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Inorganics, Volume 11, Issue 3

2023 March - 46 articles

Cover Story: Tetrylidyne complexes are compounds featuring a triple bond between a transition metal and the tetrels Si – Pb. They bear great synthetic potential in organoelement chemistry due to the highly reactive, polar M≡E bond. Following our earlier experimental work on cationic Group 10 tetrylidyne complexes, we provide in the present study a detailed insight into the electronic structure of the complex cations [(PMe3)3MER]+ (M = Ni, Pd, Pt; E = C, Si, Ge, Sn, Pb; R = ArMes, Tbb (Si)), utilizing a comprehensive quantum-chemical toolset that includes the Pipek–Mezey orbital localization method, the energy decomposition analysis (EDA), and the extended-transition state method with natural orbitals of chemical valence (ETS-NOCV). View this paper
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Articles (46)

  • Article
  • Open Access
3 Citations
3,462 Views
13 Pages
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A New 1D Ni (II) Coordination Polymer of s-Triazine Type Ligand and Thiocyanate as Linker via Unexpected Hydrolysis of 2,4-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine

  • Kholood A. Dahlous,
  • Saied M. Soliman,
  • Matti Haukka,
  • Ayman El-Faham and
  • Raghdaa A. Massoud
Inorganics2023, 11(3), 135;https://doi.org/10.3390/inorganics11030135

22 March 2023

A new 1D Ni(II) coordination polymer was synthesized by the reaction of NiSO4·6H2O with 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine (BPT) and SCN− as a linker in an acidic medium by heating under reflux conditions. Unu...

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  • Article
  • Open Access
3 Citations
2,371 Views
12 Pages
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Multiferroics Made via Chemical Co-Precipitation That Is Synthesized and Characterized as Bi(1−x)CdxFeO3

  • Syed Zain Mehmood,
  • Mubashar Arshad,
  • Fahad M. Alharbi,
  • Sayed M. Eldin and
  • Ahmed M. Galal
Inorganics2023, 11(3), 134;https://doi.org/10.3390/inorganics11030134

21 March 2023

Cd-doped BiFeO3 powders, with varying doping concentrations of Cd (Bi(1−x)CdxFeO3, where x = 0–0.3), were prepared through a facile chemical co-precipitation method and calcinated at 550 °C in the air. The BiFeO3 has a rhombohedral cr...

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  • Article
  • Open Access
24 Citations
5,410 Views
17 Pages
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Photocatalytic Reduction of Cr(VI) to Cr(III) and Photocatalytic Degradation of Methylene Blue and Antifungal Activity of Ag/TiO2 Composites Synthesized via the Template Induced Route

  • Zunaira Zahid,
  • Abdul Rauf,
  • Mohsin Javed,
  • Ahmad Alhujaily,
  • Shahid Iqbal,
  • Adnan Amjad,
  • Muhammad Arif,
  • Sajjad Hussain,
  • Ali Bahadur and
  • Eslam B. Elkaeed
  • + 3 authors
Inorganics2023, 11(3), 133;https://doi.org/10.3390/inorganics11030133

21 March 2023

Water treatment through photocatalysts has become an important topic regarding environmental protection. In the present study, silver and TiO2 (Ag/TiO2) composites for photocatalysts were effectively synthesized by adopting the template induced metho...

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  • Article
  • Open Access
4 Citations
2,801 Views
21 Pages
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A Tridentate Cu(II) Complex with a 2-(4′-Aminophenyl)Benzothiazole Derivative: Crystal Structure and Biological Evaluation for Anticancer Activity

  • Barbara Mavroidi,
  • Marina Sagnou,
  • Eleftherios Halevas,
  • George Mitrikas,
  • Fotis Kapiris,
  • Penelope Bouziotis,
  • Antonios G. Hatzidimitriou,
  • Maria Pelecanou and
  • Constantinos Methenitis
Inorganics2023, 11(3), 132;https://doi.org/10.3390/inorganics11030132

20 March 2023

Herein, the synthesis, structural characterization and in vitro biological evaluation of a novel Cu(II) complex with the 2-(4-aminophenyl)benzothiazole pharmacophore conjugated with the (2-pyridinyl)methylamino chelating moiety is reported for the fi...

