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Inorganics, Volume 13, Issue 8

2025 August - 27 articles

Cover Story: Our study evaluates three deposition methods—RF sputtering, spin-coating, and chemical bath deposition—to find the optimal approach for a uniform, pinhole-free TiO2 blocking layer. Our work provides a comparative analysis of the morphological, optical, and electrochemical properties of the obtained layers. By combining analyses of current density, charge transfer resistance, and surface potential distribution, we can determine with high certainty if a film is homogeneously covered or contains pinholes. Proposed examination is to be performed prior to full device fabrication for reducing material waste and minimizing environmental impact. The suggested approach was confirmed by fabrication and determination of the relevant parameters of DSSC. View this paper
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Articles (27)

  • Feature Paper
  • Review
  • Open Access
4,251 Views
19 Pages

Development of Catalysts for the Electrochemical CO2 Reduction Reaction

  • Lucija Josipovic,
  • Deema Alyones,
  • Shawn Roybal,
  • Quanwen Sun,
  • Yuhuan Fei,
  • Meng Zhou and
  • Hongmei Luo

The electrochemical reduction of CO2 (eCO2RR) has emerged as a promising route for carbon-neutral fuel and chemical production, offering a sustainable alternative to fossil-based processes. This article begins with an overview of conventional CO2 con...

  • Article
  • Open Access
1,371 Views
16 Pages

The recovery and control of volatile organic compounds (VOCs) have gained significant attention. Supported sulfonic acid materials show potential in converting aromatic VOCs into non-volatile sulfonic acid derivatives. However, their effectiveness is...

  • Review
  • Open Access
1,132 Views
20 Pages

Mono-Cyclopentadienyl Titanium and Rare-Earth Metal Catalysts for Syndiospecific Polymerization of Styrene and Its Derivatives

  • Junsong Wang,
  • Mingming Bai,
  • Wenyan Wang,
  • Handou Zheng,
  • Chunyu Feng,
  • Jiayue Gu,
  • Guoliang Mao and
  • Haiyang Gao

Syndiotactic polystyrene (sPS) is an important class of engineering plastics, primarily produced through metal-catalyzed highly stereoselective polymerization of styrene monomer. This paper summarizes the advances in metal catalysts for syndiospecifi...

  • Article
  • Open Access
1 Citations
1,006 Views
27 Pages

To exploit the near-infrared (NIR) light of MoO3, the MoVOx mixed oxide was synthesized using a one-pot approach. The effects of different electrodes, V doping, and bias on the optoelectronic properties were investigated. The photoelectric responses...

  • Article
  • Open Access
1,135 Views
14 Pages

A Rapid and Low-Cost Synthesis of ZSM-5 Single Crystals: The Inhibitory Effect of NH4F on Twinning

  • Juan Du,
  • Xiang Wan,
  • Caixiong Song,
  • Kangsheng Wu,
  • Wenbing Yang,
  • Beiye Liu,
  • Qi Yang,
  • Jingjing Fang and
  • Ayesha Razzaq

Crystal twinning, a common growth phenomenon, can substantially affect material performance in fields such as semiconductors, nonlinear optics, and drug development, yet its elimination during crystallization is challenging. This study presents a met...

  • Article
  • Open Access
1,285 Views
34 Pages

The present study reports the sono-chemical synthesis of novel nanosized Cr(III), Mn(II), and Pd(II) complexes incorporating the chloro-2-(quinolin-8-yliminomethyl)-phenol imine ligand. The synthesized complexes were characterized using various spect...

  • Article
  • Open Access
1 Citations
1,514 Views
27 Pages

The Comprehensive Study of TiO2 Blocking Layer with Complementary Electrochemical and SPM Methods for the Application in Photovoltaics

  • Evgenija Milinković,
  • Katarina Cvetanović,
  • Marko V. Bošković,
  • Nastasija Conić,
  • Vladislav Jovanov,
  • Dragomir Stanisavljev and
  • Dana Vasiljević-Radović

The blocking layer is crucial for inhibiting recombination processes in photovoltaics that utilize oxide semiconductors, such as dye-sensitized solar cells (DSSCs), quantum-dot-sensitized solar cells (QDSSCs), and perovskite solar cells. However, its...

  • Article
  • Open Access
1,177 Views
16 Pages

The Influences of π-Conjugated Aliphatic Chains in Ionic Liquids of Antimony Pentachloride with Pyridine Imidazolium Hybrid Salts: A DFT Study

  • Manuel Luque-Román,
  • Jesús Baldenebro-López,
  • José J. Campos-Gaxiola,
  • Adriana Cruz-Enríquez,
  • Carlos A. Peñuelas,
  • Alberto Báez-Castro,
  • Rody Soto-Rojo,
  • Tomás Delgado-Montiel,
  • Samuel Soto-Acosta and
  • Daniel Glossman-Mitnik

A theoretical study was performed using Density Functional Theory (DFT) to investigate the impact of π-conjugated aliphatic chain growth on the chemical and electronic properties of hybrid antimony pentachloride salts with pyridine- and imidazoliu...

