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132 Results Found

  • Article
  • Open Access
4 Citations
1,769 Views
14 Pages

Adsorption and Diffusion Properties of Gas in Nanopores of Kerogen: Insights from Grand Canonical Monte Carlo and Molecular Dynamics Simulations

  • Shouheng Xiao,
  • Xiugang Liu,
  • Yun Li,
  • Qiang Zheng,
  • Ning Wang,
  • Yun Qiao,
  • Youyin Zhang and
  • Chuanjun Yi

9 July 2024

Investigating the adsorption and diffusion processes of shale gas within the nanopores of kerogen is essential for comprehending the presence of shale gas in organic matter of shale. In this study, an organic nanoporous structure was constructed base...

  • Article
  • Open Access
1 Citations
1,561 Views
10 Pages

6 March 2024

To investigate the characteristics and generation potential of gas generated from over-mature shale, hydrous and anhydrous pyrolysis experiments were carried out on the Longmaxi Formation in the Anwen 1 well of the Sichuan Basin of China at temperatu...

  • Article
  • Open Access
929 Views
21 Pages

29 April 2025

To investigate the methane adsorption characteristics in different types of kerogen, microscopic models for three kerogen types—sapropelic (Type I), mixed (Type II), and humic (Type III)—were developed in this paper based on the paradigm...

  • Article
  • Open Access
2,905 Views
19 Pages

10 December 2021

Semi-open hydrous pyrolysis experiments on coal-measure source rocks in the Xihu Sag were conducted to investigate the carbon isotope evolution of kerogen, bitumen, generated expelled oil, and gases with increasing thermal maturity. Seven correspondi...

  • Article
  • Open Access
2 Citations
1,555 Views
23 Pages

2 September 2024

This work is focused on developing a computational model to predict the production rate and pressure evolution of natural gas from unconventional reservoirs, particularly shale gas deposits. The model is based on the principle of conservation of mech...

  • Article
  • Open Access
2,307 Views
23 Pages

Effect of Temperature on Kerogen Transformation and Hydrocarbon Generation in Bazhenov Formation (Western Siberia, Russia) Rocks During Hydrous Pyrolysis

  • Grigorii G. Savostin,
  • Margarita S. Tikhonova,
  • Anton G. Kalmykov,
  • Dmitry S. Volkov,
  • Mariia O. Kostyshina,
  • Olesya N. Vidishcheva,
  • Mariia L. Makhnutina,
  • Yuliya A. Kotochkova,
  • Tatiana V. Grigorenko and
  • Mikhail A. Proskurnin

25 December 2024

The aim of this investigation is to determine the role of temperature in hydrocarbon generation in Bazhenov formation source rocks, as hydrothermal processes in situ are supposed to be the main contributor to kerogen transformation in Western Siberia...

  • Article
  • Open Access
58 Citations
7,616 Views
15 Pages

Study on the Adsorption, Diffusion and Permeation Selectivity of Shale Gas in Organics

  • Zhouhua Wang,
  • Yun Li,
  • Huang Liu,
  • Fanhua Zeng,
  • Ping Guo and
  • Wei Jiang

23 January 2017

As kerogen is the main organic component in shale, the adsorption capacity, diffusion and permeability of the gas in kerogen plays an important role in shale gas production. Based on the molecular model of type II kerogen, an organic nanoporous struc...

  • Article
  • Open Access
1,287 Views
16 Pages

30 October 2024

Accurately determining the pore structure and heterogeneity characteristics of marine-continental transitional shale in the Taiyuan Formation is crucial for evaluating the shale gas resources in the northern Ordos Basin. However, the studies on pore...

  • Article
  • Open Access
3 Citations
1,914 Views
14 Pages

19 September 2022

In order to analyze the organic matter (OM) composition, this study carefully identified the OM types of 66 samples from Well A in the Dingshan area under microscope, and made an effort to obtain the semi-quantitative statistics contents of different...

