

17 February 2023

Two new Co(II) and Cu(II) azido complexes with 4-picoline (4-Pic) and pyridine-2-carboxaldoxime (HAld) were synthesized by self-assembly of the organic ligand and the M(II) nitrate in the presence of azide as a co-ligand. Their structures were determ...

  • Review
  • Open Access
5 Citations
4,766 Views
17 Pages

Microstructural, Mechanical, and Corrosion Properties of AZXX Magnesium Alloy: A Review of Processing Methods

  • Shalu Pargavi B.,
  • Todkar Utkarsh Dhanaji,
  • Sejal Dassani,
  • M. Somasundaram,
  • A. Muthuchamy and
  • A. Raja Annamalai

17 February 2023

Magnesium (Mg) and its alloys are considered an ideal material for aerospace, medical, energy, and automotive purposes, because of their low density and high specific strength. Researchers are interested in AZ alloys because of their superior flow ch...

  • Article
  • Open Access
4 Citations
3,534 Views
15 Pages

17 February 2023

Two Ni(II) complexes with the formula [{Ni(dppf)}2{(L1)2}](PF6)2 (Ni-I) and [{Ni(dppe)}2{(L1)2}](PF6)2 (Ni-II) were prepared by reacting [Ni(dppf)Cl2] and [Ni(dppe)Cl2] (dppf = 1,1′-Bis-(diphenylphosphino)ferrocene; dppe = 1,2-Bis-(diphenylphos...

  • Article
  • Open Access
2,424 Views
10 Pages

Hydrogen Bond-Directed Self-Assembly of a Novel Pyrene Derivative

  • Yang Yu,
  • Yuzhen Zhao,
  • Yongsheng Mi,
  • Fengmei Fang,
  • Huimin Zhang,
  • Zhun Guo,
  • Yang Zhao and
  • Dong Wang

17 February 2023

A symmetrical pyrene derivative chemical structure was prepared by a classical synthetic method such as the Sonogashira cross-coupling reaction. The molecular structure of the product was characterised in detail by nuclear magnetic resonance (NMR), m...

  • Article
  • Open Access
13 Citations
3,290 Views
10 Pages

N-Heterocyclic Carbene–Palladium Functionalized Coordination Polymer (Pd-NHC@Eu-BCI) as an Efficient Heterogeneous Catalyst in the Suzuki–Miyaura Coupling Reaction

  • Lixin You,
  • Rui Tan,
  • Xiaojuan Wang,
  • Jianhong Hao,
  • Shiyu Xie,
  • Gang Xiong,
  • Fu Ding,
  • Andrei S. Potapov and
  • Yaguang Sun

17 February 2023

In the present work, a new heterogeneous catalyst Pd-NHC@Eu-BCI was synthesized by introducing N-heterocyclic carbene–palladium active sites into a 2D coordination polymer [Eu(BCI)(NO3)2H2O]n (Eu-BCI) based on a 1,3-bis(carboxymethyl)imidazoliu...

  • Article
  • Open Access
10 Citations
2,922 Views
18 Pages

The Fabrication of Gold–Silver Bimetallic Colloids by Microplasma: A Worthwhile Strategy for Counteracting the Surface Activity of Avian Influenza Virus

  • Muhammad Zubair,
  • Muhammad Shahid Rafique,
  • Afshan Khalid,
  • Tahir Yaqub,
  • Muhammad Furqan Shahid,
  • Suliman Yousef Alomar and
  • Muhammad Ali Shar

16 February 2023

In the present project, fructose-stabilized gold, silver and gold–silver bimetallic colloids have been synthesized by the electrochemical reduction of HAuCl4·3H2O (Au precursor) and AgNO3 (Ag precursor), employing the atmospheric pressur...

  • Article
  • Open Access
4 Citations
2,922 Views
13 Pages

16 February 2023

In this paper, the chemical composition and spectroscopy of 38 violet-red to orange-red spinel samples were analyzed by energy dispersive X-ray fluorescence spectrometer and UV-visible spectrophotometer, based on CIE LAB color space, to explore the e...

  • Editorial
  • Open Access
2 Citations
2,792 Views
4 Pages

Novel ZnO-Based Nanostructures: Synthesis, Characterization and Applications

  • Yamin Leprince-Wang,
  • Guangyin Jing and
  • Basma El Zein

16 February 2023

The Special Issue “Novel ZnO-Based Nanostructures: Synthesis, Characterization and Applications” is a collection of 13 papers, including 3 review papers and 10 original articles dedicated to both experimental research works and numerical...

