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27 Results Found

  • Article
  • Open Access
12 Citations
3,581 Views
12 Pages

Non-Coplanar Diphenyl Fluorene and Weakly Polarized Cyclohexyl Can Effectively Improve the Solubility and Reduce the Dielectric Constant of Poly (Aryl Ether Ketone) Resin

  • Feng Bao,
  • Yanxing Liu,
  • Ludi Shi,
  • Jinze Cui and ,
  • Muwei Ji,
  • Huichao Liu,
  • Jiali Yu,
  • Caizhen Zhu and
  • Jian Xu
  • + 4 authors+ 0 author

15 February 2023

With the rapid development of high-frequency communication and large-scale integrated circuits, insulating dielectric materials require a low dielectric constant and dielectric loss. Poly (aryl ether ketone) resins (PAEK) have garnered considerable a...

(This article belongs to the Section Smart and Functional Polymers)
  • Article
  • Open Access
3 Citations
1,944 Views
12 Pages

Novel Aryl Phosphate for Improving Fire Safety and Mechanical Properties of Epoxy Resins

  • Yue Xu,
  • Wenjia Zhang,
  • Ru Yin,
  • Jun Sun and ,
  • Bin Li and
  • Lubin Liu
  • + 1 author+ 0 author

30 October 2024

Epoxy resins (EPs) are highly flammable, and traditional flame retardant modifications often lead to a significant reduction in their mechanical performance, limiting their applications in aerospace and electrical and electronic fields. In this study...

(This article belongs to the Section Polymer Composites and Nanocomposites)
  • Article
  • Open Access
3 Citations
3,320 Views
18 Pages

Polypy: A Framework to Interpret Polymer Properties from Mass Spectrometry Data

  • Vitor Vlnieska,
  • Ankita Khanda,
  • Evgeniia Gilshtein,
  • Jorge Luis Beltrán and ,
  • Jakob Heier and
  • Danays Kunka
  • + 1 author+ 0 author

22 June 2024

Mass spectroscopy (MS) is a robust technique for polymer characterization, and it can provide the chemical fingerprint of a complete sample regarding polymer distribution chains. Nevertheless, polymer chemical properties such as polydispersity (Pd),...

(This article belongs to the Section Polymer Analysis and Characterization)
  • Article
  • Open Access
20 Citations
4,083 Views
15 Pages

Bonding and Thermal Cycling Performances of Two (Poly)Aryl–Ether–Ketone (PAEKs) Materials to an Acrylic Denture Base Resin

  • Tzu-Yu Peng,
  • Saiji Shimoe,
  • Lih-Jyh Fuh,
  • Chung-Kwei Lin and ,
  • Dan-Jae Lin and
  • Masato Kaku
  • + 1 author+ 0 author

12 February 2021

Poly(aryl–ether–ketone) materials (PAEKs) are gaining interest in everyday dental practices because of their natural properties. This study aims to analyze the bonding performance of PAEKs to a denture acrylic. Testing materials were pretreated by gr...

(This article belongs to the Special Issue Polymers for Oral and Dental Health)
  • Article
  • Open Access
7 Citations
3,596 Views
15 Pages

Synthesis and Characterization of Block Copolymers of Poly(silylene diethynylbenzen) and Poly(silylene dipropargyl aryl ether)

  • Man Gao,
  • Chengyuan Shang,
  • Jixian Li,
  • Gang Han and ,
  • Junkun Tang,
  • Qiaolong Yuan and
  • Farong Huang
  • + 2 authors+ 0 author

7 May 2021

Poly(silylene diethynylbenzene)–b–poly(silylene dipropargyloxy diphenyl propane) copolymer (ABA-A), poly(silylene diethynylbenzene)–b–poly(silylene dipropargyloxy diphenyl ether) copolymer (ABA-O), and a contrast poly(silylene diethynylbenzene) with...

(This article belongs to the Section Polymer Chemistry)
  • Article
  • Open Access
4 Citations
5,071 Views
9 Pages

4 January 2019

We described a synthetic approach to bisphenol-based monocyanate esters based on mono-O-methylation of parental bisphenols followed by cyanation of the residual phenolic hydroxyl. Structures of the synthesized compounds were determined by the applica...

(This article belongs to the Section Organic Chemistry)
  • Article
  • Open Access
10 Citations
1,951 Views
16 Pages

16 August 2025

Aryl diazonium salt chemistry offers a robust and versatile approach for the modification of material surfaces via the covalent immobilization of reactive functional groups under mild conditions. In this study, this strategy was successfully applied...