  • Review
  • Open Access
2 Citations
2,470 Views
25 Pages

Advances in Synthesis and Applications of Bismuth Vanadate-Based Structures

  • Dragana Marinković,
  • Giancarlo C. Righini and
  • Maurizio Ferrari

In recent years, researchers have made great efforts to develop effective semiconductor photocatalysts to harness the visible spectrum of sunlight in photocatalytic applications. Bismuth vanadate, BiVO4, has emerged as one of the most promising candi...

  • Article
  • Open Access
1 Citations
1,475 Views
18 Pages

Antimicrobial Activity of Ethyl (2-(Methylcarbamoyl)phenyl)carbamate and Its Mixed Ligand Ni(II) and Co(II) Complexes

  • Slava Tsoneva,
  • Miglena Milusheva,
  • Nikola Burdzhiev,
  • Petya Marinova,
  • Evelina Varbanova,
  • Yulian Tumbarski,
  • Rositsa Mihaylova,
  • Emiliya Cherneva and
  • Stoyanka Nikolova

The aim of this paper is to obtain ethyl (2-(methylcarbamoyl)phenyl)carbamate and its metal complexes as promising antimicrobial agents. The title compound was synthesized using the ring-opening of isatoic anhydride with methylamine and further acyla...

  • Article
  • Open Access
947 Views
9 Pages

Two-dimensional (2D) organic−inorganic hybrid perovskites (OIHPs) have emerged as promising candidates for next-generation optoelectronic applications. While vertical heterostructures of 2D OIHPs have been explored through mechanical stacking,...

  • Article
  • Open Access
1,260 Views
16 Pages

A series of Zn complexes containing guanidine– and amidine–phenolate ligands were synthesized and evaluated as catalysts for the polymerization of rac-lactide at 130 °C, under solvent-free conditions, giving rate constants in the rang...

  • Article
  • Open Access
1 Citations
1,257 Views
11 Pages

Pressure Effects on Structure and Optical Properties in Sn(II)-Doped Cs2ZnCl4 All-Inorganic Zero-Dimensional Halide Perovskite

  • Ting Geng,
  • Mengqing Wang,
  • Yuhan Qin,
  • Zhuo Chen,
  • Ao Zhang,
  • Chunmei Zhang,
  • Yongguang Li and
  • Guanjun Xiao

The toxicity of lead in conventional perovskites and their inherent chemical instability impede the commercialization of perovskite-based optoelectronics. Therefore, it is vital to develop chemically stable and environmentally friendly Pb-free altern...

  • Article
  • Open Access
911 Views
15 Pages

The interaction of manganese(II) with deprotonated 3,5–dibromo–salicylaldehyde (3,5–diBr–saloH) in the absence or the presence of the N,N′-donors 2,2′–bipyridylamine (bipyam), 2,2′–bipyridine (bip...

  • Article
  • Open Access
1,125 Views
20 Pages

The development of efficient photocatalytic materials for waterborne pathogen inactivation and self-cleaning surfaces in biomedical applications remains a critical challenge due to the rising prevalence of antimicrobial-resistant bacteria. This study...

  • Article
  • Open Access
1 Citations
2,422 Views
13 Pages

Mg-Doped O3-Na[Ni0.6Fe0.25Mn0.15]O2 Cathode for Long-Cycle-Life Na-Ion Batteries

  • Zebin Song,
  • Hao Zhou,
  • Yin Zhang,
  • Haining Ji,
  • Liping Wang,
  • Xiaobin Niu and
  • Jian Gao

The O3-type layered oxide materials have the advantage of high specific capacity, which makes them more competitive in the practical application of cathode materials for sodium-ion batteries (SIBs). However, the existing reported O3-type layered oxid...

  • Review
  • Open Access
1 Citations
2,272 Views
27 Pages

An Insight into the Disease Prognostic Potentials of Nanosensors

  • Nandu K. Mohanan,
  • Nandana S. Mohanan,
  • Surya Mol Sukumaran,
  • Thaikatt Madhusudhanan Dhanya,
  • Sneha S. Pillai,
  • Pradeep Kumar Rajan and
  • Saumya S. Pillai

Growing interest in the future applications of nanotechnology in medicine has led to groundbreaking developments in nanosensors. Nanosensors are excellent platforms that provide reliable solutions for continuous monitoring and real-time detection of...

