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Batteries, Volume 9, Issue 4

2023 April - 46 articles

Cover Story: With increasing commercial applications of vanadium flow batteries (VFB), containerised VFB systems are gaining attention as they can be mass produced and easily transported and configured for different energy storage applications. However, there are limited studies on the thermodynamic modelling of containerised vanadium redox flow battery systems and thermal control designs. In this paper, a dynamic thermal model is developed for containerised VFB systems, based on which thermal design options are evaluated using simulation studies. View this paper
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Articles (46)

  • Article
  • Open Access
5 Citations
5,057 Views
11 Pages

This study develops a composite cathode material suitable for solid-state Li-ion batteries (SSLIB). The composite cathode consists of LiFePO4 as the active material, Super P and KS-4 carbon materials as the conductive agents, and LiTFSI as the lithiu...

  • Review
  • Open Access
35 Citations
9,373 Views
25 Pages

Nb2CTx is an important member of MXene family. It has attracted widespread attention because of its abundant functional groups, high hydrophilicity, high electrical conductivity as well as low ion transport barrier, showing great potential in various...

  • Article
  • Open Access
5 Citations
4,890 Views
22 Pages

Pyrrolidinium-based (Pyr) ionic liquids (ILs) have been proposed as electrolyte components in lithium-ion batteries (LiBs), mainly due to their higher electrochemical stability and wider electrochemical window. Since they are not naturally electroact...

  • Article
  • Open Access
17 Citations
3,977 Views
14 Pages

Mechanical internal short circuit (ISC) is one of the significant safety issues in lithium-ion battery design. As a result, it is possible to subject LIB cells to thorough mechanical abuse tests to determine when and why failure may occur. The indent...

  • Article
  • Open Access
38 Citations
10,658 Views
13 Pages

This study aimed at a quantitative analysis of the material flows associated with End of Life (EoL) lithium-ion batteries’ (LIBs) materials in Europe. The European electric vehicles fleet in 2020 was taken as a case study, assuming a 10-year li...

  • Article
  • Open Access
11 Citations
4,648 Views
13 Pages

The aging behavior of lithium-ion batteries is crucial for the development of electric vehicles and many other battery-powered devices. The cells can be generally classified into two types: high-energy (HE) and high-power (HP) cells. The cell type us...

  • Article
  • Open Access
17 Citations
5,664 Views
16 Pages

Accelerated cyclic aging tests are very important for research and industry to quickly characterize lithium-ion cells. However, the accentuation of stress factors and the elimination of rest periods lead to an apparent capacity fade, that can be subs...

  • Article
  • Open Access
6 Citations
3,375 Views
22 Pages

Manganese, Fluorine, and Nitrogen Co-Doped Bronze Titanium Dioxide Nanotubes with Improved Lithium-Ion Storage Properties

  • Denis P. Opra,
  • Sergey L. Sinebryukhov,
  • Evgeny B. Modin,
  • Alexander A. Sokolov,
  • Anatoly B. Podgorbunsky,
  • Albert M. Ziatdinov,
  • Alexander Y. Ustinov,
  • Vitaly Y. Mayorov and
  • Sergey V. Gnedenkov

Because of the unique crystal framework, bronze TiO2 (or TiO2(B)) is considered the prospective choice for high-performance lithium-ion battery anodes. Nevertheless, TiO2(B) requires efficient modification, e.g., suitable doping with other elements,...

  • Review
  • Open Access
19 Citations
8,289 Views
12 Pages

Solid-state lithium batteries have attracted considerable research attention for their potential advantages over conventional liquid electrolyte lithium batteries. The discovery of lithium solid-state electrolytes (SSEs) is still undergoing to solve...

  • Article
  • Open Access
7 Citations
4,280 Views
11 Pages

Microstructure engineering of electrodes is one of the efficient routes to improve rate performance of lithium-ion batteries (LIBs). Currently, there is a lack of descriptors to rationally guide the regional electrode design. Here, we propose two des...

