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48 Results Found

  • Article
  • Open Access
2 Citations
1,849 Views
10 Pages

The present article introduces a strategy for controlling oxidation and reduction reactions within polymer electrolyte membrane (PEM) networks as a means of enhancing storage capacity through the complexation of dissociated lithium cations with multi...

  • Article
  • Open Access
15 Citations
3,697 Views
11 Pages

Fabrication of a Covalent Triazine Framework Functional Interlayer for High-Performance Lithium–Sulfur Batteries

  • Ben Hu,
  • Bing Ding,
  • Chong Xu,
  • Zengjie Fan,
  • Derong Luo,
  • Peng Li,
  • Hui Dou and
  • Xiaogang Zhang

14 January 2022

The shuttling effect of polysulfides is one of the major problems of lithium–sulfur (Li–S) batteries, which causes rapid capacity fading during cycling. Modification of the commercial separator with a functional interlayer is an effective...

  • Article
  • Open Access
10 Citations
4,031 Views
12 Pages

Construction of KB@ZIF-8/PP Composite Separator for Lithium–Sulfur Batteries with Enhanced Electrochemical Performance

  • Bingyi Ma,
  • Xin Zhang,
  • Xiaoqian Deng,
  • Sheng Huang,
  • Min Xiao,
  • Shuanjin Wang,
  • Dongmei Han and
  • Yuezhong Meng

1 December 2021

Lithium–sulfur batteries (LSBs) have attracted wide attention, but the shuttle effect of polysulfide hinders their further practical application. Herein, we develop a new strategy to construct a Ketjen black@zeolite imidazole framework-8/polypropylen...

  • Article
  • Open Access
3 Citations
3,747 Views
12 Pages

Fluorinated Multi-Walled Carbon Nanotubes Coated Separator Mitigates Polysulfide Shuttle in Lithium-Sulfur Batteries

  • Devashish Salpekar,
  • Changxin Dong,
  • Eliezer F. Oliveira,
  • Valery N. Khabashesku,
  • Guanhui Gao,
  • Ved Ojha,
  • Robert Vajtai,
  • Douglas S. Galvao,
  • Ganguli Babu and
  • Pulickel M. Ajayan

22 February 2023

Li-S batteries still suffer from two of the major challenges: polysulfide shuttle and low inherent conductivity of sulfur. Here, we report a facile way to develop a bifunctional separator coated with fluorinated multiwalled carbon nanotubes. Mild flu...

  • Article
  • Open Access
15 Citations
3,733 Views
11 Pages

ZnO Nanoparticles Anchored on a N-Doped Graphene-Coated Separator for High Performance Lithium/Sulfur Batteries

  • Suyu Wang,
  • Fan Gao,
  • Ruina Ma,
  • An Du,
  • Taizhe Tan,
  • Miao Du,
  • Xue Zhao,
  • Yongzhe Fan and
  • Ming Wen

25 September 2018

Fabrication of a nanocrystalline zinc oxide (ZnO)/nitrogen-doped graphene (NDG) composite using a novel and facile in situ sol-gel technique is demonstrated in this study. A two-dimensional nanostructured morphology with uniform ZnO nanoparticles (av...

  • Article
  • Open Access
1 Citations
946 Views
14 Pages

The Design of Diatomite/TiO2/MoS2/Nitrogen-Doped Carbon Nanofiber Composite Separators for Lithium–Sulfur Batteries

  • Wei Zhong,
  • Wenjie Xiao,
  • Jianfei Liu,
  • Chuxiao Yang,
  • Sainan Liu and
  • Zhenyang Cai

4 August 2025

Severe polysulfide shuttling and sluggish redox kinetics critically hinder lithium–sulfur (Li-S) battery commercialization. In this study, a multifunctional diatomite (DE)/TiO2/MoS2/N-doped carbon nanofiber (NCNF) composite separator was fabric...

  • Article
  • Open Access
1 Citations
2,387 Views
17 Pages

6 January 2023

Lithium-sulfur (Li-S) batteries are regarded as one of the promising advanced energy storage systems due to their ultrahigh capacity and energy density. However, their practical applications are still hindered by the serious shuttle effect and sluggi...

