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Crystals, Volume 16, Issue 10

2026 October - 83 articles

Cover Story: Tertiary batteries (TBs) convert environmental temperature change (ΔT) to electric energy. Shibata et al. demonstrated that CoPBA and NiPBA electrodes exhibit higher temperature coefficients of potential E for Li+ than Na+. The thermal electromotive force (VTB) of a CoPBA/NiPBA TB increases from 23–25 mV (Li+) to 29–30 mV (Na+) at ΔT = 30 K. This enhanced VTB is interpreted in terms of the smaller ionic radius of Li+. The lithium substitution is an effective strategy for enhancing VTB for TB. View this paper
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Articles (83)

  • Article
  • Open Access
149 Views
20 Pages

Hydrogen-Induced Damage Evolution and Quasi-Cleavage Cracking in API X70 Pipeline Girth Welds Under Blended CH4-H2 Environments

  • Yufa Deng,
  • Chun Kang,
  • Guichuan Chang,
  • Gang Yang and ,
  • Penggang Zhang,
  • Mingji Huang and
  • Tingshu Chen
  • + 2 authors+ 0 author

21 October 2026

Hydrogen blending in natural gas pipelines poses an embrittlement risk to girth welds. This study investigated an API X70 girth weld in CH4-H2 mixtures containing 5–20% H2 at 4–10 MPa using slow strain rate tensile testing, fractography,...

(This article belongs to the Section Crystalline Metals and Alloys)
  • Article
  • Open Access
128 Views
21 Pages

The Influence of In Situ Alumina Defect Filling on the CMAS Corrosion Resistance of High-Entropy Rare-Earth Zirconate Thermal Barrier Coatings and Its Anti-Penetration Mechanism

  • Jianhai Yu,
  • Jiaqi You,
  • Shihua Zhang,
  • Chao Sang and ,
  • Zhongshen Dong,
  • Lulu Wang,
  • Taotao Cheng,
  • Tao Zhang,
  • Changyao Sun and
  • Kunying Ding
  • + 5 authors+ 0 author

21 October 2026

As turbine inlet temperatures increase, the long-term stability of conventional yttria-stabilized zirconia (YSZ) thermal barrier coatings (TBCs) becomes difficult to maintain. Molten calcium–magnesium–alumino-silicate (CMAS) rapidly infil...

(This article belongs to the Special Issue High-Performance Crystalline Materials: Structural Design, Functional Properties and Advanced Manufacturing)
  • Article
  • Open Access
110 Views
27 Pages

21 October 2026

Fourier-based analysis of strain and rotation in differently oriented crystal domains in high-resolution electron microscopy lattice images requires consideration of the lattice signals and reciprocal bases associated with each domain. Here, the stra...

(This article belongs to the Special Issue Research in Magnesium-Based Alloys)
  • Article
  • Open Access
598 Views
15 Pages

New Evidence for Low-Temperature Heat Treatment Detection in Vietnamese Magmatic Sapphires Using FTIR Spectroscopy

  • Ratthaphon Amphon,
  • Sutas Singbamroong,
  • Tasnara Sripoonjan,
  • Chawalit Chankhantha and
  • Andy H. Shen

21 October 2026

Low-temperature heat treatment in magmatic sapphires can be difficult to detect because conventional indicators, including hydroxyl-related absorptions and short-wave ultraviolet fluorescence, are often weak, absent, or inconclusive in Fe-rich materi...

(This article belongs to the Special Issue Spectroscopic and Crystallographic Analysis of Gemstones)
  • Article
  • Open Access
137 Views
19 Pages

20 October 2026

Understanding the extent to which the supramolecular crystalline organisation of native wood is associated with its macroscopic, thermal and micromechanical properties remains an active area of inquiry in biomass characterisation. In this study, the...