  • Review
  • Open Access
26 Citations
7,683 Views
18 Pages

Impact of Surface Structure on SEI for Carbon Materials in Alkali Ion Batteries: A Review

  • Xvtong Zhao,
  • Ying Chen,
  • Hao Sun,
  • Tao Yuan,
  • Yinyan Gong,
  • Xinjuan Liu and
  • Taiqiang Chen

Due to their low cost, suitable working potential and high stability, carbon materials have become an irreplaceable anode material for alkali ion batteries, such as lithium ion batteries, sodium ion batteries and potassium ion batteries. During the i...

  • Article
  • Open Access
2 Citations
2,717 Views
14 Pages

Battery Sharing: A Feasibility Analysis through Simulation

  • Mattia Neroni,
  • Erika M. Herrera,
  • Angel A. Juan,
  • Javier Panadero and
  • Majsa Ammouriova

Nowadays, several alternatives to internal combustion engines are being proposed in order to reduce CO2 emissions in freight transportation and citizen mobility. According to many experts, the use of electric vehicles constitutes one of the most prom...

  • Article
  • Open Access
21 Citations
2,994 Views
21 Pages

The accuracy of predicting the remaining useful life of lithium batteries directly affects the safe and reliable use of the supplied equipment. Since the degradation of lithium batteries can easily be influenced by different operating conditions and...

  • Review
  • Open Access
21 Citations
6,167 Views
34 Pages

Room-temperature sodium-sulfur batteries (RT-NaSBs) with high theoretical energy density and low cost are ideal candidates for next-generation stationary and large-scale energy storage. However, the dissolution of sodium polysulfide (NaPS) intermedia...

  • Article
  • Open Access
14 Citations
4,840 Views
14 Pages

Grain Boundary Characterization and Potential Percolation of the Solid Electrolyte LLZO

  • Shuo Fu,
  • Yulia Arinicheva,
  • Claas Hüter,
  • Martin Finsterbusch and
  • Robert Spatschek

The influence of different processing routes and grain size distributions on the character of the grain boundaries in Li7La3Zr2O12 (LLZO) and the potential influence on failure through formation of percolating lithium metal networks in the solid elec...

  • Review
  • Open Access
21 Citations
20,500 Views
19 Pages

An Overview of the Design and Optimized Operation of Vanadium Redox Flow Batteries for Durations in the Range of 4–24 Hours

  • Vilayanur V. Viswanathan,
  • Alasdair J. Crawford,
  • Edwin C. Thomsen,
  • Nimat Shamim,
  • Guosheng Li,
  • Qian Huang and
  • David M. Reed

An extensive review of modeling approaches used to simulate vanadium redox flow battery (VRFB) performance is conducted in this study. Material development is reviewed, and opportunities for additional development identified. Various crossover mechan...

  • Article
  • Open Access
12 Citations
7,151 Views
21 Pages

Liquid cooling strategies such as cold plates have been widely employed as an effective approach for battery thermal management systems (BTMS) due to their high cooling capacity and low power consumption. The structural design of the cold plates is t...

  • Article
  • Open Access
18 Citations
4,295 Views
16 Pages

The joint optimization of power systems, mobile energy storage systems (MESSs), and renewable energy involves complex constraints and numerous decision variables, and it is difficult to achieve optimization quickly through the use of commercial solve...

  • Article
  • Open Access
29 Citations
11,454 Views
18 Pages

Experimental Investigation on Reversible Swelling Mechanisms of Lithium-Ion Batteries under a Varying Preload Force

  • Emanuele Michelini,
  • Patrick Höschele,
  • Simon Franz Heindl,
  • Simon Erker and
  • Christian Ellersdorfer

The safety of lithium-ion batteries has to be guaranteed over the complete lifetime considering geometry changes caused by reversible and irreversible swellings and degradation mechanisms. An understanding of the pressure distribution and gradients i...

  • Article
  • Open Access
9 Citations
3,638 Views
25 Pages

Degradation-Conscious Multiobjective Optimal Control of Reconfigurable Li-Ion Battery Energy Storage Systems

  • Dulmini Karunathilake,
  • Mahinda Vilathgamuwa,
  • Yateendra Mishra,
  • Paul Corry,
  • Troy Farrell and
  • San Shing Choi

Lithium-ion battery energy storage systems are made from sets of battery packs that are connected in series and parallel combinations depending on the application’s needs for power. To achieve optimal control, advanced battery management system...