  • Article
  • Open Access
9 Citations
5,691 Views
40 Pages

27 September 2022

The Middle Devonian Marcellus Formation of North America is the most prolific hydrocarbon play in the Appalachian basin, the second largest producer of natural gas in the United States, and one of the most productive gas fields in the world. Regional...

  • Article
  • Open Access
3 Citations
2,175 Views
14 Pages

17 February 2022

In the last decade, exploration for unconventional hydrocarbon (shale gas) reservoirs has been carried out in Poland. The drilling of wells in prospective shale gas areas supplies numerous physicochemical measurements from rock and reservoir fluid sa...

  • Article
  • Open Access
50 Citations
4,562 Views
14 Pages

18 August 2020

The presence of kerogen in source rocks gives rise to a plethora of potential gas storage mechanisms. Proper estimation of the gas reserve requires knowledge of the quantities of free and adsorbed gas in rock pores and kerogen. Traditional methods of...

  • Article
  • Open Access
10 Citations
2,927 Views
23 Pages

Nanostructure Effect on Methane Adsorption Capacity of Shale with Type III Kerogen

  • Yong Han,
  • Yanming Zhu,
  • Yu Liu,
  • Yang Wang,
  • Han Zhang and
  • Wenlong Yu

3 April 2020

This study focuses on the nanostructure of shale samples with type III kerogen and its effect on methane adsorption capacity. The composition, pore size distribution, and methane adsorption capacities of 12 shale samples were analyzed by using the hi...

  • Article
  • Open Access
7 Citations
4,942 Views
16 Pages

Sustainable Production from Shale Gas Resources through Heat-Assisted Depletion

  • Saad Alafnan,
  • Murtada Aljawad,
  • Guenther Glatz,
  • Abdullah Sultan and
  • Rene Windiks

10 March 2020

Advancements in drilling and production technologies have made exploiting resources, which for long time were labeled unproducible such as shales, as economically feasible. In particular, lateral drilling coupled with hydraulic fracturing has created...

  • Article
  • Open Access
8 Citations
2,687 Views
15 Pages

Molecular Simulation of Methane Adsorption in Deep Shale Nanopores: Effect of Rock Constituents and Water

  • Jianfa Wu,
  • Xuefeng Yang,
  • Shan Huang,
  • Shengxian Zhao,
  • Deliang Zhang,
  • Jian Zhang,
  • Chunyu Ren,
  • Chenglin Zhang,
  • Rui Jiang and
  • Dongchen Liu
  • + 2 authors

31 May 2023

The molecular models of nanopores for major rock constituents in deep shale were constructed. The microscopic adsorption behavior of methane was simulated by coupling the grand canonical Monte Carlo and Molecular Dynamics methods and the effect of ro...

  • Article
  • Open Access
535 Views
16 Pages

22 July 2025

Surfactants can be utilized to improve oil recovery by changing the performance of reservoirs in rock pores. Kerogen is the primary organic matter in shale; however, high temperatures will affect the overall performance of this surfactant, resulting...

  • Article
  • Open Access
42 Citations
4,335 Views
16 Pages

20 November 2019

The adsorption behavior and the mechanism of a CO2/CH4 mixture in shale organic matter play significant roles to predict the carbon dioxide sequestration with enhanced gas recovery (CS-EGR) in shale reservoirs. In the present work, the adsorption per...

  • Article
  • Open Access
779 Views
19 Pages

10 April 2025

Kerogen micropores in shale are crucial for gas sorption; nevertheless, their formation and evolution have been insufficiently studied. To qualitatively and quantitatively analyze changes in the molecular structure and associated micropores of keroge...

