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57 Results Found

  • Article
  • Open Access
23 Citations
4,968 Views
28 Pages

17 October 2019

The zwitterionic monomers, N,N’-diallylamino propanephosphonate and amino acid residual N,N’-diallyl-l-methionine hydrochloride were synthesized, with excellent yields. These monomers were utilized in the preparation of zwitterionic homo...

  • Article
  • Open Access
41 Citations
3,242 Views
33 Pages

10 February 2023

Herein, the inhibition impacts of chitin, pectin, and amylopectin as carbohydrate polymers on the corrosion of mild steel in 0.5 M HCl were researched utilizing various experimental and theoretical tools. The acquired outcomes showed that the inhibit...

  • Article
  • Open Access
4 Citations
1,454 Views
12 Pages

Mechanochemically Synthesized PEG-OTs as a Green Corrosion Inhibitor

  • Qiannian Wang,
  • Yuan Sang,
  • Jiang Yang and
  • Hailing Liu

5 February 2025

Polymer corrosion inhibitors are reported to form dense films on carbon steel surfaces, and their thermostability enables survival in harsh downhole environments. In this paper, PEG-OTs was synthesized by mechanochemistry using ball mill by grafting...

  • Article
  • Open Access
52 Citations
10,977 Views
17 Pages

16 May 2014

A facile method was developed to synthesize in high yield dispersed silver nanoparticles (AgNPs) with small particle sizes of less than 10 nm. Silver nitrate was reduced to silver nanoparticles by p-chloroaniline in the presence of polyoxyethylene ma...

  • Article
  • Open Access
1 Citations
2,143 Views
17 Pages

Methods of Formation of Protective Inhibited Polymer Films on Tungsten

  • Natalia A. Shapagina,
  • Alexey V. Shapagin,
  • Vladimir V. Dushik,
  • Andrey A. Shaporenkov,
  • Uliana V. Nikulova,
  • Valentina Yu. Stepanenko,
  • Vladimir V. Matveev,
  • Alexey L. Klyuev and
  • Boris A. Loginov

22 September 2023

A comparative study of anticorrosive inhibited polymer films on the tungsten surface formed from an aqueous solution of inhibited formulations (INFOR) containing organosilane and corrosion inhibitors was carried out by means of the prolonged exposure...

  • Article
  • Open Access
44 Citations
5,206 Views
20 Pages

8 April 2019

Constructing molecular assembly between a soluble cyclodextrin polymer (SCDP) and an anticorrosive component is conducive to increasing the availability of a corrosion inhibitor with low molecular polarity in aqueous solution. The SCDP was prepared v...

  • Article
  • Open Access
44 Citations
3,374 Views
23 Pages

Computational Foretelling and Experimental Implementation of the Performance of Polyacrylic Acid and Polyacrylamide Polymers as Eco-Friendly Corrosion Inhibitors for Copper in Nitric Acid

  • Arafat Toghan,
  • Ahmed Fawzy,
  • Areej Al Bahir,
  • Nada Alqarni,
  • Moustafa M. S. Sanad,
  • Mohamed Khairy,
  • Abbas I. Alakhras and
  • Ahmed A. Farag

8 November 2022

Copper is primarily used in many industrial processes, but like many other metals, it suffers from corrosion damage. Polymers are not only one of the effective corrosion inhibitors but also are environmentally friendly agents in doing so. Hence, in t...

  • Article
  • Open Access
10 Citations
2,905 Views
17 Pages

30 April 2020

New generations of hyperbranched aramids were synthesized from diarylamine and methyl acrylate using an AB2 monomer approach in a straightforward one-pot preparation. The chemical structure of hyperbranched Phenylenediamine/Methyl Acrylate HB(PDMA wa...

  • Article
  • Open Access
40 Citations
5,509 Views
14 Pages

Development and Properties of Polymeric Nanocomposite Coatings

  • Muddasir Nawaz,
  • Noor Yusuf,
  • Sehrish Habib,
  • Rana Abdul Shakoor,
  • Fareeha Ubaid,
  • Zubair Ahmad,
  • Ramazan Kahraman,
  • Said Mansour and
  • Wei Gao

10 May 2019

Polymeric-based nanocomposite coatings were synthesized by reinforcing epoxy matrix with titanium nanotubes (TNTs) loaded with dodecylamine (DOC). The performance of the developed nanocomposite coatings was investigated in corrosive environments to e...

