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Crystals, Volume 14, Issue 1

2024 January - 104 articles

Cover Story: Titanium dioxide (TiO2) nanocrystals (TNPs) are utilized in diverse applications, including cosmetics and as a food additive. In our study, we attempted to understand the influence of TNPs on the growth and aggregation of two main stone-forming crystalline substances, calcium phosphate (CaP) and monosodium urate (MSU), particularly its implications in gout disease. Our finding through studying dissolution kinetics revealed that TNPs promote the co-aggregations of CaP+MSU in the presence of hydroxycitrate (HCT). Overall, TNPs stabilized CaP+MSU mixed crystals, which implicates the significance of TNP exposure in the pathogenesis of gout disease. We observed the background polymorphs of TiO2 anatase; the top panel shows the easy dissolution by HCT, which is prevented by TiO2 (bottom panel). View this paper
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Articles (104)

  • Article
  • Open Access
2 Citations
1,878 Views
12 Pages

The Effects of Indium Additions on Tribological Behavior of Spark Plasma Sintering-Produced Graphene-Doped Alumina Matrix Composites for Self-Lubricating Applications

  • Viktor Puchý,
  • Mária Podobová,
  • Richard Sedlák,
  • Ladislav Falat,
  • Róbert Džunda,
  • František Kromka and
  • Ján Dusza

22 January 2024

Alumina (Al2O3) ceramics are interesting for low-weight and mid-high temperature applications. The addition of indium (In) and graphene nanoplatelets (GNPs) can be used to reduce the density and modify the functional properties and mechanical perform...

  • Article
  • Open Access
1 Citations
2,917 Views
19 Pages

Microstructure and Properties Variation of High-Performance Grey Cast Iron via Small Boron Additions

  • Grega Klančnik,
  • Jaka Burja,
  • Urška Klančnik,
  • Barbara Šetina Batič,
  • Luka Krajnc and
  • Andrej Resnik

22 January 2024

A study was undertaken to investigate the effects of small boron additions on the solidification and microstructure of hypo-eutectic alloyed grey cast iron. The characteristic temperatures upon crystallisation of the treated metal melt were recorded,...

  • Article
  • Open Access
6 Citations
2,751 Views
15 Pages

22 January 2024

Topological states of matter have attracted significant attention due to their intrinsic wave-guiding and localization capabilities robust against disorders and defects in electronic, photonic, and phononic systems. Despite the above topological feat...

  • Review
  • Open Access
9 Citations
4,803 Views
17 Pages

22 January 2024

Aluminum alloys with low-weight property are promising structure materials for sports equipment. Alloying element-rich second-phase particles create the risk of localized corrosion and result in failure of sports equipment. Chromate conversion coatin...

  • Article
  • Open Access
5 Citations
2,265 Views
24 Pages

Influence of Ultrahigh Dilution Treatment of the Charge on the Growth and Spectroscopic Properties of Nd:MgMoO4 Potential Laser Crystal

  • Kirill A. Subbotin,
  • Yana S. Didenko,
  • Anatolii I. Titov,
  • Denis A. Lis,
  • Sergei K. Pavlov,
  • Pavel A. Volkov,
  • Kristina I. Runina,
  • Valerii V. Voronov,
  • Elena V. Chernova and
  • Yulia I. Zimina
  • + 2 authors

22 January 2024

The influence of the charge treatment by ultrahigh dilution (UHD) technology on oxide single crystals grown by the Czochralski technique was studied for monoclinic MgMoO4 crystals doped by 1 at. % of Nd3+ ions. The series of 10 Nd:MgMoO4 crystals was...

  • Article
  • Open Access
4 Citations
3,183 Views
16 Pages

22 January 2024

A series of syringaldehyde imines with para-substituted anilines have been synthesized in a good yield, and their crystal structures have been analyzed. The orientation of the syringaldehyde hydroxyl group plays in important role in the intermolecula...

  • Article
  • Open Access
4 Citations
3,015 Views
20 Pages

22 January 2024

A survey of the trends in metal–ligand coordination and hydrogen bonding has been carried out on complexes of singly deprotonated cyanuric acid CY and alkaline earth metals, synthesised from aqueous solution and characterised by X-ray cr...