  • Article
  • Open Access
3 Citations
3,013 Views
11 Pages

A New Graphitic Nitride and Reduced Graphene Oxide-Based Sulfur Cathode for High-Capacity Lithium-Sulfur Cells

  • Artur M. Suzanowicz,
  • Youngjin Lee,
  • Hao Lin,
  • Otavio J. J. Marques,
  • Carlo U. Segre and
  • Braja K. Mandal

19 January 2022

Lithium-sulfur (Li-S) batteries can provide at least three times higher energy density than lithium-ion (Li-Ion) batteries. However, Li-S batteries suffer from a phenomenon called the polysulfide shuttle (PSS) that prevents the commercialization of t...

  • Article
  • Open Access
12 Citations
3,442 Views
12 Pages

15 March 2023

The high theoretical charge-storage capacity and energy density of lithium–sulfur batteries make them a promising next-generation energy-storage system. However, liquid polysulfides are highly soluble in the electrolytes used in lithium–s...

  • Article
  • Open Access
5 Citations
2,895 Views
9 Pages

22 July 2022

The separators with high absorbability of polysulfides are essential for improving the electrochemical performance of lithium–sulfur (Li–S) batteries. Herein, the aramid fibers coated polyethylene (AF-PE) films are designed by roller coat...

  • Article
  • Open Access
5 Citations
2,561 Views
14 Pages

Synergistic Effect of Zn–Co Bimetallic Selenide Composites for Lithium–Sulfur Battery

  • Deng Li,
  • Huinan Pan,
  • Zhonghai Lin,
  • Xiulian Qiu,
  • Xinyu Zhao,
  • Wei Yang,
  • Wenzhi Zheng and
  • Fengming Ren

Compared with monometallic selenides, heterogeneous bimetallic selenides have rich phase boundaries and superior electrical conductivity. ZnSe/CoSe2 composites were prepared by introducing Zn metal and using ZIF-8/67 as the precursor through the syne...

  • Article
  • Open Access
8 Citations
2,865 Views
11 Pages

Polyglutamic Acid Binder for High-Performance Lithium–Sulfur Batteries

  • Zhiyuan Pang,
  • Hongzhou Zhang,
  • Yue Ma,
  • Dawei Song,
  • Xixi Shi,
  • Lianqi Zhang and
  • Yong Zhou

29 September 2022

Binders play a very important part in electrodes, as they closely bind active materials, conductive agents, and current collectors together. The application of binders is critical to the electrochemical performance of Li-S batteries. Herein, a series...

  • Article
  • Open Access
5 Citations
2,012 Views
12 Pages

27 January 2024

Lithium–sulfur batteries offer the potential for significantly higher energy density and cost-effectiveness. However, their progress has been hindered by challenges such as the “shuttle effect” caused by lithium polysulfides and the...

  • Article
  • Open Access
999 Views
14 Pages

Dual-Strategy Design Based on Polymer–Matrix Composite Cathode and Coated Separator for High-Performance Lithium–Iron Disulfide Batteries

  • Fan Zhang,
  • Qiang Lu,
  • Jiachen Li,
  • Qiongyue Zhang,
  • Haotian Yu,
  • Yahao Wang,
  • Jinrui Li,
  • Haodong Ren,
  • Huirong Liang and
  • Fei Shen
  • + 1 author

29 August 2025

Lithium–iron disulfide (Li-FeS2) batteries are plagued by the polysulfide shuttle effect and cathode structural degradation, which significantly hinder their practical application. This study proposes a dual-strategy design that combines a poly...

  • Article
  • Open Access
6 Citations
2,234 Views
14 Pages

Facile Synthesizing Yolk-Shelled Fe3O4@Carbon Nanocavities with Balanced Physiochemical Synergism as Efficient Hosts for High-Performance Lithium–Sulfur Batteries

  • Lai Chen,
  • Chenying Zhao,
  • Yun Lu,
  • Lingyi Wan,
  • Kang Yan,
  • Youxiang Bai,
  • Zhiyu Liu,
  • Xulai Yang,
  • Yuefeng Su and
  • Feng Wu

The severe “shuttle effect” of dissolved polysulfide intermediates and the poor electronic conductivity of sulfur cathodes cause capacity decay of lithium–sulfur batteries and impede their commercialization. Herein, we synthesized a...