(This article belongs to the Section Organic Crystalline Materials)
  • Article
  • Open Access
114 Views
18 Pages

Influence of Preparation Parameters on Thermal Control and Corrosion Behavior of ZnO Nanoparticle-Incorporated MAO Coatings on Magnesium Alloy

  • Kailang Hao,
  • Yanli Yang,
  • Shitai Shen,
  • Yukai Wang and ,
  • Zhongquan Zhang and
  • Guoying Wei
  • + 1 author+ 0 author

20 October 2026

In this study, ZnO nanoparticle-incorporated micro-arc oxidation (MAO) coatings were prepared on AZ31 magnesium alloy in a sodium silicate-based electrolyte. The effects of applied current density (3–6 A·dm−2), oxidation time (3&nd...

(This article belongs to the Special Issue Coating Materials: Preparation, Tribological Properties, and Corrosion Resistance)
  • Article
  • Open Access
225 Views
21 Pages

20 October 2026

Chemical short-range order (CSRO) is associated with heterogeneous lattice distortion in refractory multi-principal-element alloys, but its relationship with cyclic dislocation organization remains unresolved. Hybrid Monte Carlo and molecular dynamic...

(This article belongs to the Special Issue Advances in Medium/High-Entropy Materials)
  • Article
  • Open Access
161 Views
22 Pages

A New Look at the Isomeric Purity and Its Impact on the Thermotropic Properties of Alkylbenzene Sulfonate-Derived Catanionic Surfactants

  • Robin Jose,
  • Aileen M. Sanchez Medina,
  • Reema Rawal,
  • Seonghyeok Lee Cox and ,
  • Haesook Han,
  • Pradip Kumar Bhowmik,
  • Christopher Schmiedl and
  • Michael R. Fisch
  • + 3 authors+ 0 author

19 October 2026

Thermotropic polymorphism of catanionic surfactants and its dependence on molecular structure was studied in seven catanionic surfactants with varying cationic and anionic chain lengths that were synthesized using isomerically pure para-alkylbenzene...

(This article belongs to the Special Issue Polymorphism and Phase Transitions in Crystal Materials)
  • Article
  • Open Access
200 Views
18 Pages

19 October 2026

The straightforward decarboxylation of pyridazin-3(2H)-one-2-yl acetic acids and some of its alkyl homologues was achieved without the need for a catalyst and in solvent-free conditions by simple heating above the melting points. By this procedure N-...

  • Article
  • Open Access
259 Views
17 Pages

Static Fatigue and Lifetime Prediction of Rosa Porriño Granite: Role of Flaw Population and Slow Crack Growth

  • Jorge Cruz Fernandes,
  • Raquel S. Henriques,
  • Adriano Coelho,
  • Pedro M. Amaral and
  • Fernando A. Costa Oliveira

18 October 2026

Rosa Porriño granite is a widely used dimension stone in architectural and structural applications, yet its long-term reliability under sustained loading remains insufficiently quantified. Here, we combine mechanical testing, fractography and...

(This article belongs to the Special Issue Feature Papers on “Inorganic Crystalline Materials”)
  • Article
  • Open Access
161 Views
23 Pages

17 October 2026

To address the low computational efficiency associated with the large deformation and transient evolution of the solid–liquid interface during the shoulder growth stage of sapphire crystals grown by the Kyropoulos method, a lightweight explicit...

(This article belongs to the Special Issue Bridging the Embryonic Period for Disruptive Innovation in Crystal Growth)
  • Article
  • Open Access
554 Views
15 Pages

Microgravity Crystallization of Active Pharmaceutical Ingredients (APIs): Impact on Crystalline Forms

  • Kamryn Williams,
  • Jessica Paulson,
  • Miriam Garringer,
  • Joanna Rajkumar and ,
  • Chloe Brecht,
  • Carson Powers,
  • Lillian Miller,
  • Stephen Tuma,
  • Dom Hebrault and
  • Anne M. Wilson
  • + 5 authors+ 0 author

17 October 2026

Controlling the nature of solid forms of active pharmaceutical ingredients (APIs) can enhance the chemical stability, increase or decrease the solubility, reduce the dose required, reduce waste production, increase manufacturing yield, and improve th...

