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45 Results Found

  • Article
  • Open Access
8 Citations
3,400 Views
16 Pages

14 April 2023

With the depletion of fossil fuel energy and both the slow development and low utilization rate of new eco-friendly energy, finding new ways to efficiently store energy has become a research hotspot. Presently, polyethylene glycol (PEG) is an excelle...

  • Article
  • Open Access
29 Citations
4,749 Views
17 Pages

Modified Ammonium Polyphosphate and Its Application in Polypropylene Resins

  • Lingyu Meng,
  • Xiangrui Li,
  • Mingli Liu,
  • Chunfeng Li,
  • Lipeng Meng and
  • Sen Hou

13 November 2022

Herein, a simple and environment-friendly method of coupling agent treatment of APP (ammonium polyphosphate) is provided and an optimum process of modification via coupling agent is identified. The effects of coupling agent type, dosage, modification...

  • Article
  • Open Access
19 Citations
3,537 Views
15 Pages

23 September 2021

A novel diaminodiphenylmethane (DDM) modified ammonium polyphosphate (APP) flame retardant, DDP, was successfully synthesized via ion-exchange reaction. DDP was introduced into epoxy resins (EPs) to reduce flammability. A comparable level of DDP exer...

  • Article
  • Open Access
24 Citations
3,591 Views
16 Pages

13 March 2021

Ammonium polyphosphate (APP) was modified with a silane coupling agent (vinyltrimethoxysilane, Si-171), and then the synergistic flame retarding effect of graphene and surface-modified APP (APP@Si-171) on high-impact polystyrene (HIPS) was investigat...

  • Article
  • Open Access
17 Citations
3,784 Views
14 Pages

Influence of Antimony Oxide on Epoxy Based Intumescent Flame Retardation Coating System

  • Riyazuddin,
  • Samrin Bano,
  • Fohad Mabood Husain,
  • Rais Ahmad Khan,
  • Ali Alsalme and
  • Jamal Akhter Siddique

17 November 2020

Ethylenediamine modified Ammonium polyphosphate (EDA-MAPP), and Charring-Foaming Agents (CFA) was prepared via a simple chemical approach and further utilizes for the preparation of Epoxy resin based intumescent flame retardation coatings. The ratio...

  • Article
  • Open Access
23 Citations
4,197 Views
17 Pages

23 November 2020

Modified ammonium polyphosphate (MAPP) was prepared as a novel mono-component intumescent flame retardant (IFR) via the ionic exchange between ammonium polyphosphate (APP) and piperazine sulfonate, which is synthesized by self-assembly using 1-(2-ami...

  • Article
  • Open Access
17 Citations
2,926 Views
24 Pages

5 August 2024

Ammonium polyphosphate (APP) and self-made nickel phytate (PANi) were used as modified materials to prepare green biomass rigid polyurethane foam (RPUF). The flame retardancy, thermal stability, smoke toxicity and mechanical properties of the modifie...

  • Article
  • Open Access
3 Citations
1,936 Views
15 Pages

Effect of Silane-Modified Ammonium Polyphosphate on the Mechanical, Thermal, and Flame-Retardant Properties of Rice Husk/Polylactic Acid Composites

  • Yufeng Sun,
  • Mingyang Liu,
  • Ziheng Zhang,
  • Hengyu Liu,
  • Dongming Shi,
  • Jilai Ying,
  • Wenlong Mu,
  • Defeng Li and
  • Ing Kong

In this study, rice husk (RH, 15wt%) served as a carbonizing agent, and ammonium polyphosphate (APP) served as an acid and gas source. These were combined with polylactic acid (PLA) to develop a high-strength and flame-retardant PLA-based composite....

  • Article
  • Open Access
11 Citations
2,829 Views
13 Pages

26 October 2021

To achieve the requirements of modified bismaleimide resin composites in electronic industry and high energy storage devices, flame retardancy, water resistance and dielectric properties must be improved. Hence, a highly efficient multifunctional gra...