  • Article
  • Open Access
2,555 Views
12 Pages

The label-less characteristics of real vehicle data make engineering modeling and capacity identification of lithium-ion batteries face great challenges. Different from ideal laboratory data, the raw data collected from vehicle driving cycles have a...

  • Feature Paper
  • Review
  • Open Access
7 Citations
4,552 Views
13 Pages

Modeling and Simulation of Non-Aqueous Redox Flow Batteries: A Mini-Review

  • Haotian Zhou,
  • Ruiping Zhang,
  • Qiang Ma,
  • Zhuo Li,
  • Huaneng Su,
  • Ping Lu,
  • Weiwei Yang and
  • Qian Xu

Redox flow batteries (RFBs) have been widely recognized in the domain of large-scale energy storage due to their simple structure, long lifetime, quick response, decoupling of capacity and power, and structural simplicity. Because of the limited open...

  • Article
  • Open Access
1 Citations
3,337 Views
15 Pages

All autonomous electrically powered devices require a continuous power supply from batteries. Increasing the discharge performance is the top priority in the Lithium-Ion (Li-Ion) battery field and pulsed discharge is proving numerous advantages. In t...

  • Article
  • Open Access
4 Citations
3,063 Views
13 Pages

Carbon materials, such as graphite and activated carbon, have been widely used as electrodes in batteries and electric double-layer capacitors (EDLCs). Graphene, which has an extremely thin sheet-like structure, is considered as a fundamental carbon...

  • Article
  • Open Access
17 Citations
2,723 Views
21 Pages

Fractional-Order Sliding-Mode Observers for the Estimation of State-of-Charge and State-of-Health of Lithium Batteries

  • Minghao Zhou,
  • Kemeng Wei,
  • Xiaogang Wu,
  • Ling Weng,
  • Hongyu Su,
  • Dong Wang,
  • Yuanke Zhang and
  • Jialin Li

Lithium batteries are widely used in power storage and new energy vehicles due to their high energy density and long cycle life. The accurate and real-time estimation for the state-of-charge (SoC) and the state-of-health (SoH) of lithium batteries is...

  • Review
  • Open Access
52 Citations
12,492 Views
29 Pages

Hybrid Energy Storage Systems Based on Redox-Flow Batteries: Recent Developments, Challenges, and Future Perspectives

  • Christina Schubert,
  • Wiem Fekih Hassen,
  • Barbara Poisl,
  • Stephanie Seitz,
  • Jonathan Schubert,
  • Estanis Oyarbide Usabiaga,
  • Pilar Molina Gaudo and
  • Karl-Heinz Pettinger

Recently, the appeal of Hybrid Energy Storage Systems (HESSs) has been growing in multiple application fields, such as charging stations, grid services, and microgrids. HESSs consist of an integration of two or more single Energy Storage Systems (ESS...

  • Article
  • Open Access
7 Citations
3,751 Views
16 Pages

Evaluation of Glyoxal-Based Electrolytes for Lithium-Sulfur Batteries

  • Sebastian Kirchhoff,
  • Christian Leibing,
  • Paul Härtel,
  • Thomas Abendroth,
  • Susanne Dörfler,
  • Holger Althues,
  • Stefan Kaskel and
  • Andrea Balducci

Lithium-sulfur batteries (LSBs) are among the most promising next generation battery technologies. First prototype cells show higher specific energies than conventional Li-ion batteries (LIBs) and the active material is cost-effective and ubiquitousl...

  • Article
  • Open Access
10 Citations
4,081 Views
19 Pages

A High-Performance Vortex Adjustment Design for an Air-Cooling Battery Thermal Management System in Electric Vehicles

  • Gang Zhao,
  • Xiaolin Wang,
  • Michael Negnevitsky,
  • Chengjiang Li,
  • Hengyun Zhang and
  • Yingyao Cheng

To boost the performance of the air-cooling battery thermal management system, this study designed a novel vortex adjustment structure for the conventional air-cooling battery pack used in electric vehicles. T-shape vortex generating columns were pro...

