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Materials, Volume 18, Issue 22

2025 November-2 - 191 articles

Cover Story: The LSPR property of metal nanoparticles has found widespread use in medical diagnostics, drug delivery, energy harvesting, and photocatalysis. However, the primary methods to fabricate these nanomaterials are in aqueous medium and rely on electrostatic interactions to stabilize them in the colloidal state. In this work, we demonstrate methods for successful functionalization and phase-transfer of these nanoparticles into organic solvents. Various nanoparticles, ligands, and solvents were scanned to identify polymeric systems that can successfully envelope the nanoparticle providing transferable intermolecular options such as dipole–dipole and hydrogen-bonding interactions. These methods establish brand-range solutions for this class of materials, enabling stable transfer of their LSPR property into organic solvents, expanding their scope for modification and utilization. View this paper
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Articles (191)

  • Article
  • Open Access
604 Views
15 Pages

20 November 2025

In this study, surface alloying technology based on Gas Tungsten Arc Welding (GTAW) was used to synthesize in situ NiTiTa coatings on a NiTi substrate using commercially pure Ta foils. The influence of different Ta contents (0.91, 1.42, and 2.91 at.%...

  • Article
  • Open Access
798 Views
24 Pages

Study of Preparation and Performance Porous Thermal Insulation Refractory Materials from Aluminum Ash and Red Mud

  • Jiayi Zhong,
  • Zichao Li,
  • Weiyuan Li,
  • Hongzhi Yue,
  • Laijun Ma,
  • Haoyu Zhao,
  • Wenjuan Jiao,
  • Yan Wang and
  • Zhiyang Chang

20 November 2025

The risk of environmental accumulation of aluminum ash and red mud is increasing, emphasizing the demand for high-value utilization. In this study, the conversion of aluminum ash and red mud into porous refractory materials with good thermal insulati...

  • Communication
  • Open Access
769 Views
15 Pages

20 November 2025

In this work, Sm3+-activated lead phosphate glass has been studied using spectroscopic methods. Based on absorption spectrum measurements, the oscillator strengths for Sm3+ ions were determined and compared to those calculated from the Judd–Ofe...

  • Article
  • Open Access
1 Citations
574 Views
23 Pages

Experimental and Molecular Dynamics Investigation of the Rejuvenation Effect of Bio-Oils on Aged High-Penetration Asphalt

  • Hongxia Xiong,
  • Shichao Liang,
  • Quantao Liu,
  • Shisong Ren,
  • Georgios Pipintakos,
  • Shaopeng Wu,
  • Muyu Liu and
  • Shi Xu

20 November 2025

The deterioration of high-penetration asphalt pavements due to oxidative aging presents a significant challenge in highway maintenance. This study investigates the rejuvenation effect of three bio-oils, namely palm oil, soybean oil, and sunflower oil...

  • Article
  • Open Access
675 Views
24 Pages

20 November 2025

This study investigates the mechanical behavior of glass bead specimens with different surface roughness under triaxial testing using the Discrete Element Method (DEM). The microscopic parameters for the DEM simulation were calibrated by referencing...

  • Article
  • Open Access
639 Views
19 Pages

20 November 2025

This study analyzes the influence of material extrusion (MEX) 3D printing and ironing parameters on parts made of polylactic acid (PLA), such as top surface roughness and flatness. Surface ironing is one of the post-processing methods. It is an inter...

  • Editorial
  • Open Access
459 Views
2 Pages

20 November 2025

From information technology, life, and healthcare to the energy revolution and sustainable development, a series of major technological breakthroughs depend on the substantial improvement of material properties [...]

  • Review
  • Open Access
904 Views
20 Pages

20 November 2025

As the lightest structural materials among practical metals, magnesium (Mg) alloys have broad application prospects in various fields, including automobiles, electronics, communications, aerospace and biomaterials. However, the main problem currently...

  • Article
  • Open Access
832 Views
22 Pages

20 November 2025

Lock-in thermography is a widely used nondestructive testing technique for detecting subsurface defects in solid materials. In this study, one-dimensional analytical modeling and three-dimensional finite element simulations were combined to elucidate...