  • Article
  • Open Access
2 Citations
4,831 Views
12 Pages

Study of Flow Pattern Defects and Oxidation Induced Stacking Faults in Czochralski Single-Crystal Silicon Growth

  • Chao-Chun Yen,
  • Anoop Kumar Singh,
  • Yi-Min Chung,
  • Hsin-Yu Chou and
  • Dong-Sing Wuu

16 February 2023

This paper emphasizes that the furnace pressure, crucible rotation, and pulling rate have important effects on interstitial oxygen (Oi) concentrations and micro-defects during growth in a Czochralski single-crystal silicon (CZ-Si) growth furnace. Sin...

  • Article
  • Open Access
1 Citations
2,917 Views
12 Pages

16 February 2023

Single-crystal X-ray structure determinations are reported for four lanthanide complexes, [Dy(bipy)2Cl2(OH2)2]Cl.H2O (bipy = 2,2′-bipyridine), 1; [La2(phen)2(O2CCH3)4(NO3)2] (phen = 1,10-phenanthroline), 2; [Lu(terpy)(O2CCH3)3].NaNO3 (terpy = 2...

  • Article
  • Open Access
5 Citations
2,341 Views
12 Pages

Effect of Processing Parameters on Wear Properties of Hybrid AA1050/Al2O3/TiO2 Composites

  • Yuanfei Gao,
  • Mohammad Heydari Vini,
  • Saeed Daneshmand,
  • Ameer A. Alameri,
  • Omrane Benjeddou and
  • Raed H. C. Alfilh

16 February 2023

In this study, hybrid AA1050/Al2O3/TiO2 composites have been produced via combined liquid casting and powder metallurgy techniques. Degassing was utilized to improve the wettability of molten aluminum alloys, and then successful bonding was generated...

  • Article
  • Open Access
6 Citations
3,355 Views
14 Pages

Study of the Bandgap and Crystal Structure of Cu4TiSe4: Theory vs. Experiment

  • Grzegorz Matyszczak,
  • Szymon Sutuła,
  • Paweł Jóźwik,
  • Krzysztof Krawczyk and
  • Krzysztof Woźniak

16 February 2023

The aim of this study was to investigate the crystal structure and bandgap of the emerging material Cu4TiSe4 using both theoretical and experimental methods. We synthesized the title compound via solid-state synthesis from elements. The occurrence of...

  • Article
  • Open Access
8 Citations
3,586 Views
10 Pages

High-Peak-Power Passively Q-Switched Laser at 589 nm with Intracavity Stimulated Raman Scattering

  • Jian-Cheng Chen,
  • Yu-Wen Ho,
  • Yueh-Chi Tu,
  • Hsing-Chih Liang and
  • Yung-Fu Chen

16 February 2023

A novel scheme was developed for a diode-pumped passively Q-switched Nd:YVO4/KGW Raman laser at 589 nm with a diode-to-orange conversion efficiency reaching 11.4%. The compact near-concentric cavity was designed to achieve the criterion of good passi...

  • Article
  • Open Access
6 Citations
2,678 Views
14 Pages

16 February 2023

In this study, effective and environmentally friendly methods were used to achieve the synthesis of silver nanoparticles (Ag NPs) by an aqueous plant extract. The Ag NPs were synthesized via Zingiber officinale plant extract that acted as a reducing...

  • Article
  • Open Access
5 Citations
2,423 Views
12 Pages

16 February 2023

The number and the strength of acid sites in catalysts have paramount importance on their efficiency. In zeolites chemistry, increased content of framework Al in zeolites gives a higher number of strong acid sites. Their strength can be a disadvantag...

  • Review
  • Open Access
112 Citations
11,661 Views
26 Pages

15 February 2023

Antibiotics are pervasive contaminants in aqueous systems that pose an environmental threat to aquatic life and humans. Typically, antibiotics are developed to counteract bacterial infections; however, their prolonged and excessive use has provoked u...

  • Article
  • Open Access
22 Citations
3,529 Views
14 Pages

Antibacterial, Antioxidant and Physicochemical Properties of Pipper nigram Aided Copper Oxide Nanoparticles

  • Javeria Aien,
  • Ashfaq Ahmad Khan,
  • Sirajul Haq,
  • Abdul Rehman Khan,
  • Khaled Elmnasri,
  • Manel Ben Ali,
  • Mohammad S. AL-Harbi,
  • Mohammed I. Alghonaim,
  • Sulaiman A. Alsalamah and
  • Mohamed Dellali
  • + 3 authors

15 February 2023

The Pipper nigram (P. nigram) leaf extract was used for the biosynthesis of copper oxide nanoparticles (CuO NPs) and the successful formation of the resultant product was confirmed through several physicochemical techniques. The chemical structure an...

