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39 Results Found

  • Article
  • Open Access
5 Citations
3,014 Views
18 Pages

Machine Learning Modeling and Run-to-Run Control of an Area-Selective Atomic Layer Deposition Spatial Reactor

  • Matthew Tom,
  • Henrik Wang,
  • Feiyang Ou,
  • Gerassimos Orkoulas and
  • Panagiotis D. Christofides

27 December 2023

Semiconducting materials require stringent design specifications that make their fabrication more difficult and prone to flaws that are costly and damaging to their computing and electrical properties. Area-selective atomic layer deposition is a proc...

  • Article
  • Open Access
35 Citations
6,568 Views
14 Pages

Influence of the Geometric Parameters on the Deposition Mode in Spatial Atomic Layer Deposition: A Novel Approach to Area-Selective Deposition

  • César Masse de la Huerta,
  • Viet Huong Nguyen,
  • Jean-Marc Dedulle,
  • Daniel Bellet,
  • Carmen Jiménez and
  • David Muñoz-Rojas

22 December 2018

Within the materials deposition techniques, Spatial Atomic Layer Deposition (SALD) is gaining momentum since it is a high throughput and low-cost alternative to conventional atomic layer deposition (ALD). SALD relies on a physical separation (rather...

  • Feature Paper
  • Article
  • Open Access
14 Citations
6,564 Views
26 Pages

Multiscale CFD Modeling of Area-Selective Atomic Layer Deposition: Application to Reactor Design and Operating Condition Calculation

  • Sungil Yun,
  • Henrik Wang,
  • Matthew Tom,
  • Feiyang Ou,
  • Gerassimos Orkoulas and
  • Panagiotis D. Christofides

5 March 2023

Area-selective atomic layer deposition (ASALD) as a bottom-up nanopatterning technique has gained recognition for its ability to address misalignment issues in semiconductor manufacturing. This in silico study investigates process operation condition...

  • Article
  • Open Access
22 Citations
5,941 Views
11 Pages

Inherently Area-Selective Atomic Layer Deposition of Manganese Oxide through Electronegativity-Induced Adsorption

  • Yi-Cheng Li,
  • Kun Cao,
  • Yu-Xiao Lan,
  • Jing-Ming Zhang,
  • Miao Gong,
  • Yan-Wei Wen,
  • Bin Shan and
  • Rong Chen

Manganese oxide (MnOx) shows great potential in the areas of nano-electronics, magnetic devices and so on. Since the characteristics of precise thickness control at the atomic level and self-align lateral patterning, area-selective deposition (ASD) o...

  • Article
  • Open Access
5 Citations
2,779 Views
13 Pages

Area-Selective Atomic Layer Deposition of ZnO on Si\SiO2 Modified with Tris(dimethylamino)methylsilane

  • Behnam Moeini,
  • Tahereh G. Avval,
  • Hidde H. Brongersma,
  • Stanislav Průša,
  • Pavel Bábík,
  • Elena Vaníčková,
  • Brian R. Strohmeier,
  • David S. Bell,
  • Dennis Eggett and
  • Matthew R. Linford
  • + 1 author

29 June 2023

Delayed atomic layer deposition (ALD) of ZnO, i.e., area selective (AS)-ALD, was successfully achieved on silicon wafers (Si\SiO2) terminated with tris(dimethylamino)methylsilane (TDMAMS). This resist molecule was deposited in a home-built, near-atmo...

  • Review
  • Open Access
13 Citations
5,980 Views
20 Pages

Surface Modification of Catalysts via Atomic Layer Deposition for Pollutants Elimination

  • Xiaofeng Wang,
  • Zhe Zhao,
  • Chengcheng Zhang,
  • Qingbo Li and
  • Xinhua Liang

10 November 2020

In recent years, atomic layer deposition (ALD) is widely used for surface modification of materials to improve the catalytic performance for removing pollutants, e.g., CO, hydrocarbons, heavy metal ions, and organic pollutants, and much progress has...

  • Review
  • Open Access
15 Citations
6,844 Views
56 Pages

15 August 2020

Supported nanoparticles are commonly applied in heterogeneous catalysis. The catalytic performance of these solid catalysts is, for a given support, dependent on the nanoparticle size, shape, and composition, thus necessitating synthesis techniques t...

  • Article
  • Open Access
5 Citations
6,602 Views
14 Pages

16 September 2021

Patterning of thin films with lithography techniques for making semiconductor devices has been facing increasing difficulties with feature sizes shrinking to the sub-10 nm range, and alternatives have been actively sought from area-selective thin fil...