  • Article
  • Open Access
1 Citations
1,125 Views
23 Pages

Corrosion-Modulating Effect of Pharmaceutical Agents in a Hybrid Coating System on Pure Magnesium

  • Lara Moreno,
  • Adrián Belarra-Rodriguez,
  • Marta Mohedano,
  • Laura Castro,
  • Margarita Chevalier,
  • Raul Arrabal and
  • Endzhe Matykina

30 October 2025

There is a knowledge gap about the effect of pharmaceutical agents on the biodegradation of Mg-based resorbable implants. The present work investigates how three common antibiotics and three anti-inflammatory drugs affect the corrosion of high-purity...

  • Review
  • Open Access
58 Citations
17,685 Views
33 Pages

Polymer-Based Coating for Steel Protection, Highlighting Metal–Organic Framework as Functional Actives: A Review

  • Sarah Bill Ulaeto,
  • Rajimol Puthenpurackal Ravi,
  • Inime Ime Udoh,
  • Gincy Marina Mathew and
  • Thazhavilai Ponnu Devaraj Rajan

Polymer-based coatings are a long-established category of protective coatings for metals and alloys regarding corrosion inhibition. The polymer films can degrade, and when coated on metallic substrates, the degradation facilitates moisture and oxygen...

  • Article
  • Open Access
14 Citations
3,711 Views
16 Pages

6 November 2020

Chromate free corrosion inhibitors are searched for to mitigate the economic loss caused by mid-steel corrosion. Here, we show metal-free organic inhibitors having free coumarate anions that can be used either as direct corrosion inhibitors or incorp...

  • Article
  • Open Access
27 Citations
4,228 Views
12 Pages

L-Arginine Grafted Chitosan as Corrosion Inhibitor for Mild Steel Protection

  • Sani Nazifi Dalhatu,
  • Kolo Alhaji Modu,
  • Auwal Adamu Mahmoud,
  • Zakariyya Uba Zango,
  • Abdullahi Bello Umar,
  • Fahad Usman,
  • John Ojur Dennis,
  • Ahmed Alsadig,
  • Khalid Hassan Ibnaouf and
  • Osamah A. Aldaghri

12 January 2023

Corrosion prevention has been a global phenomenon, particularly in metallic and construction engineering. Most inhibitors are expensive and toxic. Therefore, developing nontoxic and cheap corrosion inhibitors has been a way forward. In this work, L-a...

  • Feature Paper
  • Article
  • Open Access
9 Citations
3,153 Views
16 Pages

Corrosion Inhibition of Low-Carbon Steel by Hydrophobic Organosilicon Dispersions

  • Yuri Makarychev,
  • Natalia Gladkikh,
  • Ivan Arkhipushkin and
  • Yuri Kuznetsov

11 August 2021

This article proposes a method for obtaining stable hydrophobic inhibitor dispersions, where the micelle core contains a hydrophobic solvent, a corrosion inhibitor and an organosilane. Such compositions can be used as polymer-type corrosion inhibitor...

  • Article
  • Open Access
49 Citations
3,780 Views
24 Pages

The Effect of Smart PEO-Coatings Impregnated with Corrosion Inhibitors on the Protective Properties of AlMg3 Aluminum Alloy

  • Andrey S. Gnedenkov,
  • Yana I. Kononenko,
  • Sergey L. Sinebryukhov,
  • Valeriia S. Filonina,
  • Igor E. Vyaliy,
  • Alexey D. Nomerovskii,
  • Alexander Yu. Ustinov and
  • Sergey V. Gnedenkov

9 March 2023

The protective coating with a self-organized microtubular structure was formed using plasma electrolytic oxidation (PEO) on AlMg3 aluminum alloy in the tartrate-fluoride electrolyte. This protective layer was further modified using corrosion inhibito...