  • Article
  • Open Access
14 Citations
6,608 Views
11 Pages

MnO2-Coated Dual Core–Shell Spindle-Like Nanorods for Improved Capacity Retention of Lithium–Sulfur Batteries

  • Hamza Dunya,
  • Maziar Ashuri,
  • Dana Alramahi,
  • Zheng Yue,
  • Kamil Kucuk,
  • Carlo U. Segre and
  • Braja K. Mandal

The emerging need for high-performance lithium–sulfur batteries has motivated many researchers to investigate different designs. However, the polysulfide shuttle effect, which is the result of dissolution of many intermediate polysulfides in el...

  • Article
  • Open Access
25 Citations
4,687 Views
16 Pages

Microporous Carbon Nanoparticles for Lithium–Sulfur Batteries

  • Hui-Ju Kang,
  • Gazi A. K. M. Rafiqul Bari,
  • Tae-Gyu Lee,
  • Tamal Tahsin Khan,
  • Jae-Woo Park,
  • Hyun Jin Hwang,
  • Sung Yong Cho and
  • Young-Si Jun

12 October 2020

Rechargeable lithium–sulfur batteries (LSBs) are emerging as some of the most promising next-generation battery alternatives to state-of-the-art lithium-ion batteries (LIBs) due to their high gravimetric energy density, being inexpensive, and h...

  • Article
  • Open Access
1 Citations
1,796 Views
10 Pages

1 May 2024

Lithium–sulfur batteries suffer from a reduced cycle life and diminished coulombic efficiency, which is attributed to the polysulfide shuttle effect. We herein present a process for the fabrication of lithium–sulfur battery cathode materi...

  • Article
  • Open Access
3 Citations
3,483 Views
14 Pages

12 October 2021

One of the critical issues hindering the commercialization of lithium–sulfur (Li–S) batteries is the dissolution and migration of soluble polysulfides in electrolyte, which is called the ‘shuttle effect’. To address this issue, previous studies have...

  • Feature Paper
  • Article
  • Open Access
9 Citations
2,712 Views
13 Pages

Tubular C3N4 Nanotubes as Metal-Free Sulfur Hosts toward Stable Lithium–Sulfur Batteries

  • Chaoqi Zhang,
  • Ruifeng Du,
  • Sara Martí-Sánchez,
  • Ke Xiao,
  • Dawei Yang,
  • Chaoyue Zhang,
  • Canhuang Li,
  • Guifang Zeng,
  • Xingqi Chang and
  • Ren He
  • + 4 authors

6 June 2023

Lithium–sulfur batteries (LSBs) with high energy density have the potential to replace current commercial lithium-ion batteries. However, the shuttle effect and the low conversion kinetics of lithium polysulfide (LiPS) remain the main challenge...

  • Review
  • Open Access
4 Citations
3,079 Views
37 Pages

A Review of the Application of Metal-Based Heterostructures in Lithium–Sulfur Batteries

  • Yichao Luo,
  • Zhen Zhang,
  • Yaru Wang,
  • Yalong Zheng,
  • Xinyu Jiang,
  • Yan Zhao,
  • Yi Zhang,
  • Xiang Liu,
  • Zhoulu Wang and
  • Baizeng Fang

22 January 2025

Lithium–sulfur (Li-S) batteries are recognized as a promising alternative in the energy storage domain due to their high theoretical energy density, environmental friendliness, and cost-effectiveness. However, challenges such as polysulfide dis...

  • Review
  • Open Access
5 Citations
3,816 Views
26 Pages

Cellulose-Based Materials and Their Application in Lithium–Sulfur Batteries

  • Muriel Zampieri,
  • Guillermina Tommasone,
  • Luciana Morel and
  • Guillermina Leticia Luque

10 January 2025

Lithium–sulfur (Li-S) batteries are promising candidates for next-generation energy storage due to their high energy density, cost-effectiveness, and environmental friendliness. However, their commercialization is hindered by challenges, such a...

  • Article
  • Open Access
3 Citations
3,526 Views
13 Pages

1 October 2024

Lithium-sulfur (Li-S) batteries are a promising option for energy storage due to their theoretical high energy density and the use of abundant, low-cost sulfur cathodes. Nevertheless, several obstacles remain, including the dissolution of lithium pol...

  • Article
  • Open Access
16 Citations
2,588 Views
10 Pages

25 August 2023

Nanocomposites that combine porous materials and a continuous conductive skeleton as a sulfur host can improve the performance of lithium–sulfur (Li-S) batteries. Herein, carbon nanotubes (CNTs) anchoring small-size (~40 nm) N-doped porous carb...

