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Inorganics, Volume 13, Issue 10

2025 October - 31 articles

Cover Story: Inorganic nanomaterials such as manganese dioxide, iron oxide, and cerium oxide can selectively alleviate hypoxia, buffer acidity, regulate redox balance, and even stimulate anti-tumor immunity through catalytic or structural mechanisms. These materials can further serve as carriers for stimuli-responsive drug delivery, enabling synergistic therapies that include chemodynamic, photothermal, and immunomodulatory treatments. This review summarizes recent developments in smart inorganic nanomaterials for TME modulation, discusses design considerations including biosafety and biodegradability, and evaluates the current translational status and future directions. Such strategies represent a promising leap toward precise and personalized cancer nanomedicine. View this paper
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Articles (31)

  • Review
  • Open Access
1,980 Views
33 Pages

21 October 2025

Silver nanoparticles (AgNPs) are highly promising components for the development of innovative biomedical products. However, a critical issue remains the insufficient deep and quantitative understanding of their fundamental physicochemical properties...

  • Article
  • Open Access
1,019 Views
17 Pages

16 October 2025

The organic/inorganic hybrid compound bis(2-amino-6-bromopyridinium) tetrachloridocuprate(II) (HABPy)2[CuCl4] was synthesized in crystalline form in a 77% yield from aqueous HCl solutions containing Cu(OAc)2 and 2-amino-6-bromopyridine (ABPy). Single...

  • Article
  • Open Access
887 Views
13 Pages

Catalytic Activity of Rhenium(I) Tricarbonyl Complexes Containing Polypyridine and Phosphorus–Nitrogen Ligands in the Hydrogen Transfer of Acetophenone

  • César Zúñiga,
  • Mauricio Fuentealba,
  • Elizabeth Olave,
  • Diego P. Oyarzún,
  • Andrés Aracena,
  • Mauricio Yañez-S,
  • Plinio Cantero-López and
  • Pedro A. Aguirre

14 October 2025

This work reports the synthesis and characterization of a novel rhenium(I) complex incorporating a phosphorus–nitrogen (P,N) ligand. The compound crystallizes in a distorted octahedral geometry, as confirmed by single-crystal X-ray diffraction...

  • Review
  • Open Access
23 Citations
1,728 Views
26 Pages

14 October 2025

The tumor microenvironment (TME) is characterized by hypoxia; acidic pH; oxidative stress; and immune suppression; all of which severely impair the efficacy of conventional cancer therapies. Recent advances in inorganic nanotechnology have led to the...

  • Review
  • Open Access
1,258 Views
18 Pages

Chiral Transition Metal Complexes Featuring Limonene-Derived Ligands: Roles in Catalysis and Biology

  • Ghaita Chahboun,
  • Mohamed El Hllafi,
  • Eva Royo and
  • Mohamed Amin El Amrani

13 October 2025

Chiral coordination compounds are of growing interest due to their structural diversity and wide applicability. Besides chirality, alcohol and especially oxime-functionalized limonene derivatives confer water solubility, stability, and the appropriat...

  • Article
  • Open Access
1,063 Views
17 Pages

Synthesis, Structural Characterization, Cytotoxicity, and Antibacterial Properties of Gold(III) Complexes with Hydrazones Derived from Vitamin B6

  • Daria V. Petrova,
  • Aleksandra K. Isagulieva,
  • Olga N. Sineva,
  • Vera S. Sadykova,
  • Maksim N. Zavalishin and
  • George A. Gamov

11 October 2025

The rise in the number of cancer cases and the dissemination of strains with multiple drug resistance in the world pose a serious threat to public health care and human well-being. The design and study of new chemotherapeutic agents for cancer and in...

  • Article
  • Open Access
1,068 Views
16 Pages

6 October 2025

This research prepared and characterised novel mixed coordination complexes derived from escitalopram with eugenol and curcumin to form (L1) and (L2), respectively. The complexes were prepared via Williamson ether synthesis and analysed by FTIR, UV&n...

