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Polymers, Volume 12, Issue 3

2020 March - 229 articles

Cover Story: The efficient regeneration of a fully functional tissue assisted by the presence of a polymeric scaffold depends on its design and the manufacturing method used. The incorporation of bioactive compounds during scaffold processing is of particular interest to improve environment–scaffold interactions. Namely, solvent-free manufacturing techniques offer remarkable advantages in terms of incorporation yield and retained activity of the loaded bioactive agents. In this work, solvent-free technologies for the processing of scaffolds are discussed, highlighting meaningful cases reported in the regenerative medicine field. View this paper.
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Articles (229)

  • Article
  • Open Access
46 Citations
5,394 Views
18 Pages

24 March 2020

Over the last decades, natural fiber-reinforced polymer composites (NFRPs) gained great attention in several engineering fields thanks to the reduction of the environmental impact and the end-of-life cost disposal. Unfortunately, the use of NFRPs is...

  • Article
  • Open Access
46 Citations
8,590 Views
20 Pages

Long-Term Evaluation of Dip-Coated PCL-Blend-PEG Coatings in Simulated Conditions

  • Anita Ioana Visan,
  • Gianina Popescu-Pelin,
  • Oana Gherasim,
  • Andreea Mihailescu,
  • Marcela Socol,
  • Irina Zgura,
  • Mari Chiritoiu,
  • Livia Elena Sima,
  • Felicia Antohe and
  • Gabriel Socol
  • + 4 authors

24 March 2020

Our study focused on the long-term degradation under simulated conditions of coatings based on different compositions of polycaprolactone-polyethylene glycol blends (PCL-blend-PEG), fabricated for titanium implants by a dip-coating technique. The deg...

  • Article
  • Open Access
3 Citations
3,519 Views
15 Pages

24 March 2020

Two novel polyimines were synthesized from a benzodifuran based diamino monomer and two dialdehydes bearing bulky groups and a flexible spacer. The polymers display tuned luminescence performance according to the presence of half-salen groups. The ef...

  • Article
  • Open Access
45 Citations
6,419 Views
11 Pages

Ferrocene-Based Conjugated Microporous Polymers Derived from Yamamoto Coupling for Gas Storage and Dye Removal

  • Zhiqiang Tan,
  • Huimin Su,
  • Yiwen Guo,
  • Huan Liu,
  • Bo Liao,
  • Abid Muhammad Amin and
  • Qingquan Liu

24 March 2020

Conjugated microporous polymers (CMPs) have conjugated skeleton and permanent porosity, and exhibit huge potential in developing novel functional materials for resolving the challenging energy and environment issues. Metal-containing CMPs often exhib...

  • Article
  • Open Access
16 Citations
5,658 Views
11 Pages

Synthesis and Evaluation of Scalable D-A-D π-Extended Oligomers as p-Type Organic Materials for Bulk-Heterojunction Solar Cells

  • Peshawa Osw,
  • Andrea Nitti,
  • Media N. Abdullah,
  • Samuel I. Etkind,
  • Jeremiah Mwaura,
  • Alessandro Galbiati and
  • Dario Pasini

24 March 2020

The synthesis and characterization of four novel donor-acceptor-donor π-extended oligomers, incorporating naphtha(1–b)thiophene-4-carboxylate or benzo(b)thieno(3,2-g) benzothiophene-4-carboxylate 2-octyldodecyl esters as end-capping moieties...

  • Article
  • Open Access
90 Citations
12,300 Views
14 Pages

24 March 2020

Electret filters as opposed to mechanical filters display the enhanced ability to capture airborne particles with the electrostatic attraction. However, the environmental aging during shelf-life or use may cancel its benefit by dissipating the charge...

  • Article
  • Open Access
7 Citations
4,248 Views
13 Pages

24 March 2020

Room-temperature ionic liquids (RTILs) together with nano-porous electrodes are the most promising materials for supercapacitors and batteries. Many theoretical works have addressed the structures and performances of RTILs inside nanopores. However,...

  • Article
  • Open Access
1 Citations
3,423 Views
16 Pages

24 March 2020

The pursuit of mechanical strength in the injection molding of long-fiber-reinforced resins continues to pose major challenges, namely (1) improvement of fiber defibration and fiber distribution and (2) suppression of fiber breakage during the moldin...

