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25 Results Found

  • Review
  • Open Access
16 Citations
10,453 Views
30 Pages

Recent Advancements in Na Super Ionic Conductor-Incorporated Composite Polymer Electrolytes for Sodium-Ion Battery Application

  • Kanya Koothanatham Senthilkumar,
  • Rajagopalan Thiruvengadathan and
  • Ramanujam Brahmadesam Thoopul Srinivasa Raghava

Sodium-ion batteries (SIBs) have garnered significant attention as a cost-effective and sustainable alternative to lithium-ion batteries (LIBs) due to the abundance and eco-friendly extraction of sodium. Despite the larger ionic radius and heavier ma...

  • Article
  • Open Access
14 Citations
5,901 Views
25 Pages

11 September 2021

With a crystal lattice structure first characterized in the 1970s, NASICON sodium-based superionic conductors have recently found renewed interest as solid electrolytes in sodium-ion and seawater flow batteries due to their exceptional ionic conducti...

(This article belongs to the Section Materials Science and Engineering)
  • Article
  • Open Access
9 Citations
3,644 Views
18 Pages

Influence of 3d Transition Metal Doping on Lithium Stabilized Na-β″-Alumina Solid Electrolytes

  • Cornelius L. Dirksen,
  • Karl Skadell,
  • Matthias Schulz,
  • Micha P. Fertig and
  • Michael Stelter

17 September 2021

Na-β″-alumina is the commercially most successful solid electrolyte due to its application in ZEBRA and NAS® batteries. In this work, Li-stabilized Na-β″-alumina electrolytes were doped with 3d transition metal oxides, namely TiO2, Mn3O4, and NiO, in...

(This article belongs to the Special Issue Battery Technology and Materials Development for Grid Energy Storage)
  • Article
  • Open Access
9 Citations
4,377 Views
11 Pages

Chlorine-Rich Na6−xPS5−xCl1+x: A Promising Sodium Solid Electrolyte for All-Solid-State Sodium Batteries

  • Yi Zhang,
  • Haoran Zheng,
  • Jiale You,
  • Hongyang Zhao,
  • Abdul Jabbar Khan,
  • Ling Gao and
  • Guowei Zhao

24 April 2024

Developing argyrodite-type, chlorine-rich, sodium-ion, solid-state electrolytes with high conductivity is a long-term challenge that is crucial for the advancement of all-solid-state batteries (ASSBs). In this study, chlorine-rich, argyrodite-type Na...

(This article belongs to the Topic Advances in Energy Storage Materials/Devices and Solid-State Batteries)
  • Article
  • Open Access
794 Views
14 Pages

Solid-Phase Synthesis of Na3V2(PO4)3/C Composite for Cathode Materials of Sodium-Ion Batteries

  • Ilya Sidorov,
  • Valery Zhylinski,
  • Sergei Kusmanov,
  • Alexey Vereschaka,
  • Ihar Razanau and
  • Sergey Grigoriev

The aim of this article was to improve the solid-phase synthesis of Na3V2(PO4)3/C composite for sodium-ion battery cathode materials using an innovative technique for creating a protective reducing atmosphere, which is formed by incomplete oxidation...

(This article belongs to the Special Issue Editorial Board Members' Collection Series: Electrochemical Composites)
  • Article
  • Open Access
7 Citations
3,187 Views
17 Pages

Sol–Gel Synthesis of Carbon-Containing Na3V2(PO4)3: Influence of the NASICON Crystal Structure on Cathode Material Properties

  • Oleg O. Shichalin,
  • Zlata E. Priimak,
  • Alina Seroshtan,
  • Polina A. Marmaza,
  • Nikita P. Ivanov,
  • Anton V. Shurygin,
  • Danil K. Tsygankov,
  • Roman I. Korneikov,
  • Vadim V. Efremov and
  • Eugeniy K. Papynov
  • + 1 author

3 October 2025

With the rapid advancement of energy storage technologies, there is a growing demand for affordable, efficient, and environmentally benign battery systems. Sodium-ion batteries (SIBs) present a promising alternative to lithium-ion systems due to sodi...