  • Article
  • Open Access
1,954 Views
9 Pages

Scalable Ni12P5-Coated Carbon Cloth Cathode for Lithium–Sulfur Batteries

  • Artur M. Suzanowicz,
  • Thulitha M. Abeywickrama,
  • Hao Lin,
  • Dana Alramahi,
  • Carlo U. Segre and
  • Braja K. Mandal

31 August 2024

As a better alternative to lithium-ion batteries (LIBs), lithium–sulfur batteries (LSBs) stand out because of their multi-electron redox reactions and high theoretical specific capacity (1675 mA h g−1). However, the long-term stability of...

  • Article
  • Open Access
9 Citations
3,273 Views
15 Pages

15 April 2021

With a higher theoretical specific capacity (1675 mAh g−1) and energy density (2600 Wh kg−1), the lithium-sulfur (Li-S) battery is considered as a promising candidate for a next-generation energy storage device. However, the shuttle effect of polysul...

  • Article
  • Open Access
6 Citations
2,571 Views
10 Pages

Synergistic Adsorption-Catalytic Sites TiN/Ta2O5 with Multidimensional Carbon Structure to Enable High-Performance Li-S Batteries

  • Chong Wang,
  • Jian-Hao Lu,
  • Zi-Long Wang,
  • An-Bang Wang,
  • Hao Zhang,
  • Wei-Kun Wang,
  • Zhao-Qing Jin and
  • Li-Zhen Fan

28 October 2021

Lithium-sulfur (Li-S) batteries are deemed to be one of the most optimal solutions for the next generation of high-energy-density and low-cost energy storage systems. However, the low volumetric energy density and short cycle life are a bottleneck fo...

  • Article
  • Open Access
2 Citations
1,994 Views
17 Pages

Li–S batteries are positioned as a strong alternative for efficient energy storage due to their high theoretical energy density and their theoretical specific capacity (1675 mA h g−1) compared to current Li-ion batteries; however, their c...

  • Article
  • Open Access
15 Citations
2,801 Views
12 Pages

11 November 2022

The shuttle effect is understood to be the most significant issue that needs to be solved to improve the performance of lithium–sulfur batteries. In this study, ultrathin two-dimensional Fe–Co bimetallic oxide nanosheets were prepared usi...

  • Article
  • Open Access
5 Citations
3,834 Views
14 Pages

Tailoring Mesopores and Nitrogen Groups of Carbon Nanofibers for Polysulfide Entrapment in Lithium–Sulfur Batteries

  • Snatika Sarkar,
  • Jong Sung Won,
  • Meichun An,
  • Rui Zhang,
  • Jin Hong Lee,
  • Seung Goo Lee and
  • Yong Lak Joo

25 March 2022

In the current work, we combined different physical and chemical modifications of carbon nanofibers through the creation of micro-, meso-, and macro-pores as well as the incorporation of nitrogen groups in cyclic polyacrylonitrile (CPAN) using gas-as...

  • Article
  • Open Access
1,749 Views
12 Pages

An Integrated Na2S−Electrocatalyst Nanostructured Cathode for Sodium–Sulfur Batteries at Room Temperature

  • Sichang Ma,
  • Yueming Zhu,
  • Yadong Yang,
  • Dongyang Li,
  • Wendong Tan,
  • Ling Gao,
  • Wanwei Zhao,
  • Wenbo Liu,
  • Wenyu Liang and
  • Rui Xu

27 December 2024

Room-temperature sodium–sulfur (RT Na–S) batteries offer a superior, high-energy-density solution for rechargeable batteries using earth-abundant materials. However, conventional RT Na–S batteries typically use sulfur as the cathode...

  • Article
  • Open Access
3 Citations
3,018 Views
14 Pages

Cement/Sulfur for Lithium–Sulfur Cells

  • Tzu-Ming Hung,
  • Cheng-Che Wu,
  • Chung-Chan Hung and
  • Sheng-Heng Chung

19 February 2024

Lithium–sulfur batteries represent a promising class of next-generation rechargeable energy storage technologies, primarily because of their high-capacity sulfur cathode, reversible battery chemistry, low toxicity, and cost-effectiveness. Howev...