  • Article
  • Open Access
808 Views
25 Pages

Electrochemical Synthesis of Mesoporous Alumina as an Adsorbent of Corrosion Inhibitors for Active Corrosion Protection in Organic Coatings

  • Abenchara M. Betancor-Abreu,
  • Javier Izquierdo,
  • Raquel Rodríguez-Raposo,
  • Ricardo A. Liria-Romero,
  • Juan J. Santana and
  • Ricardo M. Souto

19 September 2025

This work describes a simple and economical electrochemical route for the generation of mesoporous alumina (MA) particles that can serve as containers for corrosion inhibitors for the active corrosion protection elements of metals when dispersed in o...

  • Review
  • Open Access
10 Citations
5,149 Views
18 Pages

20 December 2022

The presented paper analyzes polymer films formed from aqueous solutions of organosilanes, corrosion inhibitors and their compositions. Methods of depositing inhibited films on metal samples, such as dipping and exposure of the sample in a modifying...

  • Article
  • Open Access
3 Citations
1,498 Views
13 Pages

16 October 2024

In this investigation, the efficacy of PCA-GLU, a polymer obtained by copolymerizing citric acid and glutamic acid, as a corrosion inhibitor for carbon steel was investigated in a 3.5wt% NaCl solution. Electrochemical impedance spectroscopy (EIS) tec...

  • Feature Paper
  • Review
  • Open Access
42 Citations
5,993 Views
26 Pages

Recent Progress of Polymeric Corrosion Inhibitor: Structure and Application

  • Xuanyi Wang,
  • Shuang Liu,
  • Jing Yan,
  • Junping Zhang,
  • Qiuyu Zhang and
  • Yi Yan

7 April 2023

An anti-corrosion inhibitor is one of the most useful methods to prevent metal corrosion toward different media. In comparison with small molecular inhibitors, a polymeric inhibitor can integrate more adsorption groups and generate a synergetic effec...

  • Article
  • Open Access
25 Citations
4,156 Views
18 Pages

Performance of Waterborne Polyurethanes in Inhibition of Gas Hydrate Formation and Corrosion: Influence of Hydrophobic Fragments

  • Roman S. Pavelyev,
  • Yulia F. Zaripova,
  • Vladimir V. Yarkovoi,
  • Svetlana S. Vinogradova,
  • Sherzod Razhabov,
  • Khasan R. Khayarov,
  • Sergei A. Nazarychev,
  • Andrey S. Stoporev,
  • Rais I. Mendgaziev and
  • Malcolm A. Kelland
  • + 3 authors

1 December 2020

The design of new dual-function inhibitors simultaneously preventing hydrate formation and corrosion is a relevant issue for the oil and gas industry. The structure-property relationship for a promising class of hybrid inhibitors based on waterborne...

  • Article
  • Open Access
77 Citations
8,292 Views
16 Pages

17 June 2013

Corrosion inhibition of aluminum (Al) in hydrochloric acid by anionic polyeletrolyte pectates (PEC) as a water-soluble natural polymer polysaccharide has been studied using both gasometric and weight loss techniques. The results drawn from these two...

  • Review
  • Open Access
45 Citations
7,003 Views
27 Pages

30 June 2022

Production chemistry is an important field in the petroleum industry to study the physicochemical changes in the production system and associated impact on production fluid flow from reservoir to topsides facilities. Mineral scale deposition and meta...

  • Article
  • Open Access
12 Citations
3,564 Views
15 Pages

Lignin-Derivative Ionic Liquids as Corrosion Inhibitors

  • Sharon Monaci,
  • Daniela Minudri,
  • Lorenzo Guazzelli,
  • Andrea Mezzetta,
  • David Mecerreyes,
  • Maria Forsyth and
  • Anthony Somers

21 July 2023

Corrosion is a significant problem that negatively affects a wide range of structures and buildings, resulting in their premature failure, which causes safety hazards and significant economic loss. For this reason, various approaches have been develo...

  • Article
  • Open Access
51 Citations
3,499 Views
23 Pages

A Superior Corrosion Protection of Mg Alloy via Smart Nontoxic Hybrid Inhibitor-Containing Coatings

  • Andrey S. Gnedenkov,
  • Valeriia S. Filonina,
  • Sergey L. Sinebryukhov and
  • Sergey V. Gnedenkov

10 March 2023

The increase of corrosion resistance of magnesium and its alloys by forming the smart self-healing hybrid coatings was achieved in this work in two steps. In the first step, using the plasma electrolytic oxidation (PEO) treatment, a ceramic-like bioa...

