Ceramics, Volume 6, Issue 4
2023 December - 30 articles
Cover Story: This study highlights the effect of rare-earth ion doping on the magnetic and magnetocaloric properties of the ferrimagnetic garnet compound Gd1-xRExFe5O12 (RE = Nd, Sm, Dy, and Y). The rare-earth ion substitution resulted in site-to-site bond lengths and bond angle alterations, thereby influencing the magnetic exchange interaction among site ions. The variation in maximum magnetic entropy change (−∆SMmax) was enhanced via Dy3+ and Sm3+ substitution but decreased with Nd3+ and Y3+ substitution. A first-principal density function theory (DFT) technique was used to shed light on the observed magnetic behavior of the substituted compound. The study shows that the magnetic moments of the doped rare-earth ions play a vital role in tuning the magnetocaloric properties of the garnet compound. View this paper - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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