Open AccessArticle
Thermal Cracking of Jatropha Oil with Hydrogen to Produce Bio-Fuel Oil
by
Yi-Yu Wang 1, Chia-Chi Chang 1, Ching-Yuan Chang 1,2,*, Yi-Hung Chen 3, Je-Lueng Shie 4, Min-Hao Yuan 5, Yen-Hau Chen 1, Li-Xuan Huang 1, Cesar Augusto Andrade-Tacca 1, Do Van Manh 6, Min-Yi Tsai 1 and Michael Huang 1
1
Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 10617, Taiwan
2
Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan
3
Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, Taipei 10608, Taiwan
4
Department of Environmental Engineering, National Ilan University, I-Lan 26047, Taiwan
5
Department of Occupational Safety and Health, China Medical University, Taichung 40402, Taiwan
6
Danang Environmental Technology Center, Institute of Environmental Technology, Vietnam Academy of Science and Technology, Da Nang City 550000, Vietnam
Cited by 3 | Viewed by 4981
Abstract
This study used thermal cracking with hydrogen (HTC) to produce bio-fuel oil (BFO) from
jatropha oil (JO) and to improve its quality. We conducted HTC with different hydrogen pressures (
PH2; 0–2.07 MPa or 0–300 psig), retention times (
tr
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This study used thermal cracking with hydrogen (HTC) to produce bio-fuel oil (BFO) from
jatropha oil (JO) and to improve its quality. We conducted HTC with different hydrogen pressures (
PH2; 0–2.07 MPa or 0–300 psig), retention times (
tr; 40–780 min), and set temperatures (
TC; 623–683 K). By applying HTC, the oil molecules can be hydrogenated and broken down into smaller molecules. The acid value (
AV), iodine value, kinematic viscosity (
KV), density, and heating value (
HV) of the BFO produced were measured and compared with the prevailing standards for oil to assess its suitability as a substitute for fossil fuels or biofuels. The results indicate that an increase in
PH2 tends to increase the
AV and
KV while decreasing the
HV of the BFO. The BFO yield (
YBFO) increases with
PH2 and
tr. The above properties decrease with increasing
TC. Upon HTC at 0.69 MPa (100 psig) H
2 pressure, 60 min time, and 683 K temperature, the
YBFO was found to be 86 wt%. The resulting BFO possesses simulated distillation characteristics superior to those of boat oil and heavy oil while being similar to those of diesel oil. The BFO contains 15.48% light naphtha, 35.73% heavy naphtha, 21.79% light gas oil, and 27% heavy gas oil and vacuum residue. These constituents can be further refined to produce gasoline, diesel, lubricants, and other fuel products.
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