(This article belongs to the Special Issue Composite Materials for Energy Management, Storage or Transportation)
  • Article
  • Open Access
4 Citations
4,019 Views
20 Pages

Assessing the Efficacy of Seawater Batteries Using NASICON Solid Electrolyte

  • Mihaela Iordache,
  • Anișoara Oubraham,
  • Mihaela Bazga,
  • Gheorghe Eugen Ungureanu,
  • Simona Elena Borta and
  • Adriana Marinoiu

21 March 2025

The need to reduce greenhouse gas emissions and guarantee a stable and reliable energy supply has resulted in an increase in the demand for sustainable energy storage solutions over the last decade. Rechargeable batteries with solid-state electrolyte...

(This article belongs to the Special Issue Novel Ceramic Materials: Processes, Properties and Applications)
  • Article
  • Open Access
10 Citations
5,119 Views
10 Pages

21 January 2023

Sodium–ion batteries (SIBs) are essential for large–scale energy storage attributed to the high abundance of sodium. Polyanion Na3V2(PO4)3 (NVP) is a dominant cathode candidate for SIBs because of its high-voltage and sodium superionic co...

(This article belongs to the Special Issue Nanostructured and Functional Nanomaterials for Energy Storage and Removal of Pollutants)
  • Article
  • Open Access
10 Citations
5,108 Views
13 Pages

16 March 2021

Na-β″-alumina (Na2O.~6Al2O3) is known to be an excellent sodium ion conductor in battery and sensor applications. In this study we report fabrication of Na- β″-alumina + YSZ dual phase composite to mitigate moisture and CO2 corrosion that otherwise c...

(This article belongs to the Special Issue Highly-Conductive Ceramics with Multiple Types of Mobile Charge Carriers)
  • Article
  • Open Access
5 Citations
1,844 Views
11 Pages

Cobalt Doping of Na2VTi(PO4)3 Enables a High-Energy NASICON-Type Cathode Material for Sodium-Ion Batteries

  • Yu Zhang,
  • Mengyao Wang,
  • Hao Fan,
  • Chenyang Huang,
  • Mingfei Liu,
  • Xiaofa Liang,
  • Ping Hu,
  • Xuanpeng Wang,
  • Qin Wang and
  • Liang Zhou
  • + 1 author

22 May 2025

Natrium superionic conductor (NASICON) compounds have emerged as a rising star in the field of sodium-ion batteries (SIBs) owing to their stable framework structure and high Na+ ionic conductivity. The NASICON-structured Na2VTi(PO4)3 manifests signif...

  • Article
  • Open Access
5 Citations
3,846 Views
15 Pages

Preparation of Porous Composite Phase Na Super Ionic Conductor Adsorbent by In Situ Process for Ultrafast and Efficient Strontium Adsorption from Wastewater

  • Yuliang Chen,
  • Xiangbiao Yin,
  • Hao Fu,
  • Zheyang Lin,
  • Guangcan Ma,
  • Xinpeng Wang,
  • Qingsong Wang and
  • Fangqiang Chen

29 March 2023

Strontium, the main component of radioactive nuclear wastewater, is characterized by a high fission yield and an extended half-life. It is easily absorbed by the human body, thus greatly threatening the environment and the human body. In this study,...

(This article belongs to the Section Extractive Metallurgy)
  • Article
  • Open Access
1 Citations
3,126 Views
11 Pages

Chemically Driven Ion Exchanging Synthesis of Na5YSi4O12-Based Glass-Ceramic Proton Conductors

  • Toshinori Okura,
  • Naoki Matsuoka,
  • Yoshiko Takahashi,
  • Naoya Yoshida and
  • Kimihiro Yamashita

7 March 2023

We have developed 12-membered silica-tetrahedra-ringed Na5YSi4O12-type sodium ion conducting glass-ceramics on the basis of the composition Na3+3x-yR1-xPySi3-yO9 (R: rare earth elements; denoted as Narpsio); especially, the material of Na4Y0.6P0.2Si2...