  • Article
  • Open Access
9 Citations
3,749 Views
18 Pages

Synergistic Flame Retardant Properties of Polyoxymethylene with Surface Modified Intumescent Flame Retardant and Calcium Carbonate

  • Zheng Yang,
  • Xueting Chen,
  • Shike Lu,
  • Zhenhua Wang,
  • Jiantong Li,
  • Baoying Liu,
  • Xiaomin Fang,
  • Tao Ding and
  • Yuanqing Xu

20 January 2023

Ammonium polyphosphate (APP) was successfully modified by a titanate coupling agent which was compounded with benzoxazine (BOZ) and melamine (ME) to become a new type of intumescent flame retardant (Ti-IFR). Ti-IFR and CaCO3 as synergists were utiliz...

  • Article
  • Open Access
1,785 Views
13 Pages

2 September 2024

The search for a straightforward method to obtain efficient, affordable, and long-lasting flame retardants with both desirable flame-retardant and mechanical properties for polyurethane (PU) composites remains a significant challenge. In this study,...

  • Article
  • Open Access
12 Citations
3,090 Views
14 Pages

5 March 2023

A unique hybridized intumescent flame retardant named reduced-graphene-oxide-modified ammonium polyphosphate (RGO-APP) was successfully synthesized via the simple hydrothermal method and reduced process. Then, the obtained RGO-APP was applied in epox...

  • Article
  • Open Access
30 Citations
6,252 Views
15 Pages

11 April 2019

The current study aims at comparatively investigating the effect of apparent density on flame retardancy, thermal degradation and combustion behaviors of rigid polyurethane foam (RPUF), RPUF/ expandable graphite (EG) and RPUF/ ammonium polyphosphate...

  • Article
  • Open Access
6 Citations
2,823 Views
12 Pages

23 May 2023

Developing flame-retarded styrene-acrylic emulsion (SAE) based damping composites is a challenging task because of their very high flammability. A promising approach is the synergistic combination of expandable graphite (EG) and ammonium polyphosphat...

  • Article
  • Open Access
20 Citations
5,905 Views
15 Pages

Fire Performance of Intumescent Waterborne Coatings with Encapsulated APP for Wood Constructions

  • Atif Hussain,
  • Véronic Landry,
  • Pierre Blanchet,
  • Doan-Trang Hoang and
  • Christian Dagenais

20 October 2021

In this work, intumescent coatings were prepared for protection of wood from fire. The fire-retardant chemical ammonium polyphosphate (APP) is known to have poor resistance to water and high humidity as it is hygroscopic in nature. To improve the wat...

  • Article
  • Open Access
1 Citations
1,184 Views
17 Pages

26 May 2025

To investigate the fire prevention and suppression characteristics of coal gangue slurry grouting in goafs and the enhanced regulatory mechanisms of additives, the slurry-forming performance of coal gangue slurry was tested. The effects of heating te...

  • Article
  • Open Access
26 Citations
6,223 Views
14 Pages

15 October 2020

The influence of basic components of intumescent paint on fire protection properties is studied. The resulting changes in properties are assessed by the intumescence coefficient and thermal analysis data. Influence of the binder polymer composition o...

  • Article
  • Open Access
646 Views
15 Pages

Development of a Novel Modified High-Modulus Asphalt Based on Waste Rubber Powder

  • Maowen Li,
  • Chao Pu,
  • Ping Zheng,
  • Waiti Litifu,
  • Zhe Ma and
  • Peng Yin

15 September 2025

This study developed a novel waste rubber powder modified high-modulus asphalt based on composite modification technology. The preparation process was determined by orthogonal tests, and the mechanical properties of modified high-modulus asphalt were...

  • Article
  • Open Access
20 Citations
3,307 Views
13 Pages

15 April 2022

The flame retardancy of layered double hydroxides (LDHs) correlates with their structure and dispersion in a polymeric matrix. To improve the flame retardant effectiveness of Mg-Al LDH in polyethylene (PE), 2-carboxy ethyl (phenyl) phosphinic acid (C...

