2018 June - 126 articles
Laponite XLS™, which is a synthetic clay of nanometric dimensions containing a peptizing agent, has been associated with silanized hydroxypropylmethylcellulose (Si-HPMC) to form, after crosslinking, a novel composite hydrogel. Different protocols of...
Wear particle-induced biological responses are the major factors for the failure of total joint arthroplasties, but it is possible to improve the lubrication and reduce the wear of an artificial joint system. Polyetheretherketone (PEEK), with ultra-h...
The pulmonary delivery of antitubercular drugs is a promising approach to treat lung tuberculosis. This strategy not only allows targeting the infected organ instantly, it can also reduce the systemic adverse effects of the antibiotics. In light of t...
In this work, a new class of highly stretchable peptide-polyurethane/ureas (PUUs) were synthesized containing short β-sheet forming peptide blocks of poly(γ-benzyl-l-glutamate)-b-poly(propylene glycol)-b-poly(γ-benzyl-l-glutamate) (P...
Macrocyclic polymers present an important class of macromolecules, displaying the reduced radius of gyration or impossibility to entangle. A rare approach for their synthesis is the ring expansion-controlled radical “vinyl” polymerization...
The hydrolytic stability of polymers to be used for coatings in aqueous environments, for example, to confer anti-fouling properties, is crucial. However, long-term exposure studies on such polymers are virtually missing. In this context, we synthesi...
A novel phthalonitrile-terminated polyaryl ether nitrile (PEN-Ph) was synthesized and characterized. The crystallization behavior coexisting with the crosslinking behavior in the PEN-Ph system was confirmed by rheological measurements. DSC was applie...
In this study, corn stalk lignin was used to react with non-volatile and non-toxic glyoxal under the catalysis of a sodium hydroxide solution, and a wood adhesive based on glyoxalated corn stalk lignin was prepared. The effect of the hydroxylation re...
In this article, iota-carrageenan (IC) and kappa-carrageenan (KC) are used as dopants for the chemical and electrochemical synthesis of polypyrrole (PPy). The composites of chemically synthesized PPy with multi-walled carbon nanotubes (MWNTs) were pr...
The free-radical graft polymerization of acryloxyethyl-trimethylammonium chloride onto commercial silica particles was studied experimentally for extraction of arsenic ions from water. Two steps were used to graft acryloxyethyl-trimethylammonium chlo...
Polymer flooding plays an important role in enhanced oil recovery (EOR), particularly in China, where partially hydrolyzed polyacrylamide (HPAM) and hydrophobically associating water-soluble polymers (HAWP) are used in onshore and offshore reservoirs...
A pultruded unidirectional carbon/glass reinforced epoxy hybrid FRP rod with 19 mm of diameter was developed for a sucker rod and lifting oil wells. The rod possesses a 12-mm diameter carbon fiber core and a 3.5-mm thick outer shell. The rod was expo...
3D printing has attracted a lot of attention in recent years. Over the past three decades, various 3D printing technologies have been developed including photopolymerization-based, materials extrusion-based, sheet lamination-based, binder jetting-bas...
To meet the demand for next-generation flexible optoelectronic devices, it is crucial to accurately establish the chemical structure-property relationships of new optical polymer films from a theoretical point of view, prior to production. In the cur...
Due to its excellent performance, aerogel is considered to be an especially promising new material. Cellulose is a renewable and biodegradable natural polymer. Aerogel prepared using cellulose has the renewability, biocompatibility, and biodegradabil...
Four new metal–organic coordination polymers [Cu(L)(mpa)]·3H2O (1), [Co(L)(mpa)]·H2O (2), [Zn(L)(mpa)]·H2O (3), and [Cd(L)(mpa)(H2O)]·H2O (4) were synthesized by reactions of the corresponding metal(II) salts based o...
The bilayered structure of hard thin film on soft substrate can lose stability and form specific patterns, such as wrinkles or creases, on the surface, induced by external stimuli. For bilayer hydrogels, the surface morphology caused by the instabili...
Hybrid composites with low flammability based on renewable calcium alginate and nano-calcium borate were fabricated using an in situ method through a simple, eco-friendly vacuum drying process. The composites were characterized by X-ray diffractometr...
The immobilization of biocatalysts on magnetic nanomaterial surface is a very attractive alternative to achieve enzyme nanoderivatives with highly improved properties. The combination between the careful tailoring of nanocarrier surfaces and the site...
Polydimethylsiloxane (PDMS) polymers are extensively used in a wide range of research and industrial fields, due to their highly versatile chemical, physical, and biological properties. Besides the different two-dimensional PDMS formulations availabl...
A classification of gluten polymer networks would support a better understanding of structure-function relationships of any gluten polymer material and thus, the control of processing properties. However, quantification and interpretation of the glut...
During biomass fractionation, any native acetylation of lignin and heteropolysaccharide may affect the process and the resulting lignin structure. In this study, Typha capensis (TC) and its lignin isolated by milling (MWL), ionosolv (ILL) and organos...
Electrically conductive plastics with a stable electric response within a wide temperature range are promising substitutes of conventional inorganic conductive materials. This study examines the preparation of thermoplastic polyketones (PK30) functio...
It is desirable to combine load-bearing and bone regeneration capabilities in a single bone tissue engineering scaffold. For this purpose, we developed a high strength hybrid scaffold using a sintered poly(lactic-co-glycolic acid) (PLGA)/nanohydroxya...
This study aims to verify the effectiveness of fiber reinforcing with and without cement on settlement controlling of subgrade models, and to investigate the effect of fiber reinforcement on the load-settlement behavior of subgrade models. To this en...
This paper introduces electrospun nanofibers embedded with ceria nanoparticles as silicon solar cells coaters, showing their influence on the solar cells efficiency. Ceria nanoparticles can be synthesized to have formed oxygen vacancies (O-vacancies)...