  • Article
  • Open Access
16 Citations
5,940 Views
16 Pages

24 March 2020

The influence of morphology on the rheological properties of poly(ethylene oxide) (PEO) and natural rubber-graft-poly(methyl methacrylate) (NR-g-PMMA) blends in the melt was investigated. The blends were prepared at different blend compositions by a...

  • Article
  • Open Access
33 Citations
7,279 Views
21 Pages

24 March 2020

Polypropylene (PP) is an outstanding material for polymeric foams due to its favorable mechanical and chemical properties. However, its low melt strength and fast crystallization result in unfavorable foaming properties. Long-chain branching of PP is...

  • Article
  • Open Access
36 Citations
6,093 Views
17 Pages

Effect of Chitin Nanocrystals on Crystallization and Properties of Poly(lactic acid)-Based Nanocomposites

  • Shikha Singh,
  • Mitul Patel,
  • Daniel Schwendemann,
  • Marta Zaccone,
  • Shiyu Geng,
  • Maria Lluisa Maspoch and
  • Kristiina Oksman

24 March 2020

The crystalline phase of poly(lactic acid) (PLA) has crucial effects on its own properties and nanocomposites. In this study, the isothermal crystallization of PLA, triethyl citrate-plasticized PLA (PLA–TEC), and its nanocomposite with chitin n...

  • Article
  • Open Access
37 Citations
5,609 Views
15 Pages

Comparative Structure-Property Characterization of Poly(3-Hydroxybutyrate-Co-3-Hydroxyvalerate)s Films under Hydrolytic and Enzymatic Degradation: Finding a Transition Point in 3-Hydroxyvalerate Content

  • Vsevolod A. Zhuikov,
  • Yuliya V. Zhuikova,
  • Tatiana K. Makhina,
  • Vera L. Myshkina,
  • Alexey Rusakov,
  • Alexey Useinov,
  • Vera V. Voinova,
  • Garina A. Bonartseva,
  • Alexandr A. Berlin and
  • Alexey L. Iordanskii
  • + 1 author

24 March 2020

The hydrolytic and enzymatic degradation of polymer films of poly(3-hydroxybutyrate) (PHB) of different molecular mass and its copolymers with 3-hydroxyvalerate (PHBV) of different 3-hydroxyvalerate (3-HV) content and molecular mass, 3-hydroxy-4-meth...

  • Article
  • Open Access
42 Citations
5,349 Views
13 Pages

24 March 2020

To improve the interfacial adhesion and dispersion of a poplar fiber in a polylactic acid (PLA) matrix, maleic anhydride (MA) and a silane coupling agent (KH550) were used to modify the poplar fiber. The poplar fiber/PLA composites were produced with...

  • Article
  • Open Access
13 Citations
6,512 Views
20 Pages

24 March 2020

The self-emulsifying acrylate-based emulsions with solid content 45 wt.% were prepared in 3.5 h by reverse iodine transfer polymerization (RITP), and the polymer molecular weight (Mn) could be 30,000 g·mol−1. The influences of methacryli...

  • Article
  • Open Access
100 Citations
6,993 Views
18 Pages

Synthesis, Physical, Mechanical and Antibacterial Properties of Nanocomposites Based on Poly(vinyl alcohol)/Graphene Oxide–Silver Nanoparticles

  • Mónica Cobos,
  • Iker De-La-Pinta,
  • Guillermo Quindós,
  • María Jesús Fernández and
  • María Dolores Fernández

24 March 2020

The design of new materials with antimicrobial properties has emerged in response to the need for preventing and controlling the growth of pathogenic microorganisms without the use of antibiotics. In this study, partially reduced graphene oxide decor...

  • Article
  • Open Access
10 Citations
3,800 Views
12 Pages

Robust Polymer Planar Bragg Grating Sensors Embedded in Commercial-Grade Composites

  • Stefan Kefer,
  • Theresia Sauer,
  • Steffen Hessler,
  • Michael Kaloudis,
  • Bernhard Schmauss and
  • Ralf Hellmann

23 March 2020

This contribution demonstrates the functionality of polymer planar Bragg grating (PPBG) sensors integrated into commercial-grade carbon fiber reinforced polymer (CFRP) components. Multiple CFRP specimens are generated by curing a stack of pre-impregn...