(This article belongs to the Special Issue Advances in Pharmaceutical Crystals: Numerical Simulations and Experimental Investigations)
  • Article
  • Open Access
222 Views
17 Pages

Thickness-Dependent Thermo-Optical Response in Micro/Nanostructured Bioglass Films

  • Marco Antonio Hernandez-Acosta,
  • Ohtokani Cabrera,
  • Ignacio Duarte-Yañez,
  • Felipe Gesser Battisti and ,
  • Roberto Villarroel,
  • Martin Daniel Trejo-Valdez and
  • José Antonio García-Merino
  • + 2 authors+ 0 author

16 October 2026

Bioglass (BG) thin films are promising materials for integrating bioactivity with dynamically tunable optical functionality. Here, BG coatings containing two, four, and six deposited layers were fabricated by spin coating to investigate how depositio...

(This article belongs to the Special Issue Functional Thin Films: Growth, Characterization, and Applications)
  • Review
  • Open Access
249 Views
33 Pages

Impurity-Tolerance Design and Strengthening–Toughening Strategies in Recycled Aluminium Alloys

  • Dongxu Yang,
  • Huafeng Wei,
  • Haozhe Li,
  • Hongwu Zhang and ,
  • Zengwu Yue and
  • Xingshuo Liu
  • + 1 author+ 0 author

16 October 2026

Recycled aluminium moves from downcycling towards the automotive sheet, structural castings and high-performance extrusions. The central constraint on closed-loop recycling is no longer the mere presence of impurities. It is the multiscale microstruc...

(This article belongs to the Section Crystalline Metals and Alloys)
  • Article
  • Open Access
197 Views
16 Pages

Effect of High-Energy Mechanical Alloying Duration and Boron Content on the Structural and Phase Evolution of W–B Powder Mixtures

  • Yerkhat Dauletkhanov,
  • Dias Yerbolat,
  • Yerzhan Sapatayev,
  • Leonid Izmaylov and ,
  • Piotr Kowalewski,
  • Azamat Urkunbay,
  • Sardor Kambarbekov,
  • Elfira Sagymbekova,
  • Gulnara Yerbolatova and
  • Amangeldi Sagidugumar
  • + 5 authors+ 0 author

15 October 2026

Tungsten borides are promising superhard materials, but their mechanochemical synthesis requires prolonged processing, leaving the early and intermediate stages of mechanical alloying (MA) and the role of boron content largely unexplored. This study...

(This article belongs to the Section Inorganic Crystalline Materials)
  • Article
  • Open Access
236 Views
11 Pages

Investigating the Role of Dangling Bond DOS in Dark- and Light-Induced Conductivity of a-Si:H for Photovoltaic Applications

  • Ilias Sbahi,
  • Baya Zebentout,
  • Abdelaziz Rabehi,
  • Abdelmalek Douara and ,
  • Mohamed Arbi Khlifi,
  • Mustapha Habib and
  • Zineb Benamara
  • + 2 authors+ 0 author

15 October 2026

This paper examines the impact of defect-related Density of States (DOS) on both dark and illuminated conductivity of intrinsic amorphous silicon (a-Si:H). The quality of the a-Si:H layer plays a crucial role in achieving high photovoltaic (PV) conve...

(This article belongs to the Section Materials for Energy Applications)
  • Article
  • Open Access
223 Views
10 Pages

15 October 2026

Five compounds with the formula Ln2Zr2O7 (Ln = La, Nd, Sm, Eu, and Gd) were investigated. These materials exhibit important physicochemical properties and find practical applications for the development of high-temperature barriers, gas traps, and th...