  • Review
  • Open Access
6 Citations
5,139 Views
34 Pages

21 January 2024

Recently, the formation of chiral materials by the self-organization of achiral small molecules has attracted much attention. How can we obtain chirality without a chiral source? Interesting approaches, such as mechanical rotation, circularly polariz...

  • Article
  • Open Access
2 Citations
2,258 Views
11 Pages

21 January 2024

During our nanomineralogical investigation of melt inclusions in corundum xenocrysts from the Mount Carmel area, Israel, seven new oxide and alloy minerals have been discovered since 2021. Herein, we report toledoite (TiFeSi; IMA 2022-036), a new all...

  • Article
  • Open Access
2 Citations
1,551 Views
11 Pages

20 January 2024

The results of dielectric relaxation spectroscopy of the chiral liquid crystal 4′-butyl-4-(2-methylbutoxy)azoxybenzene in the crystal phase are presented. The scaling procedure showed complex molecular dynamics and allows one to decompose the o...

  • Article
  • Open Access
4 Citations
2,906 Views
24 Pages

19 January 2024

Recovering scandium from hydrometallurgical residue bears the potential of a better supply of an industry depending on imports from countries with more mineral resources than Europe. To recover scandium from unused metal production residue, strip liq...

  • Article
  • Open Access
1 Citations
1,592 Views
13 Pages

19 January 2024

A system of steady lamellar eutectic growth in directional solidification is considered with the case of small tangent values of the contact angles. The mathematical model is given in the non-dimensional rectangular coordinate system and the uniforml...

  • Article
  • Open Access
3 Citations
2,077 Views
13 Pages

Pseudo-Spin Polarized One-Way Elastic Wave Eigenstates in One-Dimensional Phononic Superlattices

  • Pierre A. Deymier,
  • Keith Runge,
  • Alexander Khanikaev and
  • Andrea Alù

19 January 2024

We investigate a one-dimensional discrete binary elastic superlattice bridging continuous models of superlattices that showcase a one-way propagation character, as well as the discrete elastic Su–Schrieffer–Heeger model, which does not ex...

  • Article
  • Open Access
1 Citations
2,116 Views
13 Pages

Piezoelectric Properties and Thermal Stability of Pb(Yb1/2Nb1/2)O3-BiScO3-PbTiO3 Ternary Ceramics

  • Fan Zhang,
  • Hua Hao,
  • Minghe Cao,
  • Zhonghua Yao,
  • Shuai Fu and
  • Hanxing Liu

19 January 2024

Piezoelectric ceramics with excellent piezoelectric properties and a high Curie temperature are important for numerous electromechanical devices in a broad range of temperature environments. In this work, the relaxor ferroelectric Pb(Yb1/2Nb1/2)O3 en...

  • Article
  • Open Access
14 Citations
2,815 Views
14 Pages

Room-Temperature O3 Detection: Zero-Bias Sensors Based on ZnO Thin Films

  • Eleonora Bolli,
  • Alice Fornari,
  • Alessandro Bellucci,
  • Matteo Mastellone,
  • Veronica Valentini,
  • Alessio Mezzi,
  • Riccardo Polini,
  • Antonio Santagata and
  • Daniele Maria Trucchi

18 January 2024

ZnO thin films with a thickness of 300 nm were deposited on Si and Al2O3 substrates using an electron beam evaporation technique with the aim of testing them as low cost and low power consumption gas sensors for ozone (O3). Scanning electron microsco...

  • Article
  • Open Access
13 Citations
3,913 Views
25 Pages

18 January 2024

Inconel 718 (UNS N07718) is a nickel-base superalloy containing iron that is used at cryogenic temperatures (arctic pipe components) and at high temperatures (gas turbines). This alloy is also used in off-shore oil drilling due to its high overall st...