  • Article
  • Open Access
70 Citations
7,642 Views
12 Pages

Multi-Material 3D Printed Shape Memory Polymer with Tunable Melting and Glass Transition Temperature Activated by Heat or Light

  • Ela Sachyani Keneth,
  • Rama Lieberman,
  • Matthew Rednor,
  • Giulia Scalet,
  • Ferdinando Auricchio and
  • Shlomo Magdassi

23 March 2020

Shape memory polymers are attractive smart materials that have many practical applications and academic interest. Three-dimensional (3D) printable shape memory polymers are of great importance for the fabrication of soft robotic devices due to their...

  • Article
  • Open Access
91 Citations
8,823 Views
14 Pages

23 March 2020

The pyrolysis of poly (ethylene terephthalate) (PET) in the presence of ZSM-5 zeolite and NiCl2 as a catalyst was studied at different temperatures under N2 atmosphere. Quantitative 13C nuclear magnetic resonance (NMR) and Fourier transform infrared...

  • Article
  • Open Access
11 Citations
4,879 Views
13 Pages

Crystal Structure and Mechanical Properties of Uniaxially Stretched PA612/SiO2 Films

  • Yichao Wu,
  • Anmin Huang,
  • Shuhong Fan,
  • Yuejun Liu and
  • Xiaochao Liu

23 March 2020

Stretching has a significant effect on the microstructure and ultimate performance of semi-crystalline polymers. To investigate the effect of stretching on structure and mechanical properties of uniaxial stretched PA612/SiO2, PA612 and PA612/SiO2 fil...

  • Article
  • Open Access
19 Citations
3,747 Views
18 Pages

Reliability Analysis of FRP-Confined Concrete at Ultimate using Conjugate Search Direction Method

  • Behrooz Keshtegar,
  • Aliakbar Gholampour,
  • Togay Ozbakkaloglu,
  • Shun-Peng Zhu and
  • Nguyen-Thoi Trung

23 March 2020

In this paper compressive strength and ultimate strain results in the current database of fiber-reinforced polymer (FRP)-confined concrete are used to determine the reliability of their design space. The Lognormal, Normal, Frechet, Gumbel, and Weibul...

  • Review
  • Open Access
59 Citations
13,066 Views
23 Pages

23 March 2020

Since the discovery of conductive polyacetylene, conductive electroactive polymers are at the focal point of technology generation and biocommunication materials. The reasons why this research never stops growing, are twofold: first, the demands from...

  • Article
  • Open Access
30 Citations
4,579 Views
11 Pages

The Piezoresistive Highly Elastic Sensor Based on Carbon Nanotubes for the Detection of Breath

  • Romana Daňová,
  • Robert Olejnik,
  • Petr Slobodian and
  • Jiri Matyas

23 March 2020

Wearable electronic sensor was prepared on a light and flexible substrate. The breathing sensor has a broad assumption and great potential for portable devices in wearable technology. In the present work, the application of a flexible thermoplastic p...

  • Article
  • Open Access
22 Citations
4,661 Views
24 Pages

23 March 2020

The near infrared (NIR) laser drilling of a carbon fiber reinforced polymer (CFRP) composite in the continuous wave (CW) mode and the ms pulse mode was investigated by an experiment and a numerical simulation. The relationships between the laser pene...

  • Communication
  • Open Access
19 Citations
4,673 Views
7 Pages

23 March 2020

A novel and effective strategy was first proposed for the codeposition of a mussel-inspired nanohybrid coating with excellent wettability onto the surface of carbon fibers (CFs) by simultaneous polymerization of bioinspired dopamine (DA) and hydrolys...

  • Article
  • Open Access
16 Citations
4,228 Views
14 Pages

Macroscopic Poly Schiff Base-Coated Bacteria Cellulose with High Adsorption Performance

  • Lili Ren,
  • Zhihui Yang,
  • Lei Huang,
  • Yingjie He,
  • Haiying Wang and
  • Liyuan Zhang

23 March 2020

Here, a nanofiber-exfoliated bacteria cellulose aerogel with improved water affinity and high mass transfer was synthesized. Consequently, poly Schiff base can be uniformly coated within the body of bacteria cellulose aerogel without the traditional...