  • Article
  • Open Access
907 Views
12 Pages

4 October 2025

This paper describes two low-cost, modular instruments developed for rapid room-temperature characterization of mainly thermoelectrics. The first instrument measures the Seebeck coefficient across diverse sample geometries and incorporates a four-poi...

  • Review
  • Open Access
2 Citations
1,633 Views
32 Pages

2 October 2025

Over the last century, improvements in computational power resulting from the exponential growth of microelectronics have been the driving force of outstanding global economic growth as well as of deep changes in society and ethical values. Manufactu...

  • Article
  • Open Access
1,353 Views
16 Pages

A Comprehensive Study of the Optical, Structural, and Morphological Properties of Chemically Deposited ZnO Thin Films

  • Sayra Guadalupe Ruvalcaba-Manzo,
  • Rafael Ramírez-Bon,
  • Ramón Ochoa-Landín and
  • Santos Jesús Castillo

2 October 2025

Zinc oxide (ZnO) is a wide bandgap semiconductor with optoelectronic and photocatalytic properties, which depend on its optical, structural, and morphological characteristics. In this study, we synthesized ZnO thin films by chemical bath deposition (...

  • Review
  • Open Access
1,514 Views
21 Pages

Use of N-Heterocyclic Carbene Compounds (NHCs) Under Sustainable Conditions—An Update

  • Abdelkarim El Qami,
  • Adrien Kibongui-Fila and
  • Sabine Berteina-Raboin

1 October 2025

In this review, we focused on advances made over the last two decades in the field of catalysis using N-heterocyclic carbenes (NHCs), which can be used for metallic or non-metallic catalysis. We listed the advantages of these NHCs and their modes of...

  • Article
  • Open Access
1 Citations
846 Views
18 Pages

1 October 2025

In this study, high-conductivity W-doped Ga2O3 thin films were successfully fabricated by directly depositing a composition of Ga2O3 with 10.7 at% WO3 (W:Ga = 12:100) using electron beam evaporation. The resulting thin films were found to be amorphou...

  • Feature Paper
  • Article
  • Open Access
841 Views
9 Pages

30 September 2025

Treatment of N,N-dimethylhydrazinoalkenes with diethylzinc followed by exposure of the resulting ethylzinc amides to high vacuum drives a Schlenck redistribution metalloamination/cyclization to generate the corresponding bis(organozinc) intermediates...

  • Article
  • Open Access
847 Views
13 Pages

Complexation-Induced Reduction of CuII to CuI Promoted by a Distorted Tetrahedral N4-Type Schiff-Base Ligand

  • Tomoyuki Takeyama,
  • Daisuke Shirabe,
  • Nobutsugu Hamamoto and
  • Takehiro Ohta

30 September 2025

Although spontaneous or complexation-induced reductions of CuII to CuI have occasionally been observed, controlling these processes remains a challenge. Herein, we report the synthesis of CuI complexes via the complexation-induced reduction of CuII c...

  • Article
  • Open Access
811 Views
21 Pages

Facile Reversible Eu2+/Eu3+ Redox in Y2SiO5 via Spark Plasma Sintering: Dwell Time-Dependent Luminescence Tuning

  • Fernando Juárez-López,
  • Merlina Angélica Navarro-Villanueva,
  • Rubén Cuamatzi-Meléndez,
  • Margarita García-Hernández,
  • María José Soto-Miranda and
  • Angel de Jesús Morales-Ramírez

30 September 2025

The present study investigates the luminescent behaviour of sol–gel derived Y2SiO5 powders doped with Eu3+ ions, subjected to spark plasma sintering. The sintering process induces the partial reduction of Eu3+ to Eu2+, and the phenomenon is str...

