Crystals, Volume 8, Issue 11

Quantum wells and barriers with precise thicknesses and abrupt composition changes at their interfaces are critical for obtaining the desired emission wavelength from quantum cascade laser devices. High-resolution X-ray diffraction and transmission e...

Microbially induced calcite precipitation (MICP) through a ureolytic pathway is a process that promotes calcite precipitation as a result of the urease enzymatic activity of several microorganisms. It has been studied for different technological appl...

In this paper, we report on the synthesis, crystal structure, and photomagnetic properties of the spin-crossover salt of formula [Fe(bpp)₂](C₆H₄NO₂)₂·4H₂O (1·4H₂O) (bpp = 2,6-bis(pyrazol-3-yl)pyridine; C₆H₄NO₂⁻ = nicotinate anion)...

Human carbonic anhydrase IX (CA IX) is a multi-domain membrane protein that is therefore difficult to express or crystalize. To prepare crystals that are suitable for neutron studies, we are using only the catalytic domain of CA IX with six surface m...

Cu-Ni-Si alloy with a different Co content was prepared by inductive melting and hot rolling. The alloy was solution treated at 950 °C for 1.5 h and aged at 450 °C, 500 °C, and 550 °C for different times. The phase diagram calculation and transmissio...

We report the synthesis, characterization, and self-assembly behavior of a 4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dye functionalized at the meso-position with a butyric acid group. Various spectroscopic investigations (UV-Vis, emission,...

In this work, a novel metal-organic framework (MOF) and BiVO₄ (BVO) composite photocatalyst was successfully synthesized by an in-situ growth method. The characterization of obtained samples was done by X-ray diffraction, scanning electron microscopy...

Metal-organic complex exhibiting spin crossover (SCO) behavior has drawn attention for its functionality as a nanoscale spin switch. The spin states in the metal ions can be tuned by external stimuli such as temperature or light. This article demonst...

Here we report the synthesis and characterization of a mononuclear gadolinium complex (Gd) and two heteronuclear Zn-Gd complexes (ZnGd and Zn₂Gd), which contain two similar three-armed ligands that display an external compartment suitable for lanthan...

Structural, electronic, magnetic and mechanic properties of the inverse Heusler alloy Ti₂NiIn under different pressure are systematically studied with density functional theory (DFT). The equilibrium lattice constant and electronic band structure at...

Crystalline silicon (c-Si) is the dominating photovoltaic technology today, with a global market share of about 90%. Therefore, it is crucial for further improving the performance of c-Si solar cells and reducing their cost. Since 2014, continuous br...

New ferroelectric crystals Pb(Er_1/2Nb_1/2)-Pb(Mg_1/3Nb_1/3)O-PbTiO₃ (PEN-PMN-PT) were grown by using the flux method. Phase structure of the crystals was described by the X-ray diffraction analysis. Dielectric, ferroelectric and optical properties of th...

The thermal conductivity of the Mg-1Mn-2Zn-xNd alloys (x = 0.5, 1.0, 1.5 wt. %) was studied for the potential applications of heat dissipation. The phase constituents were examined by X-ray diffraction analysis, and the microstructure was observed by...

The mechanical and electronic properties of two GaN crystals, wurtzite and zinc-blende GaN, under various hydrostatic pressures were investigated using first principles calculations. The results show that the lattice constants of the two GaN crystals...

A new compound, namely, [Zn(L)₂]_n (1) was obtained by the reaction of 2-methyl-4-(4H-1,2,4-triazol-4-yl) benzoic acid (HL) with ZnSO₄·7H₂O, and the compound was characterized by single-crystal X-ray diffraction, infrared spectroscopy, elementa...

The chlorine (Cl) and bromine (Br) co-doped lithium nickel manganese cobalt oxide (LiNi_1/3Co_1/3Mn_1/3O₂) was successfully synthesized by the molten salt method. The synthesized LiNi_1/3Co_1/3Mn_1/3O₂ compound demonstrates spherical morphology, which is f...

Ytterbium doped Lu_1.5Y_1.5Al₅O₁₂ (LuYAG) nanocrystalline powders were synthesized by a wet chemical mixed precipitant co-precipitation (MPP) method, and then the mixed crystal of Yb:LuYAG was grown in an optical floating zone (OFZ) furnace at the spee...

To realize high-efficiency AlGaN-based deep-ultraviolet light-emitting diodes (DUV-LEDs), enhancing their light-extraction efficiency (LEE) is crucial. This paper proposes an aluminum-based sidewall reflector structure that could replace the conventi...

Among colours, the green colour has the most sensitivity in human vision so that green colour defects on displays can be effortlessly perceived by a photopic eye with the most intensity in the wavelength 555 nm of the spectrum. With the market moving...

This paper reviews investigations on protein crystallization. It aims to present a comprehensive rather than complete account of recent studies and efforts to elucidate the most intimate mechanisms of protein crystal nucleation. It is emphasized that...

Although the minerals belonging to the carbonate group are a widely discussed subject, their relevance remains unchanged due to their many applications in a wide range of disciplines, from mineralogy, geochemistry and geology, to biology, medicine, i...