  • Article
  • Open Access
2 Citations
2,841 Views
17 Pages

Mammalian Cell Cytotoxicity, Antibacterial Activity and the Properties of Methylenebis(Hydroxybenzoic Acid) and Its Related Zinc(II) Complex

  • Ayman H. Ahmed,
  • Ibrahim O. Althobaiti,
  • Marwah Aljohani,
  • Ehab S. Gad,
  • Yazeed M. Asiri and
  • Omar A. Hussein

17 January 2024

Formaldehyde, sulfuric acid and salicylic acid were combined to create a 3,3′-methylenebis(2-hydroxybenzoic acid) (MHB) ligand, which was subsequently permitted to bind with zinc(II) ions. The ligand and its zinc(II) complex (Zn–MHB) have...

  • Article
  • Open Access
1 Citations
2,247 Views
14 Pages

16 January 2024

The organic–inorganic hybrid compound, (o-BrAH)[H2Co(CN)6]0.5·(18-crown-6)0.5·H2O, was synthesized and characterized by variable-temperature X-ray diffraction, single-crystal diffraction, infrared spectroscopy, elemental analysis,...

  • Review
  • Open Access
55 Citations
11,093 Views
26 Pages

16 January 2024

Metal halide perovskite materials have shown significant advancements in their application as light absorbers in perovskite solar cells, with power conversion efficiencies reaching 27%. However, lead-based perovskites pose a concern due to their toxi...

  • Article
  • Open Access
3 Citations
1,725 Views
13 Pages

16 January 2024

In protein crystallography, the determination of an accurate protein envelope is of paramount importance for ab initio phasing of diffraction data. In our previous work, we introduced an approach to ascertain the protein envelope by seeking an optima...

  • Article
  • Open Access
18 Citations
3,110 Views
15 Pages

16 January 2024

Demantoid is the green variety of andradite [Ca3Fe2(SiO4)3], an exceptionally rare and precious gemstone worldwide. In recent years, a small amount of gem-quality demantoid has been found in Pakistan. This research focuses on nine demantoids sourced...

  • Article
  • Open Access
7 Citations
2,701 Views
12 Pages

15 January 2024

By employing the technology of laser cladding, AlCoCrFeNi–TiC20−x/WCx high-entropy alloy coatings (where x = 0, 5, 10, 15, and 20 is the mass fraction) were fabricated on 316L stainless steel (316Lss). The effects of changes in different...

  • Article
  • Open Access
4 Citations
2,224 Views
15 Pages

15 January 2024

Metallic transition-metal dichalcogenides are emerging as promising electrode materials for applications such as 2D electronic devices owing to their good electrical conductivity. In this study, a high-performance humidity sensor based on NbTe2 elect...

  • Article
  • Open Access
9 Citations
4,762 Views
20 Pages

15 January 2024

The powder bed fusion–laser beam (PBF-LB) process, a method of additive manufacturing (AM), was used to print duplex stainless steel (DSS) using commercial-grade 2507 powders. While conventionally processed DSS has a two-phase microstructure co...

  • Article
  • Open Access
2 Citations
3,060 Views
22 Pages

Gemological and Chemical Characterization of Gem-Quality Titanite from Morocco

  • Yu Yuan,
  • Zhuang Miao,
  • Yi Zhao,
  • Bo Xu,
  • Jialu Gu and
  • Pengyu Yuan

14 January 2024

Titanite is a widespread accessory mineral in igneous, metamorphic, and hydrothermal rocks, but few comply with gem-grade requirements. Previous studies on Moroccan titanite focused on elementary composition and U-Pb dating. In this study, two gem-gr...

  • Article
  • Open Access
5 Citations
2,697 Views
13 Pages

A Self-Powered Broadband Photodetector with High Photocurrent Based on Ferroelectric Thin Film Using Energy Band Structure Design

  • Xing Gao,
  • Xin Song,
  • Shan Zhang,
  • Xinxiang Yang,
  • Pei Han,
  • Liwen Zhang,
  • Chunxiao Lu,
  • Xihong Hao and
  • Yong Li

13 January 2024

Self-powered photodetectors have the advantages of high sensitivity, sustainability, and small size and have become a research hotspot in advanced optoelectronic systems. However, the low output photocurrent density seriously hinders the practical ap...

