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Polymers, Volume 14, Issue 18

2022 September-2 - 222 articles

Cover Story: Natural biopolymers such as chitosan and gelatin, which are biodegradable and inherently functional, have significant potential for biomedical and other specialized applications. Given this, determining how to create composite materials with the desired molecular interactions and tailored properties has attracted intense research interest. Herein, thermomechanically processed chitosan–gelatin biopolymer nanocomposite materials plasticised by glycerol or isosorbide and filled with nanoclay (MMT) or graphene oxide (GO) were studied. This work highlights different mechanisms that control the different properties of dual-biopolymer systems and provides an updated definition of biopolymer plasticization and insights into the design of polymeric materials involving multiple ways of chain interaction. View this paper
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Articles (222)

  • Article
  • Open Access
4 Citations
2,760 Views
18 Pages

19 September 2022

The one-dimensional (1D) polyethylene (PE) nanocrystals were generated in epoxy thermosets via crystallization-driven self-assembly. Toward this end, an ABA triblock copolymer composed of PE midblock and poly(ε-caprolactone) (PCL) endblocks w...

  • Article
  • Open Access
24 Citations
5,661 Views
18 Pages

19 September 2022

Generally, poly(ethylene glycol) (PEG) is added to poly(lactic acid) (PLA) to reduce brittleness and improve mechanical properties. However, shape memory properties of PEG/PLA blends suffered due to the blend’s incompatibility. To enhance shape...

  • Article
  • Open Access
6 Citations
2,934 Views
18 Pages

19 September 2022

For the photocatalytic removal of the Reactive Blue 4 dye from an aqueous stream, new polyaniline/multi walled carbon nanotube nanocomposites (PANI-MWCNTs) were applied as a promising photocatalyst. The PANI-MWCNT nanocomposites were fabricated by an...

  • Article
  • Open Access
29 Citations
2,959 Views
28 Pages

19 September 2022

In this paper, urea-formaldehyde resin microcapsules with shellac resin as core material were prepared by in-situ polymerization. Morphologies of shellac resin microcapsules were characterized by optical microscope (OM) and scanning electron microsco...

  • Article
  • Open Access
27 Citations
4,649 Views
11 Pages

19 September 2022

Sulfur compounds are removed from propylene through purification processes. However, these processes are not 100% effective, so low concentrations of compounds such as H2S may be present in polymer-grade propylene. This article studies the effects of...

  • Article
  • Open Access
18 Citations
3,573 Views
11 Pages

19 September 2022

For digging out eco−friendly and well−performed energy harvesters, piezoelectric nanogenerators are preferred owing to their effortless assembly. Corona−poling promotes output performance of either aligned or porous PVDF electrospun...

  • Article
  • Open Access
20 Citations
3,744 Views
21 Pages

19 September 2022

The Bacillus xiamenensis RT6 strain was isolated and identified by morphological, biochemical and molecular tests from an extreme acidic environment, Rio Tinto (Huelva). Optimisation tests for exopolysaccharide (EPS) production in different culture m...

  • Article
  • Open Access
13 Citations
3,340 Views
18 Pages

Carbon/Basalt Fibers Hybrid Composites: Hybrid Design and the Application in Automobile Engine Hood

  • Yongfeng Pu,
  • Baichuan Liu,
  • Guilian Xue,
  • Hongyu Liang,
  • Fangwu Ma,
  • Meng Yang and
  • Guangdong Tian

19 September 2022

The low-velocity impact properties and the optimal hybrid ratio range for improving the property of hybrid composites are studied, and the application of hybrid composites in automobile engine hoods is discussed in this paper. The low-velocity impact...

  • Article
  • Open Access
9 Citations
3,874 Views
15 Pages

Alkaline Treatment Variables to Characterize Poly(Vinyl Alcohol)/Poly(Vinyl Butyral/Vinyl Alcohol) Blend Films

  • Seong Baek Yang,
  • Mohammad Rezaul Karim,
  • Jungeon Lee,
  • Jeong Hyun Yeum and
  • Sabina Yeasmin

19 September 2022

Novel poly(vinyl alcohol) (PVA)/poly(vinyl butyral–vinyl alcohol) (P(VB-VA)) films with improved hydrophobicity were prepared from poly(vinyl acetate) (PVAc)/poly(vinyl butyral) (PVB) blend films with various mass ratios by saponification in a...