  • Article
  • Open Access
8 Citations
2,555 Views
21 Pages

Adsorption and Diffusion Behaviors of CO2 and CH4 Mixtures in Different Types of Kerogens and Their Roles in Enhanced Energy Recovery

  • Shan Yuan,
  • Hong-Ze Gang,
  • Yi-Fan Liu,
  • Lei Zhou,
  • Muhammad Irfan,
  • Shi-Zhong Yang and
  • Bo-Zhong Mu

11 November 2022

CO2 geological sequestration in subsurface shale formations is a promising strategy to store CO2 and to increase shale gas production. The understanding of gas adsorption and diffusion mechanisms in microporous media is critical for CO2 storage-enhan...

  • Article
  • Open Access
61 Citations
4,599 Views
18 Pages

H2, CO2, and CH4 Adsorption Potential of Kerogen as a Function of Pressure, Temperature, and Maturity

  • Arshad Raza,
  • Mohamed Mahmoud,
  • Saad Alafnan,
  • Muhammad Arif and
  • Guenther Glatz

23 October 2022

We performed molecular dynamics simulation to elucidate the adsorption behavior of hydrogen (H2), carbon dioxide (CO2), and methane (CH4) on four sub-models of type II kerogens (organic matter) of varying thermal maturities over a wide range of press...

  • Article
  • Open Access
5 Citations
1,499 Views
19 Pages

27 November 2024

Shale gas reservoirs have a large amount of resources, a wide range of burial, and great development potential. In order to evaluate the elastic properties of the shale, elastic wave velocity and anisotropy measurements of Longmaxi shale samples were...

  • Article
  • Open Access
6 Citations
2,312 Views
17 Pages

A significant part of organic carbon found on the earth is deposited as fossil organic matter in the lithosphere. The most important reservoir of carbon is shale rocks enriched with organic matter in the form of kerogen created during diagenesis. The...

  • Article
  • Open Access
2 Citations
1,498 Views
23 Pages

This study systematically analyzed the composition of organic functional groups and changes in the carbon structure of kerogen at different stages of thermal maturity using Fourier Transform Infrared (FTIR) spectroscopy and Laser Raman spectroscopy t...

  • Article
  • Open Access
23 Citations
5,689 Views
13 Pages

29 November 2020

Porosity and water saturation are the most critical and fundamental parameters for accurate estimation of gas content in the shale reservoirs. However, their determination is very challenging due to the direct influence of kerogen and clay content on...

  • Article
  • Open Access
21 Citations
2,772 Views
16 Pages

Cyclic Subcritical Water Injection into Bazhenov Oil Shale: Geochemical and Petrophysical Properties Evolution Due to Hydrothermal Exposure

  • Aman Turakhanov,
  • Albina Tsyshkova,
  • Elena Mukhina,
  • Evgeny Popov,
  • Darya Kalacheva,
  • Ekaterina Dvoretskaya,
  • Anton Kasyanenko,
  • Konstantin Prochukhan and
  • Alexey Cheremisin

28 July 2021

In situ shale or kerogen oil production is a promising approach to developing vast oil shale resources and increasing world energy demand. In this study, cyclic subcritical water injection in oil shale was investigated in laboratory conditions as a m...

  • Article
  • Open Access
6 Citations
1,698 Views
12 Pages

Catalytic Conversion of Oil Shale over Fe or Ni Catalysts under Sub-Critical Water

  • Chang Che,
  • Junwen Wu,
  • Zhibing Shen,
  • Haolong Ning,
  • Ruiyuan Tang,
  • Shengrong Liang,
  • Juntao Zhang,
  • Haiyan Jiang and
  • Shibao Yuan

7 May 2024

Sub-critical water is an environment-friendly solvent. It is widely used for the extraction of various organic compounds. It can be used to dissolve and transport organic matter in oil shale. In this study, the conversion of oil shale was synergistic...

  • Article
  • Open Access
14 Citations
4,397 Views
16 Pages

14 October 2021

In this study, collected samples of nine different wells from the Middle East are used for various geochemical analyses to determine the hydrocarbon generation potential. The determination is carried out following the grain density, specific surface...