  • Article
  • Open Access
2 Citations
5,289 Views
17 Pages

Area-Selective Atomic Layer Deposition of Ru Using Carbonyl-Based Precursor and Oxygen Co-Reactant: Understanding Defect Formation Mechanisms

  • Jayant Kumar Lodha,
  • Johan Meersschaut,
  • Mattia Pasquali,
  • Hans Billington,
  • Stefan De Gendt and
  • Silvia Armini

16 July 2024

Area selective deposition (ASD) is a promising IC fabrication technique to address misalignment issues arising in a top–down litho-etch patterning approach. ASD can enable resist tone inversion and bottom–up metallization, such as via pre...

  • Review
  • Open Access
50 Citations
16,297 Views
28 Pages

Is Poly(methyl methacrylate) (PMMA) a Suitable Substrate for ALD?: A Review

  • Marta Adriana Forte,
  • Ricardo Manuel Silva,
  • Carlos José Tavares and
  • Rui Ferreira e Silva

20 April 2021

Poly (methyl methacrylate) (PMMA) is a thermoplastic synthetic polymer, which displays superior characteristics such as transparency, good tensile strength, and processability. Its performance can be improved by surface engineering via the use of fun...

  • Communication
  • Open Access
5 Citations
3,063 Views
14 Pages

Stearic Acid as an Atomic Layer Deposition Inhibitor: Spectroscopic Insights from AFM-IR

  • Saumya Satyarthy,
  • Md Hasan Ul Iqbal,
  • Fairoz Abida,
  • Ridwan Nahar,
  • Adam J. Hauser,
  • Mark Ming-Cheng Cheng and
  • Ayanjeet Ghosh

6 October 2023

Modern-day chip manufacturing requires precision in placing chip materials on complex and patterned structures. Area-selective atomic layer deposition (AS-ALD) is a self-aligned manufacturing technique with high precision and control, which offers co...

  • Article
  • Open Access
1 Citations
2,641 Views
14 Pages

22 January 2025

Area-selective atomic layer deposition (AS-ALD) is a technique utilized for the fabrication of patterned thin films in the semiconductor industry due to its capability to produce uniform and conformal structures with control over thickness at the ato...

  • Article
  • Open Access
5 Citations
3,247 Views
18 Pages

In-Situ Imaging of a Light-Induced Modification Process in Organo-Silica Films via Time-Domain Brillouin Scattering

  • Sathyan Sandeep,
  • Alexey S. Vishnevskiy,
  • Samuel Raetz,
  • Sergej Naumov,
  • Dmitry S. Seregin,
  • Artem Husiev,
  • Konstantin A. Vorotilov,
  • Vitalyi E. Gusev and
  • Mikhail R. Baklanov

We applied time-domain Brillouin scattering (TDBS) for the characterization of porogen-based organosilicate glass (OGS) films deposited by spin-on-glass technology and cured under different conditions. Although the chemical composition and porosity m...

  • Proceeding Paper
  • Open Access
2 Citations
2,334 Views
7 Pages

Predictive Evaluation of Atomic Layer Deposition Characteristics for Synthesis of Al2O3 thin Films

  • Sachin Shendokar,
  • Moha Feroz Hossen,
  • Swapnil Nalawade,
  • Shobha Mantripragada and
  • Shyam Aravamudhan

The atomic layer deposition (ALD) synthesis process is being heavily researched for its conformality, high aspect ratio with thickness control, selective area deposition versatility, and variety of low-temperature oxide, nitride, and transition metal...

  • Article
  • Open Access
1 Citations
1,603 Views
21 Pages

5 March 2025

Nanocomposites composed of Cu and Mo were investigated by means of molecular dynamics (MD) simulations to study the incoherent interface between Cu and Mo. In order to select an appropriate potential capable of accurately describing the Cu-Mo system,...

  • Article
  • Open Access
12 Citations
7,160 Views
11 Pages

Characterisation Studies of the Structure and Properties of As-Deposited and Annealed Pulsed Magnetron Sputtered Titania Coatings

  • Justyna Kulczyk-Malecka,
  • Peter J. Kelly,
  • Glen West,
  • Gregory C.B. Clarke and
  • John A. Ridealgh

10 September 2013

Titanium dioxide thin films are durable, chemically stable, have a high refractive index and good electro/photochemical proprieties. Consequently, they are widely used as anti-reflective layers in optical devices and large area glazing products, die...