  • Article
  • Open Access
12 Citations
3,023 Views
14 Pages

19 September 2022

The incorporation of plastic aggregates as a partial replacement of natural aggregates in cementitious materials is interesting in several ways. From a mechanical point of view, the partial substitution of sand with plastic aggregates could improve s...

  • Article
  • Open Access
17 Citations
4,486 Views
17 Pages

Composite Coatings of Chitosan and Silver Nanoparticles Obtained by Galvanic Deposition for Orthopedic Implants

  • C. Zanca,
  • S. Carbone,
  • B. Patella,
  • F. Lopresti,
  • G. Aiello,
  • V. Brucato,
  • F. Carfì Pavia,
  • V. La Carrubba and
  • R. Inguanta

19 September 2022

In this work, composite coatings of chitosan and silver nanoparticles were presented as an antibacterial coating for orthopedic implants. Coatings were deposited on AISI 304L using the galvanic deposition method. In galvanic deposition, the differenc...

  • Article
  • Open Access
17 Citations
3,472 Views
20 Pages

Biomimetic Synthesis of PANI/Graphitic Oxidized Carbon Nitride for Supercapacitor Applications

  • Manuel Eduardo Martínez-Cartagena,
  • Juan Bernal-Martínez,
  • Arnulfo Banda-Villanueva,
  • Javier Enríquez-Medrano,
  • Víctor D. Lechuga-Islas,
  • Ilse Magaña,
  • Teresa Córdova,
  • Diana Morales-Acosta,
  • José Luis Olivares-Romero and
  • Ramón Díaz-de-León

19 September 2022

Polyaniline (PANI) composites have gained momentum as supercapacitive materials due to their high energy density and power density. However, some drawbacks in their performance remain, such as the low stability after hundreds of charge-discharge cycl...

  • Article
  • Open Access
3 Citations
2,186 Views
11 Pages

Kinetics of Pectin Biopolymer Facial Erosion Characterized by Fluorescent Tracer Microfluidics

  • Matthew W. Liao,
  • Betty S. Liu,
  • Joseph Sutlive,
  • Willi L. Wagner,
  • Hassan A. Khalil,
  • Zi Chen,
  • Maximilian Ackermann and
  • Steven J. Mentzer

19 September 2022

Pectin is a plant-derived heteropolysaccharide that has been implicated in drug development, tissue engineering, and visceral organ repair. Pectin demonstrates remarkable biostability in a variety of physiologic environments but is biodegradable in w...

  • Article
  • Open Access
46 Citations
6,121 Views
10 Pages

Electroactive Oxidized Alginate/Gelatin/MXene (Ti3C2Tx) Composite Hydrogel with Improved Biocompatibility and Self-Healing Property

  • Hui Zhu,
  • Weitao Dai,
  • Liming Wang,
  • Cong Yao,
  • Chenxi Wang,
  • Bingsong Gu,
  • Dichen Li and
  • Jiankang He

19 September 2022

Conductive hydrogels (CHs) have shown promising potential applied as wearable or epidermal sensors owing to their mechanical adaptability and similarity to natural tissues. However, it remains a great challenge to develop an integrated hydrogel combi...

  • Article
  • Open Access
18 Citations
5,650 Views
13 Pages

Bioabsorbable Carboxymethyl Starch–Calcium Ionic Assembly Powder as a Hemostatic Agent

  • Young-Gwang Ko,
  • Byeong Nam Kim,
  • Eun Jin Kim,
  • Ho Yun Chung,
  • Seong Yong Park,
  • Young-Jin Kim and
  • Oh Hyeong Kwon

19 September 2022

In contrast to hemostatic fabrics, foams, and gels, hemostatic spray powders may be conveniently applied on narrow and complex bleeding sites. However, powdered hemostatic agents are easily desorbed from the bleeding surface because of blood flow, wh...