  • Article
  • Open Access
8 Citations
2,383 Views
14 Pages

Molecular Simulation of Methane Adsorption Capacity of Matrix Components of Shale

  • Xiaoxue Liu,
  • Zhenxue Jiang,
  • Shibin Liu,
  • Bo Zhang,
  • Kun Zhang and
  • Xianglu Tang

17 November 2022

Shale gas occurs mainly as adsorption and free gas. Among them, whether the adsorbed gas can be gradually desorbed or not is a major cause of stable and high yield. The matrix component is the main factor affecting the adsorption capacity of shale. I...

  • Article
  • Open Access
1 Citations
1,310 Views
17 Pages

Differences in the Genesis and Sources of Hydrocarbon Gas Fluid from the Eastern and Western Kuqa Depression

  • Xianzhang Yang,
  • Taohua He,
  • Bin Wang,
  • Lu Zhou,
  • Ke Zhang,
  • Ya Zhao,
  • Qianghao Zeng,
  • Yahao Huang,
  • Jiayi He and
  • Zhigang Wen

11 October 2024

The Kuqa Depression is rich in oil and gas resources and serves as a key production area in the Tarim Basin. However, controversy persists over the genesis of oil and gas in the various structural zones of the Kuqa Depression. This study employs natu...

  • Article
  • Open Access
11 Citations
4,450 Views
13 Pages

Molecular Simulation Study on Methane Adsorption in Amorphous Shale Structure

  • Aminah Qayyimah Mohd Aji,
  • Dzeti Farhah Mohshim,
  • Belladonna Maulianda and
  • Khaled Abdalla El-Raeis

1 February 2023

Gas adsorption in the porous shale matrix is critical for gas-in-place (GIP) evaluation and exploration. Adsorption investigations benefit significantly from the use of molecular simulation. However, modelling adsorption in a realistic shale topology...

  • Article
  • Open Access
2 Citations
2,400 Views
21 Pages

Hydrocarbon Generation Mechanism of Mixed Siliciclastic–Carbonate Shale: Implications from Semi–Closed Hydrous Pyrolysis

  • Jian Wang,
  • Jun Jin,
  • Jin Liu,
  • Jingqiang Tan,
  • Lichang Chen,
  • Haisu Cui,
  • Xiao Ma and
  • Xueqi Song

28 March 2023

Affected by the complex mechanism of organic–inorganic interactions, the generation–retention–expulsion model of mixed siliciclastic–carbonate sediments is more complicated than that of common siliciclastic and carbonate shale...

  • Article
  • Open Access
3 Citations
1,485 Views
17 Pages

1 March 2024

The Lower Cambrian Niutitang Formation in the Northern Guizhou harbors abundant organic-rich mud shale, constituting the most significant marine shale gas reservoir in Guizhou. In this article, the reservoir characteristics of Lower Cambrian Niutitan...

  • Article
  • Open Access
2 Citations
1,110 Views
14 Pages

Characteristics and Origin of Natural Gas in Yongfeng Sub-Sag of Bogda Mountain Front Belt

  • Xiangcan Sun,
  • Yi Chen,
  • Xingui Zhou,
  • Zhongkai Bai,
  • Yukun Du,
  • Lei Wen and
  • Kun Yuan

8 October 2024

By systematically analyzing the natural gas composition, carbon isotopes, and source rock characteristics in the Yongfeng sub-sag of the Bogda Mountain front belt, natural gas characteristics were determined, and the genetic types and sources of natu...

  • Article
  • Open Access
250 Views
14 Pages

Geochemical Characteristics and Genetic Origin of Tight Sandstone Gas in the Daning–Jixian Block, Ordos Basin

  • Bo Wang,
  • Ming Chen,
  • Haonian Tian,
  • Junyi Sun,
  • Lei Liu,
  • Xing Liang,
  • Benliang Chen,
  • Baoshi Yu,
  • Zhuo Zhang and
  • Zhenghui Qu

12 December 2025

Tight sandstone gas constitutes a strategically significant resource in the exploration of unconventional hydrocarbon systems. Current understanding of the geochemical composition and genesis of tight sandstone gas in the Daning–Jixian Block, s...