  • Article
  • Open Access
2 Citations
2,550 Views
12 Pages

Chemo-Mechanical Coupling Measurement of LiMn2O4 Composite Electrode during Electrochemical Cycling

  • Huijie Yu,
  • Jiangtao Li,
  • Hainan Jiang,
  • Wei Li,
  • Guorui Li and
  • Dawei Li

Real-time monitoring of the mechanical behavior of cathode materials during the electrochemical cycle can help obtain an in-depth understanding of the working mechanism of lithium-ion batteries. The LiMn2O4 composite electrode is employed as the work...

  • Feature Paper
  • Article
  • Open Access
13 Citations
4,344 Views
14 Pages

With the development trend and technological progress of lithium batteries, the battery market is booming. This means that the demand for lithium batteries has increased significantly, resulting in a large number of discarded lithium batteries. The c...

  • Article
  • Open Access
12 Citations
6,107 Views
15 Pages

Experimental Investigation for the Phase Change Material Barrier Area Effect on the Thermal Runaway Propagation Prevention of Cell-to-Pack Batteries

  • Kai Shen,
  • Jieyu Sun,
  • Chengshan Xu,
  • Shaw Kang WONG,
  • Yuejiu Zheng,
  • Changyong Jin,
  • Huaibin Wang,
  • Siqi Chen and
  • Xuning Feng

Thermal runaway propagation (TRP) is a primary safety issue in lithium-ion battery (LIB) applications, and the use of a thermal barrier is considered to be a promising solution for TRP prevention. However, the operating conditions of the battery are...

  • Article
  • Open Access
2 Citations
2,246 Views
10 Pages

Metal-oxygen batteries (especially Li-O2 battery) with ultrahigh theoretical energy density are of great promise for long-range vehicle electrification. However, the limited enduring stability and low-rate property further restricted the large-scale...

  • Article
  • Open Access
10 Citations
5,931 Views
20 Pages

In this paper, the thermal management of a battery module with a novel liquid-cooled shell structure is investigated under high charge/discharge rates and thermal runaway conditions. The module consists of 4 × 5 cylindrical batteries embedded in a li...

  • Review
  • Open Access
14 Citations
5,228 Views
19 Pages

Advances in Cathodes for High-Performance Magnesium-Sulfur Batteries: A Critical Review

  • Ying Ying Yao,
  • Yang Zhan,
  • Xin Yu Sun,
  • Zhao Li,
  • Hao Xu,
  • Richard M. Laine and
  • Jian Xin Zou

Large-scale energy storage with high performance and at a reasonable cost are prerequisites for promoting clean energy utilization. With a high theoretical energy density of 1722 Wh·kg−2, high element abundance (e.g., Mg of 23,000 ppm, S...

  • Review
  • Open Access
200 Citations
36,673 Views
45 Pages

The enormous demand for energy due to rapid technological developments pushes mankind to the limits in the exploration of high-performance energy devices. Among the two major energy storage devices (capacitors and batteries), electrochemical capacito...

  • Article
  • Open Access
7 Citations
3,417 Views
16 Pages

Preparation of Electrospun Membranes and Their Use as Separators in Lithium Batteries

  • Mariasole Di Carli,
  • Annalisa Aurora,
  • Antonio Rinaldi,
  • Noemi Fiaschini and
  • Pier Paolo Prosini

In this work, electrospun nanofiber membranes are investigated as separators for lithium batteries. Membrane consisting of polyacrylonitrile-polycaprolactone mixtures were produced following a combinatorial approach inspired by design of experiments...

  • Article
  • Open Access
1 Citations
2,843 Views
18 Pages

Electrochemical Modelling of Na-MCl2 Battery Cells Based on an Expanded Approximation Method

  • Nils Büttner,
  • Foelke Purr,
  • Clara Sangrós Giménez,
  • Maria Richter,
  • Laura Nousch,
  • Sabrina Zellmer and
  • Alexander Michaelis

Battery models are mathematical systems that aim to simulate real battery cell sufficiently accurately. Finding a comprise between complexity, computational effort and accuracy is thereby key. In particular, modelling sodium–nickel–chlori...