  • Article
  • Open Access
1,064 Views
10 Pages

Temperature-Dependent Degradation of Volatile Organic Compounds Using Ga2O3 Photocatalyst

  • Dayoun Hong,
  • Jiwon Kwak,
  • Hyeongju Cha,
  • Heejoong Ryou,
  • Sunjae Kim,
  • Wan Sik Hwang and
  • Hyunah Kim

30 September 2025

Volatile organic compounds (VOCs), including benzene, toluene, and formaldehyde, are hazardous air pollutants that require efficient and sustainable mitigation strategies. Photocatalytic degradation of VOCs offers a promising pathway; however, its pe...

  • Article
  • Open Access
1 Citations
1,006 Views
23 Pages

A Heterobimetallic Au(I)–Ru(II) Complex Bridged by dppb: Synthesis, Structural and Solution Characterization, BSA Interaction and In Vivo Toxicity Evaluation in Wistar Rats

  • Adnan Zahirović,
  • Sunčica Roca,
  • Muhamed Fočak,
  • Selma Fetahović,
  • Višnja Muzika,
  • Damir Suljević,
  • Anela Topčagić,
  • Maja Mitrašinović-Brulić,
  • Irnesa Osmanković and
  • Aleksandar Višnjevac
  • + 1 author

29 September 2025

A novel heterobimetallic ruthenium(II)–gold(I) complex featuring a bridging bis(diphenylphosphino)butane (dppb) ligand was prepared and fully characterized. Single-crystal X-ray diffraction revealed a piano-stool geometry around Ru(II) with &et...

  • Review
  • Open Access
2,241 Views
46 Pages

MIL Series in MOFs for the Removal of Emerging Contaminants: Application and Mechanisms

  • Yixiang Chen,
  • Yusheng Jiang,
  • Weiping Li,
  • Wei Su,
  • Yi Xing,
  • Shuyan Yu,
  • Wenxin Li,
  • Ying Guo,
  • Duo Zhang and
  • Bo Jiang
  • + 3 authors

29 September 2025

In global economic integration and rapid urbanization, the equilibrium between resource utilization efficiency and ecological preservation is confronted with significant challenges. Emerging contaminants have further exacerbated environmental pressur...

  • Review
  • Open Access
2,533 Views
34 Pages

28 September 2025

Calcium carbonate (CaCO3) is a dominant component of sedimentary rocks and biogenic structures, and is one of the most frequently studied inorganic compounds. It also plays a key role in preparing modern engineered materials. CaCO3 has three well-kno...

  • Article
  • Open Access
1 Citations
956 Views
21 Pages

Photoactive TiO2 Nanotubes and SILAR-Synthesized PbS/TiO2 Heterojunctions for Tetracycline Antibiotic Photodegradation

  • Safa Jemai,
  • Karim Choubani,
  • Anouar Hajjaji,
  • Syrine Sassi,
  • Mohamed Ben Rabha,
  • Mohammed A. Almeshaal,
  • Bernabé Mari Soucase and
  • Brahim Bessais

27 September 2025

Titanium dioxide nanotubes (TiO2 NTs) decorated with lead sulfide nanoparticles (PbS NPs) were synthesized using the Successive Ionic Layer Adsorption and Reaction (SILAR) method at different number (n) of cycles (where n = 3, 5, and 8) and evaluated...

  • Review
  • Open Access
3 Citations
1,958 Views
30 Pages

Recent Advances in Graphitic Carbon Nitride-Based Materials in the Photocatalytic Degradation of Emerging Contaminants

  • Dan Xu,
  • Heshan Cai,
  • Daguang Li,
  • Feng Chen,
  • Shuwen Han,
  • Xiaojuan Chen,
  • Zhenyi Li,
  • Zebang He,
  • Zhuhong Chen and
  • Yejun Feng
  • + 4 authors

26 September 2025

The increasing presence of emerging contaminants (ECs) has attracted considerable attention due to their potential harm to human health and ecosystems. Graphitic carbon nitride (g-C3N4), a semiconductor devoid of metals, stands out due to its distinc...