  • Article
  • Open Access
9 Citations
2,762 Views
14 Pages

13 January 2024

The detection and real-time monitoring of temperature parameters are important, and indium oxide-based thin film thermocouples can be integrated on the surface of heaters because they operate normally under harsh conditions and provide accurate onlin...

  • Review
  • Open Access
6 Citations
4,558 Views
26 Pages

13 January 2024

Rising atmospheric CO2 levels demand efficient and sustainable carbon capture solutions. Direct air capture (DAC) via crystallizing hydrogen-bonded frameworks such as carbonate salts has emerged as a promising approach. This review explores the poten...

  • Article
  • Open Access
3 Citations
2,659 Views
17 Pages

Cobalt(II) Paddle-Wheel Complex with 3,5-Di(tert-butyl)-4-hydroxybenzoate Bridges: DFT and ab initio Calculations, Magnetic Dilution, and Magnetic Properties

  • Tatiana V. Astaf’eva,
  • Stanislav A. Nikolaevskii,
  • Evgeniy N. Egorov,
  • Stanislav N. Melnikov,
  • Dmitriy S. Yambulatov,
  • Anna K. Matiukhina,
  • Marina E. Nikiforova,
  • Maxim A. Shmelev,
  • Aleksandr V. Kolchin and
  • Mikhail A. Kiskin
  • + 5 authors

13 January 2024

A new binuclear "paddle-wheel" complex, [Co2(bhbz)4(EtOH)2]·4EtOH (1, Hbhbz-3,5-di(tert-butyl)-4-hydroxybenzoic acid); an isostructural zinc complex (2); a and magnetically diluted sample of [Zn1.93Co0.07(bhbz)4(EtOH)2]·4EtOH (3) were o...

  • Article
  • Open Access
2 Citations
1,852 Views
12 Pages

Hot-Electron Microwave Noise and Energy Relaxation in (Be)MgZnO/ZnO Heterostructures

  • Emilis Šermukšnis,
  • Artūr Šimukovič,
  • Vitaliy Avrutin,
  • Natalia Izyumskaya,
  • Ümit Özgür and
  • Hadis Morkoç

12 January 2024

Pulsed hot-electron microwave noise measurements of the (Be)MgZnO/ZnO heterostructures are presented in this work. The heterostructures of different barrier thicknesses and different bulk electron densities in ZnO layer are compared. Capacitance&ndas...

  • Article
  • Open Access
3 Citations
2,453 Views
11 Pages

12 January 2024

The study of the effects of impurity on grain boundaries is a critical aspect of materials science, particularly when it comes to understanding and controlling the properties of materials for specific applications. One of the related key issues is th...

  • Article
  • Open Access
2,057 Views
13 Pages

11 January 2024

A multi-channel mode-division multiplexing based on a chalcogenide-lithium niobate platform using chalcogenide films with adjustable refractive index is proposed, with the aim of overcoming issues with narrow bandwidth and large crosstalk in conventi...

  • Article
  • Open Access
7 Citations
2,584 Views
14 Pages

Numerical Simulation of CdTe Crystal Growth Using the Vertical Gradient Freeze Technique Assisted by Axial Low-Frequency Oscillations of the Melt

  • Oleg Nefedov,
  • Alexey Dovnarovich,
  • Vladimir Kostikov,
  • Elena Mozhevitina,
  • Dmitry Bocharnikov and
  • Igor Avetissov

11 January 2024

The problem of intensification of the melt crystal growth process has been analyzed using CdTe as an actual material. Numerical simulation of 100 mm diameter CdTe crystal growth using the VGF technique has been carried out. The heat–mass transf...

  • Article
  • Open Access
1 Citations
1,709 Views
9 Pages

11 January 2024

Anti-solvent crystallization of carbapenem CS-023 was performed at 25 °C. The following results were obtained: (1) A solvate crystal, Form A (5/2 Ethanol·1/2 H2O), was recovered from 80 v/v% ethanol solution; (2) Form A transformed to Form...