  • Article
  • Open Access
1,049 Views
25 Pages

Stabilizing the Localized Surface Plasmon Resonance (LSPR) of Citrate-Synthesized Metal Nanoparticles in Organic Solvents

  • Jacob P. Magdon,
  • Matthew J. Jasienski,
  • Madison R. Waltz,
  • Gabrielle A. Grzymski,
  • Calvin Chen,
  • Arion M. Solomon,
  • Minh Dang Nguyen,
  • Jong Moon Lee,
  • John C. Deàk and
  • Riddhiman Medhi
  • + 1 author

20 November 2025

Gold–silver nanoshells (GS-NSs) are hollow spherical nanoparticles with an alloyed Ag-Au shell. GS-NSs exhibit a tunable localized surface plasmon resonance (LSPR) in the visible to near-IR wavelengths as a function of composition and shell thi...

  • Article
  • Open Access
603 Views
20 Pages

Research on Mixing Uniformity Evaluation and Molding Method for Crumb Rubber Asphalt Mixtures

  • Wenhua Wang,
  • Yi Lu,
  • Lingdi Kong,
  • Wenke Yan,
  • Yilong Li,
  • Mulian Zheng,
  • Chuan Lu and
  • Guanglei Qu

20 November 2025

The broader adoption of crumb rubber asphalt mixtures (CRAM) as sustainable pavement materials is currently limited by two key technical barriers. Firstly, there is a lack of standardized methods to evaluate mixing uniformity. Secondly, the material&...

  • Article
  • Open Access
512 Views
17 Pages

20 November 2025

This study systematically investigated the effects of solution temperature (460–560 °C) on the microstructure, mechanical properties, and corrosion behavior of AlSi37Cu0.7Mg0.9Ni0.2 alloy rods prepared by rapid solidification and hot-extrus...

  • Article
  • Open Access
621 Views
18 Pages

20 November 2025

This study investigates the effects of chromium (0.4~1.2) Cr content and temperature (35–80 °C) on the corrosion behavior and mechanisms of steels in a water-saturated supercritical CO2 (S-CO2) environment, aiming to provide theoretical fou...

  • Article
  • Open Access
601 Views
25 Pages

Development of an Ergonomic Additively Manufactured Modular Saddle for Rehabilitation Cycling

  • Alberto Iglesias Calcedo,
  • Chiara Bregoli,
  • Valentina Abbate,
  • Marta Mondellini,
  • Jacopo Fiocchi,
  • Gennaro Rollo,
  • Cristina De Capitani,
  • Marino Lavorgna,
  • Marco Sacco and
  • Alfredo Ronca
  • + 3 authors

19 November 2025

This work reports the design, fabrication, and validation of a modular ergonomic saddle for rehabilitation cycling, developed through a combined additive manufacturing approach. The saddle consists of a metallic support produced by Laser Powder Bed F...

  • Article
  • Open Access
620 Views
15 Pages

Influence of Fused Filament Fabrication Strategy on Polyamide Properties

  • Marta Beata Krawczyk,
  • Marcin Andrzej Królikowski and
  • Kamil Urbanowicz

19 November 2025

This study investigates the influence of Fused Filament Fabrication (FFF) parameters on the properties of polyamide (PA, Nylon™) parts, which are valued for their excellent mechanical properties in additive manufacturing. The parameters examine...

  • Article
  • Open Access
616 Views
24 Pages

19 November 2025

This study explores an integrated strategy combining gypsum activation and pressurized flue gas heat curing (FHC) to enhance the interfacial transition zone (ITZ) in concrete incorporating over 80% circulating fluidized bed fly ash (CFBFA)-based arti...

  • Article
  • Open Access
2,266 Views
14 Pages

19 November 2025

Two series of glasses with compositions (90 − x)TeO2-xV2O5-10Bi2O3 and (80 − x)TeO2-xV2O5-20Bi2O3, where x = 20, 30, 40 mol %, were synthesized. Glasses were obtained by the melt-quenching technique. The molar volume (33.48–48.37 cm...

  • Article
  • Open Access
2 Citations
821 Views
25 Pages

Numerical and Experimental Correlation Between Half-Cell Potential and Steel Mass Loss in Corroded Reinforced Concrete

  • Max Lawrence L. Li,
  • Seong-Hoon Kee,
  • Cris Edward F. Monjardin and
  • Kevin Paolo V. Robles

19 November 2025

Half-cell potential (HCP) measurement is widely applied as a non-destructive technique for assessing corrosion probability, yet its diagnostic capacity remains limited to probabilistic interpretations rather than quantifying the extent of steel mass...