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  • Article
  • Open Access
12 Citations
2,420 Views
13 Pages
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Effectiveness of Artificially Synthesized Granitic Residual Soil-Supported Nano Zero-Valent Iron (Gr-nZVI) as Effective Heavy Metal Contaminant Adsorbent

  • Nur ‘Aishah Zarime,
  • Badariah Solemon,
  • Wan Zuhairi Wan Yaacob,
  • Habibah Jamil,
  • Rohayu Che Omar and
  • Adeleke Abdulrahman Oyekanmi
Inorganics2023, 11(3), 131;https://doi.org/10.3390/inorganics11030131

20 March 2023

Supported nano zero-valent iron is receiving great attention nowadays due to its effectiveness in treating heavy metal pollutants. Therefore, this study aimed to investigate the effectiveness of granitic residual soil-supported nano zero-valent iron...

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  • Feature Paper
  • Article
  • Open Access
14 Citations
3,586 Views
30 Pages
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The Electronic Nature of Cationic Group 10 Ylidyne Complexes

  • Leonard R. Maurer,
  • Jens Rump and
  • Alexander C. Filippou
Inorganics2023, 11(3), 129;https://doi.org/10.3390/inorganics11030129

18 March 2023

We report a broad theoretical study on [(PMe3)3MER]+ complexes, with M = Ni, Pd, Pt, E = C, Si, Ge, Sn, Pb, and R = ArMes, Tbb, (ArMes = 2,6-dimesitylphenyl; Tbb = C6H2-2,6-[CH(SiMe3)2]2-4-tBu). A few years ago, our group succeeded in obtaining heavi...

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  • Article
  • Open Access
6 Citations
2,612 Views
15 Pages
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Destabilization of the LiBH4–NaBH4 Eutectic Mixture through Pore Confinement for Hydrogen Storage

  • Filippo Peru,
  • Seyedhosein Payandeh,
  • Torben R. Jensen,
  • Georgia Charalambopoulou and
  • Theodore Steriotis
Inorganics2023, 11(3), 128;https://doi.org/10.3390/inorganics11030128

18 March 2023

Both LiBH4 and NaBH4 are well known for having high hydrogen contents, but also high decomposition temperatures and slow hydrogen absorption–desorption kinetics, preventing their use for hydrogen storage applications. The low melting temperatur...

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  • Article
  • Open Access
1 Citations
2,347 Views
13 Pages
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Half-Sandwich Nickelacarboranes Derived from [7-(MeO(CH2)2S)-7,8-C2B9H11]−

  • Dmitriy K. Semyonov,
  • Marina Yu. Stogniy,
  • Kyrill Yu. Suponitsky and
  • Igor B. Sivaev
Inorganics2023, 11(3), 127;https://doi.org/10.3390/inorganics11030127

17 March 2023

New carboranyl thioethers 1-MeO(CH2)nS-1,2-C2B10H11 (n = 2, 3) were prepared by the alkylation of the trimethylammonium salt of 1-mercapto-ortho-carborane with 1-bromo- 2-methoxyethane and 1-bromo-3-methoxypropane, respectively. Their deboronation wi...

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  • Article
  • Open Access
20 Citations
3,668 Views
15 Pages
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Inorganic Sorbents for Wastewater Treatment from Radioactive Contaminants

  • Natalya A. Nekrasova,
  • Vitaly V. Milyutin,
  • Victor O. Kaptakov and
  • Evgeny A. Kozlitin
Inorganics2023, 11(3), 126;https://doi.org/10.3390/inorganics11030126

16 March 2023

The article presents the distribution coefficient (Kd) values of 137Cs and 90Sr tracer radionuclides in solutions of sodium and calcium salts for a wide range of commercially available inorganic sorbents: natural and synthetic aluminosilicates, manga...

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