The solidified natural gas (SNG) technology presents a prospective strategy for CH
4 storage and transportation. Low gas storage capacity and slow formation rate remain the key challenges for its field applications. This study suggested a compound system of cyclopentane (CP) + graphite
[...] Read more.
The solidified natural gas (SNG) technology presents a prospective strategy for CH
4 storage and transportation. Low gas storage capacity and slow formation rate remain the key challenges for its field applications. This study suggested a compound system of cyclopentane (CP) + graphite nanoparticle (GNP) nanofluid to enhance the formation kinetics of CH
4 hydrate. Results indicated that both gas consumption and hydrate formation rate were higher at a higher CP concentration, peaking at 14 wt%, where t
90 (the time to reach 90% of the final gas uptake) was 65.7 min, and the gas uptake reached 0.1346 mol/mol. However, an excessive CP (21 wt%) negatively affected CH
4 hydrate generation kinetics due to the excessive cage occupancy of CP in 5
126
4 cavities. A lower temperature was determined to be more favorable for CH
4 hydrate formation within nanofluids, which was visually demonstrated by the denser hydrate crystals formed at 275.15 K. Moreover, storage stability analysis revealed that CH
4 hydrate formed in CP + GNP nanofluids can be preserved at atmospheric pressure and 268.15 K without significant decomposition. This work provides a superior scheme for hydrate-based CH
4 storage, offering great contributions to SNG technology advancement.
Full article