Biogas is a crucial renewable energy source for green hydrogen (H
2) production, reducing greenhouse gas emissions and serving as a carbon-free energy carrier with higher specific energy than traditional fuels. Currently, methane reforming dominates H
2 production to meet growing global
[...] Read more.
Biogas is a crucial renewable energy source for green hydrogen (H
2) production, reducing greenhouse gas emissions and serving as a carbon-free energy carrier with higher specific energy than traditional fuels. Currently, methane reforming dominates H
2 production to meet growing global demand, with biogas/landfill gas (LFG) reform offering a promising alternative. This study provides a comprehensive simulation-based evaluation of Steam Methane Reforming (SMR) and Dry Methane Reforming (DMR) of biogas/LFG, using Aspen Plus. Simulations were conducted under varying operating conditions, including steam-to-carbon (S/C) for SMR and steam-to-carbon monoxide (S/CO) ratios for DMR, reforming temperatures, pressures, and LFG compositions, to optimize H
2 yield and process efficiency. The comparative study showed that SMR attains higher specific H
2 yields (0.14–0.19 kgH
2/Nm
3), with specific energy consumption between 0.048 and 0.075 MWh/kg of H
2, especially at increased S/C ratios. DMR produces less H
2 than SMR (0.104–0.136 kg H
2/Nm
3) and requires higher energy inputs (0.072–0.079 MWh/kg H
2), making it less efficient. Both processes require an additional 1.4–2.1 Nm
3 of biogas/LFG per Nm
3 of feed for energy. These findings provide key insights for improving biogas-based H
2 production for sustainable energy, with future work focusing on techno–economic and environmental assessments to evaluate its feasibility, scalability, and industrial application.
Full article