The anchoring effect on free-base carboxyphenyl porphyrin films using TiO
2 microstructured columns as a host matrix and its influence on NO
2 sensing have been studied in this work. Three porphyrins have been used: 5-(4-carboxyphenyl)10,15,20-triphenyl-21
H,23
H-porphyrin (MCTPP); 5,10,15,20-tetrakis(4-carboxyphenyl)-21
H
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The anchoring effect on free-base carboxyphenyl porphyrin films using TiO
2 microstructured columns as a host matrix and its influence on NO
2 sensing have been studied in this work. Three porphyrins have been used: 5-(4-carboxyphenyl)10,15,20-triphenyl-21
H,23
H-porphyrin (MCTPP); 5,10,15,20-tetrakis(4-carboxyphenyl)-21
H,23
H-porphyrin (
p-TCPP); and 5,10,15,20-tetrakis(3-carboxyphenyl)-21
H,23
H-porphyrin (
m-TCPP). The analysis of UV-Vis spectra of MCTPP/TiO
2,
p-TCPP/TiO
2 and
m-TCPP/TiO
2 composite films has revealed that
m-TCPP/TiO
2 films are the most stable, showing less aggregation than the other porphyrins. IR spectroscopy has shown that
m-TCPP is bound to TiO
2 through its four carboxylic acid groups, while
p-TCPP is anchored by only one or two of these groups. MCTPP can only be bound by one carboxylic acid. Consequently, the binding of
p-TCPP and MCTPP to the substrate allows them to form aggregates, whereas the more fixed anchoring of
m-TCPP reduces this effect. The exposure of MCTPP/TiO
2,
p-TCPP/TiO
2 and
m-TCPP/TiO
2 films to NO
2 has resulted in important changes in their UV-Vis spectra, revealing good sensing capabilities in all cases. The improved stability of films made with
m-TCPP suggests this molecule as the best candidate among our set of porphyrins for the fabrication of NO
2 sensors. Moreover, their concentration-dependent responses upon exposure to low concentrations of NO
2 confirm the potential of
m-TCPP as a NO
2 sensor.
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