  • Article
  • Open Access
1 Citations
1,582 Views
12 Pages

Efficient Oxygen Evolution Reaction Performance Achieved by Tri-Doping Modification in Prussian Blue Analogs

  • Yanhong Ding,
  • Bin Liu,
  • Haiyan Xiang,
  • Fangqi Ren,
  • Tianzi Xu,
  • Jiayi Liu,
  • Haifeng Xu,
  • Hanzhou Ding,
  • Yirong Zhu and
  • Fusheng Liu

The high cost of hydrogen production is the primary factor limiting the development of the hydrogen energy industry chain. Additionally, due to the inefficiency of hydrogen production by water electrolysis technology, the development of high-performa...

  • Article
  • Open Access
1,069 Views
12 Pages

Lanthanide rare earth elements possess significant promise for material applications owing to their distinctive optical and magnetic characteristics, as well as their versatile coordination capabilities. This study introduced a lanthanide-functionali...

  • Review
  • Open Access
5 Citations
4,159 Views
13 Pages

Recent Progress of Carbon Dots in Fluorescence Sensing

  • Xiao-Tian Lou,
  • Lei Zhan and
  • Bin-Bin Chen

Carbon dots (CDs) have attracted much attention as new types of luminescent carbon nanomaterials in recent years because of their tunable fluorescence, good biocompatibility, high stability, and low cost. In this review, the classification of CDs is...

  • Article
  • Open Access
1,046 Views
19 Pages

The highly fluorescent fluorene group is of interest for its unique optical and electronic properties. By incorporating it into a metal complex, these properties are extended to the complex and are useful in a number of different applications. Four &...

  • Article
  • Open Access
1 Citations
1,466 Views
15 Pages

A Missing Member of the Anderson–Evans Family: Synthesis and Characterization of the Trimethylolmethane-Capped {MnMo6O24} Cluster

  • Andreas Winter,
  • Patrick Endres,
  • Nishi Singh,
  • Nils E. Schlörer,
  • Helmar Görls,
  • Stephan Kupfer and
  • Ulrich S. Schubert

In this work, the synthesis and structural characterization of the smallest possible member of the family of bis-functionalized {MnMo6O24} Anderson–Evans polyoxometalates (POMs) is reported. The synthesis of the title compound TBA3{[HC(CH2O)3]2...

  • Article
  • Open Access
1,445 Views
19 Pages

Structural, Quantum Chemical, and Cytotoxicity Analysis of Acetylplatinum(II) Complexes with PASO2 and DAPTA Ligands

  • Stefan Richter,
  • Dušan Dimić,
  • Milena R. Kaluđerović,
  • Fabian Mohr and
  • Goran N. Kaluđerović

The development of novel platinum-based anticancer agents remains a critical objective in medicinal inorganic chemistry, particularly in light of resistance and toxicity limitations associated with cisplatin. In this study, the synthesis, structural...

  • Article
  • Open Access
4 Citations
1,629 Views
22 Pages

Synthesis, Structural Characterization, and In Silico Antiviral Prediction of Novel DyIII-, YIII-, and EuIII-Pyridoxal Helicates

  • Francisco Mainardi Martins,
  • Yuri Clemente Andrade Sokolovicz,
  • Morgana Maciél Oliveira,
  • Carlos Serpa,
  • Otávio Augusto Chaves and
  • Davi Fernando Back

The synthesis and structural characterization of three new triple-stranded helical complexes ([Dy2(L2)3]2Cl∙15H2O (C1), [Y2(L2)3]3(NO3)Cl∙14H2O∙DMSO (C2), and [Eu2(L4)3]∙12H2O (C3), where L2 and L4 are ligands derived from pyr...

  • Article
  • Open Access
1,759 Views
12 Pages

Ultrahigh Water Permeance of a Reduced Graphene Oxide Membrane for Separation of Dyes in Wastewater

  • Chengju Wu,
  • Shouyuan Hu,
  • Shoupeng Li,
  • Hangxiang Zhuge,
  • Liuhua Mu,
  • Jie Jiang,
  • Pei Li and
  • Liang Chen

Membrane separation technology has shown significant potential in the treatment of mixed dye wastewater. In this study, a reduced graphene oxide (AH-rGO) membrane was prepared using an amino-hydrothermal method and applied for the first time in mixed...

  • Review
  • Open Access
3 Citations
2,216 Views
40 Pages

Metal Complexes with Hydroxyflavones: A Study of Anticancer and Antimicrobial Activities

  • Ljiljana E. Mihajlović,
  • Monica Trif and
  • Marijana B. Živković

Metal chelation to bioactive small molecules is a well-established strategy to enhance the biological activity of the resulting complexes. Among the widely explored structural motifs, the combination of prominent metal centers with naturally inspired...

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Inorganics - ISSN 2304-6740