  • Article
  • Open Access
1 Citations
2,089 Views
19 Pages

10 January 2024

Molten titanium-containing blast furnace slag can be used to obtain cast stone materials by controlling a reasonable heat treatment system. The material acquired during this process showcases residual stress, which additionally impacts the macroscopi...

  • Review
  • Open Access
10 Citations
9,677 Views
18 Pages

Transistor-Based Synaptic Devices for Neuromorphic Computing

  • Wen Huang,
  • Huixing Zhang,
  • Zhengjian Lin,
  • Pengjie Hang and
  • Xing’ao Li

9 January 2024

Currently, neuromorphic computing is regarded as the most efficient way to solve the von Neumann bottleneck. Transistor-based devices have been considered suitable for emulating synaptic functions in neuromorphic computing due to their synergistic co...

  • Article
  • Open Access
2,872 Views
16 Pages

8 January 2024

A metal oxide-based interconnecting and window layer consisting of a molybdenum oxide (MoO3)/Zn-doped In2O3 (IZO) bilayer was investigated in efficient solution-processed perovskite/n-Si monolithic tandem solar cells using formamidinium cesium lead t...

  • Article
  • Open Access
5 Citations
2,447 Views
13 Pages

Synthesis, Crystal Structure and Photoluminescent Properties of Novel 9-Cyano-Pyrrolo[1,2-a][1,10]Phenanthrolines

  • Mihaela Cristea,
  • Mihai Răducă,
  • Sergiu Shova,
  • Constantin Drăghici,
  • Vlad A. Neacșu,
  • Maria Maganu,
  • Loredana Albotă (Barbu),
  • Denisa Dumitrescu and
  • Florea Dumitrascu

7 January 2024

Novel 9-cyano-pyrrolo[1,2-a][1,10]phenanthrolines 6ad were obtained by an efficient one-pot regioselective reaction between 1,10-phenanthrolinium bromides 2ad and acrylonitrile as a dipolarophile, in the presence of triethylamine and te...

  • Article
  • Open Access
2 Citations
2,536 Views
12 Pages

Monitoring of Carbonated Hydroxyapatite Growth on Modified Polycrystalline CVD-Diamond Coatings on Titanium Substrates

  • Rocco Carcione,
  • Valeria Guglielmotti,
  • Francesco Mura,
  • Silvia Orlanducci and
  • Emanuela Tamburri

6 January 2024

Production of diamond coatings on titanium substrates has demonstrated as a promising strategy for applications ranging from biosensing to hard tissue engineering. The present study focuses on monitoring the nucleation and growth of bone-like carbona...

  • Article
  • Open Access
5 Citations
2,490 Views
10 Pages

ZnO-Au Hybrid Metamaterial Thin Films with Tunable Optical Properties

  • Nirali A. Bhatt,
  • Robynne L. Paldi,
  • James P. Barnard,
  • Juanjuan Lu,
  • Zihao He,
  • Bo Yang,
  • Chao Shen,
  • Jiawei Song,
  • Raktim Sarma and
  • Haiyan Wang
  • + 1 author

6 January 2024

ZnO-Au nanocomposite thin films have been previously reported as hybrid metamaterials with unique optical properties such as plasmonic resonance properties and hyperbolic behaviors. In this study, Au composition in the ZnO-Au nanocomposites has been...

  • Article
  • Open Access
7 Citations
2,837 Views
16 Pages

Effects of Friction Stir Processing on the Microstructure and Mechanical Properties of an Ultralight Mg-Li Alloy

  • Wenjie Song,
  • Zongyu Wu,
  • Shuai He,
  • Jie Liu,
  • Guang Yang,
  • Yanhui Liu,
  • Huijin Jin,
  • Yupeng He and
  • Zhonghao Heng

4 January 2024

Magnesium–lithium alloys are arguably the lightest metal structural materials but have low strength. In order to increase strength, friction stir processing (FSP) is applied to a hot-rolled Mg-10Li-3Al-3Zn (LA103Z) sheet to study the effects on...