(This article belongs to the Section Chemical and Molecular Sciences)
  • Feature Paper
  • Article
  • Open Access
16 Citations
5,382 Views
13 Pages

Development of Facile and Simple Processes for the Heterogeneous Pd-Catalyzed Ligand-Free Continuous-Flow Suzuki–Miyaura Coupling

  • Tsuyoshi Yamada,
  • Jing Jiang,
  • Naoya Ito,
  • Kwihwan Park and ,
  • Hayato Masuda,
  • Chikara Furugen,
  • Moeka Ishida,
  • Seiya Ōtori and
  • Hironao Sajiki
  • + 4 authors+ 0 author

19 October 2020

The Suzuki–Miyaura coupling reaction is one of the most widely utilized C–C bond forming methods to create (hetero)biaryl scaffolds. The continuous-flow reaction using heterogeneous catalyst-packed cartridges is a practical and efficient...

(This article belongs to the Special Issue Advances in Catalytic Coupling Reactions)
  • Article
  • Open Access
27 Citations
4,031 Views
10 Pages

Supported Eosin Y as a Photocatalyst for C-H Arylation of Furan in Batch and Flow

  • Sergio Rossi,
  • Fabian Herbrik,
  • Simonetta Resta and
  • Alessandra Puglisi

10 August 2022

Eosin Y is one of the most popular organic dyes used as a photoredox catalyst and is largely employed in photochemical reactions both as a homogeneous and heterogeneous photocatalyst after immobilization. Immobilization of Eosin Y onto a solid suppor...

(This article belongs to the Special Issue The Latest Trends in Catalyst Immobilization)
  • Article
  • Open Access
5 Citations
2,564 Views
16 Pages

Effect of Electrochemical Aryl Diazonium Salt Modification on Interfacial Properties of CF/PEEK Composites

  • Mingchen Sun,
  • Xuekuan Li,
  • Hansong Liu,
  • Chengyu Huang and ,
  • Kai Wang and
  • Yan Zhao
  • + 1 author+ 0 author

13 June 2024

The interfacial properties between carbon fiber (CF) and thermoplastic resin are relatively weak, which can be problematic for composites in structural applications. Improving the surface roughness of CF is regarded as an effective way to enhance the...

(This article belongs to the Section Polymeric Materials)
  • Article
  • Open Access
17 Citations
7,930 Views
13 Pages

Laser Ablation Mechanism and Performance of Carbon Fiber-Reinforced Poly Aryl Ether Ketone (PAEK) Composites

  • Jindong Zhang,
  • Ran Bi,
  • Shengda Jiang,
  • Zihao Wen and ,
  • Chuyang Luo,
  • Jianan Yao,
  • Gang Liu,
  • Chunhai Chen and
  • Ming Wang
  • + 4 authors+ 0 author

30 June 2022

The ablation mechanism and performance of carbon fiber (CF)-reinforced poly aryl ether ketone (PAEK) thermoplastic composites were studied in this paper. The results show that the ablation damaged area is controlled by the irradiation energy, while t...

(This article belongs to the Special Issue Thermal Behavior of Polymer Materials)
  • Article
  • Open Access
16 Citations
5,317 Views
14 Pages

Structural Analysis of Lignin-Based Furan Resin

  • Xuhai Zhu,
  • Bardo Bruijnaers,
  • Tainise V. Lourençon and
  • Mikhail Balakshin

4 January 2022

The global “carbon emission peak” and “carbon neutrality” strategic goals promote us to replace current petroleum-based resin products with biomass-based resins. The use of technical lignins and hemicellulose-derived furfuryl...

(This article belongs to the Special Issue Synthesis and Application of New Lignin-Based Polymers and Composites)
  • Article
  • Open Access
3 Citations
3,123 Views
17 Pages

20 December 2024

Background: N-succinimidyl-[18F]fluorobenzoate ([18F]SFB) is commonly prepared through a three-step procedure starting from [18F]fluoride ion. A number of methods for the single-step radiosynthesis of [18F]SFB have been introduced recently, incl...

(This article belongs to the Section Radiopharmaceutical Sciences)
  • Article
  • Open Access
4 Citations
4,825 Views
16 Pages

Lithographic Performance of Aryl Epoxy Thermoset Resins as Negative Tone Photoresist for Microlithography

  • Vitor Vlnieska,
  • Margarita Zakharova,
  • Andrey Mikhaylov and
  • Danays Kunka

14 October 2020

Photoresists (or photo-resins) are the main and most important raw material used for lithography techniques such as deep X-ray (DXRL), ultraviolet (UVL), deep-UV (DUVL), and extreme UV (EUVL). In previous work, we showed how complicated could be the...

