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Inorganics

Inorganics is an international, peer-reviewed, open access journal on inorganic chemistry, published monthly online by MDPI.

Quartile Ranking JCR - Q2 (Chemistry, Inorganic and Nuclear)

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All Articles (2,240)

Development of Modified Zeolites for Methane Separation from Diluted Streams

  • Giulia De Felice,
  • Devi Rejendran and
  • Fausto Gallucci
  • + 2 authors

Methane (CH4) is the second-largest contributor to climate change after carbon dioxide (CO2) and has a global warming potential about 72 times greater than CO2 over a 20-year timescale. A possible solution to mitigate CH4 emissions from diluted sources is direct removal of CH4 through tailored sorbents. In this work, ion-exchanged zeolites have been investigated, owing to their low cost, excellent chemical stability, and ease of production. The impact of barium, lithium, and nickel exchange was investigated, along with one, three, and five ion-exchange sequences. XRD analysis confirmed that the structure remained intact after ion exchange. However, nitrogen physisorption revealed that nickel- and barium-exchanged zeolites had reduced pore volume and surface area compared to the parent zeolite, possibly due to mesopore formation from lattice strain relaxation. ICP-OES and SEM-EDX confirmed the successful incorporation of metals into the zeolite. Finally, breakthrough experiments were carried out to assess the saturation capacity of the synthesized sample. The results demonstrated that the lithium-exchanged samples provided the highest saturation capacity, namely 1.58 ± 0.05 mmol g−1 for the Li-13X-3 and 1.76 ± 0.07 mmol g−1 for the Li-SAPO34-5 over 10 adsorption cycles. Furthermore, the stability of the Li-SAPO34-5 was confirmed over 100 adsorption cycles.

12 March 2026

TGA results for (a) Ba-13X-1, (b) Li-13X-1, and (c) Ni-13X-1.

Electrodeposition of copper on the surface of the high-carbon steel (HCS) cathode was carried out in situ during the electrolysis of an aqueous KOH solution with a copper anode. A mechanism was proposed for the transfer of the copper from the anode to the cathode, followed by the formation of a copper film on the HCS. The surface roughness of the substrate and the copper coating was studied using AFM and profilographic data. There is a discrepancy between the roughness values of the substrate and coating obtained using different techniques. The surface morphology of the substrate was found to affect the copper film quality. The roughness of the copper coating calculated using AFM data replicated the roughness of the substrate surface. It was found that, despite some difference in the roughness calculated by profilographic and AFM data, the overall roughness trend remains unchanged.

11 March 2026

2D and 3D AFM images ((a) and (b), respectively) of the high-carbon steel surface after polishing by P600 sandpaper (<Ra1> is 44 nm) and 2D and 3D AFM images ((c) and (d), respectively) of the surface of copper coating on the substrate (<Ra2> is 66 nm) (AFM scanning range is 100 μm × 100 μm).
  • Correction
  • Open Access

In the original publication [...]

9 March 2026

SEM micrographics of the CoMo-Ni/Al2O3-K2O(x) catalysts. (a) CoMo-Ni/Al2O3-K2O(0), (b) CoMo-Ni/Al2O3-K2O(1), (c) CoMo-Ni/Al2O3-K2O(3), and (d) CoMo-Ni/Al2O3-K2O(5).

Synergistic Enhancement of Structural and Thermal Properties in Samaria-Doped Zirconia (ZrO2-Sm2O3)

  • Cristina Florentina Ciobota,
  • Florentina-Gabriela Ioniță and
  • Dragos-Florin Marcu
  • + 6 authors

The study investigates the structural and thermal properties of zirconia ceramics doped with Sm2O3. The powders were prepared via a mild hydrothermal synthesis route at a temperature of 200 °C, for 2 h with a pressure of 60–100 atm, starting from ZrO2-Sm2O3 compositions. Structural and physicochemical characterization was performed using XRD, SEM-EDAX, BET and FT-IR analyses after synthesis and subsequent heat treatments up to 1500 °C. The results indicate good thermal stability of the materials, while a single cubic phase is achieved after calcination at 1500 °C. The ceramics show low thermal conductivity (0.41 W·m−1·K−1), reduced heat capacity (0.26 J·g−1·K−1), and low thermal diffusivity (0.34 mm2·s−1), with all measured parameters lower than those commonly reported for conventional rare-earth-stabilized zirconia.

6 March 2026

X-ray diffractograms of ZrO2-Sm2O3.

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Inorganics - ISSN 2304-6740