Editor’s Choice Articles

Water yield is a key ecosystem function index, directly impacting the sustainable development of the basin economy and ecosystem. Climate and land use/land cover (LULC) changes are the main driving factors affecting water yield. In the context of global climate change, assessing the impacts of climate and LULC changes on water yield in the alpine regions of the Qinghai–Tibet Plateau (QTP) is essential for formulating rational management and development strategies for water resources. On the basis of the Integrated Valuation of Ecosystem Services and Tradeoffs (InVEST) model, we simulated and analyzed the spatiotemporal variations and the impacts of LULC and climate changes on water yield from 2001 to 2019 in the upstream regions of the Shule River Basin (USRB) on the northeastern margin of the QTP. Three scenarios were designed in the InVEST model to clearly analyze the contributions of climate and LULC changes on the variation of water yield. The first scenario integrated climate and LULC change into the model according to the actual conditions. The second scenario was simulation without LULC change, and the third scenario was without climate change. The results showed that (1) the InVEST model had a good performance in estimating water yield (coefficient of determination (R²) = 0.986; root mean square error (RMSE) = 3.012, p < 0.05); (2) the water yield significantly increased in the temporal scale from 2001 to 2019, especially in the high altitude of the marginal regions (accounting for 32.01%), while the northwest regions significantly decreased and accounted for only 8.39% (p < 0.05); (3) the spatial distribution of water yield increased from the middle low-altitude regions to the marginal high-altitude regions; and (4) through the analysis of the three scenarios, the impact of climate change on water yield was 90.56%, while that of LULC change was only 9.44%. This study reveals that climate warming has a positive impact on water yield, which will provide valuable references for the integrated assessment and management of water resources in the Shule River Basin. Full article

Water is an essential resource that facilitates the existence of human life forms. In recent years, the demand for the consumption of freshwater has substantially increased. Seawater contains a high concentration of salt particles and salinity, making it unfit for consumption and domestic use. Water treatment plants used to treat seawater are less efficient and reliable. Deep learning systems can prove to be efficient and highly accurate in analyzing salt particles in seawater with higher efficiency that can improve the performance of water treatment plants. Therefore, this work classified different concentrations of salt particles in water using convolutional neural networks with the implementation of transfer learning. Salt salinity concentration images were captured using a designed Raspberry Pi based model and these images were further used for training purposes. Moreover, a data augmentation technique was also employed for the state-of-the-art results. Finally, a deep learning neural network was used to classify saline particles of varied concentration range images. The experimental results show that the proposed approach exhibited superior outcomes by achieving an overall accuracy of 90% and f-score of 87% in classifying salt particles. The proposed model was also evaluated using other evaluation metrics such as precision, recall, and specificity, and showed robust results. Full article

Groundwater is the main resource for irrigation and drinking supply in most parts of Syria, as for most Mediterranean countries, however this resource suffers from mismanagement. In the study area (northeast of Mt. Hermon), the lack of information makes water management in this area extremely difficult. Assessing groundwater pollution risk is the most essential issue for water resources management, especially in the regions where complex interaction between climate, geology, geomorphology, hydrogeology, water scarcity and water resource mismanagement exist. This complexity leads to significant complication in determining pollution risk of studied system. In the present work, we adopted an integrative approach to assess groundwater pollution risk in the study area. This methodology is based on the analysis of hydrogeological characteristics of aquifer systems and the available information about socioeconomic context and physiochemical groundwater conditions that might affect this system. This approach allowed us to delineate the groundwater pollution risk map based on the analysis of concerning parameters/indicators. The degree of risk was assessed as the sum and average of rating of these parameters and indicators for each subarea. Typically, very high pollution risk index was identified over the Quaternary/Neogene horizon, i.e., shallow and unconfined aquifer and in the lower part of Jurassic aquifer. In these two parts, the majority of anthropogenic activities are concentrated. Low pollution risk index was found for the outcropping of low permeable Quaternary basalt at the Southern part of the study area. A moderate pollution index was identified for the low/moderate permeability of silt, clay and marly limestone-rich horizons of the major part of Neogene aquifer outside of the intersected zones with Quaternary aquifer and for the Paleogene formations. The spatial analysis shows that about 50% of the study area is characterized as being at very high and high pollution risk index. Hence, the overall natural protective capacity of this area is still poor. This study demonstrates the flexibility of the proposed approach to assess groundwater pollution risk in local complex aquifer system characterized by lack of information and data in order to reduce the risk of future groundwater pollution. Full article