(This article belongs to the Section Polymer Analysis and Characterization)
  • Article
  • Open Access
37 Citations
4,563 Views
16 Pages

Synergistic Effects of Liquid Rubber and Thermoplastic Particles for Toughening Epoxy Resin

  • Zhaodi Wang,
  • Yuanchang Lai,
  • Peiwen Xu,
  • Junchi Ma and ,
  • Yahong Xu and
  • Xin Yang
  • + 1 author+ 0 author

30 September 2024

This study aims to investigate the toughening effects of rubber and thermoplastic particles on epoxy resin (EP), and to understand the mechanism underlying their synergistic effect. For this purpose, three EP systems were prepared using diglycidyl et...

(This article belongs to the Special Issue Damage and Failure Analysis of Polymer-Based Composites)
  • Article
  • Open Access
4 Citations
4,408 Views
15 Pages

Continuous-Flow Synthesis of Arylthio-Cyclopropyl Carbonyl Compounds

  • Davide Moi,
  • Maria Chiara Cabua,
  • Viktoria Velichko,
  • Andrea Cocco and ,
  • Annalisa Chiappone,
  • Rita Mocci,
  • Stefania Porcu,
  • Monica Piras,
  • Stefano Bianco and
  • Francesco Secci
  • + 6 authors+ 1 author

16 November 2022

The straightforward, continuous-flow synthesis of cyclopropyl carbaldehydes and ketones has been developed starting from 2-hydroxycyclobutanones and aryl thiols. This acid-catalyzed mediated procedure allows access to the multigram and easily scalabl...

(This article belongs to the Section Organic Chemistry)
  • Article
  • Open Access
14 Citations
3,980 Views
16 Pages

Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubes

  • Szymon Demski,
  • Dariusz Brząkalski,
  • Maciej Gubernat,
  • Kamil Dydek and ,
  • Paweł Czaja,
  • Konrad Żochowski,
  • Paulina Kozera,
  • Zuzanna Krawczyk,
  • Bogna Sztorch and
  • Anna Boczkowska
  • + 8 authors+ 3 authors

2 February 2024

The main goal of this work was an improvement in the mechanical and electrical properties of acrylic resin-based nanocomposites filled with chemically modified carbon nanotubes. For this purpose, the surface functionalization of multi-walled carbon n...

(This article belongs to the Special Issue Advances in Thermal, Electrical and Mechanical Properties of Polymer Composites)
  • Article
  • Open Access
2,263 Views
13 Pages

Grafting Carbon Fibers with Graphene via a One-Pot Aryl Diazonium Reaction to Refine the Interface Performance of T1100-Grade CF/BMI Composites

  • Weidong Li,
  • Ziqi Duan,
  • Mingchen Sun,
  • Pengfei Shen and ,
  • Huanzhi Yang,
  • Xiangyu Zhong,
  • Yang Zhang,
  • Xiaolan Hu and
  • Jianwen Bao
  • + 4 authors+ 0 author

3 July 2024

In this study, a one-pot aryl diazonium reaction was used as a simple and mild method to graft graphene onto the smooth and inert surface of T1100-grade carbon fiber (CF) through covalent bonding without any damage on CF, to refine the interface perf...

(This article belongs to the Section Advanced Composites)
  • Article
  • Open Access
14 Citations
5,148 Views
18 Pages

New Polymer Composites with Aluminum Phosphates as Hybrid Flame Retardants

  • Kamil Dziuba,
  • Krystyna Wnuczek,
  • Patryk Wojtachnio,
  • Rodolphe Sonnier and
  • Beata Podkościelna

2 January 2023

Polymeric aluminum organophosphates are a class of nanostructured aluminum-based compounds that can be considered organic and inorganic hybrid materials. Aluminum phosphates have attracted considerable interest due to their ability to enhance composi...

(This article belongs to the Section Polymeric Materials)
  • Article
  • Open Access
26 Citations
6,377 Views
12 Pages

Polyvinylpyridine-Supported Palladium Nanoparticles: An Efficient Catalyst for Suzuki–Miyaura Coupling Reactions

  • Graziano Fusini,
  • Fabio Rizzo,
  • Gaetano Angelici,
  • Emanuela Pitzalis and ,
  • Claudio Evangelisti and
  • Adriano Carpita
  • + 1 author+ 0 author

15 March 2020

Palladium nanoparticles (Pd NPs) synthesized by the metal vapor synthesis technique were supported on poly(4-vinylpyridine) 2% cross-linked with divinylbenzene (Pd/PVPy). Transmission electron microscopy revealed the presence of small metal nanoparti...