(This article belongs to the Section Inorganic Crystalline Materials)
  • Article
  • Open Access
297 Views
25 Pages

Effect of Post-Swaging Annealing on Charpy Impact Behavior of Metastable Austenitic Stainless Steel

  • Dmitrii Panov,
  • Egor Kudryavtsev,
  • Ruslan Chernichenko,
  • Stanislav Naumov and ,
  • K. Chandra Sekhar,
  • Alexey Pertcev and
  • Gennady Salishchev
  • + 2 authors+ 0 author

14 October 2026

The development of steels with good mechanical properties is essential for high-strength and deflection fabrications. This paper investigates the effect of annealing temperature on the dynamic mechanical behavior, microstructural response, and fractu...

(This article belongs to the Special Issue From Processing to Performance: Microstructure Engineering in Advanced Metallic Alloys)
  • Article
  • Open Access
183 Views
15 Pages

Mineralogical, Geochemical and Gemological Characteristics of Chalcedony from the Ergani Region (Diyarbakır, Türkiye)

  • İlkay Kaydu Akbudak,
  • Zeynel Başıbüyük,
  • Hilal Dokuz,
  • Gökhan Ekincioğlu and
  • Meltem Gürbüz

14 October 2026

In this study, the mineralogical, petrographic, geochemical, and gemological characteristics of siliceous gemstones exposed in the Ergani (Diyarbakır) region were investigated. The siliceous gemstones occur within Eocene sedimentary units, filli...

(This article belongs to the Special Issue Modern Gem Crystals: Synthesis, Characterization, Genesis and Intelligent Analysis)
  • Article
  • Open Access
259 Views
20 Pages

Cr3+/Er3+ Co-Doped BaTiO3 Ceramics: Structural Evolution, Microstructural Development, and Dielectric Response

  • Edgar Ricardo Ramírez-Martínez,
  • Irma Mendoza-Sánchez,
  • Miguel Pérez-Labra,
  • José Antonio Romero-Serrano and ,
  • José Agustín Palmas-León,
  • Aurelio Hernández-Ramírez,
  • Alejandro Cruz-Ramírez,
  • Martin Reyes-Pérez and
  • Aislinn Michelle Teja Ruiz
  • + 4 authors+ 0 author

14 October 2026

Cr3+/Er3+ co-doping was investigated as a strategy to modify the structural, microstructural, and dielectric response of BaTiO3 ceramics. Ba1−3xCr2xTi1−3xEr4xO3 compositions (x = 0, 0.001, 0.0015, and 0.002) were prepared by mechanical mi...

(This article belongs to the Section Polycrystalline Ceramics)
  • Article
  • Open Access
164 Views
16 Pages

Predicting Highly Anisotropic Dislocation Core Properties of B2 Alloys Using an Ab Initio-Informed Fully Discrete Peierls–Nabarro Model

  • Linkun Liu,
  • Biruk Abiot Mengistu,
  • Lin Cheng,
  • Xuanye Zeng and ,
  • Xingzhen Huang,
  • Xiaoqing Chen,
  • Bozhao Wu,
  • Xiangsheng Hu and
  • Guowei Zeng
  • + 4 authors+ 0 author

14 October 2026

An ab initio-informed fully discrete Peierls–Nabarro (FDPN) framework is employed to establish quantitative links among the generalized stacking fault energy (GSFE) landscape, dislocation core structure, and intrinsic lattice resistance in six...

(This article belongs to the Section Crystalline Metals and Alloys)
  • Article
  • Open Access
213 Views
22 Pages

Opposite Effects of Surface Nanostructures on CO2 Desublimation over Hydrophilic and Hydrophobic Surfaces: A Molecular Dynamics Study

  • Ming-Long Fan,
  • Rui He,
  • Bing-Bing Wang,
  • Hao Cheng and ,
  • Qing-Bo Su and
  • Fang-Qiu Li
  • + 1 author+ 0 author

14 October 2026

In this study, we perform molecular dynamics simulations to investigate the desublimation of carbon dioxide (CO2) on hydrophilic and hydrophobic surfaces with nanostructures. The results reveal that the presence of surface nanostructures substantiall...

