Inorganics, Volume 10, Issue 10
2022 October - 30 articles
Cover Story: Single-phase luminophores are highly appreciated in real applications due to their permanent composition and enhanced synthesis stability and reproducibility. The chemical design of such luminophores by carefully choosing their photoactive constituents presents a great challenge. Combining 1,10-phenanthroline and Sm3+, with both bearing remarkable emission characteristics, within an aliphatic-bridged metal-organic framework, we were able to obtain a multi-colored MOF emitter, changing its color between red, white and yellow upon varying excitation wavelengths. A competitive crystallization of two topological isomers was observed for similar neodymium(III)-based systems, and surprisingly, the minor phase possessing rare snz topology has not been found even for its closest Pr(III) and Sm(III) neighbors. View this paper - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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