  • Review
  • Open Access
970 Views
39 Pages

19 November 2025

Metals with a hexagonal close-packed (HCP) structure such as magnesium, titanium and zirconium constitute key structural materials in the aerospace, automotive, biomedical and nuclear energy industries. Their welding and regeneration by conventional...

  • Review
  • Open Access
1 Citations
711 Views
14 Pages

Review of Radiation Embrittlement of Aluminum Alloys Used in Research Reactors

  • Ferenc Gillemot,
  • Murthy Kolluri,
  • Ildiko Szenthe,
  • Frideriki Naziris and
  • Lajos Berzy

19 November 2025

Research reactors are generally built from aluminum alloys during the last century. Most of the operation times of them already exceed the design lifetime. The original mechanical properties change during service. The radiation embrittlement affects...

  • Article
  • Open Access
571 Views
13 Pages

Laser-Based Crystallization of Chemical Solution Deposited Proton-Conducting Thin Films

  • Jonas Frühling,
  • Samuel Fink,
  • Theodor Schneller and
  • Christian Vedder

19 November 2025

This work investigates the laser-based solid-phase crystallization of wet-chemically deposited BZY (yttrium doped barium zirconate) thin films on metallic substrates. For this purpose, amorphous BZY thin films are deposited on nickel-based alloy subs...

  • Article
  • Open Access
657 Views
25 Pages

Application of an Improved Dual-Branch Model Based on Multi-Scale Feature Fusion in Fracture Surface Image Recognition

  • Fei Gao,
  • Denghui Wang,
  • Fulai Yang,
  • Mingping Zhou,
  • Yuan Li,
  • Zhen Zheng,
  • Jianpeng Shi and
  • Zheng Zhang

19 November 2025

In order to improve the recognition accuracy and model interpretability of metal fracture scanning electron microscope (SEM) images, this research presents an improved dual-branch model (IDBM) based on multi-scale feature fusion. This model employs V...

  • Article
  • Open Access
1 Citations
480 Views
16 Pages

Dynamic Compressive Mechanical Behavior of a Novel Three-Dimensional Re-Entrant Honeycomb (3D-RH) Structure

  • Xiyan Du,
  • Lun Qi,
  • Yulong Shi,
  • Lei Xing,
  • Gang Wang,
  • Haibo Zhang,
  • Wenting Bai,
  • Xiaofei Cao and
  • Chunwang He

19 November 2025

Negative Poisson’s ratio structural materials have unique deformation characteristics and excellent mechanical properties, and are widely used in multiple key fields, such as aerospace, nuclear safety, rail transit, and so on. However, most of...

  • Article
  • Open Access
548 Views
18 Pages

19 November 2025

Cross-laminated timber (CLT) panels, composed of orthogonally bonded layers, are often used in civil engineering and tall constructions owing to their sustainability, prefabrication advantages and favourable mechanical performance. However, their mul...

  • Article
  • Open Access
1 Citations
842 Views
16 Pages

Ultra-Strong Transparent ZnAl2O4 Glass-Ceramics via Controlled Crystallization and Ion Exchange

  • Ivan Veselov,
  • Georgiy Shakhgildyan,
  • Vitaliy Savinkov,
  • Nikita Golubev,
  • Kirill Tregubov,
  • Daniil Vinogradov,
  • Leon Avakyan,
  • Michael Ojovan,
  • Manasi Ghosh and
  • Vladimir Sigaev

19 November 2025

Enhancing the mechanical strength of transparent glass-ceramics (TGCs) without compromising their optical performance remains a key challenge for advanced optical and photonic materials. Among aluminosilicate systems, ZnO–MgO–Al2O3–...

  • Article
  • Open Access
471 Views
20 Pages

OVI-Guided Tuning of Oxygen Vacancies in Fly Ash Denitrification Catalysts

  • Zhanfeng Qi,
  • Shuyang Wang,
  • Xiuli Guo,
  • Guancheng Li and
  • Jingliang Li

19 November 2025

Denitrification catalysts are essential for reducing NOx emissions from combustion and protecting air quality. This study introduces and validates an Oxygen Vacancy Index (OVI) that quantifies redox-active vacancies and guides defect engineering in f...

  • Article
  • Open Access
678 Views
15 Pages

19 November 2025

It is crucial to control and comprehend the interaction between elemental adsorbates and two-dimensional materials to drive future generations of electronic, sensing, and energy applications. One such material, particularly interesting from the persp...