(This article belongs to the Special Issue Supported Metal Catalysts and Their Applications in Fine Chemicals)
  • Article
  • Open Access
116 Citations
7,468 Views
11 Pages

28 December 2019

A facile in situ polymerization was developed for grafting renewable cardanol onto the carbon fiber (CF) surfaces to strengthen the fiber–matrix interface. CFs were chemically modified with hydroxyl groups by using an aryl diazonium reaction, a...

  • Article
  • Open Access
467 Views
21 Pages

30 August 2026

Phenolphthalein poly (aryl ether ketone) (PEK-C) is highly compatible with epoxy resin, which is applied in epoxy resin-based composites to improve their strength. Solution spinning and electrospinning techniques are often used to produce PEK-C fiber...

(This article belongs to the Section Polymer Fibers)
  • Feature Paper
  • Article
  • Open Access
5 Citations
2,837 Views
20 Pages

Composition of Oil after Hydrothermal Treatment of Cabonate-Siliceous and Carbonate Domanic Shale Rocks

  • Galina P. Kayukova,
  • Zukhra R. Nasyrova,
  • Anastasiya N. Mikhailova,
  • Igor P. Kosachev and ,
  • Firdavs A. Aliev and
  • Alexey V. Vakhin
  • + 1 author+ 0 author

11 October 2021

The hydrocarbon compositions of shale oils, generated from two different lithological–facial Domanic deposits of the Tatarstan Republic (Russia), were studied under hydrothermal impact with 30% of water addition in a 350 °С and CO2 environment. The s...

(This article belongs to the Section Chemical Processes and Systems)
  • Article
  • Open Access
21 Citations
4,922 Views
17 Pages

Alcohol-Supported Cu-Mediated 18F-Fluorination of Iodonium Salts under “Minimalist” Conditions

  • Victoriya V. Orlovskaya,
  • Daniel J. Modemann,
  • Olga F. Kuznetsova,
  • Olga S. Fedorova and ,
  • Elizaveta A. Urusova,
  • Niklas Kolks,
  • Bernd Neumaier,
  • Raisa N. Krasikova and
  • Boris D. Zlatopolskiy
  • + 4 authors+ 0 author

3 September 2019

In the era of personalized precision medicine, positron emission tomography (PET) and related hybrid methods like PET/CT and PET/MRI gain recognition as indispensable tools of clinical diagnostics. A broader implementation of these imaging modalities...

(This article belongs to the Section Medicinal Chemistry)
  • Review
  • Open Access
62 Citations
7,412 Views
18 Pages

Bisphenols as a Legacy Pollutant, and Their Effects on Organ Vulnerability

  • Jong-Joo Kim,
  • Surendra Kumar,
  • Vinay Kumar,
  • Yun-Mi Lee and ,
  • You-Sam Kim and
  • Vijay Kumar
  • + 1 author+ 0 author

Bisphenols are widely used in the synthesis of polycarbonate plastics, epoxy resins, and thermal paper, which are used in manufacturing items of daily use. Packaged foods and drinks are the main sources of exposure to bisphenols. These chemicals affe...

(This article belongs to the Special Issue Toxicity of Pesticides and Legacy Pollutants)
  • Article
  • Open Access
23 Citations
4,640 Views
17 Pages

18 June 2023

This paper used poly (aryl ether ketone) (PAEK) resin with a low melting temperature to prepare laminate via the compression-molding process for continuous-carbon-fiber-reinforced composites (CCF-PAEK). Then, poly (ether ether ketone) (PEEK), or a sh...

(This article belongs to the Special Issue Advanced Manufacturing Technologies of Thermoplastic Composites)
  • Article
  • Open Access
11 Citations
4,107 Views
18 Pages

Structural and Rheological Properties of Nonedible Vegetable Oil-Based Resin

  • Nurul Huda Mudri,
  • Luqman Chuah Abdullah,
  • Min Min Aung,
  • Dayang Radiah Awang Biak and
  • Rida Tajau

28 July 2021

Jatropha oil-based polyol (JOL) was prepared from crude Jatropha oil via an epoxidation and hydroxylation reaction. During the isocyanation step, two different types of diisocyanates; 2,4-toluene diisocyanate (2,4-TDI) and isophorone diisocyanate (IP...

(This article belongs to the Special Issue Advanced Bio-Based Polymers and Nanocomposites)