  • Review
  • Open Access
182 Citations
12,643 Views
59 Pages

9 March 2022

Most studies on the corrosion inhibition performance of organic molecules and (nano)materials were conducted within “carbon steel/1.0 M HCl” solution system using similar experimental and theoretical methods. As such, the numerous researc...

  • Article
  • Open Access
9 Citations
1,756 Views
21 Pages

Thin Films of a Complex Polymer Compound for the Inhibition of Iron Alloy Corrosion in a H3PO4 Solution

  • Yaroslav G. Avdeev,
  • Tatyana A. Nenasheva,
  • Andrei Yu. Luchkin,
  • Andrei I. Marshakov and
  • Yurii I. Kuznetsov

31 October 2023

The etching of iron alloy items in a H3PO4 solution is used in various human activities (gas and oil production, metalworking, transport, utilities, etc.). The etching of iron alloys is associated with significant material losses due to their corrosi...

  • Feature Paper
  • Review
  • Open Access
40 Citations
12,934 Views
18 Pages

Matrix Acidizing in Carbonate Formations

  • Ofelia Gomez Chacon and
  • Maysam Pournik

17 January 2022

Matrix acidizing in carbonate reservoirs is a process that has been long used to increase productivity in oil and gas producing formations. The main goal is to create wormholes that bypass the damage in the formation. Hydrochloric acid (HCl) is the m...

  • Review
  • Open Access
10 Citations
4,072 Views
18 Pages

1 September 2024

Microbial metal corrosion has become an important topic in metal research, which is one of the main causes of equipment damage, energy loss, and economic loss. At present, the research on microbial metal corrosion focuses on the characteristics of co...

  • Article
  • Open Access
2 Citations
3,471 Views
21 Pages

Effective Inhibition of Carbon Steel Corrosion by Waterborne Polyurethane Based on N-tert-Butyl Diethanolamine in 2M HCl: Experimental and Computational Findings

  • Yulia F. Zaripova,
  • Sherzod Razhabov,
  • Roman S. Pavelyev,
  • Svetlana S. Vinogradova,
  • Renat R. Nazmutdinov,
  • Iskander R. Vakhitov and
  • Mikhail A. Varfolomeev

7 March 2022

The efficiency of corrosion inhibition for waterborne polyurethane based on N-tert-butyl diethanolamine (tB-WPU) is investigated using different techniques. Corrosion weight loss, open circuit potential experiments, electrochemical impedance spectros...

  • Article
  • Open Access
59 Citations
4,506 Views
24 Pages

New Polycaprolactone-Containing Self-Healing Coating Design for Enhance Corrosion Resistance of the Magnesium and Its Alloys

  • Andrey S. Gnedenkov,
  • Sergey L. Sinebryukhov,
  • Valeriia S. Filonina,
  • Alexander Yu. Ustinov,
  • Sviatoslav V. Sukhoverkhov and
  • Sergey V. Gnedenkov

31 December 2022

The method of hybrid coating formation on the surface of a bioresorbable wrought magnesium alloy and magnesium obtained by additive technology was proposed. Plasma electrolytic oxidation (PEO) with subsequent treatment of the material using an organi...

  • Article
  • Open Access
12 Citations
4,245 Views
15 Pages

17 January 2020

In the milestone of straggling to make water hydraulics more advantageous, the choice of coating polymer for water hydraulics valves plays an essential role in alleviating the impact of cavitation erosion and corrosion, and this is a critical task fo...

  • Review
  • Open Access
40 Citations
9,734 Views
23 Pages

Polyester-Based Coatings for Corrosion Protection

  • Abesach M. Motlatle,
  • Suprakas Sinha Ray,
  • Vincent Ojijo and
  • Manfred R. Scriba

21 August 2022

The article is the first review encompassing the study and the applications of polyester-based coatings for the corrosion protection of steel. The impact of corrosion and the challenges encountered thus far and the solutions encountered in industry a...