A highly graphitized carbon on a silicon monoxide (SiO) surface coating at low temperature, based on polymer precursor π–π stacking, was developed. A novel conductive and electrochemically stable carbon coating was rationally designed to...
The targeted delivery of chemotherapy drugs to tumor lesions is a major challenge for the treatment of tumors. Up until now, various polymeric nanoparticles have been explored to improve the targetability of these therapeutic drugs through passive or...
The induction of supramolecular chirality from achiral polymers has been widely investigated in composite systems consisting of a chiral guest, achiral host, and solvents. To further study and understand the process of chirality transfer from a chira...
In this study, the molten salt hydrate of lithium bromide (LiBr) was utilized as a non-derivatizing cellulose dissolution solvent to prepare regenerated cellulose films for kraft pulp. The effects of LiBr concentrations (60, 62, and 65 wt %) and diss...
In this article, graphene oxide nanosheets grafted with low molecular weight poly(ethylene terephthalate) were in situ synthesized via carboxylation, acyl chlorination and grafting modification in order to improve the compatibility between GO and PET...
Bamboo fibers demonstrate enormous potential as the reinforcement phase in composite materials. In this study, in order to find suitable NaOH concentration for bamboo fiber treatment, bamboo fibers were treated with 2 wt.%, 6 wt.% and 10 wt.% NaOH so...
Superabsorbent polymers (SAPs) are crosslinked hydrophilic polymers that are capable of absorbing large amounts of water. Commercial SAPs are mostly produced with acrylic acid that cannot be easily biodegraded. Therefore, in this study, polysaccharid...
In this work, multi-layered polyimide (PI) films were surface fluorinated at 328 K and 0.05 MPa using F2/N2 mixture with 20% F2 by volume, for a fluorination time of 0, 30 and 60 min, respectively. Then, they were subjected to discharge plasma as bar...
New membranes based on chitosan and chitosan-hyaluronic acid containing new arginine derivatives with thiazolidine-4-one scaffold have been prepared using the ionic cross-linking method. The presence of the arginine derivatives with thiazolidine-4-on...
The structural changes during three-step synthesis of low-molar ratio urea–formaldehyde (UF) resin were tracked by quantitative 13C nuclear magnetic resonance (13C NMR) analysis and electrospray ionization-mass spectrometry (ESI–MS). Cond...
Polymers are promising materials for fabricating photonic integrated waveguide devices. Versatile functional devices can be manufactured using a simple process, with low cost and potential mass-manufacturing. This paper reviews the recent progress of...
2,6-Di(9H-carbazol-9-yl)pyridine (DiCP) was synthesized and its corresponding homopolymer (PDiCP) and copolymers (P(DiCP-co-CPDT), P(DiCP-co-CPDT2), P(DiCP-co-CPDTK), and P(DiCP-co-CPDTK2)) were synthesized electrochemically. The anodic copolymer wit...
The mechanical behavior of phase-change microcapsules (microPCMs) is of vital significance for practical applications in thermal energy storage. Hence, a new type of microPCMs based on an n-octadecane (C18) core and a melamine-urea-formaldehyde (MUF)...
Poly(ethylene terephthalate) (PET) composites containing carbon fiber (CF) or polymethyl methacrylate (PMMA)-grafted carbon fiber (PMMA-g-CF) were prepared by melt compounding. The rheology, non-isothermal crystallization behavior, and mechanical and...
Dendritic polyglycerol sulfate (dPGS) has originally been investigated as an anticoagulant to potentially substitute for the natural glycosaminoglycan heparin. Compared to unfractionated heparin, dPGS possesses lower anticoagulant activity but a much...
Copolymerization is the typical method to obtain the high-performance resin composites, due to its universality and regulation performance. It can be employed among various resin matrices with active groups to obtain the desired structures, and subse...
We report the lateral order and self-organized morphology of diblock copolymer polystyrene-block-poly(2-vinylpyridine), P(S-b-2VP), and micelles on silicon substrates (SiOx/Si). These micellar films were prepared by spin coating from polymer solution...
The diffusion dynamics of fullerene (C ) in unentangled linear atactic polystyrene (PS) and polypropylene (PP) melts and the structure and dynamic properties of polymers in interface area are investigated by performing all-atom molecular dy...
Star-shaped polymers show a continuous change of properties from flexible linear chains to soft colloids, as the number of arms is increased. To investigate the effect of macromolecular architecture on the flow properties, we employ computer simulati...
Biomass-derived polyester coatings for coil applications have been successfully developed and characterized. The coatings were constituted by carbohydrate-derived monomers, namely 2,5-furan dicarboxylic acid, isosorbide, succinic acid, 1,3-propanedio...
Lactobacillus acidophilus was encapsulated in xanthan–chitosan (XC) and xanthan–chitosan–xanthan (XCX) polyelectrolyte complex (PEC) gels by extrusion method. The obtained capsules were characterized by X-ray diffraction and FTIR spectroscopy. The ef...
Thanks to a wide range of biological functions of RNA, and advancements in nanotechnology, RNA nanotechnology has developed in multiple ways for RNA-based therapeutics. In particular, among RNA engineering techniques, enzymatic self-assembly of RNA s...
The effect of the polymer chain topology structure on the adsorption behavior in the polymer-nanoparticle (NP) interface is investigated by employing coarse-grained molecular dynamics simulations in various polymer-NP interaction and chain stiffness....
The effect of single-layer graphene sheets (Gr) on the corrosion protection of zinc-rich epoxy primers (ZRPs) was investigated. Scanning electron microscopy (SEM) with an energy dispersive spectrometer (EDS) were used to characterize morphology and c...
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