  • Systematic Review
  • Open Access
827 Views
30 Pages

18 November 2025

Peri-implantitis (PI) is characterized by inflammatory tissue destruction and alveolar bone loss surrounding dental implants, posing clinical challenges. To promote bone regeneration, clinicians often use resorbable or non-resorbable membranes in com...

  • Article
  • Open Access
522 Views
20 Pages

18 November 2025

To overcome the corrosion issues of conventional steel reinforcement and the brittleness of fiber-reinforced polymer (FRP) materials, steel-FRP composite bars (SFCBs) offer an innovative solution by combining the ductility of steel with the high stre...

  • Article
  • Open Access
708 Views
16 Pages

The MT-FEM Model for Predicting Young’s Modulus of Graphene Composites with Complex Morphologies

  • Xiaoxia Zhai,
  • Huzaifa Bin Hashim,
  • Jun Huang,
  • Eugene Zhen Xiang Soo and
  • Lina Luo

18 November 2025

To address the inaccuracy of the traditional Mori-Tanaka method in predicting the Young’s modulus of graphene composites—caused by the mismatch between the assumed reinforcement shape (e.g., ellipsoidal) and the actual morphology of graph...

  • Article
  • Open Access
554 Views
25 Pages

18 November 2025

We present analytical investigations of evolution of localized disturbances during their propagation in an infinite monoatomic nonlinear one-dimensional lattice, specifically the α-Fermi-Pasta-Ulam (FPU) chain. We focus on two key disturbance c...

  • Article
  • Open Access
606 Views
18 Pages

18 November 2025

The increasing generation of construction and demolition waste (CDW) and the overexploitation of natural aggregates (NA) have necessitated sustainable solutions for recycled aggregate concrete (RAC). This study proposes an innovative inorganic–...

  • Article
  • Open Access
1 Citations
677 Views
31 Pages

Development and Characterization of Biogenic Hydroxyapatite Coatings Derived from Crab Shell Waste on Ti6Al4V Substrates

  • Yago Antonio de Lima Guedes,
  • Maurício Maia Ribeiro,
  • Douglas Santos Silva,
  • Raí Felipe Pereira Junio,
  • Roberto Paulo Barbosa Ramos,
  • Sergio Neves Monteiro,
  • Elza Monteiro Leão Filha and
  • Jean da Silva Rodrigues

18 November 2025

In this work, we developed and characterized a hydroxyapatite (HA) ceramic coating derived from Ucides cordatus crab-shell waste and applied it onto Ti–Al–V titanium substrates for biomedical use. Substrate analysis confirmed an α +...

  • Article
  • Open Access
570 Views
32 Pages

18 November 2025

The sustainable use of recycled aggregate concrete (RAC) is a critical pathway toward resource-efficient and environmentally responsible construction. However, the mechanical performance of RAC—particularly its elastic modulus—exhibits pr...

  • Article
  • Open Access
600 Views
19 Pages

18 November 2025

The migration of the long-lived isotope technetium-99 (half-life 2.1 × 105 years) presents a significant challenge for the deep geological disposal of radioactive waste. This study investigates the immobilization of technetium by carbon steel c...

  • Article
  • Open Access
1 Citations
593 Views
25 Pages

18 November 2025

The objective of the study was to determine the minimum thickness of a thin wall for milling at a maximized axial depth of cut, considering the effect of cutting speed on residual stress and post-machining distortion. Test samples were made of alumin...

  • Article
  • Open Access
468 Views
15 Pages

Investigation of the Carbonation Behavior of Cement Mortar Containing Interior Stone Sludge and Recycled Mask Fibers

  • Junhyeok Choi,
  • Seongjin Cho,
  • Dongkyu Lee,
  • Gwang Mok Kim,
  • Beomjoo Yang and
  • Daeik Jang

18 November 2025

This study examines the carbonation and mechanical behavior of cement mortar incorporating artificial interior stone (AIS) sludge and recycled mask fibers (RMFs). Sludge, derived from AIS waste, replaced 30 wt.% of fine aggregate, while RMF from poly...

  • Review
  • Open Access
1,328 Views
45 Pages

18 November 2025

This review article summarizes the most widely used and effective technologies for producing protective and functional bilayer coatings. Particular attention is given to methods such as electroplating and electroless metallization, chemical vapor dep...