(This article belongs to the Section Industrial Crystallization)
  • Editorial
  • Open Access
149 Views
3 Pages

14 October 2026

Photoluminescent materials convert absorbed photon energy into radiative emission and constitute the functional basis of technologies, including solid-state lighting, displays, sensors, bioimaging, and anti-counterfeiting, etc [...]

(This article belongs to the Special Issue Research Progress of Photoluminescent Materials)
  • Article
  • Open Access
162 Views
24 Pages

13 October 2026

In a recently published continuum thermodynamic approach to the phase-field method, the order parameter is considered an internal state variable, and the phase-field method is interpreted as an approximation of the corresponding sharp-interface theor...

  • Article
  • Open Access
190 Views
17 Pages

13 October 2026

Mali garnet is a gem-quality variety of the grossular–andradite solid-solution series and exhibits a wide range of colors, from near-colorless through light yellow, medium yellow, yellow, yellow-green, green with a yellow tint, to green. In thi...

(This article belongs to the Section Mineralogical Crystallography and Biomineralization)
  • Article
  • Open Access
282 Views
22 Pages

Structural, Surface-Chemical and Morphological Control of Effective Thermal Transport in La2O3-Modified ZnO Nanopowder Compacts

  • Cevher Kursat Macit,
  • Mehmet Das,
  • Emrullah Kocaman,
  • Alperen Tozlu and ,
  • Hakan Tutumlu,
  • Burak Tanyeri and
  • Ebru Akpinar
  • + 2 authors+ 0 author

12 October 2026

Pristine ZnO and ZnO containing 1, 5, 10 and 20 wt.% nominal La2O3 were prepared by sol–gel-assisted chemical precipitation to investigate composition-dependent thermal transport in porous pressed-powder compacts. X-ray diffraction, Fourier-tra...

(This article belongs to the Special Issue Crystal Structure and Physical Properties of Functional Materials)
  • Article
  • Open Access
227 Views
11 Pages

11 October 2026

A previously reported crystalline assembly of the γ-form of trans-1,2-bis(4-pyridyl)ethylene (BPE) with citric acid (CA) was investigated under UV irradiation to examine its structural evolution and solid-state [2 + 2] photodimerization. Single...

(This article belongs to the Section Crystal Engineering)
  • Article
  • Open Access
191 Views
22 Pages

11 October 2026

Steel, copper, and magnesium slags are typical metallurgical solid wastes containing potentially recoverable Fe, Ca, Mg, and Si. Copper slag is relatively rich in iron, but much of this iron is bound in fayalite or Fe–Mg olivine, which limits d...

(This article belongs to the Section Hybrid and Composite Crystalline Materials)
  • Article
  • Open Access
177 Views
17 Pages

10 October 2026

A device intended to detect and remember light needs more than a large photocurrent: its later electrical response must also remain distinguishable. Here, we examine these two requirements in MAPbBr3 single crystals with Au/Au, Ni/Ni, Au/Ni, and Ni/A...

(This article belongs to the Special Issue The Cutting Edge of Energy Materials Research Aimed at Practical Application)
  • Article
  • Open Access
309 Views
36 Pages

Nanoparticle Size Effects on Thermal Conductivity of Hybrid Nanofluids: Experiments and Neural Network Modeling

  • Irfan Kilic,
  • Abdulsamed Güneş,
  • Cebrail Barut,
  • Beytullah Erdoğan and ,
  • Orhan Yaman and
  • Adnan Topuz
  • + 1 author+ 0 author

10 October 2026

Traditional cutting fluids are insufficient to mitigate problems such as the high temperatures and tool wear that occur during machining processes. Therefore, the use of nanoparticle-modified coolant oils has gained importance in recent years. In thi...