(This article belongs to the Section Advanced and Functional Ceramics and Glasses)
  • Article
  • Open Access
12 Citations
3,914 Views
18 Pages

Synthesis, Electrical Properties and Na+ Migration Pathways of Na2CuP1.5As0.5O7

  • Ohud S. A. ALQarni,
  • Riadh Marzouki,
  • Youssef Ben Smida,
  • Majed M. Alghamdi,
  • Maxim Avdeev,
  • Radhouane Belhadj Tahar and
  • Mohamed Faouzi Zid

6 March 2020

A new member of sodium metal diphosphate-diarsenate, Na2CuP1.5As0.5O7, was synthesized as polycrystalline powder by a solid-state route. X-ray diffraction followed by Rietveld refinement show that the studied material, isostructural with β-Na2Cu...

(This article belongs to the Special Issue Materials Processing for Production of Nanostructured Thin Films)
  • Review
  • Open Access
55 Citations
15,129 Views
42 Pages

Sodium Polymer Electrolytes: A Review

  • Sumit Kumar,
  • Rajesh Raghupathy and
  • Michele Vittadello

21 February 2024

Lithium-based electrolytes are, at least from a thermodynamic standpoint, the most suitable ion-transport materials for energy storage systems. However, lithium-based ionic conductors suffer from safety concerns, and the limited availability of lithi...

(This article belongs to the Section Battery Materials and Interfaces: Anode, Cathode, Separators and Electrolytes or Others)
  • Article
  • Open Access
2 Citations
2,630 Views
18 Pages

Mineral-like Synthetic Compounds Stabilized under Hydrothermal Conditions: X-ray Diffraction Study and Comparative Crystal Chemistry

  • Galina Kiriukhina,
  • Olga Yakubovich,
  • Polina Verchenko,
  • Anatoly Volkov,
  • Larisa Shvanskaya,
  • Olga Dimitrova and
  • Sergey Simonov

29 December 2023

Under hydrothermal conditions emulating natural hydrothermalites, three oxo-salts with sodium and transition metal cations were obtained in the form of single crystals. Their compositions and crystal structures were studied using scanning electron mi...

(This article belongs to the Section Crystallography and Physical Chemistry of Minerals & Nanominerals)
  • Article
  • Open Access
7 Citations
4,551 Views
21 Pages

Sodium ion batteries have been receiving increasing attention and may see potential revival in the near future, particularly in large-scale grid energy storage coupling with wind and solar power generation, due to the abundant sodium resources, low c...

(This article belongs to the Topic Electromaterials for Environment & Energy)
  • Review
  • Open Access
40 Citations
9,357 Views
18 Pages

Impact of Surface Structure on SEI for Carbon Materials in Alkali Ion Batteries: A Review

  • Xvtong Zhao,
  • Ying Chen,
  • Hao Sun,
  • Tao Yuan,
  • Yinyan Gong,
  • Xinjuan Liu and
  • Taiqiang Chen

Due to their low cost, suitable working potential and high stability, carbon materials have become an irreplaceable anode material for alkali ion batteries, such as lithium ion batteries, sodium ion batteries and potassium ion batteries. During the i...

(This article belongs to the Special Issue Review of Electrode Materials and Electrolyte for Batteries)
  • Article
  • Open Access
6 Citations
1,918 Views
14 Pages

In-Situ One-Step Hydrothermal Synthesis of LiTi2(PO4)3@rGO Anode for High Performance Lithium-Ion Batteries

  • Otmane Zoubir,
  • Abdelfettah Lallaoui,
  • M’hamed Oubla,
  • Alvaro Y. Tesio,
  • Alvaro Caballero and
  • Zineb Edfouf

17 March 2025

The sodium super ionic conductor (NASICON) structured LiTi2(PO4)3 (LTP) has been developed as electrode material for Li-ion batteries (LIBs) with promising electrochemical performance, owing to its outstanding structural stability and rapid lithium-i...

