151 Results Found

CeO2 is an outstanding support commonly used for the CuO-based CO oxidation catalysts due to its excellent redox property and oxygen storage–release property. However, the inherently small specific surface area of CeO2 support restricts the fur...

The catalytic properties of CuO-CeO2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO2/γ-Al2O3 catalyst provided complete DMM co...

Formic acid decomposition to H2-rich gas was investigated over a CuO-CeO2/γ-Al2O3 catalyst. The catalyst was characterized by XRD, HR TEM and EDX methods. A 100% conversion of formic acid was observed over the copper-ceria catalyst under ambient pres...

This study presented an optimisation study of two-stage vapour-phase catalytic glycerol reforming (VPCGR) using response surface methodology (RSM) with a central composite experimental design (CCD) approach. Characterisation through Brunauer–Em...

Cerium-rich metal oxide materials have recently emerged as promising candidates for the photocatalytic oxygen evolution reaction (OER). In this article, we report the synthesis of ordered mesoporous CuO/CeO2 composite frameworks with different conten...

Bimetallic synergism plays an important role in lattice-doped catalysts. Therefore, lattice-doped bimetallic CuO/CeO2 catalysts were prepared by secondary alkaline hydrothermal reaction. During this process, the CeO2 nanomaterials were partially diss...

Several CeO2 and CuO-CeO2 catalysts were prepared using different methods, i.e., a homogeneous precipitation with urea, a nanocasting route using CMK-3 carbon as a hard template and a sol–gel process using Poly(methyl methacrylate) (PMMA) polymer as...

The present work is focused on nickel catalysts supported on La2O3-CeO2 binary oxides without and with the addition of Cu to the active component for the dry reforming of methane (DRM). The catalysts are characterized using XRD, XRF, TPD-CO2, TPR-H2,...

In this work, the activity of xCuO-Ce0.9Zr0.1O2 catalysts for the reaction of NO + CO was investigated. Especially, in situ DRIFTS was applied to investigate the surface species under the adsorption of NO and/or CO and the reaction of NO and CO to un...

CeO2 nanooctahedrons, nanorods, and nanocubes were prepared by the hydrothermal method and were then used as supports of Cu-based catalysts for the water-gas shift (WGS) reaction. The chemical and physical properties of these catalysts were character...

In this study, xCuO-CeO2 mixed oxide catalysts (Cu weight ratio x = 1.5, 3, 4.5, 6 and 15 wt.%) were prepared using solution combustion synthesis (SCS) and their catalytic activities towards the methane (CH4) oxidation reaction were studied. The comb...

CuO-based catalysts are usually used for CO oxidation owing to their low cost and excellent catalytic activities. In this study, a series of metal oxide (La2O3, Fe2O3, PrO2, Sm2O3, and MnO2)-doped CuO-based catalysts with mesoporous Ce0.8Zr0.2O2 supp...

Pt-based catalysts, because of their outstanding activity for hydrocarbon oxidation, are widely used in the engine-exhaust aftertreatment system to remove hydrocarbon emissions. However, the CO and NOx present in real engine exhausts compete with hyd...

Despite of the huge number of papers about the catalytic preferential oxidation of CO (CO-PROX) for the purification of H2 streams, there is still a need for more effective catalysts in order to reduce the large required catalyst volume of CO-PROX un...

Cu-containing and Ce-modified OMS-2 catalysts were prepared at various calcination temperatures using the hydrothermal method and tested for low-temperature CO oxidation. The structure, chemical compositions, and physical–chemical properties of...

The development of an efficient and economic catalyst with high catalytic performance is always challenging. In this study, we report the synthesis of hollow CeO2 nanostructures and the crystallinity control of a CeO2 layer used as a support material...

A series of mixed oxides of CuO, CeO2, and SiO2 were prepared by gel combustion and employed for the first time as efficient solid catalysts in a solvent-less liquid-phase cross-dehydrogenative coupling. The facile one-pot catalyst synthesis resulted...