  • Article
  • Open Access
13 Citations
3,649 Views
15 Pages

Effect of Bacterial Cellulose Plasma Treatment on the Biological Activity of Ag Nanoparticles Deposited Using Magnetron Deposition

  • Alexander Vasil’kov,
  • Alexander Budnikov,
  • Tatiana Gromovykh,
  • Marina Pigaleva,
  • Vera Sadykova,
  • Natalia Arkharova and
  • Alexander Naumkin

19 September 2022

New functional medical materials with antibacterial activity based on biocompatible bacterial cellulose (BC) and Ag nanoparticles (Ag NPs) were obtained. Bacterial cellulose films were prepared by stationary liquid-phase cultivation of the Gluconacet...

  • Article
  • Open Access
35 Citations
3,402 Views
23 Pages

Application of Ensemble Machine Learning Methods to Estimate the Compressive Strength of Fiber-Reinforced Nano-Silica Modified Concrete

  • Madiha Anjum,
  • Kaffayatullah Khan,
  • Waqas Ahmad,
  • Ayaz Ahmad,
  • Muhammad Nasir Amin and
  • Afnan Nafees

19 September 2022

In this study, compressive strength (CS) of fiber-reinforced nano-silica concrete (FRNSC) was anticipated using ensemble machine learning (ML) approaches. Four types of ensemble ML methods were employed, including gradient boosting, random forest, ba...

  • Article
  • Open Access
12 Citations
4,552 Views
11 Pages

Effect of Polycarboxylic Grinding Aid on Cement Chemistry and Properties

  • Jianyu Yang,
  • Guanglin Li,
  • Weijun Yang and
  • Junfeng Guan

19 September 2022

In view of the disadvantages of polycarboxylic acid grinding aids, such as poor reinforcement effect and cumbersome synthesis process, a new type of polycarboxylic acid grinding aid was prepared to meet the requirements of multifunctional admixture f...

  • Article
  • Open Access
4 Citations
3,261 Views
14 Pages

19 September 2022

Polyether ketone (PEK) plastics are linear thermoplastic polymers connected by at least one ether bond and at least one ketone bond on the aryl group. The reason for their excellent heat resistance, rigidity, and mechanical strength is that their mai...

  • Article
  • Open Access
8 Citations
2,879 Views
12 Pages

18 September 2022

Helical springs are indispensable mechanical parts widely used in industry. Lightweight is one of the development trends of helical springs. In this study, three kinds of lightweight polymer matrix composite helical springs (PMCHSs) with unidirection...

  • Article
  • Open Access
17 Citations
5,521 Views
13 Pages

18 September 2022

Bombyx mori silk fibroin (SF) is widely used in the field of biomaterials due to its excellent biocompatibility and mechanical properties. However, SF cannot be used directly in many applications and needs to be dissolved first. Lithium bromide (LiBr...

  • Article
  • Open Access
5 Citations
2,709 Views
15 Pages

18 September 2022

Brittle matrix composites such as concrete are susceptible to damage in the form of cracks. Most of the current self-repair and self-healing techniques have repair limits on crack widths or high costs of an external stimulator, or have an unfavorable...

  • Article
  • Open Access
8 Citations
2,885 Views
15 Pages

18 September 2022

We investigated the evolution of the γ-phase spherulites of poly(vinylidene fluoride) (PVDF) added to 1 wt% of tetrabutylammonium hydrogen sulfate during the isothermal crystallization at 165 °C through polarized optical microscopy and ligh...