  • Article
  • Open Access
9 Citations
4,532 Views
9 Pages

12 June 2021

Intumescent flame-retardant (IFR) coatings have been gaining more attention. The behaviors of intumescent char in IFR coatings play the most important role in its flame-retardant properties. However, the evolution of intumescent char throughout the w...

  • Article
  • Open Access
21 Citations
3,882 Views
17 Pages

11 March 2023

Intumescent flame retardants (IFR) are an excellent solution to the problem of easy combustion of polymers. Still, the negative effect of the addition of flame retardants is the decline of the mechanical properties of polymers. In this context, carbo...

  • Article
  • Open Access
19 Citations
4,635 Views
15 Pages

3 April 2019

An ammonium polyphosphate (APP) surface-modified by silane coupling agent was used as flame retardant in high-impact polystyrene (HIPS). A series of HIPS nanocomposites containing different mass fractions of APP (k-APP) surface-modified by silane cou...

  • Article
  • Open Access
1,722 Views
12 Pages

The Effect of Expanded Vermiculite on the Fire Resistance of Waterborne Acrylic Coatings

  • Sihong Jiang,
  • Jihu Wang,
  • Shaoguo Wen,
  • Kaimin Chen,
  • Jianlong Zhou,
  • Haopeng Wang and
  • Xuying Deng

15 August 2024

Due to their ability to prevent or slow the spread of fires, fire-retardant coatings are utilized as the main means of fire protection for steel structures, combining easy application and high economic efficiency. This study investigates the effects...

  • Article
  • Open Access
17 Citations
3,322 Views
14 Pages

Flame Retardancy and Thermal Behavior of an Unsaturated Polyester Modified with Kaolinite–Urea Intercalation Complexes

  • Lina Yue,
  • Junfei Li,
  • Xuan Zhou,
  • Yingjuan Sun,
  • Ming Gao,
  • Taohua Zhu,
  • Xiaoqian Zhang,
  • Teng Feng,
  • Zhanhong Shi and
  • Yongchun Liu

15 October 2020

Organic modified kaolinite-urea intercalation complex (KUIC) was prepared using dimethyl sulfoxide (DMSO) as the precursor of kaolinite intercalation. Its structure was characterized by Fourier transform infrared (FTIR) and X-ray diffraction (XRD). S...

  • Article
  • Open Access
3 Citations
1,847 Views
15 Pages

1 December 2022

Biodegradable polylactide (PLA) has been widely utilized in people’s daily lives. In order to improve the fire safety of PLA, ammonium polyphosphate (APP) was self-assembled onto the surface of serpentine Ni3Si2O5(OH)4 through the electrostatic...

  • Article
  • Open Access
23 Citations
5,716 Views
12 Pages

3 February 2019

A comparative study between graphene and modified graphene oxide (mGO) on the flame retardancy of graphite doped intumescent flame retardant (IFR) coatings is preliminarily investigated by cone calorimeter (CC), XRD, and SEM, with the final aim of cl...

  • Article
  • Open Access
50 Citations
5,518 Views
13 Pages

22 August 2018

Lignin can be a candidate as a charring agent applied in halogen-free flame retardant polymers, and incorporation of silicon and nitrogen elements in lignin can benefit to enhancing its thermal stability and charring ability. In the present work, whe...

  • Article
  • Open Access
24 Citations
5,215 Views
16 Pages

19 January 2020

In this study, water-soluble ammonium polyphosphate- (APP) and methyl trimethoxysilane (MTMS)-modified industrial bamboo residue (IBR)-derived holocellulose nanofibrils (HCNF/APP/MTMS) were used as the raw materials to prepare aerogels in a freeze-dr...

  • Article
  • Open Access
13 Citations
7,850 Views
11 Pages

9 September 2016

A new intumescent flame-retardants (IFR) system including the charing-foaming agent (CFA), ammonium polyphosphate (APP) and modified-layered double hydroxides (LDHs) with different transition metals (Ni, Co, Cu) were used in the ethylene vinyl acetat...