Cu/Ce binary oxides were prepared via the one-pot solvothermal method, and the effects of different cerium precursors (cerium nitrate and cerium ammonium nitrate) on the catalytic activity and resistance to water vapor or CO2 of the prepared samples...

Nanosizedceria (n-CeO2) was synthesized by a facile method in 2-methylimidazolesolution. The characterization results of XRD, N2 adsorption-desorption, Raman and TEM indicate that n-CeO2 shows a regular size of 10 ± 1 nm, a high surface area of 130 m...

Several Cu and Ni-based catalysts were synthetized over Ce-based supports, either pure or mixed with different amounts of alumina (1:2 and 1:3 mol/mol). Different metal loadings (10–40 wt%) and preparation methods (wet impregnation, co-precipit...

In the present study, Ni/Ce-Sm-xCu (x = 5, 7, 10 at.%) catalysts were prepared using microwave radiation coupled with sol-gel and followed by wetness impregnation method for the Ni incorporation. Highly dispersed nanocrystallites of CuO and NiO on th...

The electrocatalytic carbon dioxide (CO2) reduction reaction (CO2RR) is extensively regarded as a promising strategy to reach carbon neutralization. Copper sulfide (CuS) has been widely studied for its ability to produce C1 products with high selecti...

In this paper, the effect of KMnO4 modification on the performance of CO oxidation over a CuCeOx/Fe2O3 catalyst in industrial flue gas was studied. X-ray diffraction (XRD), scanning electron microscopy (SEM), temperature-programmed reduction by H2 (H...

Proton exchange membrane (PEM) fuel cells represent one of the most interesting systems for converting hydrogen from fossil or renewable fuels into electric power at low temperature. To prevent poisoning of fuel cell anodes, CO concentration has to b...

Copper oxides tend to agglomerate on the surface of CeO2, with a high amount of Cu. In this study, a CeO2 catalyst with a high CuO doping amount was treated with nitric acid to improve its catalytic performance for soot oxidation. The effect of acid...

Nitrogen oxides (NOx) emissions pose environmental and health risks. Selective catalytic reduction (SCR) is effective for NOx removal, and using CO as a reductant can eliminate both NOx and CO. This study explores CuCe catalysts on SiO2, Al2O3, and T...

Hydrodeoxygenation (HDO) of bio-oil is a method of bio-oil upgrading. In this paper, x%CeO2–Ni–Cu/HZSM-5 (x = 5, 15, and 20) was synthesized as an HDO catalyst by the co-impregnation method. The HDO performances of x%CeO2–Ni–C...

Improving the dispersion of CuxO species is critical for enhancing the catalytic performance of CuxO/CeO2 catalysts in the preferential oxidation of CO. Herein, the 10CuxO/CeO2 catalyst was synthesized using a combined approach of one-step thermal de...

Greatly efficient chemical processes are customarily based upon a catalyst activating the process pathway to achieve higher yields of a product with desired specifications. Catalysts capable of achieving good performance without compromising green cr...

The development of superior low-temperature catalytic performance and inexpensive catalysts for the removal of volatile organic compounds (VOCs) is crucial for their industrial application. Herein, CuO/Ce0.6Zr0.4O2 catalysts calcinated at different t...

This study presents a comprehensive characterization of monometallic (Co or Cu) and bimetallic (Co-Cu) catalysts supported on cerium oxide (CeO2). XRD and TEM analyses revealed that crystallinity decreases after reduction and that metal dispersion is...

Dimethyl disulfide (DMDS, CH3SSCH3) is an odorous and harmful air pollutant (volatile organic compound (VOC)) causing nuisance in urban areas. The abatement of DMDS emissions from industrial sources can be realized through catalytic oxidation. Howeve...

The accumulation of NH4HSO4 leads to the deactivation of commercial V2O5-WO3/TiO2 catalyst (VWTi) in practical application. The commercial catalyst is modified with 0.3 wt. % Ce and 0.05 wt. % Cu (donated as VWCeCuTi), and its sulfur resistance is no...

