2020 January - 53 articles
Creep of an alloy based on the intermetallic compound Fe2AlCo was studied by compressive creep tests in the temperature range from 873 to 1073 K. The stress exponent n and the activation energy of creep Q were determined using the multivariable regre...
A 1:1 salt of carvedilol (CVD), an anti-hypertensive drug, with DL-mandelic acid (DL-MA) was crystallized from ethanol and the structure was characterized by X-ray single-crystal diffraction, revealing salt formation by transfer of an acidic proton f...
(ZrO2)0.89(Sc2O3)0.1(CeO2)0.01 crystals have been grown by directional melt crystallization in a cold crucible. The chemical and phase compositions of the crystals have been characterized using energy dispersion X-ray spectroscopy (EDX), Raman scatte...
Fe-doped LiTaO3 thin films with a low and high Fe concentration (labeled as LTO:Fe-LC and LTO:Fe-HC, respectively) were deposited by magnetron sputtering from two home-made targets. The dopant directly influenced the crystalline structure of the LiTa...
A detailed study of the effect of temperature and pressure on heat capacity, entropy and hysteresis phenomena near the ferroelectric phase transition in ammonium sulfate (AS) was performed. An analysis of experimental results within the framework of...
Liquid crystals were discovered by Friedrich Reinitzer in 1888 when he observed colors in cholesterol derivatives that are characteristic of highly birefringent materials [...]
Even though sub-micron and nano-sized iron particles generally display single or polycrystalline structures, a growing interest has also been dedicated to the class of amorphous ones, whose absence of a crystal structure is capable of modifying their...
Co-crystallization is a promising approach to improving both the solubility and the dissolution rate of active pharmaceutical ingredients. Crystal structure determination from powder diffraction data plays an important role in determining co-crystal...
Microtubules (MTs) are self-assembling, high-aspect-ratio tubular nanostructures formed from the polymerization of tubulin protein. MTs are capable of globally assembling into optically birefringent morphologies, but there is disagreement on the mech...
Ion irradiation, combined with nanoindentation, has long been recognized as an effective way to study effects of irradiation on the mechanical properties of metallic materials. In this research, hardening and creep of ion irradiated Chinese low activ...
Biological crystals and their properties have recently unveiled the complex mechanisms where life is supported [...]
Theoretical model is suggested, which describes of a new micromechanism of crossover from deformation twinning to lattice dislocation slip in metal–graphene nanocomposite with a bimodal structure. In the framework of the model, the lattice dislocatio...
In this work, we consider low-enthalpy polymorphs of ice, predicted previously using a modified basin-hopping algorithm for crystal-structure prediction with the TIP4P empirical potential at three pressures (0, 4 and 8 kbar). We compare and (re)-rank...
Cyclodextrin (CD) has been used to prepare biocompatible and nontoxic metal-organic frameworks (MOFs) suitable for biomedical applications as drug carriers. In this study, γ-CD/K-based MOF (γ-CD-MOF-1-α) was synthesized and its stab...
This is a review of relevant Raman spectroscopy (RS) techniques and their use in structural biology, biophysics, cells, and tissues imaging towards development of various medical diagnostic tools, drug design, and other medical applications. Classica...
Composite materials that contain metal-organic frameworks (MOFs) as a filler and a polymer matrix have attracted attention because they present a combination of high porosity and structural integrity. Phase compatibilities of the MOF and polymer play...
Functionalization of 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) chromophores at the 2,6-positions with iodo substituents and morpholino-substituted α-methyl groups affords molecules with strong absorbance in the visible spectrum. The e...
Tuning the electrical properties of materials by controlling their doping content has been utilized for decades in semiconducting oxides. Here, an atomistic view is successfully employed to obtain local information on the charge distribution and poin...
Diodes with an erbium and nitrogen codoped magnesium zinc oxide (MgZnO:Er,N) active layer were fabricated by spray pyrolysis on Si substrate with aqueous solutions including magnesium nitrate, zinc acetate, erbium acetate, ammonium acetate, and indiu...
Slag beads with different crystal content could be obtained through the gas quenching blast furnace slag (BFS) process. In order to increase the additional value of the slag beads as much as possible, it was necessary to restrain the crystallization...
The electric and dielectric properties of SrF2:Tb3+ nanocrystals were studied by AC impedance spectroscopy. The grain and grain boundary resistances and the complex permittivity with different Tb-doped concentrations were obtained. As the Tb-doping c...
Pressurizing Xe or Kr noble gas into the protein crystal for de novo phasing has been one method of choice when the introduction of other heavy-atom compounds fails. One reason is because, unlike other heavy-atom compounds, their immobilized sites ar...
The effect of Fe doping on SrTiO3 single crystals was investigated in terms of crystal and electronic structure over a wide temperature range in both oxidizing and reducing conditions. The electrical properties were thoroughly studied with a special...
The present study aimed to experimentally evaluate the mechanical properties of Pb(In1/2Nb1/2)O3–Pb(Mg1/3Nb2/3)O3–PbTiO3 (PIN–PMN–PT) bulk single crystals with different crystallographic directions using the nanoindentation te...
In this work, chemical vapor infiltration (CVI) was combined with reactive melt infiltration (RMI) using Ti–6Al–4V titanium alloy powder to prepare Cf/C–TiC composites. The microstructure and composition of Cf/C–TiC composites...