  • Article
  • Open Access
732 Views
17 Pages

18 November 2025

The practical application of vanadium-based cathode materials in aqueous zinc-ion batteries (AZIBs) is severely hindered by vanadium dissolution, low electronic conductivity, and sluggish reaction kinetics in aqueous electrolytes. In this work, a thr...

  • Review
  • Open Access
1 Citations
2,361 Views
27 Pages

18 November 2025

Increased needs arising from efficient utilization of renewable energy sources and the emerging use of portable electronic devices have introduced new requirements and challenges, such as fast charging and discharging, high-speed energy delivery, lon...

  • Article
  • Open Access
626 Views
23 Pages

18 November 2025

This study introduces a novel dual-model deep learning framework based on Bidirectional Gated Recurrent Units (Bi-GRUs) with the Attention Mechanism to predict intermediate-pressure (IP) turbine casing temperatures in a 370 MW coal-fired power plant...

  • Article
  • Open Access
719 Views
18 Pages

18 November 2025

Phosphorus (P) scarcity and pollution demand sustainable recovery strategies. This study engineered a functional straw biochar (F-SBC) from corn straw through synergistic KOH activation and MgCl2 modification for efficient P recovery and slow release...

  • Systematic Review
  • Open Access
726 Views
30 Pages

The Effect of Laser Surface Treatment on the Bond Strength of Adhesive Materials to Primary Teeth: A Systematic Review

  • Witold Świenc,
  • Jan Kiryk,
  • Mateusz Michalak,
  • Zuzanna Majchrzak,
  • Marzena Laszczyńska,
  • Sylwia Kiryk,
  • Natalia Grychowska-Gąsior,
  • Izabela Nawrot-Hadzik,
  • Jacek Matys and
  • Maciej Dobrzyński

18 November 2025

This systematic review aimed to evaluate the effect of laser surface treatment on the bond strength of adhesive restorative materials to primary teeth. A comprehensive literature search was conducted in PubMed, Scopus, Embase, Web of Science and Worl...

  • Article
  • Open Access
713 Views
14 Pages

17 November 2025

The valorization of biomass waste represents an important direction in green chemistry. This study successfully prepared blue fluorescent carbon dots (BP-CDs) from waste banana peels via a one-step hydrothermal method, establishing a dual-functional...

  • Article
  • Open Access
572 Views
16 Pages

17 November 2025

Vertical-cavity surface-emitting lasers (VCSELs) have generated extensive enthusiasm in scientific research on and applications of lasers. However, thermal resistance has seriously limited the performance of such devices for a long time, especially i...

  • Review
  • Open Access
3 Citations
1,857 Views
42 Pages

Recent Developments in Novel TPMS Lattice Materials: Design Optimization, Performance Control, and Applications in Biomimetic Scaffolds

  • Syed Zahid Ahmad,
  • Muhammad Hassan Masood,
  • Muhammad Umar Khattab,
  • Syed Sulman Ahmad,
  • Syed Asad Ali Zaidi and
  • Sohaib Z. Khan

17 November 2025

Triply Periodic Minimal Surfaces (TPMSs) are mathematically defined surfaces that exhibit periodicity in three dimensions while maintaining a minimal surface property. TPMS-based lattices have gained significant attention in recent years, fueled by a...

  • Article
  • Open Access
756 Views
11 Pages

17 November 2025

This study investigates the design and experimental evaluation of Fe–B–Si-based bilayer composites engineered for dual shielding against gamma rays and thermal neutrons. The materials integrate a boron-enriched amorphous Fe matrix with su...

  • Article
  • Open Access
713 Views
21 Pages

Development and Implementation of a Defect Detection Model for Microstructures Using Image Processing Methods

  • Sandra Gajoch,
  • Dorota Wilk-Kołodziejczyk,
  • Łukasz Marcjan,
  • Roberto Corizzo,
  • Adam Bitka,
  • Marcin Małysza and
  • Gerard Skomin

17 November 2025

The aim of this research is to develop and implement artificial intelligence models for the automatic detection of defects in the microstructures of austempered ductile iron (ADI). Our research used three different approaches, representing various ca...

  • Article
  • Open Access
564 Views
28 Pages

17 November 2025

Recycling industrial solid waste phosphogypsum into phosphogypsum concrete (PGC) is a crucial pathway for achieving high-value solid waste utilization. However, the scarcity of experimental samples for PGC has led to inaccurate predictions of compres...

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Materials - ISSN 1996-1944