  • Article
  • Open Access
14 Citations
3,395 Views
15 Pages

Properties and Hydrolysis Behavior of Celluloses of Different Origin

  • Ekaterina I. Kashcheyeva,
  • Yulia A. Gismatulina,
  • Galina F. Mironova,
  • Evgenia K. Gladysheva,
  • Vera V. Budaeva,
  • Ekaterina A. Skiba,
  • Vladimir N. Zolotuhin,
  • Nadezhda A. Shavyrkina,
  • Aleksey N. Kortusov and
  • Anna A. Korchagina

18 September 2022

The present paper is a fundamental study on the physicochemical properties and hydrolysis behavior of cellulose samples differing in origin: bacterial, synthetic, and vegetal. Bacterial cellulose was produced by Medusomyces gisevii Sa-12 in an enzyma...

  • Article
  • Open Access
7 Citations
3,222 Views
15 Pages

18 September 2022

Bone is a continually regenerating tissue with the ability to heal after fractures, though healing significant damage requires intensive surgical treatment. In this study, borate-based 13-93B3 bioactive glass scaffolds were prepared though polymer fo...

  • Article
  • Open Access
15 Citations
3,020 Views
9 Pages

18 September 2022

Carbon–silica dual-phase filler (CSDPF)/natural rubber (NR) vulcanizate was prepared by mechanical blending, followed by a hot-press vulcanization. The dispersion of CSDPF in the NR matrix and the effects of CSDPF on the filler–rubber int...

  • Article
  • Open Access
17 Citations
3,917 Views
23 Pages

Effect of Fuel Preheating on Engine Characteristics of Waste Animal Fat-Oil Biodiesel in Compression Ignition Engine

  • Gokul Raghavendra Srinivasan,
  • Ranjitha Jambulingam,
  • Amel Gacem,
  • Akil Ahmad,
  • Javed Khan Bhutto,
  • Krishna Kumar Yadav,
  • Amine Mezni,
  • Omar Khulaif R. Alharbi,
  • Saiful Islam and
  • Byong-Hun Jeon
  • + 1 author

18 September 2022

The present study aims at understanding the effects of fuel preheating on engine characteristics of waste animal fat-oil (WAF-O) biodiesel in a single-cylinder CI engine, with the preheating technique proposed as an effective means for enhancing the...

  • Review
  • Open Access
31 Citations
8,281 Views
19 Pages

Magnetic 3D-Printed Composites—Production and Applications

  • Guido Ehrmann,
  • Tomasz Blachowicz and
  • Andrea Ehrmann

17 September 2022

Three-dimensional printing enables building objects shaped with a large degree of freedom. Additional functionalities can be included by modifying the printing material, e.g., by embedding nanoparticles in the molten polymer feedstock, the resin, or...

  • Article
  • Open Access
11 Citations
2,664 Views
13 Pages

Synthesis and Performance Evaluation of a Novel Heat and Salt-Resistant Gel Plugging Agent

  • Xuejiao Li,
  • Meilong Fu,
  • Jie Liu,
  • Qi Xiao,
  • Wenhao Tang and
  • Guike Yang

17 September 2022

Tahe oil field is a typical fissure cave carbonate reservoir with a temperature of up to 120~140 °C and a total salinity of formation water of (20~25) × 104 mg/L. In this paper, AM/AMPS was selected as the polymer, 1, 5-dihydroxy naphthol a...

  • Article
  • Open Access
11 Citations
2,420 Views
13 Pages

Effects of At-Home and In-Office Bleaching Agents on the Color Recovery of Esthetic CAD-CAM Restorations after Red Wine Immersion

  • Wei-Fang Lee,
  • Hidekazu Takahashi,
  • Shiun-Yi Huang,
  • Jia-Zhen Zhang,
  • Nai-Chia Teng and
  • Pei-Wen Peng

17 September 2022

The aim of this study was to evaluate the effects of at-home and in-office bleaching agents on esthetic CAD-CAM materials after red wine immersion by measuring their optical properties. Sixty specimens were prepared out of three esthetic CAD-CAM mate...