  • Article
  • Open Access
1,606 Views
12 Pages

28 February 2025

Stearic acid was used to modify the surface of a mixed flame-retardant powder consisting of aluminum hydroxide and ammonium polyphosphate by an uneven nucleation method, aiming to improve its dispersion in a vinyl resin matrix. This study investigate...

  • Communication
  • Open Access
7 Citations
2,292 Views
11 Pages

Synergistic Flame Retardancy of Phosphatized Sesbania Gum/Ammonium Polyphosphate on Polylactic Acid

  • Qing Zhang,
  • Huiyuan Liu,
  • Junxia Guan,
  • Xiaochun Yang and
  • Baojing Luo

25 July 2022

Phosphating sesbania gum (DESG) was obtained by modifying sesbania gum (SG) with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and endic anhydride (EA). The structure of DESG was determined using Fourier transform infrared (FTIR) spectros...

  • Article
  • Open Access
8 Citations
3,602 Views
21 Pages

The Recyclability of Fire-Retarded Biobased Polyamide 11 (PA11) Composites Reinforced with Basalt Fibers (BFs): The Influence of Reprocessing on Structure, Properties, and Fire Behavior

  • Mateusz Barczewski,
  • Aleksander Hejna,
  • Jacek Andrzejewski,
  • Joanna Aniśko,
  • Adam Piasecki,
  • Adrian Mróz,
  • Zaida Ortega,
  • Daria Rutkowska and
  • Kamila Sałasińska

The growing requirements regarding the safety of using polymers and their composites are related to the emergence of more effective, sustainable, and hazardous-limited fire retardants (FRs). Significant amounts of FRs are usually required to effectiv...

  • Article
  • Open Access
12 Citations
3,450 Views
20 Pages

Balanced Thermal Insulation, Flame-Retardant and Mechanical Properties of PU Foam Constructed via Cost-Effective EG/APP/SA Ternary Synergistic Modification

  • Hongfu Li,
  • Longtao Hou,
  • Yunpeng Liu,
  • Zhiyu Yao,
  • Lixing Liang,
  • Dangxin Tian,
  • Chunhui Liu,
  • Junqiang Xue,
  • Linshan Zhan and
  • Kangmin Niu
  • + 2 authors

25 January 2024

To address the challenge of balancing the mechanical, thermal insulation, and flame-retardant properties of building insulation materials, this study presented a facile approach to modify the rigid polyurethane foam composites (RPUFs) via commercial...

  • Article
  • Open Access
40 Citations
5,170 Views
23 Pages

Development of Bioepoxy Resin Microencapsulated Ammonium-Polyphosphate for Flame Retardancy of Polylactic Acid

  • Kata Decsov,
  • Katalin Bocz,
  • Beáta Szolnoki,
  • Serge Bourbigot,
  • Gaëlle Fontaine,
  • Dániel Vadas and
  • György Marosi

14 November 2019

Ammonium-polyphosphate (APP) was modified by microencapsulation with a bio-based sorbitol polyglycidyl ether (SPE)-type epoxy resin and used as a flame retardant additive in polylactic acid (PLA) matrix. The bioresin-encapsulated APP (MCAPP) particle...

  • Article
  • Open Access
29 Citations
3,556 Views
22 Pages

Burning Behaviour of Rigid Polyurethane Foams with Histidine and Modified Graphene Oxide

  • Kamila Sałasińska,
  • Milena Leszczyńska,
  • Maciej Celiński,
  • Paweł Kozikowski,
  • Krystian Kowiorski and
  • Ludwika Lipińska

3 March 2021

Since rigid polyurethane (PU) foams are one of the most effective thermal insulation materials with widespread application, it is an urgent requirement to improve its fire retardancy and reduce the smoke emission. The current work assessed the fire b...

  • Article
  • Open Access
14 Citations
4,432 Views
18 Pages

21 January 2022

Flame-retardant water-blown rigid polyurethane foams (RPUFs) modified by ammonium polyphosphate (APP) and diethyl ethylphosphonate (DEEP) were synthesized by a one-pot free-rising method. We performed scanning electron microscopy (SEM), compression s...