The properties of the Kondo insulator in a strong magnetic field are one of the most intriguing subjects in condensed matter physics. The Kondo insulating state is expected to be suppressed by magnetic fields, which results in the dramatic change in...
X-ray powder diffraction is an ideal technique for the quantitative analysis of a multiphase sample. The intensities of diffraction lines of a phase in a multiphase sample are proportional to the phase fraction and the quantitative analysis can be ob...
Improving the thermal insulation properties of cement-based materials is the key to reducing energy loss and consumption in buildings. Lightweight cement-based composites can be used efficiently for this purpose, as a structural material with load be...
The organic acid crystal modifiers play an important role in the control of the crystal habit of α-hemihydrate gypsum (α-CaSO4·0.5H2O) from phosphogypsum, but the molecular structure characteristics of crystal modifiers have not be...
The impact of gate metal on the leakage current and breakdown voltage of normally-off p-GaN gate high-electron-mobility-transistor (HEMT) with nickel (Ni) and zirconium (Zr) metals were studied and investigated. In this study, a Zr metal as a gate co...
In this work, 0.15Pb(Er1/2Nb1/2)O3–0.63Pb(Zn1/3Nb2/3)O3–0.22PbTiO3 (15PEN–63PZN–22PT) single crystals with a pure perovskite structure are obtained through the flux method. The phase structure, dielectric, ferroelectric proper...
The uniformity of amplitude distribution and amplitude gain are two main factors affecting the performance of ultrasonic welding vibration system. In order to improve the uniformity of amplitude distribution and amplitude gain of welding surface to e...
We demonstrate the topological equivalence of the phase diagrams of molybdenum (Mo) and tungsten (W), Group 6B partners in the periodic table. The phase digram of Mo to 800 GPa from our earlier work is now extended to 2000 GPa. The phase diagram of W...
Methyl-3-aminothiophene-2-carboxylate (matc) is a key intermediate in organic synthesis, medicine, dyes, and pesticides. Single crystal X-ray diffraction analysis reveals that matc crystallizes in the monoclinic crystal system P21/c space group. Thre...
The in situ crystallization is the most suitable way to obtain a crystal of a low-melting-point compound to determine its structure via X-Ray diffraction. Herein, the intermolecular interactions and some crystal properties of low-melting-point organo...
The solution of crystal structures from X-ray powder diffraction data has undergone an intense development in the last 25 years. Overlapping, background estimate, preferred orientation are the main difficulties met in the process of determining the c...
In this report, we explore the use of supercritical CO2 (scCO2) in the synthesis of well-known metal-organic frameworks (MOFs) including Zn-MOF-74 and UiO-66, as well as on the preparation of [Cu24(OH-mBDC)24]n metal-organic polyhedra (MOPs) and two...
A numerical scheme was developed to compute the thermal and stress fields of the Czochralski process in a quasi-time dependent mode. The growth velocity was computed from the geometrical changes in melt and crystal due to pulling for every stage, for...
The one-pot fashion of three multi-component reaction provides the desired hydroacridinone-based hydrazino-s-triazine scaffold 4. Compound 4 was crystallized in an orthorhombic crystal system and Pbca space group with a = 11.6271(2) Å, b = 18.2...
For the past several decades, synchrotron radiation has been extensively used to measure the spatial distribution and chemical affinity of elements found in trace concentrations (<few µg/g) in animal and human tissues. Intense and highly foc...
Self-assembled strategy has been proven to be a promising vista in constructing organized low-dimensional nanostructures with molecular precision and versatile functionalities on solid surfaces. Herein, we investigate by a combination of scanning tun...
Co-Cr-Mo alloy fibers of 2 mm in diameter were fabricated from the melt at 1, 2, and 5 mm/min growth rates by unidirectional solidification using an alloy-micro-pulling-down (A-µ-PD) method to control the microstructure. All elements, Co, Cr, a...
The crystal structures of the inclusion complexes of naringenin in dimethylated and permethylated β-cyclodextrin (DM-β-CD and TM-β-CD) were determined and extensively analyzed. Naringenin is found with its 4-hydroxyphenyl residue fully...
Melt convection during the directional solidification process of multi-crystalline silicon plays a critical role in the transport of impurities. The utilization of a static magnetic field is an effective way to control the melt convection pattern. St...
Stress–strain calculations are presented for nano-indentations made in: (1) an ammonium perchlorate (AP), NH4ClO4, {210} crystal surface; (2) an α-iron (111) crystal surface; (3) a simulated test on an α-iron (100) crystal surface....
Enzymes are biological catalysts, which work to accelerate chemical reactions at the molecular level in living organisms. They are major players in the control of biological processes such as replication, transcription, protein synthesis, metabolism,...
Oxidative dehydrogenation of alkanes to alkenes by a mild oxidant such as carbon dioxide is an active area of research. A series of MCM41-supported bimetallic oxide catalysts containing chromium oxide in addition to metal oxides (Ce, Co, Zn, V, Nb, a...
Dislocations play a crucial role in self-organization and strain relaxation mechanisms in SiGe heterostructures. In most cases, they should be avoided, and different strategies exist to exploit their nucleation properties in order to manipulate their...
A series of [Cu(POP)(N^N][PF6] and [Cu(xantphos)(N^N][PF6] compounds has been prepared and characterized in which POP = bis[2-(diphenylphosphanyl)phenyl]ether (IUPAC PIN oxydi(2,1-phenylene)bis(diphenylphosphane), xantphos = 4,5-bis(diphenylphosphany...
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