  • Article
  • Open Access
88 Citations
6,487 Views
13 Pages

23 March 2020

In this work, a novel low molecular weight zwitterionic copolymer for improving wellbore stability, which is expected to be an alternative to the current shale inhibitors, was obtained by copolymerization of tris hydroxyethyl allyl ammonium bromide (...

  • Article
  • Open Access
52 Citations
7,335 Views
16 Pages

Bio-Nanocomposite Hydrogel Based on Zinc Alginate/Graphene Oxide: Morphology, Structural Conformation, Thermal Behavior/Degradation, and Dielectric Properties

  • Roser Sabater i Serra,
  • José Molina-Mateo,
  • Constantino Torregrosa-Cabanilles,
  • Andreu Andrio-Balado,
  • José María Meseguer Dueñas and
  • Ángel Serrano-Aroca

22 March 2020

Bio-nanocomposite hydrogels based on sodium alginate (SA) as polymer matrix and graphene oxide (GO) nanosheets with zinc as crosslinking agent were synthesized with the aim of incorporating the intrinsic properties of their constituents (bioactivity...

  • Article
  • Open Access
20 Citations
4,333 Views
16 Pages

22 March 2020

By using different conductivity of polyaniline as filler, a kind of poly(ionic liquid)/polyaniline composite particles was synthesized to investigate the influence of dielectric polarization rate difference between filler and matrix on the electrorhe...

  • Article
  • Open Access
4 Citations
3,975 Views
13 Pages

Biodegradation Pattern of Glycopolymer Based on D-Mannose Oligomer and Hydroxypropyl Acrylate

  • Ana-Maria Pană,
  • Valentin Ordodi,
  • Gerlinde Rusu,
  • Vasile Gherman,
  • Geza Bandur,
  • Lucian-Mircea Rusnac and
  • Gabriela-Alina Dumitrel

22 March 2020

Glycopolymers are polymers with sugar moieties which display biodegradable and/or biocompatible character. They have emerged as an environmentally-friendly solution to classical synthetic polymers and have attracted significant research interest in t...

  • Article
  • Open Access
34 Citations
4,219 Views
12 Pages

The Influence of Processing and Particle Size on Binderless Particleboards Made from Arundo donax L. Rhizome

  • Manuel Ferrandez-Villena,
  • Clara Eugenia Ferrandez-Garcia,
  • Teresa Garcia-Ortuño,
  • Antonio Ferrandez-Garcia and
  • Maria Teresa Ferrandez-Garcia

21 March 2020

The giant reed (Arundo donax L.) is considered one of the world’s 100 worst invasive species. The main method by which this species propagates is by growth of scattered fragments of rhizome, spreading without control with very strong, deep root...

  • Article
  • Open Access
24 Citations
3,518 Views
13 Pages

Dielectric Relaxation in the Hybrid Epoxy/MWCNT/MnFe2O4 Composites

  • Darya Meisak,
  • Jan Macutkevic,
  • Artyom Plyushch,
  • Polina Kuzhir,
  • Algirdas Selskis and
  • Juras Banys

21 March 2020

The electrical properties of epoxy/MWCNT (multi-walled carbon nanotubes)/MnFe2O4 hybrid composites loaded with MWCNTs (below, 0.09 vol.%, and above, 0.58 vol.%, percolation threshold) and varying concentrations of MnFe2O4 up to 10 vol.% were studied...

  • Article
  • Open Access
9 Citations
4,182 Views
13 Pages

Synthesis and Investigation of Thermo-Induced Gelation of Partially Cross-Linked Poly-2-isopropyl-2-oxazoline in Aqueous Media

  • Alina Amirova,
  • Serafim Rodchenko,
  • Mikhail Kurlykin,
  • Andrey Tenkovtsev,
  • Illia Krasnou,
  • Andres Krumme and
  • Alexander Filippov

21 March 2020

Water-soluble, partially cross-linked poly-2-isopropyl-2-oxazoline combining the properties of chemical and physical gels was synthesized by a two-step procedure. Thermally induced sol-gel transition in its aqueous solution was studied by rheology, l...