  • Article
  • Open Access
786 Views
15 Pages

26 September 2025

In this study, COOH-functionalized co-polymer of acrylonitrile and itaconic acid (P(AN-co-IA)) is synthesized via free radical copolymerization using DMSO as solvent. The continuous non-aligned carbon nanofibers (CNFs) with different amounts of metal...

  • Article
  • Open Access
1,165 Views
13 Pages

Low-Temperature Formation of Aluminum Nitride Powder from Amorphous Aluminum Oxalate via Carbothermal Reduction

  • Wenjing Tang,
  • Yaling Yu,
  • Zixuan Huang,
  • Weijie Wang,
  • Shaomin Lin,
  • Ji Luo,
  • Chenyang Zhang and
  • Zhijie Zhang

25 September 2025

Aluminum nitride (AlN) powder, a cornerstone material for advanced ceramics. This study examines the low-temperature formation of AlN crystals as well as their phase transformation by employing amorphous aluminum oxalate (AAO) as a novel precursor fo...

  • Article
  • Open Access
732 Views
10 Pages

25 September 2025

η6-Coordination catalysis has emerged as an effective strategy for activating electron-rich (hetero)arenes toward nucleophilic substitution. Recent experimental studies on Ru(II)-catalyzed amination of aminopyridines revealed a striking ortho&nda...

  • Article
  • Open Access
811 Views
19 Pages

25 September 2025

The appearance of spin-induced ferroelectric polarization in the so-called type-II multiferroic materials has received a lot of attention. The nature and mechanisms of such polarization were intensively studied using perovskite rare-earth manganites,...

  • Article
  • Open Access
2 Citations
1,696 Views
13 Pages

Scalable High-Yield Exfoliation of Hydrophilic h-BN Nanosheets via Gallium Intercalation

  • Sungsan Kang,
  • Dahun Kim,
  • Seonyou Park,
  • Sung-Tae Lee,
  • John Hong,
  • Sanghyo Lee and
  • Sangyeon Pak

25 September 2025

Hexagonal boron nitride (h-BN) possesses a unique combination of a wide bandgap, high thermal conductivity, and chemical inertness, making it a key insulating and thermal management material for advanced electronics and nanocomposites. However, its i...

  • Article
  • Open Access
1 Citations
773 Views
18 Pages

Calcium Phosphate Ceramic Powders Prepared from Mechanochemically Activated Precursors

  • Kostadinka Sezanova,
  • Yordanka Tuparova,
  • Pavletta Shestakova,
  • Pavel Markov,
  • Daniela Kovacheva and
  • Diana Rabadjieva

24 September 2025

The chemical and structural similarity of calcium orthophosphates to hard tissues in the human body makes them suitable as biomaterials for bone implants, cements, injection systems, etc., for bone regeneration and reconstruction. Tetracalcium phosph...

  • Article
  • Open Access
767 Views
19 Pages

Single-Atom Cobalt-Doped 2D Graphene: Electronic Design for Multifunctional Applications in Environmental Remediation and Energy Storage

  • Zhongkai Huang,
  • Yue Zhang,
  • Chunjiang Li,
  • Liang Deng,
  • Bo Song,
  • Maolin Bo,
  • Chuang Yao,
  • Haolin Lu and
  • Guankui Long

24 September 2025

Through atomic-scale characterization of a single cobalt atom anchored in a pyridinic N3 vacancy of graphene (Co-N3-gra), this study computationally explores three interconnected functionalities mediated by cobalt’s electronic configuration. Qu...

  • Article
  • Open Access
782 Views
11 Pages

24 September 2025

The development of metallopharmaceuticals for diabetes treatment has garnered increasing attention due to its insulin-mimetic properties, particularly in vanadium complexes. In this study, we report the biophysical evaluation of a series of 3-hydroxy...

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Inorganics - ISSN 2304-6740