Evapotranspiration (ET) is a key variable in the hydrological cycle and it directly impacts the surface balance and its accurate assessment is essential for a correct water management. ET is difficult to measure, since the existing methods for its direct estimate, such as the weighing lysimeter or the eddy-covariance system, are often expensive and require well-trained research personnel. To overcome this limit, different authors developed experimental models for indirect estimation of ET. However, since the accuracy of ET prediction is crucial from different points of view, the continuous search for more and more precise modeling approaches is encouraged. In light of this, the aim of the present work is to test the efficiency in predicting ET fluxes in a newly introduced physical-based model, named Prospero, which is based on the ability to compute the ET using a multi-layer canopy model, solving the energy balance both for the sunlight and shadow vegetation, extending the recently developed Schymanski and Or method to canopy level. Additionally, Prospero is able to compute the actual ET using a Jarvis-like model. The model is integrated as a component in the hydrological modelling system GEOframe. Its estimates were validated against observed data from five Eddy covariance (EC) sites with different climatic conditions and the same vegetation cover. Then, its performances were compared with those of two already consolidated models, the Priestley–Taylor model and Penman FAO model, using four goodness-of-fit indices. Subsequently a calibration of the three methods has been carried out using LUCA calibration within GEOframe, with the purpose of prediction errors. The results showed that Prospero is more accurate and precise with respect to the other two models, even if no calibrations were performed, with better performances in dry climatic conditions. In addition, Prospero model turned to be the least affected by the calibration procedure and, therefore, it can be effectively also used in a context of data scarcity. Full article

Environmental flows (eflows) refer to the amount of water required to sustain aquatic ecosystems. In its formal definition, three flow characteristics need to be minimally maintained: quantity, timing and quality. This overview paper highlights the challenges of some of the current methods used for eflow determination in the context of an evolving climate. As hydrological methods remain popular, they are first analyzed by describing some of the potential caveats associated with their usage when flow time series are non-stationarity. The timing of low-flow events will likely change within a season but will also likely shift in seasonality in some regions. Flow quality is a multi-faceted concept. It is proposed that a first simple step to partly incorporate flow quality in future analyses is to include the water temperature as a covariate. Finally, holistic approaches are also critically revisited, and simple modifications to the Ecological Limits of Flow Alteration (ELOHA) framework are proposed. Full article

The European Union Water Framework Directive (WFD) encourages water managers to implement active stakeholder involvement to achieve sustainable water management. However, the WFD does not describe in detail how member states should operationalize participation. The need for local experience and local understanding of collaborative governance (co-governance) processes remains. The WaterCoG project evaluated 11 local pilot schemes. Building on the participatory, qualitative evaluation of pilot schemes from Sweden, United Kingdom, Denmark, The Netherlands, and Germany, the authors take a closer look at how co-governance can improve water governance, how water managers can make best use of tools and knowledge, and how they can improve process designs. The results reflect how social learning and successful co-governance are linked. Social learning as a shared understanding of complex ecosystem and water-management issues can be supported with active stakeholder involvement and citizen science. As such, in co-governance processes, stakeholders need technical access to data and knowledge and a shared process memory. This enables them to develop a shared understanding and facilitates bringing together competing interests and finding new solutions. Participatory tools became part of successful processes by building trust and knowledge based on commitment. However, proficient process design and facilitation make these tools more effective. Full article

The photoexcitation of suitable semiconducting materials in aqueous environments can lead to the production of reactive oxygen species (ROS). ROS can inactivate microorganisms and degrade a range of chemical compounds. In the case of heterogeneous photocatalysis, semiconducting materials may suffer from fast recombination of electron–hole pairs and require post-treatment to separate the photocatalyst when a suspension system is used. To reduce recombination and improve the rate of degradation, an externally applied electrical bias can be used where the semiconducting material is immobilised onto an electrically conducive support and connected to a counter electrode. These electrochemically assisted photocatalytic systems have been termed “photoelectrocatalytic” (PEC). This review will explain the fundamental mechanism of PECs, photoelectrodes, the different types of PEC reactors reported in the literature, the (photo)electrodes used, the contaminants degraded, the key findings and prospects in the research area. Full article

We analyze how residential water consumption is influenced by the consumption of households belonging to the same social group (peer effect). Analyses are based on household-level data provided by the Brazilian Household Budget Survey and use an innovative strategy that estimates the spatial dependence of water consumption while simultaneously controlling for potential sources of sample selectivity and endogeneity. The estimates of our quantile regression models highlight that, conditional on household characteristics, the greater the household water consumption, the greater the peer effect. In other words, the overconsumption of residential water seems to be influenced mainly by the behavior of social peers. Full article