  • Article
  • Open Access
752 Views
28 Pages

Carbonation Depth, Corrosion Assessment, Repairing, and Strengthening of 49-Year-Old Marine Reinforced Concrete Structures

  • Muttaqin Hasan,
  • Syarizal Fonna,
  • Taufiq Saidi,
  • Purwandy Hasibuan,
  • Fachrurrazi Bukhary,
  • Rahmad Dawood,
  • Mahlil and
  • Azzaki Mubarak

13 November 2025

This study aims to present the results from the assessment of carbonation depth, corrosion, and compressive strength of real marine structures in a 49-year-old gas processing industry. The assessment was achieved through visual observations and non-d...

  • Article
  • Open Access
24 Citations
4,823 Views
14 Pages

8 February 2019

In order to assemble effective protective coatings against corrosion, electrochemical techniques such as linear potentiometry and cyclic voltammetry were performed on a copper surface in 0.1 mol·L−1 HCl solution containing 0.1% polyvinyl...

  • Article
  • Open Access
53 Citations
6,390 Views
14 Pages

15 January 2019

Herein, an intercalation modification technique is proposed to improve the anticorrosion performance of polymeric coatings. Molybdate, an inhibitor, was intercalated to bestow inhibitive attributes, while functionalization of the layered double hydro...

  • Article
  • Open Access
12 Citations
2,880 Views
26 Pages

Advanced Protective Films Based on Binary ZnO-NiO@polyaniline Nanocomposite for Acidic Chloride Steel Corrosion: An Integrated Study of Theoretical and Practical Investigations

  • May Ahmed Al-Masoud,
  • Mai M. Khalaf,
  • Fakiha El-Taib Heakal,
  • Mohamed Gouda,
  • Ibrahim M. A. Mohamed,
  • Kamal Shalabi and
  • Hany M. Abd El-Lateef

4 November 2022

Due to their thermal stability characteristics, polymer/composite materials have typically been employed as corrosion inhibitors in a variety of industries, including the maritime, oil, and engineering sectors. Herein, protective films based on binar...

  • Article
  • Open Access
19 Citations
3,503 Views
11 Pages

Synergistic Inhibition Effect of Chitosan and L-Cysteine for the Protection of Copper-Based Alloys against Atmospheric Chloride-Induced Indoor Corrosion

  • Elena Messina,
  • Chiara Giuliani,
  • Marianna Pascucci,
  • Cristina Riccucci,
  • Maria Paola Staccioli,
  • Monica Albini and
  • Gabriella Di Carlo

25 September 2021

The protection of metals from atmospheric corrosion is a task of primary importance for many applications and many different products have been used, sometimes being toxic and harmful for health and the environment. In order to overcome drawbacks due...

  • Article
  • Open Access
16 Citations
3,739 Views
17 Pages

10 February 2024

Novel modified Zn-Al LDH/epoxy coatings are synthesized and applied to steel substrates, providing active corrosion protection and improved barrier properties. This protective coating is made by combining Epon 828 as a polymer matrix with modified la...

  • Review
  • Open Access
153 Citations
19,186 Views
16 Pages

Metal-Organic Framework (MOF)/Epoxy Coatings: A Review

  • Farzad Seidi,
  • Maryam Jouyandeh,
  • Mohsen Taghizadeh,
  • Ali Taghizadeh,
  • Henri Vahabi,
  • Sajjad Habibzadeh,
  • Krzysztof Formela and
  • Mohammad Reza Saeb

26 June 2020

Epoxy coatings are developing fast in order to meet the requirements of advanced materials and systems. Progress in nanomaterial science and technology has opened a new era of engineering for tailoring the bulk and surface properties of organic coati...

  • Review
  • Open Access
48 Citations
6,174 Views
25 Pages

7 March 2020

The use of surface engineering techniques to tune-up the composition of nanostructured thin-films for developing functional coatings with advanced properties is a hot topic within the scientific community. The control of the coating structure at the...

  • Article
  • Open Access
6 Citations
2,267 Views
16 Pages

10 January 2022

The critical issue of the durability of marine concrete lies in the continuous penetration and rapid enrichment of corrosive ions. Here a new ion transfer inhibitor, as TIA, with calcium silicate hydrate (C-S-H) interfacial affinity and hydrophobicit...