  • Article
  • Open Access
16 Citations
3,931 Views
20 Pages

Tragacanth, an Exudate Gum as Suitable Aqueous Binder for High Voltage Cathode Material

  • Daniele Versaci,
  • Oana D. Apostu,
  • Davide Dessantis,
  • Julia Amici,
  • Carlotta Francia,
  • Marco Minella and
  • Silvia Bodoardo

The improvements in future-generation lithium-ion batteries cannot be exclusively focused on the performance. Other aspects, such as costs, processes, and environmental sustainability, must be considered. Research and development of new active materi...

  • Article
  • Open Access
5 Citations
4,160 Views
15 Pages

Energy storage systems are key to propelling the current renewable energy revolution. Accurate State-of-Charge estimation of the lithium-ion battery energy storage systems is a critical task to ensure their reliable operations. Multiple advanced batt...

  • Article
  • Open Access
30 Citations
4,079 Views
17 Pages

Off-Resonant Dicke Quantum Battery: Charging by Virtual Photons

  • Giulia Gemme,
  • Gian Marcello Andolina,
  • Francesco Maria Dimitri Pellegrino,
  • Maura Sassetti and
  • Dario Ferraro

We investigate a Dicke quantum battery in the dispersive regime, where the photons trapped in a resonant cavity are much more energetic with respect to the two-level systems embedded into it. Under such off-resonant conditions, even an empty cavity c...

  • Article
  • Open Access
7 Citations
3,354 Views
19 Pages

Thermal Modelling and Simulation Studies of Containerised Vanadium Flow Battery Systems

  • Bing Shu,
  • Logan S. Weber,
  • Maria Skyllas-Kazacos,
  • Jie Bao and
  • Ke Meng

With increasing commercial applications of vanadium flow batteries (VFB), containerised VFB systems are gaining attention as they can be mass produced and easily transported and configured for different energy storage applications. However, there are...

  • Article
  • Open Access
6 Citations
3,208 Views
19 Pages

The crash safety of lithium-ion traction batteries is a relevant concern for electric vehicles. Current passive safety strategies of traction batteries usually come at the cost of their volumetric or gravimetric energy density. This work analyses the...

  • Article
  • Open Access
8 Citations
3,751 Views
14 Pages

Interface Engineering of a NASICON-Type Electrolyte Using Ultrathin CuS Film for Lithium Metal Batteries

  • Shengnan Zhang,
  • Dongming Liu,
  • Lin Zhang,
  • Jianwei Li,
  • Guoqing Zhao,
  • Lijie Ci and
  • Guanghui Min

NASICON-type Li1.5Al0.5Ge1.5(PO4)3 (LAGP) is a remarkable solid-state electrolyte due to its high ionic conductivity and excellent air stability. However, the weak LAGP|Li interfacial compatibility (e.g., chemical instability of LAGP with Li metal an...

  • Review
  • Open Access
69 Citations
39,299 Views
41 Pages

Among the current battery technologies, lithium-ion batteries (LIBs) are essential in shaping future energy landscapes in stationary storage and e-mobility. Among all components, choosing active cathode material (CAM) limits a cell’s available...

  • Article
  • Open Access
17 Citations
9,720 Views
14 Pages

Optimisation of Industrially Relevant Electrode Formulations for LFP Cathodes in Lithium Ion Cells

  • Geanina Apachitei,
  • Marc Hidalgo,
  • Daniela Dogaru,
  • Michael Lain,
  • Robert Heymer,
  • James Marco and
  • Mark Copley

The electrode formulation has a significant effect on the performance of lithium ion cells. The active material, binder, and conductive carbon all have different roles, and finding the optimum composition can be difficult using an iterative approach....

  • Article
  • Open Access
11 Citations
4,379 Views
25 Pages

Battery state of power (SOP) estimation is an important parameter index for electric vehicles to improve battery utilization efficiency and maximize battery safety. Most of the current studies on the SOP estimation of lithium–ion batteries cons...

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Batteries - ISSN 2313-0105