The copper–ceria (CuOx/CeO2) system has been extensively investigated in several catalytic processes, given its distinctive properties and considerable low cost compared to noble metal-based catalysts. The fine-tuning of key parameters, e.g., the par...

Ba0.9A0.1MnO3 (BM-A) and Ba0.9A0.1Mn0.7Cu0.3O3 (BMC-A) (A = Mg, Ca, Sr, Ce, La) perovskite-type mixed oxides were synthesised, characterised, and used for soot oxidation in simulated Gasoline Direct Injection (GDI) engine exhaust conditions. The samp...

This study investigates the activity of transition and alkaline-earth metal-doped catalysts supported on ceria or zirconia for the NOx-assisted oxidation of diesel particulate. A series of Cu- and Fe-impregnated catalysts over CeO2 and ZrO2 supports...

To improve the catalytic performance of an active layered double hydroxide (LDH)-derived CuCeMgAlO mixed oxide catalyst in the total oxidation of methane, it was promoted with different transition-metal cations. Thus, two series of multicationic mixe...

Fe-modified Cu catalysts with CeO2 support, prepared by the impregnation method, were subjected to physicochemical analysis and catalytic tests in the steam reforming of methanol (SRM). Physicochemical studies of the catalysts were carried out using...

Multicomponent oxide systems 800-Cu-Mg-Fe-O and 800-Cu-Mg-Fe-O-Ce were tested as catalysts of selective catalytic oxidation of ammonia to dinitrogen (NH3-SCO) process. Materials were obtained by calcination of hydrotalcite-like compounds at temperatu...

CoFe2O4 prepared by sol-gel has been examined with respect to its catalytic performance for preferential CO oxidation in a H2-rich stream. In turn, the promoting effects of incorporation of Ce, Co, Cu, and Zr by impregnation on the surface of CoFe2O4...

The aim of the present work was to investigate steam reforming of ethanol with regard to H2 production over transition metal catalysts supported on CeO2. Various parameters concerning the effect of temperature (400–800 °C), steam-to-carbon (S/C) feed...

Chemical warfare agents (CWAs) are highly toxic and fast-acting and are easy to cause large-scale poisoning to humans and livestock after being released. The activated carbon used for CWAs adsorption has disadvantages of limited adsorption capacity,...

CuO-CeO2 nanocatalysts with varying CuO contents (1, 5, 9, 14 and 17 wt %) were prepared by one-step flame spray pyrolysis (FSP) and applied to CO oxidation. The influences of CuO content on the as-prepared catalysts were systematically characterized...

A series of mixed copper (II)—zinc oxide catalysts supported on unmodified and ceria-modified silica supports were synthesized using β-cyclodextrin as a template. The novelty of this work lies in the use of cyclosextrins for the template s...

Cu-based catalysts are promising for CO oxidation applications with catalyst deactivation being a major barrier. We start with a CuO/Al2O3 catalyst and find that while the CO conversion decreases, CO2 accumulates and the average Cu chemical state sta...

Hydrogen is the alternative renewable energy source for addressing the energy crisis, global warming, and climate change. Hydrogen is mostly obtained in the industrial process by steam reforming of natural gas. In the present work, CuCrO2 particles w...

The construction of heterostructured photocatalyst with an appropriate energy band structure will help realize highly efficient photo-excited charge separation. In this study, ternary CuO/CeO2/ZnO nano-particle (NP) composites were synthesized by a f...

Synthesis of anionic metal–organic framework Na[Ce(BDC)2(DMF)2] based on cerium (III)–sodium terephthalate was performed. The crystal structure, studied by the Rietveld method, consists of anionic [Ce(BDC)2]− layers, connected by in...

Catalysis is an indispensable part of our society, massively involved in numerous energy and environmental applications. Although, noble metals (NMs)-based catalysts are routinely employed in catalysis, their limited resources and high cost hinder th...

CuO-CeO2 catalysts, with 6 wt % of Cu, have been synthesised by different preparation methods (calcination of nitrate precursors, thermal urea-nitrate combustion, freeze-drying method, using polymethyl metacrylate PMMA microspheres as template and pr...