Molbank, Volume 2024, Issue 4

The oxidative esterification of 4,4′-Biphenyldicarboxaldehyde with hexafluoroisopropanol is reported. The methodology, making a novel hexafluoroisopropyl ester uses a green, recyclable oxoammonium salt along with easily obtained sodium persulfate.

The titular compound, 6-amino-7-((4-methoxybenzyl)thio)quinazolin-4(3H)-one, was prepared from 7-fluoro-6-nitroquinazolin-4(3H)-one via a nucleophilic aromatic substitution reaction followed by a reduction of the nitro group. Characterization of the...

5-Bromo-N′-(2-oxoindolin-3-ylidene)furan-2-carbohydrazide (1) was successfully synthesized in 79.4% yield by reaction of isatin with 5-bromofuran-2-carbohydrazide in acidic conditions under reflux. The structure of synthesized compound 1 was co...

Surfactants are very important compounds that are ubiquitous in biological systems and detergents. Among them, ferrocene surfactants are a very valuable class of stimuli-responsive materials since the presence of ferrocene moiety discloses the chance...

The title compound was characterised for the first time by 13C NMR, including the determination of CH coupling constants, and its X-ray structure was determined, showing double ribbons of molecules in the crystal held together by weak CH to O=C hydro...

The title compound (1) was obtained within a project to synthesize analogs of the antiepileptic drug stiripentol. Compound 1 was synthesized by aldol addition of the lithium enolate of 4-(benzo[d][1,3]dioxol-5-yl)butan-2-one (2) to 3,3-dimethylbutan-...

The crystal structure and the improved synthesis of the title compound (1) are presented. Treatment of 5,10-disilyldibenzo[a,e]pentalenes (2a and 2b) with iodine chloride (ICl) readily provided 1 in good yields. Recrystallization from a dichlorometha...

3-N-allylrhodanine was condensed with 5-(4-methoxyphenyl)-thiophene-2-carbaldehyde in an L-proline-based deep eutectic solvent (DES) to obtain the π-conjugated heterocyclic rhodanine compound (5Z)-3-allyl-5-{[5-(4-methoxyphenyl)thiophen-2-yl]methy...

We have successfully synthesized a 2-oxa androstane derivative, 17β-hydroxy-2-oxa-5α-androstan-3-one (6), and confirmed its structure using NMR spectroscopy and mass spectrometry.

New cyclotriphosphazene derivatives featuring amide–Schiff base linkages with a hydrazine bridge and different terminal ends, such as decyl alkyl chains and hydroxy groups, were successfully synthesized and characterized. Fourier-transform infr...