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Inorganics, Volume 10, Issue 10

October 2022 - 30 articles

Cover Story: Single-phase luminophores are highly appreciated in real applications due to their permanent composition and enhanced synthesis stability and reproducibility. The chemical design of such luminophores by carefully choosing their photoactive constituents presents a great challenge. Combining 1,10-phenanthroline and Sm3+, with both bearing remarkable emission characteristics, within an aliphatic-bridged metal-organic framework, we were able to obtain a multi-colored MOF emitter, changing its color between red, white and yellow upon varying excitation wavelengths. A competitive crystallization of two topological isomers was observed for similar neodymium(III)-based systems, and surprisingly, the minor phase possessing rare snz topology has not been found even for its closest Pr(III) and Sm(III) neighbors. View this paper
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Articles (30)

  • Article
  • Open Access
3 Citations
2,402 Views
10 Pages

3′-Aminothiocyclohexanespiro-5′-hydantoin and Its Pt(II) Complex—Synthesis, Cytotoxicity and Xanthine Oxidase Inhibitory Activity

  • Emiliya Cherneva,
  • Mariyana Atanasova,
  • Žaklina Šmelcerović,
  • Katarina Tomović,
  • Rossen Buyukliev,
  • Andrija Šmelcerović and
  • Adriana Bakalova

20 October 2022

Herein, we report the synthesis of platinum(II) complex bearing 3′-aminothiocyclohexanespiro-5′-hydantoin as ligand. The complex was characterized by IR, NMR spectral analyses, elemental analyses and density functional theory (DFT) calcul...

  • Review
  • Open Access
10 Citations
4,042 Views
25 Pages

18 October 2022

Tuberculosis (TB) remains the leading cause of death due to a single pathogen, accounting for 1.5 million deaths annually on the global level. Mycobacterium tuberculosis, the causative agent of TB, is persistently exposed to stresses such as reactive...

  • Article
  • Open Access
4 Citations
2,636 Views
13 Pages

Laser Ablation Synthesis and Characterization of Tb2O3 Nanoparticles for Magneto-Optical Ceramics

  • Roman N. Maksimov,
  • Vladimir V. Osipov,
  • Garegin R. Karagedov,
  • Vyacheslav V. Platonov,
  • Artem S. Yurovskikh,
  • Albert N. Orlov,
  • Alfiya V. Spirina and
  • Vladislav A. Shitov

18 October 2022

In this study, nano-sized individual Tb2O3 particles synthesized by the laser ablation method were extensively characterized and assessed as suitable precursors for the fabrication of transparent magneto-optical ceramics without requiring the introdu...

  • Article
  • Open Access
10 Citations
2,316 Views
12 Pages

Thiosemicarbazones and Derived Antimony Complexes: Synthesis, Structural Analysis, and In Vitro Evaluation against Bacterial, Fungal, and Cancer Cells

  • Amany Fathy,
  • Ahmed B. M. Ibrahim,
  • S. Abd Elkhalik,
  • Florian Meurer,
  • Michael Bodensteiner and
  • S. M. Abbas

14 October 2022

Two antimony complexes {[Sb(L1)Cl2] C1 and [Sb(L2)Cl2] C2} with the thiosemicarbazone ligands {HL1 = 4-(2,4-dimethylphenyl)-1-((pyridin-2-yl)methylene)thiosemicarbazide and HL2 = 4-(2,5-dimethoxyphenyl)-1-((pyridin-2-yl)methylene)thiosemicarbazide} w...

  • Article
  • Open Access
26 Citations
4,475 Views
16 Pages

Influence of Efficient Thickness of Antireflection Coating Layer of HfO2 for Crystalline Silicon Solar Cell

  • Deb Kumar Shah,
  • Devendra KC,
  • Ahmad Umar,
  • Hassan Algadi,
  • Mohammad Shaheer Akhtar and
  • O-Bong Yang

12 October 2022

Anti-reflective coating (ARC) layers on silicon (Si) solar cells usually play a vital role in the amount of light absorbed into the cell and protect the device from environmental degradation. This paper reports on the thickness optimization of hafniu...

  • Article
  • Open Access
4 Citations
2,686 Views
8 Pages

Judd-Ofelt Analysis of High Erbium Content Yttrium-Aluminum and Yttrium-Scandium-Aluminum Garnet Ceramics

  • Vadim Zhmykhov,
  • Elena Dobretsova,
  • Vladimir S. Tsvetkov,
  • Marina Nikova,
  • Irina Chikulina,
  • Dmitry Vakalov,
  • Vitaly Tarala,
  • Yurii Pyrkov,
  • Sergey Kuznetsov and
  • Vladimir Tsvetkov

11 October 2022

The Er1.5Y1.5Al5O12 (Er:YAG) and (Er1.43Y1.43Sc0.14)(Sc0.24Al1.76)Al3O12 (Er:YSAG) ceramics have been characterized using the Judd-Ofelt (JO) theory. The line strengths and oscillator strengths of several transitions from the ground state 4I15/2 to e...

  • Review
  • Open Access
91 Citations
7,732 Views
33 Pages

Bio-Inspired Synthesis of Carbon-Based Nanomaterials and Their Potential Environmental Applications: A State-of-the-Art Review

  • Vishal Dutta,
  • Ritesh Verma,
  • C. Gopalkrishnan,
  • Min-Hao Yuan,
  • Khalid Mujasam Batoo,
  • R. Jayavel,
  • Ankush Chauhan,
  • Kun-Yi Andrew Lin,
  • Ravindran Balasubramani and
  • Suresh Ghotekar

10 October 2022

Providing safe drinking water and clean water is becoming a more challenging task all around the world. Although some critical issues and limits remain unsolved, implementing ecologically sustainable nanomaterials (NMs) with unique features, e.g., hi...

  • Article
  • Open Access
8 Citations
7,123 Views
15 Pages

Simultaneous HPLC Determination of Clindamycin Phosphate, Tretinoin, and Preservatives in Gel Dosage Form Using a Novel Stability-Indicating Method

  • Sadaf Sarfraz,
  • Shahid Hussain,
  • Mohsin Javed,
  • Ali Raza,
  • Shahid Iqbal,
  • Hamad Alrbyawi,
  • Samar O. Aljazzar,
  • Eslam B. Elkaeed,
  • Hamoud H. Somaily and
  • Rami Adel Pashameah
  • + 2 authors

10 October 2022

The most well-known, effective medicines for acne therapy are clindamycin phosphate and tretinoin. For the first time, we have developed and validated a reversed-phase HPLC stability-indicating technique for the detection of clindamycin phosphate (CL...

  • Article
  • Open Access
6 Citations
2,538 Views
10 Pages

Stress Reduction of a V-Based BCC Metal Hydride Bed Using Silicone Oil as a Glidant

  • Xin Zheng,
  • Hanyang Kong,
  • Desheng Chu,
  • Faping Hu,
  • Yao Wang,
  • Yigang Yan and
  • Chaoling Wu

9 October 2022

The large volume expansion and self-locking phenomenon of metal hydride particles during hydrogen sorption often leads to a high stress concentration on the walls of a container, which may cause the collapse of the container. In present study, silico...

  • Article
  • Open Access
1 Citations
2,760 Views
25 Pages

3 October 2022

Chloranilic acid (2,5-dichloro-3,6-dihydroxy-1,4-benzoquinone, caH2) as a bidentate ligand for Nb(V) as a metal center is presented. The different coordination behavior of caH2 is well illustrated by a monomeric (Et4N)cis-[NbO(ca)2(H2O)OPPh3]·...

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Inorganics - ISSN 2304-6740