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Inorganics, Volume 10, Issue 11

November 2022 - 41 articles

Cover Story: The cover art shows a mouse-grey butterfly representing the MIC, which turns bright red when binding molybdenum, represented by the blossoms’ blue centers. As X-ray structural analysis shows, it does indeed require a butterfly-wing-type motion of the molecule to facilitate coordination and formation of the carbene complex. The obtained complex was additionally studied by IR spectroscopy and cyclic voltammetry, and a notably strong donor strength of the ligand was observed. All results emphasize that the ligand investigated in this work constitutes a very promising (co-)ligand for the design of Mo catalysts capable of small molecule activation. View this paper
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Articles (41)

  • Article
  • Open Access
2,995 Views
17 Pages

20 November 2022

Triazolylidene ligands belong to a class of N-heterocyclic carbenes of growing chemical interest. Their precursors are readily available using Click chemistry and, therefore, highly modular for tuning their electronic characteristics. Due to their no...

  • Article
  • Open Access
12 Citations
3,166 Views
11 Pages

Preparation of SBA-15-Supported Metals by Vapor-Phase Infiltration

  • Ching-Yu Wang,
  • Kai Shen,
  • Raymond J. Gorte and
  • John M. Vohs

19 November 2022

A simple method is presented for incorporating various catalytic metals into the pores of SBA-15 using vapor-phase infiltration. The precursors used in Atomic Layer Deposition (ALD) for Pt, Pd, Rh, Ru, and Ni were exposed to an evacuated SBA-15, resu...

  • Article
  • Open Access
2 Citations
2,766 Views
29 Pages

19 November 2022

An efficient and easy approach to the synthesis of novel racemic planar-chiral 3,4-dihydroferroceno[c]pyridines and 1H-ferroceno[c]pyrroles via the intramolecular Ritter reaction of 2-ferrocenyl-3,3-dimethylbutan-2-ol with nitriles and thiocyanates i...

  • Article
  • Open Access
5 Citations
3,636 Views
15 Pages

Electrodeposited PPy@TiO2 and PEDOT@TiO2 Counter Electrodes for [Co(bpy)3]2+/3+ Redox Mediator-Based Dye-Sensitized Solar Cells

  • Abdelaal S. A. Ahmed,
  • Xie Yi,
  • Xiujian Zhao,
  • Wanchun Xiang and
  • Mohammed Abdelmotallieb

18 November 2022

The main goal of this work is to enhance the catalytic performance of PPy and PEDOT films toward the Co2+/Co3+ redox couple. PPy and PEDOT films were electrodeposited separately on a porous TiO2 template to assess their suitability as alternative cat...

  • Article
  • Open Access
16 Citations
3,301 Views
13 Pages

A New Approach for the Synthesis of Powder Zinc Oxide and Zinc Borates with Desired Properties

  • Irina V. Kozerozhets,
  • Varvara V. Avdeeva,
  • Grigorii A. Buzanov,
  • Evgeniy A. Semenov,
  • Yulia V. Ioni and
  • Sergey P. Gubin

17 November 2022

Zinc borates are widely used in industry due to their thermal stability as a flame retardant in the production of plastics, rubber, and other polymer compositions. We have developed a simple and effective approach for the synthesis of zinc borate pow...

  • Article
  • Open Access
8 Citations
3,071 Views
18 Pages

Effect of CuO Loading on the Photocatalytic Activity of SrTiO3/MWCNTs Nanocomposites for Dye Degradation under Visible Light

  • Xuan Truong Mai,
  • Duc Nguyen Bui,
  • Van Khang Pham,
  • Thi Ha Thanh Pham,
  • Thi To Loan Nguyen,
  • Hung Dung Chau and
  • Thi Kim Ngan Tran

16 November 2022

In this study, we report on the preparation of copper oxide/strontium titanate/multi-walled carbon nanotube (CuO/STO/MWCNTs) nanocomposites and their photocatalytic activity for degradation of dye under visible light. The crystalline structures of th...

  • Article
  • Open Access
33 Citations
3,391 Views
14 Pages

Excellent Adsorption of Dyes via MgTiO3@g-C3N4 Nanohybrid: Construction, Description and Adsorption Mechanism

  • Abueliz Modwi,
  • Mohamed R. Elamin,
  • Hajo Idriss,
  • Nuha Y. Elamin,
  • Fatima A. Adam,
  • Abuzar E. Albadri and
  • Babiker Y. Abdulkhair

15 November 2022

This report investigates the elimination of hazardous Rhodamine B dye (RhB) from an aqueous medium utilizing MgTiO3@g-C3N4 nanohybrids manufactured using a facile method. The nanohybrid MgTiO3@g-C3N4 was generated using an ultrasonic approach in the...

  • Article
  • Open Access
6 Citations
2,514 Views
14 Pages

Synthesis of a New Dinuclear Ag(I) Complex with Asymmetric Azine Type Ligand: X-ray Structure and Biological Studies

  • Mezna Saleh Altowyan,
  • Saied M. Soliman,
  • Dhuha Al-Wahaib,
  • Assem Barakat,
  • Ali Eldissouky Ali and
  • Hemmat A. Elbadawy

15 November 2022

Aspects of the molecular and supramolecular structure of the new dinuclear [Ag(L)(NO3)]2 complex, where L is 2-((E)-(((E)-1-(thiazol-2-yl)ethylidene)hydrazono)methyl)phenol, were discussed. The complex was crystallized in the monoclinic crystal syste...

  • Article
  • Open Access
4 Citations
4,092 Views
12 Pages

Graphite Felt Electrode Modified by Quaternary Ammonium for Vanadium Redox Flow Battery with an Ultra-Long Cycle Life

  • Xuejiao Liu,
  • Junping Hu,
  • Jun Liu,
  • Hongyi Liu,
  • Sha Fu,
  • Xiongwei Wu and
  • Yuping Wu

15 November 2022

Vanadium redox flow batteries (VRFBs) are one of the most attractive devices for grid-scale energy storage due to their advantages of high safety, flexible assembly, and electrolyte-class recycling. However, the conventional graphite felt electrodes...

  • Article
  • Open Access
4 Citations
2,533 Views
14 Pages

13 November 2022

The 3-halogen and 3,6-dihalogen derivatives of ortho-carborane 3-X-1,2-C2B10H11 and 3,6-X2-1,2-C2B10H10 (X = Cl, Br, I) were prepared by Cu-assisted halodeboronation of the corresponding pinacolborate derivatives 3-Bpin-1,2-C2B10H11 and 3,6-(Bpin)2-1...

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Inorganics - ISSN 2304-6740