  • Article
  • Open Access
23 Citations
4,442 Views
11 Pages

Photocatalytic Bi2O3/TiO2:N Thin Films with Enhanced Surface Area and Visible Light Activity

  • Luís P. Dias,
  • Filipe C. Correia,
  • Joana M. Ribeiro and
  • Carlos J. Tavares

Bi2O3 nanocone films functionalized with an overlayer of TiO2 were deposited by d.c. reactive magnetron sputtering. The aforementioned nanocone structures were formed via a vapour-liquid-solid (VLS) growth, starting from a catalytic bismuth seed laye...

  • Article
  • Open Access
7 Citations
1,901 Views
16 Pages

Mask-Assisted Deposition of Ti on Cyclic Olefin Copolymer Foil by Pulsed Laser Deposition

  • Mariapompea Cutroneo,
  • Letteria Silipigni,
  • Anna Mackova,
  • Petr Malinsky,
  • Romana Miksova,
  • Vaclav Holy,
  • Jan Maly,
  • Marcel Stofik,
  • Petr Aubrecht and
  • Lorenzo Torrisi
  • + 2 authors

24 June 2023

Cyclic olefin copolymer (COC) is a novel type of thermoplastic polymer gaining the attention of the scientific community in electronic, optoelectronic, biomedicine and packaging applications. Despite the benefits in the use of COC such as undoubted o...

  • Article
  • Open Access
11 Citations
3,979 Views
13 Pages

A Low Temperature Growth of Cu2O Thin Films as Hole Transporting Material for Perovskite Solar Cells

  • Anna L. Pellegrino,
  • Francesca Lo Presti,
  • Emanuele Smecca,
  • Salvatore Valastro,
  • Giuseppe Greco,
  • Salvatore Di Franco,
  • Fabrizio Roccaforte,
  • Alessandra Alberti and
  • Graziella Malandrino

4 November 2022

Copper oxide thin films have been successfully synthesized through a metal–organic chemical vapor deposition (MOCVD) approach starting from the copper bis(2,2,6,6-tetramethyl-3,5-heptanedionate), Cu(tmhd)2, complex. Operative conditions of fabr...

  • Article
  • Open Access
11 Citations
6,530 Views
13 Pages

Controlled Al3+ Incorporation in the ZnO Lattice at 188 °C by Soft Reactive Co-Sputtering for Transparent Conductive Oxides

  • Salvatore Sanzaro,
  • Antonino La Magna,
  • Emanuele Smecca,
  • Giovanni Mannino,
  • Giovanna Pellegrino,
  • Enza Fazio,
  • Fortunato Neri and
  • Alessandra Alberti

3 June 2016

Transparent conductive oxide (TCO) layers, to be implemented in photo-anodes for dye-sensitized solar cells (DSCs), were prepared by co-deposition of ZnO and Al using pulsed-direct current (DC)-magnetron reactive sputtering processes. The films were...

  • Article
  • Open Access
4 Citations
1,977 Views
14 Pages

Direct Laser Writing of Diffractive Structures on Bi-Layer Si/Ti Films Coated on Fused Silica Substrates

  • Dmitrij A. Belousov,
  • Roman I. Kuts,
  • Konstantin A. Okotrub and
  • Victor P. Korolkov

This paper presents the results of an investigation of direct laser writing on a titanium film with an antireflection capping silicon coating. Bi-layer films were deposited on fused silica substrates using an e-beam evaporation system. Modeling predi...

  • Article
  • Open Access
2 Citations
1,421 Views
17 Pages

Transparent Al-Doped ZnO Thin Films for High-Sensitivity NO2 Gas Sensing

  • So-Young Bak,
  • Se-Hyeong Lee,
  • Hyeongrok Jang,
  • Minseong Kim,
  • Sungjae Kim and
  • Moonsuk Yi

9 June 2025

This study developed a transparent NO2 gas sensor with enhanced sensing performance and high optical transmittance. Al-doped ZnO thin films were deposited by atomic layer deposition, which was chosen for its capability to precisely control surface ch...

  • Proceeding Paper
  • Open Access
1,460 Views
2 Pages

Based on the 2019 report of the European Environment Agency on Air Quality in Europe nitrogen oxides (NOx) were identified as the most harmful air pollutants in terms of damage to ecosystems. Moreover, in Europe, NO2 is pinpointed as one of the most...

  • Article
  • Open Access
8 Citations
3,433 Views
15 Pages

Investigation of Field Emission Properties of Carbon Nanotube Arrays of Different Morphologies

  • Maksim A. Chumak,
  • Alexander V. Shchegolkov,
  • Eugeni O. Popov,
  • Sergey V. Filippov,
  • Anatoly G. Kolosko,
  • Aleksei V. Shchegolkov and
  • Arif A. Babaev

26 April 2024

This article presents, for the first time, a comparative analysis of the emission characteristics of large-area field-effect cathodes (LAFE) based on carbon nanotubes (CNTs) of various morphologies according to key parameters using a unique computeri...