(This article belongs to the Special Issue Thermodynamics and Kinetics of Crystalline Materials Through Advanced Characterization and Simulation)
  • Article
  • Open Access
167 Views
12 Pages

10 October 2026

Pearl luster is commonly assessed by expert visual grading, which is subjective and may show limited interlaboratory reproducibility. We developed a dual-indicator imaging method for Chinese freshwater nucleated pearls using surface luminance and int...

(This article belongs to the Section Mineralogical Crystallography and Biomineralization)
  • Article
  • Open Access
226 Views
22 Pages

9 October 2026

Finite element analysis (FEA) is a key tool for predicting the mechanical behavior of additively manufactured parts. However, its predictive accuracy relies on the underlying constitutive model and, in particular, on precise model parameters. The mai...

(This article belongs to the Special Issue Properties and Applications of 3D Printed Titanium Alloys)
  • Article
  • Open Access
261 Views
18 Pages

Coupled Effects of Sc-Zr Microalloying and Casting Conditions on the Microstructural Evolution and Mechanical Properties of Al-Ce-Mg Alloys

  • Peng Hu,
  • Xueling Yang,
  • Jinjie Wang,
  • Xiwang Du and ,
  • Zhen Han,
  • Wei Chen and
  • Liying Cui
  • + 2 authors+ 0 author

9 October 2026

The effects of Sc-Zr microalloying and casting conditions on the microstructure, precipitation behavior, and mechanical properties of Al-Ce-Mg alloys were investigated. Sc-Zr addition refined the grains, suppressed coarse primary Al11Ce3, and changed...

(This article belongs to the Special Issue Microstructure Characterization and Design of Advanced Alloys)
  • Article
  • Open Access
254 Views
16 Pages

Raman Spectroscopy of Laser-Micro-Annealing-Induced Structural Changes in Ti-6Al-4V

  • Hilde Helen Hardtdegen,
  • Martin Mikulics,
  • Ralf Eickhoff,
  • Steffen Antusch and ,
  • Joachim Mayer and
  • Thomas Hanemann
  • + 1 author+ 0 author

9 October 2026

This short study presents the results of micro-Raman investigations performed on the alloy Ti-6Al-4V, which was additively manufactured via metal fused filament fabrication (MF3). Local laser micro-annealing was applied at different power intensities...

(This article belongs to the Special Issue Microstructure and Properties of Metals and Alloys, 2nd Edition)
  • Article
  • Open Access
165 Views
12 Pages

8 October 2026

In the context of global industrial green transformation and the demand for light-weighting, magnesium alloys, as the most promising lightweight engineering materials, still face limitations due to inherent poor ductility, low strength, and insuffici...

(This article belongs to the Section Crystalline Metals and Alloys)
  • Article
  • Open Access
257 Views
14 Pages

8 October 2026

Dielectric spectroscopy is known to be one of the most powerful techniques for studying the ferroelectric and other polar fluids. Since the discovery of ferroelectricity in Liquid Crystals, the technique has successfully been employed for characteriz...

(This article belongs to the Special Issue Research on Liquid Crystal Materials and Optical Devices)
  • Article
  • Open Access
181 Views
19 Pages

8 October 2026

This study presents the effect of partially replacing milled fireclay (3% to 12%) with mineral wool melt centrifugation waste (CWW) in lightweight refractory concrete with cenospheres (CHs). We analyzed hydration heat evolution, mineral composition (...

(This article belongs to the Special Issue Crystallization and Rheological Properties of Functional Building Materials)
  • Article
  • Open Access
212 Views
12 Pages

Effect of a CaO–SiO2–Al2O3 Composite Early-Strength Agent on the Early Mechanical Properties of Cement-Based Repair Materials

  • Laifa Wang,
  • Xinyan Wang,
  • Anhua Xu,
  • Huaxin Chen and ,
  • Chenglong Li and
  • Xiang Li
  • + 1 author+ 0 author

7 October 2026

The early mechanical performance of cement-based repair materials is critical for the rapid rehabilitation of concrete structures and tunnel anchorage engineering. In this study, a reference mixture (ROA) without any accelerator, a general early-stre...