  • Article
  • Open Access
37 Citations
3,928 Views
15 Pages

A Surface Plasmon Resonance-Based Photonic Crystal Fiber Sensor for Simultaneously Measuring the Refractive Index and Temperature

  • Jingao Zhang,
  • Jinhui Yuan,
  • Yuwei Qu,
  • Shi Qiu,
  • Chao Mei,
  • Xian Zhou,
  • Binbin Yan,
  • Qiang Wu,
  • Kuiru Wang and
  • Chongxiu Yu
  • + 1 author

17 September 2022

In this paper, a surface plasmon resonance (SPR)-based photonic crystal fiber (PCF) sensor is proposed for simultaneously measuring the refractive index (RI) and temperature. In the design, the central air hole and external surface of the proposed PC...

  • Article
  • Open Access
12 Citations
3,035 Views
22 Pages

On the Response of a Herschel–Bulkley Fluid Due to a Moving Plate

  • N’dri Arthur Konan,
  • Eilis Rosenbaum and
  • Mehrdad Massoudi

17 September 2022

In this paper, we study the boundary-layer flow of a Herschel–Bulkley fluid due to a moving plate; this problem has been experimentally investigated by others, where the fluid was assumed to be Carbopol, which has similar properties to cement....

  • Article
  • Open Access
9 Citations
3,676 Views
12 Pages

17 September 2022

Using a split-Hopkinson pressure bar test instrument with a temperature control device, in this work, silicone rubber was tested at different temperatures (−40 °C–200 °C) and different strain rates (1.2 × 103 s−1&ndash...

  • Article
  • Open Access
22 Citations
6,094 Views
17 Pages

17 September 2022

Microplastics are harmful to both marine life and humans. Herein, a pyrolysis–gas chromatography–mass spectrometry (Py-GC/MS) technique for the detection of microplastics in aquatic shellfish is demonstrated. The organic matter in aquatic...

  • Article
  • Open Access
28 Citations
4,146 Views
13 Pages

N-Doped Biochar from Lignocellulosic Biomass for Preparation of Adsorbent: Characterization, Kinetics and Application

  • Jing Li,
  • Fanxun Lv,
  • Ran Yang,
  • Liping Zhang,
  • Wei Tao,
  • Guotao Liu,
  • Hui Gao and
  • Ying Guan

17 September 2022

Medulla tetrapanacis is composed of a lignocellulosic biopolymer and has a regular porous structure, which makes it a potential biomass material for preparing porous N-doped biochar. Herewith, N-doped Medulla tetrapanacis biochar (UBC) was successful...

  • Article
  • Open Access
18 Citations
3,321 Views
13 Pages

17 September 2022

Research on the synthesis of water-soluble polymers has accelerated in recent years, as they are employed in many bio-applications. Herein, the synthesis of poly[2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl)ammonium hydroxide (PSB) by free radica...

  • Article
  • Open Access
7 Citations
2,989 Views
18 Pages

Polyhydroxybutyrate Rice Hull and Torrefied Rice Hull Biocomposites

  • Zach McCaffrey,
  • Andrew Cal,
  • Lennard Torres,
  • Bor-Sen Chiou,
  • Delilah Wood,
  • Tina Williams and
  • William Orts

17 September 2022

Raw and torrefied rice hulls (RRH and TRH) were incorporated into polyhydroxybutyrate (PHB) as fillers using extrusion and injection molding to produce biomass-polymer composites. Filler and composite materials were characterized by particle size ana...

  • Article
  • Open Access
15 Citations
3,379 Views
19 Pages

Bioactivity and Thermal Stability of Collagen–Chitosan Containing Lemongrass Essential Oil for Potential Medical Applications

  • Maria Râpă,
  • Traian Zaharescu,
  • Laura Mihaela Stefan,
  • Carmen Gaidău,
  • Ioana Stănculescu,
  • Rodica Roxana Constantinescu and
  • Maria Stanca

17 September 2022

Bioactive collagen–chitosan–lemongrass (COL–CS–LG) membranes were prepared by casting method and analyzed for potential biomedical applications. For COL–CS–LG membranes, LG essential oil release, antioxidant proper...