  • Article
  • Open Access
20 Citations
10,049 Views
12 Pages

1 September 2015

Here, we report a two-step synthesis of graphene/sulfur/carbon ternary composite with a multilayer structure. In this composite, ultrathin S layers are uniformly deposited on graphene nanosheets and covered by a thin layer of amorphous carbon derived...

  • Article
  • Open Access
29 Citations
6,404 Views
9 Pages

Biomass Waste Inspired Highly Porous Carbon for High Performance Lithium/Sulfur Batteries

  • Yan Zhao,
  • Jun Ren,
  • Taizhe Tan,
  • Moulay-Rachid Babaa,
  • Zhumabay Bakenov,
  • Ning Liu and
  • Yongguang Zhang

6 September 2017

The synthesis of highly porous carbon (HPC) materials from poplar catkin by KOH chemical activation and hydrothermal carbonization as a conductive additive to a lithium-sulfur cathode is reported. Elemental sulfur was composited with as-prepared HPC...

  • Article
  • Open Access
15 Citations
3,346 Views
12 Pages

17 August 2021

An inexpensive sulfur cathode with the highest possible charge storage capacity is attractive for the design of lithium-ion batteries with a high energy density and low cost. To promote existing lithium–sulfur battery technologies in the current ener...

  • Article
  • Open Access
2 Citations
2,600 Views
13 Pages

Simultaneous Removal of Nitrate and Phosphate in a Pyrrhotite and Sulfur-Circulating Packed Bed Reactor

  • Meiling Yu,
  • Yongyou Hu,
  • Donghui Liang,
  • Guobin Wang,
  • Xiaoqiang Zhu and
  • Jieyun Xie

7 June 2023

A pyrrhotite and sulfur-circulating packed bed reactor (PS-CPBR) was constructed to study the removal process and mechanism of NO3−-N and PO43−-P with different electron donors. The results showed that the NO3−-N and PO43−-P removal performance of mi...

  • Article
  • Open Access
2 Citations
4,102 Views
15 Pages

Synthesis and Electrochemical Properties of Lignin-Derived High Surface Area Carbons

  • Artur M. Suzanowicz,
  • Youngjin Lee,
  • Abigail Schultz,
  • Otavio J. J. Marques,
  • Hao Lin,
  • Carlo U. Segre and
  • Braja K. Mandal

6 April 2022

Activated carbons play an essential role in developing new electrodes for renewable energy devices due to their electrochemical and physical properties. They have been the subject of much research due to their prominent surface areas, porosity, light...

  • Article
  • Open Access
6 Citations
3,048 Views
12 Pages

A Multifunctional Coating on Sulfur-Containing Carbon-Based Anode for High-Performance Sodium-Ion Batteries

  • Lin Zhu,
  • Bo Yin,
  • Yuting Zhang,
  • Qian Wu,
  • Hongqiang Xu,
  • Haojie Duan,
  • Meiqin Shi and
  • Haiyong He

10 April 2023

A sulfur doping strategy has been frequently used to improve the sodium storage specific capacity and rate capacity of hard carbon. However, some hard carbon materials have difficulty in preventing the shuttling effect of electrochemical products of...

  • Article
  • Open Access
6 Citations
3,375 Views
12 Pages

Carbon Nanotube-Modified Nickel Hydroxide as Cathode Materials for High-Performance Li-S Batteries

  • Qianwen Jin,
  • Yajing Yan,
  • Chenchen Hu,
  • Yongguang Zhang,
  • Xi Wang and
  • Chunyong Liang

The advantages of high energy density and low cost make lithium–sulfur batteries one of the most promising candidates for next-generation energy storage systems. However, the electrical insulativity of sulfur and the serious shuttle effect of l...

  • Article
  • Open Access
41 Citations
8,378 Views
11 Pages

Macroporous Activated Carbon Derived from Rapeseed Shell for Lithium–Sulfur Batteries

  • Mingbo Zheng,
  • Qin Hu,
  • Songtao Zhang,
  • Hao Tang,
  • Lulu Li and
  • Huan Pang

10 October 2017

Lithium–sulfur batteries have drawn considerable attention because of their extremely high energy density. Activated carbon (AC) is an ideal matrix for sulfur because of its high specific surface area, large pore volume, small-size nanopores, and sim...