  • Article
  • Open Access
83 Citations
7,866 Views
14 Pages

21 March 2020

Recently, natural sun blockers have been drawing considerable attention because synthetic UV filters could have adverse effects not only on humans but also on the environment. Even though lignin, the second most abundant renewable resource on earth,...

  • Article
  • Open Access
47 Citations
5,953 Views
11 Pages

Material Characterization of PCL:PLLA Electrospun Fibers Following Six Months Degradation In Vitro

  • Alyah H. Shamsah,
  • Sarah H. Cartmell,
  • Stephen M. Richardson and
  • Lucy A. Bosworth

21 March 2020

The annulus fibrosus—one of the two tissues comprising the intervertebral disc—is susceptible to injury and disease, leading to chronic pain and rupture. A synthetic, biodegradable material could provide a suitable scaffold that alleviate...

  • Article
  • Open Access
6 Citations
4,865 Views
19 Pages

21 March 2020

Gypsum molds have been developed as an alternative for the Rapid tooling (RT) method used in injection molding. However, the poor capability of the heat delivery forces the gypsum mold to operate under a high-risk condition, and distortion of the mol...

  • Review
  • Open Access
59 Citations
9,338 Views
29 Pages

20 March 2020

The high speed of contaminants growth needs the burgeoning of new analytical techniques to keep up with the continuous demand for monitoring and legislation on food safety and environmental pollution control. Metal-organic frameworks (MOFs) are a kin...

  • Article
  • Open Access
14 Citations
3,221 Views
13 Pages

Characterization and Preparation of Furanic-Glyoxal Foams

  • Xuedong Xi,
  • Antonio Pizzi,
  • Hong Lei,
  • Guanben Du,
  • Xiaojian Zhou and
  • Yuying Lin

20 March 2020

Synthetic foams have become an essential industrial product for a great variety of applications. Furfuryl alcohol, as a biomass chemical, was reacted with glyoxal at room temperature to prepare furanic-glyoxal rigid foams, and p-toluenesulfonic acid...

  • Article
  • Open Access
26 Citations
3,683 Views
12 Pages

20 March 2020

Two-component fibrous materials based on poly(3-hydroxybutyrate) (PHB, Tm = 160 °C) and poly(ε-caprolactone) (PCL, Tm = 60 °C) were successfully fabricated by dual-jet electrospinning of their separate spinning solutions. The desired...

  • Article
  • Open Access
13 Citations
5,012 Views
13 Pages

Developing Further Versatility in Benzoxazine Synthesis via Hydrolytic Ring-Opening

  • Shaoying Cui,
  • Carlos R. Arza,
  • Pablo Froimowicz and
  • Hatsuo Ishida

20 March 2020

In this study, 2-(aminomethyl)phenol and its derivatives, the reactants for 2-substituted 1,3-benzoxazines, are synthesized by HCl hydrolysis from the typical benzoxazines. The phenol/aniline-based mono-oxazine benzoxazine, PH-a, and the bisphenol A/...

  • Article
  • Open Access
22 Citations
4,621 Views
13 Pages

Magnetic-Electrospinning Synthesis of γ-Fe2O3 Nanoparticle–Embedded Flexible Nanofibrous Films for Electromagnetic Shielding

  • Jie Zheng,
  • Bin Sun,
  • Xiao-Xiong Wang,
  • Ze-Xing Cai,
  • Xin Ning,
  • Saad M. Alshehri,
  • Tansir Ahamad,
  • Xing-Tao Xu,
  • Yusuke Yamauchi and
  • Yun-Ze Long

20 March 2020

The exploration of a new family of flexible and high-performance electromagnetic shielding materials is of great significance to the next generation of intelligent electronic products. In this paper, we report a simple magnetic-electrospinning (MES)...

  • Article
  • Open Access
10 Citations
4,701 Views
16 Pages

19 March 2020

The Fused-Deposition Modelling (FDM) technique has transformed the manufacturing discipline by simplifying operational processes and costs associated with conventional technologies, with polymeric materials being indispensable for the development of...