An indium gallium nitride (InGaN) light-emitting diode (LED) with an embedded porous GaN reflector and a current confined aperture is presented in this study. Eight pairs of n⁺-GaN:Si/GaN in stacked structure are transformed into a conductive, porous...

On a two-dimensional quasicrystal, a Penrose tiling, we simulate for the first time a game of life dynamics governed by non-local rules. Quasicrystals have inherently non-local order since any local patch, the emperor, forces the existence of a large...

For effective utilization of the residues, calcium sulfate whiskers were prepared from semi-dry desulfurization residues by hydrothermal synthesis reactions. Aiming at collecting the products with a long length and large aspect ratio, the additives,...

Two spin crossover (SCO) coordination polymers assembled by combining Fe^II octahedral ion, 4-cyanopyridine (4-CNpy) and [Au(CN)₂]⁻ liner unit are described. These compounds, Fe(4-CNpy)₂[Au(CN)₂]₂·1/2(4-CNpy) (1a) and {Fe(4-CNpy)₂[Au(CN)₂...

A hetero-hexanuclear Zn(II)-La(III) coordination compound, [{(ZnL)₂La}₂(bdc)₂](NO₃)₂ (H₂bdc = terephthalic acid) has been synthesized with a symmetric Salamo-like bisoxime, and characterized by elemental analyses, IR, UV-Vis, fluorescent spectroscopy...

It is rare to find technical applications involving a material of any crystal structure that is not impacted by dislocations—which affect the material’s mechanical properties, interfaces, martensitic phase transformations, crystal growth,...

In this work, the CoCrFeNiNb_x (x: molar ratio, x = 0.45, 0.5, 0.75, and 1.0) high entropy alloy coatings were synthesized on a 304 stainless steel substrate by laser cladding to investigate the effect of Nb element on their microstructure, hardness,...

Zinc oxide nanoparticles codoped with Co²⁺ and Mn²⁺ ions (Zn_(1−x−y)Mn_xCo_yO NPs) were obtained for the first time by microwave solvothermal synthesis. The nominal content of Co²⁺ and Mn²⁺ in Zn_(1−x−y)Mn_xCo_yO NPs was x = y = 0,...

We have prepared a set of polycrystalline samples of La ${}_{0.8}$ Sr ${}_{0.2}$ Co ${}_{1-x}$ Al ${}_x$ O ${}_3$ ( $0\le x\le 0.2$ ), and have measured the magnetization as functions of temperature and magnetic field. We f...

Gas membrane-based separation is considered one of the most effective technologies to address energy efficiency and large footprint challenges. Various classes of advanced materials, including polymers, zeolites, porous carbons, and metal–organ...

Multiple-input multiple-output (MIMO) technology as an efficient approach to improve the transmission rate in visible light communication (VLC) has been well studied in recent years. In this paper, we focus on the MIMO VLC system using multi-color LE...

Zinc oxide is one of the most important semiconducting metal oxides and one of the most promising n-type materials, but its practical use is limited because of both its high thermal conductivity and its low electrical conductivity. Numerous studies h...

Solvate formation of bis(demethoxy)curcumin (BDMC) was screened. Six solvates were obtained out of the nineteen solvents investigated. In the present work, three solvates, i.e., BDMC-tetrahydrofuran (THF), BDMC-1,4-dioxane (DIO) and BDMC-dimethyl sul...

In crystallization, nanoparticle aggregation often leads to the formation of orderly structures, even single crystals. Why can nanoparticles form orderly structures and what is the mechanism dominating their orderly aggregation? These questions raise...

With fairness consideration, optimal linear precoding designs for multi-color, multi-user visible light communication (VLC) systems are presented in this paper. Utilizing both the spatial and multi-color resources, the precoding designs are proposed...

Space is expected to be a convection-free, quiescent environment for the production of large-size and high-quality protein crystals. However, the mechanisms by which the diffusion environment in space improves the quality of the protein crystals are...

We present here a new series of spin crossover (SCO) Fe(II) complexes based on dipyridyl-N-alkylamine and thiocyanate ligands, with the chemical formulae [Fe(dpea)₂(NCS)₂] (1) (dpea = 2,2’-dipyridyl-N-ethylamine), I-[Fe(dppa)₂(NCS)₂], (2) II-[F...

The technological inspection of the electrolyte composition in aluminum production is performed using calibration X-ray quantitative phase analysis (QPA). For this purpose, the use of QPA by the Rietveld method, which does not require the creation of...

As the turbidity induction time measurements are influenced by the size distribution of the nuclei at the detection point, these data should provide important information on both nucleation and growth. A model is developed in this work to determine t...

Ni nano-micro structures have been synthesized via a solution reduction route in the presence of ethylenediamine (EDA) under strong alkaline conditions. The phase composition, morphology, and microstructure of the resulting products are investigated...

Polymer composites with high thermal conductivity have a great potential for applications in modern electronics due to their low cost, easy process, and stable physical and chemical properties. Nevertheless, most polymer composites commonly possess u...

Silicon facet formation during directional solidification is simulated by cellular automaton (CA) modeling in which anisotropic interfacial energy and kinetics are considered. Numerical simulations were performed with different anisotropy strengths o...