  • Article
  • Open Access
575 Views
33 Pages

Geochemical Characterization of Kupferschiefer in Terms of Hydrocarbon Generation Potential and Hydrogen Content

  • Irena Matyasik,
  • Małgorzata Kania,
  • Małgorzata Labus and
  • Agnieszka Wciślak-Oleszycka

25 September 2025

The Permian Kupferschiefer shale, a key stratigraphic unit within the Zechstein sequence of the Fore-Sudetic Monocline, represents both a metal-rich lithofacies and a potential source rock for hydrocarbon generation. This study presents a comprehensi...

  • Article
  • Open Access
6 Citations
3,296 Views
27 Pages

Characteristics and Origins of the Natural Gas and Implications for Gas-Source Correlation in Deep Formations of the Songliao Basin, NE China

  • Zhengjian Xu,
  • Biao Peng,
  • Yanjun Feng,
  • Luofu Liu,
  • Chao Fang,
  • Mingli Shao,
  • Kexin Jia,
  • Kangjun Wu and
  • Yingying Chen

6 December 2019

The Songliao Basin is the most productive petroliferous lacustrine basin in NE China, and numerous large gas fields with large proven reserves occur in its deep formations. However, considerable challenges remain: (1) the origins and genetic types of...

  • Article
  • Open Access
18 Citations
2,558 Views
28 Pages

Marine shales from the Niutitang Formation and marine–continental transitional shales from the Longtan Formation are two sets of extremely important hydrocarbon source rocks in South China. In order to quantitatively compare the pore complexity...

  • Article
  • Open Access
7 Citations
2,509 Views
28 Pages

Investigating Attributes of Oil Source Rocks by Combining Geochemical Approaches and Basin Modelling (Central Gulf of Suez, Egypt)

  • Moataz Barakat,
  • Mohamed Reda,
  • Dimitra E. Gamvroula,
  • Robert Ondrak and
  • Dimitrios E. Alexakis

The present study focused on the Upper Cretaceous to Middle Miocene sequence in the Central Gulf of Suez, Egypt. The Upper Cretaceous to Middle Miocene sequence in the October field is thick and deeply buried, consisting mainly of brown limestone, ch...

  • Article
  • Open Access
10 Citations
2,490 Views
15 Pages

Hydrogen Gas Adsorption of the Triassic Chang 7 Shale Member in the Ordos Basin, China

  • Lu Wang,
  • Zhijun Jin,
  • Guanping Wang,
  • Xiaowei Huang,
  • Yutong Su and
  • Qian Zhang

27 February 2024

The present study investigates the adsorption of hydrogen gas by the Triassic Chang 7 Shale Member in the Ordos Basin, China. The mineral composition, microscopic morphology, pore characteristics, hydrogen adsorption capacity, and factors influencing...

  • Article
  • Open Access
1 Citations
1,215 Views
12 Pages

Adsorption Characteristics of Illite and Kerogen Oil Phase: Thermodynamics Experiments

  • Xin Tang,
  • Junjie Xiong,
  • Yanming Zhu,
  • Ruiyu He,
  • Xiangru Chen,
  • Qiuqi Chen,
  • Zhangping Yan,
  • Cheng Liu and
  • Litao Ma

30 May 2024

In order to study the adsorption process and adsorption characteristics of shale oil at the macro scale, the isothermal adsorption experiments of illite and kerogen on a heptadecane (oil phase) solution were carried out by infrared spectrophotometry...

  • Article
  • Open Access
479 Views
16 Pages

13 October 2025

The Northern Tibetan Plateau Basin is the most extensive and least explored Mesozoic marine basin in China and shows considerable potential for oil and gas exploration. This study systematically analyzed the abundance, type, hydrocarbon generation po...