  • Article
  • Open Access
320 Views
12 Pages

Comparative Analysis of Annealing–Dissolution Techniques for Hollow Submicron Metal Oxide Fiber Synthesis

  • Borislava Georgieva,
  • Blagoy Spasov Blagoev,
  • Albena Paskaleva,
  • Kirilka Starbova,
  • Nikolay Starbov,
  • Ivalina Avramova,
  • Peter Tzvetkov,
  • Krastyo Buchkov and
  • Vladimir Mehandzhiev

14 January 2026

Double-shell ZnO/Al2O3 submicron hollow fibers were successfully fabricated through a combined electrospinning and atomic layer deposition (ALD) approach. Polyvinyl alcohol (PVA) fibers were first produced by electrospinning and subsequently coated w...

  • Article
  • Open Access
8 Citations
3,795 Views
11 Pages

Hydrogen Induced Etching Features of Wrinkled Graphene Domains

  • Qiongyu Li,
  • Fang Li,
  • You Li,
  • Yongping Du,
  • Tien-Mo Shih and
  • Erjun Kan

Wrinkles are observed commonly in CVD (chemical vapor deposition)-grown graphene on Cu and hydrogen etching is of significant interest to understand the growth details, as well as a practical tool for fabricating functional graphene nanostructures. H...

  • Article
  • Open Access
4 Citations
2,157 Views
14 Pages

Influence of the Chemical Composition of Kulantau Vermiculite on the Structure of Modified Bitumen Compositions

  • Kulash Syrmanova,
  • Zhanat Kaldybekova,
  • Aktolkyn Agabekova and
  • Sholpan Baizhanova

The article presents the chemical composition of vermiculite ores from the Kulantau deposits and the atomic structure of vermiculite during dehydration, in 1-, 2- and 3-layer hydrated states. It has been shown that vermiculites from deposits in the T...

  • Article
  • Open Access
31 Citations
4,556 Views
14 Pages

Growth Mechanism of Periodic-Structured MoS2 by Transmission Electron Microscopy

  • Arvind Mukundan,
  • Yu-Ming Tsao,
  • Sofya B. Artemkina,
  • Vladimir E. Fedorov and
  • Hsiang-Chen Wang

31 December 2021

Molybdenum disulfide (MoS2) was grown on a laser-processed periodic-hole sapphire substrate through chemical vapor deposition. The main purpose was to investigate the mechanism of MoS2 growth in substrate with a periodic structure. By controlling the...

  • Article
  • Open Access
12 Citations
2,992 Views
11 Pages

TiO2-Coated ZnO Nanowire Arrays: A Photocatalyst with Enhanced Chemical Corrosion Resistance

  • Lan Gao,
  • Elyes Nefzaoui,
  • Frédéric Marty,
  • Mazen Erfan,
  • Stéphane Bastide,
  • Yamin Leprince-Wang and
  • Tarik Bourouina

27 October 2021

Photocatalysis is proven to be the most efficient and environmentally friendly method for the degradation of organic pollutants in water purification. To meet the requirement of large-scale water treatment, there are two important points: One is the...

  • Article
  • Open Access
36 Citations
9,040 Views
24 Pages

Atomic Layer Deposition of Lithium–Nickel–Silicon Oxide Cathode Material for Thin-Film Lithium-Ion Batteries

  • Maxim Maximov,
  • Denis Nazarov,
  • Aleksander Rumyantsev,
  • Yury Koshtyal,
  • Ilya Ezhov,
  • Ilya Mitrofanov,
  • Artem Kim,
  • Oleg Medvedev and
  • Anatoly Popovich

8 May 2020

Lithium nickelate (LiNiO2) and materials based on it are attractive positive electrode materials for lithium-ion batteries, owing to their large capacity. In this paper, the results of atomic layer deposition (ALD) of lithium–nickel–silic...

  • Article
  • Open Access
2 Citations
1,932 Views
11 Pages

A Wrinkling and Etching-Assisted Regrowth Strategy for Large-Area Bilayer Graphene Preparation on Cu

  • Qiongyu Li,
  • Tongzhi Liu,
  • You Li,
  • Fang Li,
  • Yanshuai Zhao and
  • Shihao Huang

12 July 2023

Bilayer graphene is a contender of interest for functional electronic applications because of its variable band gap due to interlayer interactions. Graphene growth on Cu is self-limiting, thus despite the fact that chemical vapor deposition (CVD) has...