(This article belongs to the Special Issue Crystallization and Rheological Properties of Functional Building Materials)
  • Article
  • Open Access
400 Views
16 Pages

Facile One-Pot Synthesis of bTiO2 Nanoparticles with Concentration-Dependent NIR Photothermal Heating Under Physiological Starting Conditions

  • Imelda Olivas-Armendariz,
  • Porfirio Estrada-Rojas,
  • Ramsés Rodríguez García,
  • Marco Antonio Espinosa-Medina and ,
  • Mónica Elvira Mendoza-Duarte,
  • María de Lourdes Ballesteros Almanza,
  • Israel Perez,
  • Nataly Arrieta Sandoval and
  • Georgina Carbajal-De la Torre
  • + 4 authors+ 0 author

7 October 2026

Black titanium dioxide nanoparticles (bTiO2 NPs) have emerged as promising materials for light-driven applications due to their extended optical absorption and reduced environmental concerns compared with heavy-metal-based quantum dots. In this work,...

(This article belongs to the Special Issue Nanostructured Functional Materials: Structure, Properties, and Emerging Applications)
  • Article
  • Open Access
216 Views
10 Pages

Study of the Structural and Phase State and Hydrogen Interaction of a TiZrNbVTa High-Entropy Alloy Prepared by SPS

  • Mazhyn Skakov,
  • Sherzod Kurbanbekov,
  • Tolegen Kaisaruly,
  • Yulduz Amangeldiyeva and ,
  • Viktor Kudiiarov,
  • Yerkhat Dauletkhanov,
  • Nurken Mussakhan,
  • Dilnoza Baltabayeva and
  • Aibar Kizatov
  • + 4 authors+ 0 author

7 October 2026

The effects of post-processing heat treatment on the structural and phase state and hydrogen sorption characteristics of an equiatomic TiZrNbVTa high-entropy alloy produced by mechanical activation and spark plasma sintering were investigated. The po...

(This article belongs to the Special Issue Advanced Machining and Sustainable Manufacturing of Metallic Alloys)
  • Article
  • Open Access
316 Views
15 Pages

Enhanced Thermal Electromotive Force in Lithiated CoPBA/NiPBA Tertiary Battery

  • Takayuki Shibata,
  • Tomoya Ishizawa,
  • Ichiro Nagai,
  • Hitoshi Ohnuki and
  • Yutaka Moritomo

6 October 2026

Tertiary batteries (TBs), or thermo-rechargeable batteries, have attracted attention as an energy harvesting technology that utilizes changes in ambient temperature. Prussian blue analogues (A-MPBAs; AxM[Fe(CN)6]y, where A and M are Li+ or Na+ ions a...

(This article belongs to the Special Issue The Cutting Edge of Energy Materials Research Aimed at Practical Application)
  • Article
  • Open Access
286 Views
23 Pages

6 October 2026

Crystalline chlorobenzofuroxan (ClBF) exhibits persistent positional isomeric disorder, with 5-ClBF and 6-ClBF sharing the same crystallographic sites. Periodic density functional theory was used to investigate the associated configurational energeti...

(This article belongs to the Special Issue Crystals: 15th Anniversary)
  • Article
  • Open Access
252 Views
9 Pages

5 October 2026

Using a liquid metal cooling (LMC) high-gradient directional solidification furnace, this study compared primary dendrite arm spacing (PDAS) for nominal <001> deviation groups of 0°, 20°, and 45° under constant withdrawal rates and...

(This article belongs to the Special Issue Research on Single-Crystal Superalloys)
  • Article
  • Open Access
401 Views
12 Pages

Distorsion of the [Ni(OH2)6]2+ Cation in a Benzenesulfonate—Correlation with Hydrogen Bonds or Intra-Cation Interactions?