  • Review
  • Open Access
20 Citations
11,490 Views
23 Pages

Advanced Micro/Nanocapsules for Self-Healing Coatings

  • Ioannis A. Kartsonakis,
  • Artemis Kontiza and
  • Irene A. Kanellopoulou

18 September 2024

The concept of intelligence has many applications, such as in coatings and cyber security. Smart coatings have the ability to sense and/or respond to external stimuli and generally interact with their environment. Self-healing coatings represent a si...

  • Review
  • Open Access
11 Citations
6,126 Views
45 Pages

13 December 2024

The indole nucleus stands out as a pharmacophore, among other aromatic heterocyclic compounds with remarkable therapeutic properties, such as benzimidazole, pyridine, quinoline, benzothiazole, and others. Moreover, a series of recent studies refer to...

  • Review
  • Open Access
54 Citations
7,882 Views
17 Pages

Development of Sustainable Inhibitors for Corrosion Control

  • Muhammad Azhar Ali Khan,
  • Osama Mohamed Irfan,
  • Faramarz Djavanroodi and
  • Muhammad Asad

3 August 2022

Metal degradation due to corrosion is a major challenge in most industries, and its control and prevention has to maintain a balance between efficiency and cost-effectiveness. The rising concern over environmental damage has greatly influenced this d...

  • Article
  • Open Access
6 Citations
3,410 Views
21 Pages

10 January 2023

Polymer–Clay Nanocomposite (PCN) coatings were prepared using the solution intercalation method. The raw Khulays clay was treated with NaCl to produce sodium clay (NaC). Thereafter, Cetyl Pyridinium Chloride (CPC) was used to convert NaC into t...

  • Review
  • Open Access
37 Citations
7,198 Views
28 Pages

Nonedible Vegetable Oil-Based Polyols in Anticorrosive and Antimicrobial Polyurethane Coatings

  • Chandrashekhar K. Patil,
  • Dong Wook Jung,
  • Harishchandra D. Jirimali,
  • Joon Hyun Baik,
  • Vikas V. Gite and
  • Sung Chul Hong

17 September 2021

This review describes the preparation of nonedible vegetable oil (NEVO)-based polyols and their application in anticorrosive and antimicrobial polyurethane (PU) coatings. PUs are a class of versatile polymers made up of polyols and isocyanates. Renew...

  • Article
  • Open Access
5 Citations
2,024 Views
16 Pages

Synthesis and Electrochemical Evaluation of MSNs-PbAE Nanocontainers for the Controlled Release of Caffeine as a Corrosion Inhibitor

  • Martín Aguirre-Pulido,
  • Jorge A. González-Sánchez,
  • Luis R. Dzib-Pérez,
  • Montserrat Soria-Castro,
  • Alejandro Ávila-Ortega and
  • William A. Talavera-Pech

In this paper, a controlled-release system of caffeine as a corrosion inhibitor was obtained by encapsulating it in MCM-41 silica nanoparticles coated with a poly(β-amino ester) (PbAE), a pH-sensible polymer. Encapsulation was verified using Fou...

  • Abstract
  • Open Access
1,037 Views
1 Page

Degradation Rate Control of MgxZnyCa Alloys by PEO Coatings

  • Lara Moreno,
  • Marta Mohedano,
  • Raúl Arrabal and
  • Endzhe Matykina

Magnesium alloys are actively researched for biodegradable implants in order to avoid an implant-removal surgery after the healing process. However, the high degradation rate of Mg leads to hydrogen evolution and may increase the pH of the environmen...

  • Article
  • Open Access
28 Citations
7,706 Views
17 Pages

One-Step Formation of Reduced Graphene Oxide from Insulating Polymers Induced by Laser Writing Method

  • Parand R. Riley,
  • Pratik Joshi,
  • Hristo Penchev,
  • Jagdish Narayan and
  • Roger J. Narayan

27 October 2021

Finding a low-cost and effective method at low temperatures for producing reduced graphene oxide (rGO) has been the focus of many efforts in the research community for almost two decades. Overall, rGO is a promising candidate for use in supercapacito...

  • Article
  • Open Access
7 Citations
3,266 Views
17 Pages

27 March 2022

Spatially resolved information on corrosion reactions operating at the cut edges of coated metals can be obtained using microelectrochemical scanning techniques using a suitable selection of operation modes and scanning probes. The scanning vibrating...

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