  • Article
  • Open Access
4 Citations
959 Views
34 Pages

Multi-Scale Pore Structure of Terrestrial, Transitional, and Marine Shales from China: Insights into Porosity Evolution with Increasing Thermal Maturity

  • Zhongrui Wu,
  • Ralf Littke,
  • Shuo Qin,
  • Yahao Huang,
  • Sheng He,
  • Gangyi Zhai,
  • Zhengqing Huang and
  • Kaiming Wang

Organic matter (OM)-hosted pores play a crucial role in unconventional shale reservoirs, with their development influenced by OM type and thermal maturity across terrestrial, transitional, and marine deposits. In this study, a comparative analysis of...

  • Article
  • Open Access
3 Citations
1,771 Views
21 Pages

5 January 2025

Shale oil and gas resources have become an alternative energy source and are crucial in the field of sustainable oil and gas exploration. In the Junggar Basin, the Permian is not only the most significant source rock, but also an important field in s...

  • Article
  • Open Access
1 Citations
1,832 Views
16 Pages

11 August 2023

The natural gas in the Triassic Xujiahe Formation (T3x) is reported to be mainly derived from the T3x source rock itself. Here, we report a new natural gas accumulation model, which demonstrates that the T3x gas in the Tongjiang-Malubei (TM) area is...

  • Article
  • Open Access
1,798 Views
16 Pages

27 June 2023

The Maoming basin in south China is rich in oil shale resources, whereas the Youganwo formation is a potential area for large-scale in situ exploration because of its relatively large thickness, high oil content, and good continuity. Based on previou...

  • Feature Paper
  • Article
  • Open Access
26 Citations
4,270 Views
17 Pages

Heavy Oil Hydrocarbons and Kerogen Destruction of Carbonate–Siliceous Domanic Shale Rock in Sub- and Supercritical Water

  • Zukhra R. Nasyrova,
  • Galina P. Kayukova,
  • Alexey V. Vakhin,
  • Richard Djimasbe and
  • Artem E. Chemodanov

8 July 2020

This paper discusses the results of the influences of subcritical (T = 320 °C; P = 17 MPa) and supercritical water (T = 374 °C; P = 24.6 MPa) on the yield and composition of oil hydrocarbons generated from carbonaceous–siliceous Domanic...

  • Article
  • Open Access
4 Citations
2,737 Views
22 Pages

Thermal Maturity and Kerogen Type of Badenian Dispersed Organic Matter from the Getic Depression, Romania

  • Maria Doina Ghiran,
  • Mihai Emilian Popa,
  • Izabela Mariș,
  • Georgeta Predeanu,
  • Ștefania Gheorghe and
  • Niculina Mihaela Bălănescu

30 January 2023

The aim of this study is to evaluate the thermal maturity of Upper Badenian (Middle Miocene) petroleum source rocks of the Getic Depression, Romania, and to characterize the dispersed organic matter using organic petrography associated with Rock-Eval...

  • Article
  • Open Access
1 Citations
1,536 Views
29 Pages

27 January 2025

Organic matter exhibits significant heterogeneity and complexity, with varying pore structures across different types influenced by multiple interacting factors. This paper introduces a “two categories, six subcategories” classification s...

  • Article
  • Open Access
4 Citations
2,329 Views
21 Pages

11 August 2023

In order to evaluate the hydrocarbon generation potential and effectiveness of the carbonate source rock from the Lower Permian Taiyuan Formation of the Upper Paleozoic gas reservoirs in the central and eastern Ordos Basin, 87 core samples from the f...

  • Article
  • Open Access
3 Citations
3,119 Views
23 Pages

13 April 2023

The Middle Jurassic in the north Western Desert, Egypt, was a time of complex tectonics and increased environmental perturbations attributed to the predominant sedimentation of organic carbon-rich fine siliciclastic and carbonate deposits of the Khat...

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