  • Ai Wang,
  • Adkhamjon Normamatov,
  • Aziz Ibragimov,
  • Ulli Englert and ,
  • Christian Lehmann and
  • Ruimin Wang
  • + 1 author+ 0 author

5 October 2026

In the absence of electronic reasons for distortion and with its ligands idealized as spherical, the hexaaquanickel(II) cation may be regarded as a simple example for octahedral metal coordination. In structurally characterized derivatives, the catio...

(This article belongs to the Section Crystal Engineering)
  • Article
  • Open Access
280 Views
15 Pages

Controlling Micro/Nano Morphology and Water Solubility of Dipotassium Pyrroloquinoline Quinone via Crystal Form Modification

  • Jinjian Wei,
  • Jiahui Kong,
  • Wenxiu An,
  • Chengfa Cai and ,
  • Ronghua Zhang,
  • Qian Chen,
  • Xu Han,
  • Yi Wen and
  • Zhide Zhang
  • + 4 authors+ 0 author

5 October 2026

The dipotassium salt of pyrroloquinoline quinone (PQQK2) is a promising nutraceutical with superior stability compared to its free acid, yet the influence of its solid-state form on solubility and particle morphology has not been explored. In this st...

(This article belongs to the Section Industrial Crystallization)
  • Article
  • Open Access
486 Views
18 Pages

Double Bragg Diffraction by Thin Liquid Crystal 2D Grating

  • Ashot H. Gevorgyan,
  • Aleksey O. Kamenev,
  • Nikolay A. Vanyushkin and
  • Francesco Simoni

3 October 2026

The diffraction properties of a 2D grating realized with heliconical cholesteric liquid crystal (ChOH) have been studied by extended computer simulation using the finite element method. In particular, the dependence of the diffraction efficiency and...

(This article belongs to the Special Issue Feature Papers on Liquid Crystals)
  • Review
  • Open Access
324 Views
30 Pages

30 September 2026

All-inorganic halide perovskite CsPbBr3 single crystals have become an ideal material for high-performance room-temperature radiation detectors, owing to their advantages of high atomic number, strong X-/γ-ray absorption, high carrier mobility,...

(This article belongs to the Special Issue Crystals: 15th Anniversary)
  • Article
  • Open Access
241 Views
18 Pages

30 September 2026

Rails are critical load-bearing components in railway transportation systems, and the quality of their welded joints is essential to operational safety. However, the large variation in rail cross-sectional geometry makes it difficult to achieve suita...

(This article belongs to the Special Issue Processing, Microstructure, and Properties of Metals)
  • Article
  • Open Access
244 Views
24 Pages

Hot Deformation Behavior and Microstructure Evolution of GTD222 Nickel-Based Superalloy

  • Zhiheng Zhu,
  • Chunhua Xiang,
  • Guangyu Wang,
  • Cunqiang Ma and ,
  • Mingpan Wan and
  • Min Lei
  • + 1 author+ 0 author

30 September 2026

Hot workability of GTD222 nickel-based superalloy was examined by isothermal compression over 1010–1090 °C and 0.01–10 s−1 to a true strain of 1.2. The flow resistance increased as the temperature decreased or the strain rate in...

(This article belongs to the Section Crystalline Metals and Alloys)
  • Article
  • Open Access
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21 Pages

Thermal Field Regulation of 6-Inch VGF-Ge Single Crystals: CGSim Simulation and Experimental Study on Defect Suppression

  • Hua Wei,
  • Lang Liao,
  • Chong Wang,
  • Tinglong Liu and ,
  • Hanbao Liu,
  • Jie Yang,
  • Feng Hui and
  • Rui Xu
  • + 3 authors+ 0 author

30 September 2026

The thermal field distribution in the vertical gradient freeze (VGF) process strongly influences the formation of dislocations, residual thermal stress, and twins in germanium (Ge) single crystals, and its effective control is essential for reducing...

(This article belongs to the Section Crystal Engineering)

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Crystals - ISSN 2073-4352