  • Article
  • Open Access
1 Citations
3,049 Views
17 Pages

15 February 2023

The deformation mechanism of a medium-Mn advanced high strength steel (AHSS) over a temperature range from 25 °C to 400 °C has been studied. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to characteri...

  • Article
  • Open Access
3 Citations
3,780 Views
11 Pages

15 February 2023

Photoalignment technology enables macroscopic alignment of liquid crystalline molecules and their aggregates in a non-contact process by irradiating photo-responsive liquid crystalline compounds with linearly polarized light. Because photoalignment t...

  • Article
  • Open Access
4 Citations
2,179 Views
10 Pages

15 February 2023

To investigate the crystallization of DNTF in modified double-base propellants, glycidyl azide polymer (GAP) was used as the coating material for the in situ coating of DNTF, and the performance of the coating was investigated to inhibit the crystall...

  • Article
  • Open Access
12 Citations
2,289 Views
17 Pages

15 February 2023

The surface of Inconel 625, a nickel-base alloy, was strengthened by vacuum electron beam scanning technology. The evolution of its microstructure was analyzed by electron backscatter diffraction (EBSD) and the friction and wear tester (RETC). The re...

  • Article
  • Open Access
3 Citations
2,932 Views
13 Pages

Investigation of the Temperature Dependence of Volt-Ampere Characteristics of a Thin-Film Si3N4 Memristor

  • Dmitry Mizginov,
  • Oleg Telminov,
  • Sergey Yanovich,
  • Dmitry Zhevnenko,
  • Fedor Meshchaninov and
  • Evgeny Gornev

15 February 2023

The compatibility of memristor materials with advanced complementary metal-oxide-semiconductor (CMOS) technology is a key factor for microelectronics element base manufacturing. Therefore, we continued studying previously fabricated CMOS-compatible N...

  • Article
  • Open Access
1 Citations
2,986 Views
11 Pages

15 February 2023

The CuCl binuclear complexes were synthesized with phenyl-1H-pyrazole-1-carbodithioate (L1) and phenyl-3-methyl-1H-pyrazole-1-carbodithioate (L2) ligands. The complexes were isolated as crystalline material in a reasonable quantity. The complexes wer...

  • Article
  • Open Access
2,067 Views
14 Pages

15 February 2023

The deformation mechanism and texture evolution of AZ31 Mg alloy compressed in three different directions at room temperature were studied, and the relationship between the two was compared through experiments and viscoplastic self-consistent (VPSC)...

  • Article
  • Open Access
5 Citations
3,249 Views
10 Pages

15 February 2023

The kagome lattice consisting of corner-sharing triangles has been studied in the context of quantum physics for more than seventy years. For the novel discovered kagome superconductor CsV3Sb5, identifying the pairing symmetry of order parameter rema...

  • Article
  • Open Access
1 Citations
2,398 Views
14 Pages

Vacuum Electrodeposition of Cu(In, Ga)Se2 Thin Films and Controlling the Ga Incorporation Route

  • Kanwen Hou,
  • Guohao Liu,
  • Jia Yang,
  • Wei Wang,
  • Lixin Xia,
  • Jun Zhang,
  • Baoqiang Xu and
  • Bin Yang

15 February 2023

The traditional electrochemical deposition process used to prepare Cu(In, Ga)Se2 (CIGS) thin films has inherent flaws, such as the tendency to produce low-conductivity Ga2O3 phase and internal defects. In this article, CIGS thin films were prepared u...

  • Article
  • Open Access
10 Citations
5,353 Views
17 Pages

Reduction Smelting of the Waelz Slag from Electric Arc Furnace Dust Processing: An Experimental Study

  • Pavel Grudinsky,
  • Dmitry Zinoveev,
  • Alex Kondratiev,
  • Leonid Delitsyn,
  • Ruslan Kulumbegov,
  • Anton Lysenkov,
  • Pavel Kozlov and
  • Valery Dyubanov

15 February 2023

Waelz slag is an iron-containing waste generated during electric arc furnace (EAF) dust processing in a rotary kiln named the Waelz process. This study focuses on the reduction smelting of the Waelz slag to produce iron-based alloy. The thermodynamic...

  • Article
  • Open Access
2 Citations
2,639 Views
22 Pages

Glycine Dissolution Behavior under Forced Convection

  • Cornelia Eder,
  • Simon A. Schiele,
  • Frederik Luxenburger and
  • Heiko Briesen

14 February 2023

The integration of a flow-through cell into a Mach–Zehnder interferometer offers the possibility to study the dissolution of crystals in detail. The influence of flow on the displacement velocity of a specific crystal facet and the distribution...

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Crystals - ISSN 2073-4352