  • Article
  • Open Access
27 Citations
6,156 Views
15 Pages

Dehydrofluorination Process of Poly(vinylidene difluoride) PVdF-Based Gel Polymer Electrolytes and Its Effect on Lithium-Sulfur Batteries

  • Julen Castillo,
  • Adrián Robles-Fernandez,
  • Rosalía Cid,
  • José Antonio González-Marcos,
  • Michel Armand,
  • Daniel Carriazo,
  • Heng Zhang and
  • Alexander Santiago

14 April 2023

Gel polymer electrolytes (GPEs) are emerging as suitable candidates for high-performing lithium-sulfur batteries (LSBs) due to their excellent performance and improved safety. Within them, poly(vinylidene difluoride) (PVdF) and its derivatives have b...

  • Article
  • Open Access
7 Citations
2,252 Views
11 Pages

22 October 2022

All solid-state room-temperature lithium-sulfur (Li-S) batteries have gained increasing attention due to their ability to eliminate the polysulfides shuttle effects and the safety dangers associated with the liquid electrolytes. Herein, a novel compo...

  • Communication
  • Open Access
18 Citations
4,200 Views
10 Pages

23 January 2022

Separators, as indispensable parts of LSBs (lithium–sulfur batteries), play a cucial role in inhibiting dendrite growth and suppressing the shuttle of lithium polysulfide (LiPSs). Herein, we prepared a functional carbon nanotube (CNT) and Fe-ba...

  • Article
  • Open Access
20 Citations
4,476 Views
19 Pages

Reduced Graphene Oxide Embedded with ZnS Nanoparticles as Catalytic Cathodic Material for Li-S Batteries

  • Roberto Colombo,
  • Daniele Versaci,
  • Julia Amici,
  • Federico Bella,
  • Maria Laura Para,
  • Nadia Garino,
  • Marco Laurenti,
  • Silvia Bodoardo and
  • Carlotta Francia

24 July 2023

Lithium-sulfur technology is a strong candidate for the future generation of batteries due to its high specific capacity (1675 mAh g−1), low cost, and environmental impact. In this work, we propose a facile and solvent-free microwave synthesis...

  • Article
  • Open Access
1,948 Views
13 Pages

Enhancing Li-S Battery Performance with Porous Carbon from Hanji

  • Yunju Choi,
  • Jaeyeong Lee,
  • Jong-Pil Kim,
  • Sei-Jin Lee,
  • Euh Duck Jeong,
  • Jong-Seong Bae and
  • Heon-Cheol Shin

25 December 2024

Hanji-derived porous carbon has been developed and utilized as a cathode material for Li-S batteries, demonstrating exceptional electrochemical performance and stability. The unique porous structure and high surface area of Hanji-based carbon enhance...

  • Feature Paper
  • Article
  • Open Access
4 Citations
3,857 Views
14 Pages

Mitigating Polysulfide Shuttles with Upcycled Alkali Metal Terephthalate Decorated Separators

  • Daniel A. Gribble,
  • Zih-Yu Lin,
  • Sourav Ghosh,
  • Brett M. Savoie and
  • Vilas G. Pol

23 November 2022

High energy density lithium–sulfur batteries (LSBs) are a potential replacement for lithium-ion batteries (LIBs). However, practical lifetimes are inhibited by lithium polysulfide (LiPS) shuttling. Concurrently, plastic waste accumulation world...

  • Article
  • Open Access
24 Citations
5,636 Views
10 Pages

Synthesis of a Flexible Freestanding Sulfur/Polyacrylonitrile/Graphene Oxide as the Cathode for Lithium/Sulfur Batteries

  • Huifen Peng,
  • Xiaoran Wang,
  • Yan Zhao,
  • Taizhe Tan,
  • Zhumabay Bakenov and
  • Yongguang Zhang

3 April 2018

Rechargeable lithium/sulfur (Li/S) batteries have received quite significant attention over the years because of their high theoretical specific capacity (1672 mAh·g−1) and energy density (2600 mAh·g−1) which has led to more...

  • Article
  • Open Access
5 Citations
3,301 Views
12 Pages

19 December 2022

Lithium-sulfur batteries (LSBs) have attracted extensive attention due to their high energy density and low cost. The separator is a key component of LSBs. An excellent LSBs separator requires not only good electrolyte wettability, but also high ther...