  • Article
  • Open Access
1,257 Views
12 Pages

Growth of Two-Dimensional Edge-Rich Screwed WS2 with High Active Site Density for Accelerated Hydrogen Evolution

  • Dengchao Hu,
  • Chaocheng Sun,
  • Yida Wang,
  • Fade Zhao,
  • Yubao Li,
  • Limei Song,
  • Cuncai Lv,
  • Weihao Zheng and
  • Honglai Li

20 May 2025

Two-dimensional transition metal dichalcogenides have attracted considerable attention in electrocatalytic hydrogen evolution due to their unique layered structures and tunable electronic properties. However, prior research has predominantly focused...

  • Article
  • Open Access
8 Citations
2,997 Views
15 Pages

Surface Nanostructuring during Selective Area Epitaxy of Heterostructures with InGaAs QWs in the Ultra-Wide Windows

  • Viktor Shamakhov,
  • Dmitriy Nikolaev,
  • Sergey Slipchenko,
  • Evgenii Fomin,
  • Alexander Smirnov,
  • Ilya Eliseyev,
  • Nikita Pikhtin and
  • Peter Kop`ev

23 December 2020

Selective area epitaxy (SAE) is widely used in photonic integrated circuits, but there is little information on the use of this technique for the growth of heterostructures in ultra-wide windows. Samples of heterostructures with InGaAs quantum wells...

  • Article
  • Open Access
3 Citations
2,268 Views
24 Pages

Hierarchical Structuring of Black Silicon Wafers by Ion-Flow-Stimulated Roughening Transition: Fundamentals and Applications for Photovoltaics

  • Vyacheslav N. Gorshkov,
  • Mykola O. Stretovych,
  • Valerii F. Semeniuk,
  • Mikhail P. Kruglenko,
  • Nadiia I. Semeniuk,
  • Victor I. Styopkin,
  • Alexander M. Gabovich and
  • Gernot K. Boiger

6 October 2023

Ion-flow-stimulated roughening transition is a phenomenon that may prove useful in the hierarchical structuring of nanostructures. In this work, we have investigated theoretically and experimentally the surface texturing of single-crystal and multi-c...

  • Abstract
  • Open Access
1,140 Views
1 Page

Stable Porous Silicon Membranes for Fast Bacterial Detection

  • Laurent A. Francis,
  • Roselien Vercauteren,
  • Audrey Leprince and
  • Jacques Mahillon

The rapid detection of hazardous bacteria is important for healthcare situations, where such identification can lead to substantial gains for patient treatment and recovery and a reduced usage of broad-spectrum antibiotics. Potential biosensors must...

  • Review
  • Open Access
45 Citations
5,025 Views
27 Pages

30 May 2022

Supercapacitors (SCs) have attracted attention as an important energy source for various applications owing to their high power outputs and outstanding energy densities. The electrochemical performance of an SC device is predominantly determined by e...

  • Article
  • Open Access
17 Citations
4,324 Views
25 Pages

28 November 2020

The mode of operation of titania-supported vanadia (VOx) catalysts for NOx abatement using ammonia selective catalytic reduction (NH3-SCR) is still vigorously debated. We introduce a new high surface area VOx/TiO2/SBA-15 model catalyst system based o...

  • Article
  • Open Access
14 Citations
4,264 Views
17 Pages

Zn- and Ti-Doped SnO2 for Enhanced Electroreduction of Carbon Dioxide

  • Katarzyna Bejtka,
  • Nicolò B. D. Monti,
  • Adriano Sacco,
  • Micaela Castellino,
  • Samuele Porro,
  • M. Amin Farkhondehfal,
  • Juqin Zeng,
  • Candido F. Pirri and
  • Angelica Chiodoni

1 May 2021

The electrocatalytic reduction of CO2 into useful fuels, exploiting rationally designed, inexpensive, active, and selective catalysts, produced through easy, quick, and scalable routes, represents a promising approach to face today’s climate challeng...

  • Article
  • Open Access
19 Citations
3,491 Views
18 Pages

Microstructure and Corrosion Behavior of Laser Cladding FeCoNiCrBSi Based High-Entropy Alloy Coatings

  • Hongling Zhang,
  • Wenjuan Li,
  • Huanhuan Xu,
  • Liang Chen,
  • Junshan Zeng,
  • Zhibing Ding,
  • Wenmin Guo and
  • Bin Liu

High-entropy amorphous alloys designed based on the concept of multi-principal components have the comprehensive advantages of high passivation element content and amorphous structure, and are considered as one of the promising alternative protective...