  • Article
  • Open Access
48 Citations
4,826 Views
17 Pages

Influence of Magnetic Nanoparticles on Modified Polypyrrole/m-Phenylediamine for Adsorption of Cr(VI) from Aqueous Solution

  • Thabiso Carol Maponya,
  • Kabelo Edmond Ramohlola,
  • Nazia Hassan Kera,
  • Kwena Desmond Modibane,
  • Arjun Maity,
  • Lebogang Maureen Katata-Seru and
  • Mpitloane Joseph Hato

19 March 2020

A novel, modified polypyrrole/m-phenylediamine (PPy–mPD) composite, decorated with magnetite (Fe3O4) nanoparticles, and prepared via an in-situ oxidative polymerisation, was investigated. The PPy–mPD/Fe3O4 nanocomposite was employed for the removal o...

  • Article
  • Open Access
62 Citations
9,143 Views
21 Pages

Different Types of Gel Carriers as Metronidazole Delivery Systems to the Oral Mucosa

  • Magdalena Wróblewska,
  • Emilia Szymańska,
  • Marta Szekalska and
  • Katarzyna Winnicka

19 March 2020

Periodontal diseases are some of the most widespread oral afflictions, and they are labeled as chronic infections caused by the accumulation of bacteria in dental plaque that produces localized inflammation of the periodontium. The use of local drug...

  • Article
  • Open Access
5 Citations
3,691 Views
12 Pages

Effect of Porosity Gradient on Mechanical Properties of Cellular Nano-Composites

  • Josef Jancar,
  • Klara Zarybnicka,
  • Jan Zidek and
  • Frantisek Kucera

19 March 2020

With their hierarchical architectures incorporating gradients in composition, porosity, and orientation, natural materials have evolved optimized balance of mechanical properties. Deciphered from the structure of bamboo, we prepared cellular solids w...

  • Article
  • Open Access
10 Citations
4,359 Views
13 Pages

Influence of Hybridization on Tensile Behaviors of Non-Absorbable Braided Polymeric Sutures

  • Moqaddaseh Afzali Naniz,
  • Mahdi Bodaghi,
  • Majid Safar Johari and
  • Ali Zolfagharian

19 March 2020

This paper aims to investigate the effects of fiber hybridization technique on the mechanical behaviors of non-absorbable braided composite sutures. Fifteen types of hybrid braided sutures (HBSs) made of polyester (PET), polypropylene (PP), and polya...

  • Article
  • Open Access
13 Citations
4,041 Views
13 Pages

19 March 2020

With the rapid development of thermal protection systems for the aerospace industry and power electronics, polyarylacetylene (PAA) resin plays an important role because of its good mechanical properties, high glass transition temperature (Tg), low wa...

  • Article
  • Open Access
2 Citations
4,407 Views
13 Pages

Elastomer Characterization Method for Trapped Rubber Processing

  • Pooria Khalili,
  • Thomas Boulanger and
  • Brina J. Blinzler

19 March 2020

The increasing high-volume demand for polymer matrix composites (PMCs) brings into focus the need for autoclave alternative processing. Trapped rubber processing (TRP) of PMCs is a method capable of achieving high pressures during polymer matrix comp...

  • Review
  • Open Access
33 Citations
7,390 Views
27 Pages

19 March 2020

Reinforced concrete flat slabs or flat plates continue to be among the most popular floor systems due to speed of construction and inherent flexibility it offers in relation to locations of partitions. However, flat slab/plate floor systems that are...

  • Article
  • Open Access
21 Citations
5,432 Views
16 Pages

Shape Tuning and Size Prediction of Millimeter-Scale Calcium-Alginate Capsules with Aqueous Core

  • Jinchao Zhao,
  • Qing Guo,
  • Wei Huang,
  • Teng Zhang,
  • Jing Wang,
  • Yu Zhang,
  • Leping Huang and
  • Youhong Tang

19 March 2020

Controllable feature and size, good mechanical stability and intelligent release behavior is the capsule products relentless pursuit of the goal. In addition, to illustrate the quantitative relationship of structure and performance is also important...

  • Article
  • Open Access
13 Citations
3,687 Views
12 Pages

19 March 2020

The transport properties of agarose hydrogels enriched by humic acids were studied. Methylene blue, rhodamine 6G and Cu(II) ions were incorporated into hydrogel as diffusion probes, and then their release into water was monitored. Cu(II) ions as well...

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Polymers - ISSN 2073-4360