- Article
The First Principal Calculation of the Temperature-Dependent Crystalline Defect Evolution in UN
- Yongheng Lu,
- Tingyu Sun and
- Kun Yang
- + 6 authors
This study systematically investigates the influence of temperature on the defect formation mechanisms in uranium nitride (UN) crystals using first-principles calculations. The formation energies and lattice distortion characteristics of various defects at 0 K and 1780 K were calculated by constructing models of perfect crystals as well as vacancy, interstitial, antisite, and divacancy defects. The results demonstrate that elevated temperatures significantly reduce defect formation energies, with interstitial and divacancy defects exhibiting negative formation energies at 1780 K, indicating a tendency for spontaneous formation. The U interstitial defect induces the most pronounced lattice expansion of 5.1% at 0 K. Furthermore, interstitial defects cause the most significant lattice distortions, while Schottky defects exhibit the lowest formation energy. The current study provides theoretical insights into the defect behavior of UN fuel under high-temperature service conditions and offers valuable guidance for optimizing sintering process parameters.
16 March 2026






![Schematic diagram of the experimental methodology: (A) Representation of the miscanthus stem and internodes used for sample preparation; (B) measurement setup for determining the characteristic dimensions of samples: Dmin—minimum stalk diameter, Dmax—maximum stalk diameter and THwall—stalk wall thickness; (C) a scheme of a static cutting test; (D) development of artificial neural networks [40].](https://mdpi-res.com/cdn-cgi/image/w=281,h=192/https://mdpi-res.com/materials/materials-19-01162/article_deploy/html/images/materials-19-01162-g001-550.jpg)