  • Article
  • Open Access
4 Citations
2,649 Views
11 Pages

Wulff Constructions for an Equilibrium MFI-Type Zeolite Shape Modelling under Different Conditions

  • Yanliang Zhao,
  • Wei Zhang,
  • Lei Sun,
  • Xiaoxian Li,
  • Weiqiao Deng and
  • Liang Zhang

3 January 2024

As an MFI-type zeolite, ZSM-5 zeolite has wide applications in industry, such as in the fine chemical, petrochemical, and coal chemical industries. However, shape control of ZSM-5 nanocrystals constitutes one of the major challenges of current nanote...

  • Article
  • Open Access
3 Citations
3,149 Views
14 Pages

2 January 2024

The monomeric red fluorescent protein DsRed (mDsRed) is widely used as an optical probe for multicolor applications in flow cytometry or fluorescence microscopy. Understanding the structure and dynamics of mDsRed provides fundamental information for...

  • Article
  • Open Access
7 Citations
3,590 Views
21 Pages

High-Temperature Oxidation Behavior of FeCoCrNi+(Cu/Al)-Based High-Entropy Alloys in Humid Air

  • Emma Marie Hamilton White,
  • Mary-Lee Bürckner,
  • Clara Schlereth,
  • Maciej Bik and
  • Mathias Christian Galetz

31 December 2023

Previous studies showed some transition metal high-entropy alloy (HEA) compositions can have good oxidation resistance in air up to 800 °C. Four equiatomic HEAs have been developed based on FeCoCrNi with additions of Mn, Cu, Al or Al+Cu. The oxid...

  • Review
  • Open Access
5 Citations
3,654 Views
17 Pages

Lithium Tetraborate as a Neutron Scintillation Detector: A Review

  • Elena Echeverria,
  • John McClory,
  • Lauren Samson,
  • Katherine Shene,
  • Juan A. Colón Santana,
  • Yaroslav Burak,
  • Volodymyr Adamiv,
  • Ihor Teslyuk,
  • Lu Wang and
  • Archit Dhingra
  • + 6 authors

31 December 2023

The electronic structure and translucent nature of lithium tetraborate (Li2B4O7) render it promising as a scintillator medium for neutron detection applications. The inherently large neutron capture cross-section due to 10B and 6Li isotopes and the e...

  • Article
  • Open Access
1 Citations
2,281 Views
15 Pages

The Structural Basis of DL0410, a Novel Multi-Target Candidate Drug for the Treatment of Alzheimer’s Disease

  • Ailin Liu,
  • Jun Zhao,
  • Nicholas J. Huls,
  • Matthias Zeller,
  • Lin Wang and
  • Tonglei Li

31 December 2023

Alzheimer’s disease (AD) is a complicated disease for which there are still no ideal one-target drugs, while multi-target drugs are closer to ideal drugs and will provide new solutions for the clinical treatment of AD. DL0410 is a promising mul...

  • Article
  • Open Access
4 Citations
2,077 Views
12 Pages

31 December 2023

The compounds AELi2Ge (AE = Ca, Sr and Ba) were synthesized, and their structures were determined as a part of the exploratory work in the Li-rich regions of the respective ternary systems. The three compounds are isostructural, and their crystal str...

  • Article
  • Open Access
1,716 Views
12 Pages

31 December 2023

In order to develop the building blocks for future biosensing and spintronic applications, an engraving technique using electron beam lithography is employed in order to develop nanomagnetic pre-patterned structures with logic potential. The paper de...

  • Article
  • Open Access
4 Citations
1,921 Views
12 Pages

30 December 2023

In this study, FeSi2 bulk specimens were prepared by mechanical alloying, spark plasma sintering, and subsequent annealing. The annealed FeSi2 bulk specimens consisted of the β-FeSi2 phase and exhibited high Seebeck coefficient values. The maxim...

  • Article
  • Open Access
5 Citations
2,757 Views
34 Pages

30 December 2023

A groundbreaking photocatalytic nanomaterial, Dy2NdSbO7, was fabricated smoothly using the hydrothermal synthesis technique for the first time. Apart from that, Dy2NdSbO7/Bi2WO6 heterojunction photocatalyst (DBHP) was initially fabricated using the s...

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Crystals - ISSN 2073-4352