  • Article
  • Open Access
11 Citations
3,320 Views
17 Pages

Influence of Magnesium Aluminate Nanoparticles on Epoxy-Based Intumescent Flame Retardation Coating System

  • Hatem Abuhimd,
  • Tentu Nageswara Rao,
  • Jung-il Song,
  • Prashanthi Yarasani,
  • Faheem Ahmed,
  • Botsa Parvatamma,
  • Asma A. Alothman,
  • Murefah Mana AL-Anazy and
  • Ahmad A. Ifseisi

12 October 2020

Ethylenediamine modified ammonium polyphosphate (EDA-MAPP) and charring-foaming agents (CFA) were prepared using a simple chemical method and further used to make intumescent flame retardant coatings based on epoxy resin. The content of MAPP and CFA...

  • Article
  • Open Access
39 Citations
10,500 Views
17 Pages

Flame Retardancy of PA6 Using a Guanidine Sulfamate/Melamine Polyphosphate Mixture

  • Mathieu Coquelle,
  • Sophie Duquesne,
  • Mathilde Casetta,
  • Jun Sun,
  • Xiaoyu Gu,
  • Sheng Zhang and
  • Serge Bourbigot

13 February 2015

Polyamide 6 (PA6) is a widely-used polymer that could find applications in various sectors, including home textiles, transportation or construction. However, due to its organic nature, PA6 is flammable, and flame-retardant formulations have to be dev...

  • Article
  • Open Access
17 Citations
3,740 Views
11 Pages

Preparation of High-Efficiency Flame-Retardant and Superhydrophobic Cotton Fabric by a Multi-Step Dipping

  • Jingda Huang,
  • Mengmeng Li,
  • Changying Ren,
  • Wentao Huang,
  • Qiang Wu,
  • Qian Li,
  • Wenbiao Zhang and
  • Siqun Wang

22 September 2021

Cotton fabric, as an important material, is suffering from some defects such as flammability, easy pollution and so on; therefore, it is important to make a flame-retardant and superhydrophobic modification on cotton fabric. In this study, we demonst...

  • Article
  • Open Access
3 Citations
1,367 Views
15 Pages

20 June 2025

The global market for flame-retardant materials is expected to grow steadily, from USD 7.0 billion in 2022 to USD 16.6 billion in 2030, driven by increasing demand for environment-friendly fire safety solutions in transportation, construction, and el...

  • Article
  • Open Access
4 Citations
2,808 Views
14 Pages

30 October 2020

In order to investigate an influence of the B:Zn:H2O molar ratio on the fire protection efficiency of poly(vinyl acetate)-based thermoplastic intumescent coating materials (ICs), systems containing ammonium polyphosphate, melamine, pentaerythritol an...

  • Article
  • Open Access
6 Citations
2,480 Views
21 Pages

7 February 2024

Multifunctional road marking coatings with the functions of high-temperature stability, degradation of exhaust gas, and self-cleaning are of great significance for the safe operation and environmental protection of tunnels. This article uses active a...

  • Article
  • Open Access
14 Citations
3,260 Views
17 Pages

6 December 2022

Flame retardancy properties of neat PLA can be improved with different phosphorus-based flame retardants (FRs), however, developing flame retardant PLA-based engineering composites with maintained mechanical performance is still a challenge. This stu...

  • Article
  • Open Access
368 Views
14 Pages

11 December 2025

The present work deals with the preparation and characterization of fire-retardant acrylonitrile–butadiene–styrene (ABS) foams incorporating 25 wt% of a phosphorus flame-retardant (PFR) system formed by 50% of ammonium polyphosphate (APP)...

  • Article
  • Open Access
24 Citations
3,084 Views
10 Pages

8 October 2019

CaMgAl-layered double hydroxides (CaMgAl-LDHs) were synthesized by a co-precipitation method to prepare sodium oleate-modified, borate-intercalated CaMgAl-LDHs (O-CaMgAl-LDHs) using in-situ intercalation and modification, and the LDHs samples were ch...