N
2O emissions exacerbate the greenhouse effect, urgently demanding advances in abatement technologies. Catalytic decomposition of N
2O over cobalt-based oxides with alkali metal promoters remains challenging because these catalysts are used in pelletized form, limiting their activity to a narrow outer-shell region due to internal diffusion limitations. However, research efforts continue to focus on enhancing Co–alkali metal contact on unsupported powder samples under inert conditions, even though, under industrial conditions, catalysts are exposed to inhibitory components of waste gases and N
2O, and the powder form is unsuitable for practical application. This study aims at testing N
2O decomposition over catalysts with a Co
3O
4-Cs active phase supported on a ceramic foam. For this purpose, we characterized these catalysts by H
2 temperature-programmed reduction, H
2O and NO temperature-programmed desorption, atomic absorption spectroscopy, and X-ray diffraction and assessed their catalytic performance under an inert-gas atmosphere and with O
2, water vapor, and NO to simulate industrial conditions. Using a pseudo-homogeneous, one-dimensional model of an ideal plug flow reactor in an isothermal regime, the simulation calculations for a full-scale catalytic reactor for N
2O abatement in waste gas from HNO
3 production were performed. The Cs
2CO
3 precursor significantly enhanced catalyst reducibility and electron transferability, increasing N
2O decomposition efficiency in inert gas, but its high hygroscopicity decreased resistance to water vapor and NO, overriding its advantages under industrial conditions. Conversely, glycerol-assisted impregnation enhanced catalyst performance regardless of Cs precursor. These foam-supported catalysts offered several other advantages, including lower pressure drop and lower active phase loading with matching catalytic activity. Based on our findings, depositing Cs
2CO
3 on ceramic foam through glycerol-assisted impregnation may facilitate catalytic N
2O decomposition at the industrial level and, therefore, promote environmental sustainability by reducing N
2O emissions.
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