  • Article
  • Open Access
6 Citations
1,975 Views
21 Pages

8 July 2024

Two ceramic samples of sodium tantalate (NaTaO3), doped with metal ions of copper (Cu; sample S1) or aluminum (Al; sample S2), were obtained by the sol-gel method. Complex impedance measurements in the frequency range (200 Hz–2 MHz) and at temp...

  • Article
  • Open Access
32 Citations
8,146 Views
10 Pages

9 October 2022

Lithium-ion batteries are popular energy storage devices due to their high energy density. Solid electrolytes appear to be a potential replacement for flammable liquid electrolytes in lithium batteries. This inorganic/hybrid solid electrolyte is a co...

(This article belongs to the Special Issue Anode and Cathode Materials for Lithium-Ion and Sodium-Ion Batteries)
  • Article
  • Open Access
42 Citations
5,967 Views
11 Pages

6 July 2021

Sodium super ionic conductor (NASICON)-type Na3Zr2Si2PO12 (NZSP) with the advantages of the high ionic conductivity, stability and safety is one of the most famous solid-state electrolytes. NZSP, however, requires the high sintering temperature about...

(This article belongs to the Section Electronic Materials)
  • Article
  • Open Access
3 Citations
2,967 Views
16 Pages

The Role of Sintering Temperature and Dual Metal Substitutions (Al3+, Ti4+) in the Development of NASICON-Structured Electrolyte

  • Hashlina Rusdi,
  • Roshidah Rusdi,
  • Shujahadeen B. Aziz,
  • Abdullah Saad Alsubaie,
  • Khaled H. Mahmoud and
  • Mohd F. Z. Kadir

30 November 2021

The aim of this study is to synthesize Li1+xAlxTixSn2−2x(PO4) sodium super ion conductor (NASICON) -based ceramic solid electrolyte and to study the effect of dual metal substitution on the electrical and structural properties of the electrolyt...

(This article belongs to the Special Issue Advanced Energy Storage Materials: Preparation, Characterization and Applications)
  • Article
  • Open Access
58 Citations
4,098 Views
21 Pages

Comprehensive Investigation of Cu2+ Adsorption from Wastewater Using Olive-Waste-Derived Adsorbents: Experimental and Molecular Insights

  • Noureddine Elboughdiri,
  • Hana Ferkous,
  • Karima Rouibah,
  • Abir Boublia,
  • Amel Delimi,
  • Krishna Kumar Yadav,
  • Alessandro Erto,
  • Djamel Ghernaout,
  • Alsamani A. M. Salih and
  • Yacine Benguerba
  • + 1 author

14 January 2024

This study investigates the efficacy of adsorbents from locally sourced olive waste—encompassing olive skins, leaves, and pits, recovered from the initial centrifugation of olives (OWP)—and a composite with sodium alginate (OWPSA) for the...

(This article belongs to the Special Issue Adsorption Materials and Adsorption Behavior 2.0)
  • Feature Paper
  • Article
  • Open Access
21 Citations
5,934 Views
10 Pages

29 July 2019

Sodium superionic conductor (NASICON)-type lithium aluminum germanium phosphate (LAGP) has attracted increasing attention as a solid electrolyte for all-solid-state lithium-ion batteries (ASSLIBs), due to the good ionic conductivity and highly stable...

(This article belongs to the Special Issue Nanomaterials and Nanofabrication for Electrochemical Energy Storage)
  • Article
  • Open Access
8 Citations
3,280 Views
11 Pages

Synthesis of Superionic Conductive Li1+x+yAlxSiyTi2−xP3−yO12 Solid Electrolytes

  • Hyeonwoo Jeong,
  • Dan Na,
  • Jiyeon Baek,
  • Sanggil Kim,
  • Suresh Mamidi,
  • Cheul-Ro Lee,
  • Hyung-Kee Seo and
  • Inseok Seo

31 March 2022

Commercial lithium-ion batteries using liquid electrolytes are still a safety hazard due to their poor chemical stability and other severe problems, such as electrolyte leakage and low thermal stability. To mitigate these critical issues, solid elect...

(This article belongs to the Topic Synthesis and Applications of Nanostructured Metals and Metal Oxides)