  • Article
  • Open Access
26 Citations
3,520 Views
18 Pages

Preparation and Optimization of Ibrutinib-Loaded Nanoliposomes Using Response Surface Methodology

  • Fareeaa Ashar,
  • Umme Hani,
  • Riyaz Ali M. Osmani,
  • Syed Mohammed Kazim and
  • S. Selvamuthukumar

17 September 2022

The main aim of this study was to optimize the formulation and process variables for the preparation of ibrutinib nanoliposomes and to evaluate the stability of nanoliposomes. The influence of four formulations and process parameters, namely, the pho...

  • Article
  • Open Access
16 Citations
3,741 Views
21 Pages

Microstructured Magnetoactive Elastomers for Switchable Wettability

  • Raphael Kriegl,
  • Gaia Kravanja,
  • Luka Hribar,
  • Lucija Čoga,
  • Irena Drevenšek-Olenik,
  • Matija Jezeršek,
  • Mitjan Kalin and
  • Mikhail Shamonin

17 September 2022

We demonstrate the control of wettability of non-structured and microstructured magnetoactive elastomers (MAEs) by magnetic field. The synthesized composite materials have a concentration of carbonyl iron particles of 75 wt.% (≈27 vol.%) and th...

  • Article
  • Open Access
12 Citations
4,306 Views
15 Pages

17 September 2022

Black polymer films with high thermal stability are highly desired in flexible electrical and electronic fields. Conventional black polymer films based on high-temperature resistant polymers and black inorganic dyes are usually suffered from the poor...

  • Article
  • Open Access
20 Citations
4,735 Views
27 Pages

17 September 2022

This study synthesized a series of new biobased copolyamides (co-PAs), namely PA56/PA66 with various comonomer ratios, by using in situ polycondensation. The structures, compositions, behaviors, and crystallization kinetics of the co-PAs were investi...

  • Article
  • Open Access
1,960 Views
24 Pages

17 September 2022

A two-velocity mathematical model is proposed for dense suspension flows through channel bifurcations. Equations agree with thermodynamic laws and they are suitable for both heavy and light particles. The pulsatile mode of injection of particles is c...

  • Article
  • Open Access
34 Citations
5,441 Views
13 Pages

Electrospinning Silk Fibroin/Graphene Nanofiber Membrane Used for 3D Wearable Pressure Sensor

  • Zulan Liu,
  • Jiaxuan Wang,
  • Qian Zhang,
  • Zheng Li,
  • Zhi Li,
  • Lan Cheng and
  • Fangyin Dai

16 September 2022

With the improvement of science and technology, flexible sensors have become a hot research topic. Flexible sensors have broad application in human health detection and motion detection and other fields. In this paper, the silk fibroin/graphene nanof...

  • Article
  • Open Access
4 Citations
3,160 Views
12 Pages

16 September 2022

Epoxy-based composites are designed for long-lasting applications, though their wide use is in contrast with their poor recyclability, which poses serious end-of-life issues. In order to reduce their environmental impact, precursors derived from foss...

  • Article
  • Open Access
13 Citations
2,277 Views
18 Pages

16 September 2022

Using locally available raw materials for preparing concrete, such as coral reefs, seawater, and sea sand, is conducive to compensating for the shortage of construction materials used on remote islands. Jacketing fiber-reinforced polymer (FRP), as pa...

  • Article
  • Open Access
2,282 Views
11 Pages

16 September 2022

This work developed an electrically conductive thermosetting resin composite that transitioned from a liquid to solid without using solvents in response to an increase in temperature. This material has applications as a matrix for carbon fiber reinfo...

  • Article
  • Open Access
13 Citations
2,725 Views
16 Pages

Melt-Crystallizations of α and γ Forms of Isotactic Polypropylene in Propene-Butene Copolymers

  • Miriam Scoti,
  • Fabio De Stefano,
  • Filomena Piscitelli,
  • Giovanni Talarico,
  • Angelo Giordano and
  • Claudio De Rosa

16 September 2022

Random isotactic propene-butene copolymers (iPPC4) of different stereoregularity have been synthesized with three different homogeneous single center metallocene catalysts having different stereoselectivity. All samples crystallize from the polymeriz...

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Polymers - ISSN 2073-4360