In this work, the pyrolysis of post-consumer mixed plastic waste (polypropylene (PP), polystyrene (PS) and polyethylene film (PE)) is carried out. The solid product of the pyrolysis is characterized and tested for its use as adsorbent of lead present in aqueous media. The pyrolysis temperature has a great influence on the solid product yield, decreasing when the temperature increases. The highest yield to solid product obtained is from the pyrolysis of film at lower temperature (450 °C), reaching almost 14%. The results of product solid characterization reveal that the carbon, hydrogen and nitrogen content decreases with increasing pyrolysis temperature. Furthermore, both the ash and the volatile content are related to the pyrolysis temperature. The ash content is higher when the pyrolysis temperature is higher, while when the temperature increases, a solid product with lower volatile content is obtained. In respect to specific surface area, a higher pyrolysis temperature improves the properties of the solid product as an adsorbent. The adsorption capacity increases as the pyrolysis temperature increases, with the highest value of 7.91 mg/g for the solid obtained in the pyrolysis at 550 °C. In addition, adsorption capacity increases as the initial concentration of lead rises, reaching a maximum value close to 26 mg/g for an initial concentration of 40 mg/L. The Sips model is the one that best reproduces the experimental results of the adsorption process equilibrium study. Full article

In the Venice Lagoon some of the highest tides in the Mediterranean occur, which have influenced the evolution of the city of Venice and the surrounding lagoon for centuries. The forecast of “high waters” in the lagoon has always been a matter of considerable practical interest. In this study, tide prediction models were developed for the entire lagoon based on Nonlinear Autoregressive Exogenous (NARX) neural networks. The NARX-based model development was performed in two different stages. The first stage was the training and testing of the NARX network, performed on data collected in a given time interval at the tide gauge of Punta della Salute, at the end of Canal Grande. The second stage consisted of a comprehensive validation of the model in the entire Venice Lagoon, with a detailed analysis of data from three measuring stations located in points of the lagoon with different characteristics. Good predictions were achieved regardless of whether the meteorological parameters were considered among input parameters, even with considerable time advance. Furthermore, the forecasting model based on NARX has proved capable of predicting even exceptional high tides. The proposed model could be a useful support tool for the management of the MOSE system, which will protect Venice from high waters. Full article

Inappropriate irrigation conditions and nitrogen application can negatively affect soil carbon–nitrogen content and yield of maize, as well as can lead to underground water pollution and soil degradation. A two year (2018, 2019) field experiment was carried out to determine the effect of irrigation and N, alone and in combination on maize grain yield, grain nitrogen content, soil inorganic N and MBC of one-year double cropping maize (Zea mays L.) in a subtropical region. Split plot design was adopted, with main plots consisting of two water regimes: drip irrigation (drip irrigation to keep soil water content no less than 70% of maximum field capacity) and rainfed (no irrigation during growing period). Split-plot treatments consisted of five nitrogen application levels, including 0 (N0), 150 (N150), 200 (N200), 250 (N250), and 300 kg/ha (N300). The results of two-year field experiment showed that soil irrigation nitrogen interaction had a significant influence on the all measured parameters. In detail, soil NH₄⁺-N and NO₃⁻-N content, total nitrogen (TN), soil organic carbon (SOC) and grain nitrogen contents under the combined treatment of N250 and supplementary irrigation were higher relative to other treatments. Compared with rainfed, maize yield, thousand grains weight (TGW) and harvest index increased by 22.0%, 7.7%, and 15.2% under supplemental irrigation. Yield and TGW N300 were 287 kg/ha and 3.1 g higher than those of N250, and yield and TGW of N250 were 59.4% and 23.1% higher than those of N0, respectively. The yield of spring maize was 24.0% significantly higher than that of autumn maize. Therefore, we suggested that 250 kg/ha nitrogen application fertilizer combined with supplementary irrigation can improve soil fertility and annual maize yield in subtropical one-year double cropping region. Full article

A comprehensive hydrogeological understanding of the deep Upper Jurassic carbonate aquifer, which represents an important geothermal reservoir in the South German Molasse Basin (SGMB), is crucial for improved and sustainable groundwater resource management. Water chemical data and environmental isotope analyses of δD, δ${}^{18}$O and ${}^{87}$Sr/${}^{86}$Sr were obtained from groundwater of 24 deep Upper Jurassic geothermal wells and coupled with a few analyses of noble gases (${}^3$He/${}^4$He, ${}^{40}$Ar/${}^{36}$Ar) and noble gas infiltration temperatures. Hierarchical cluster analysis revealed three major water types and allowed a hydrochemical zoning of the SGMB, while exploratory factor analyses identified the hydrogeological processes affecting the water chemical composition of the thermal water. Water types 1 and 2 are of Na-[Ca]-HCO${}_3$-Cl type, lowly mineralised and have been recharged under meteoric cold climate conditions. Both water types show ${}^{87}$Sr/${}^{86}$Sr signatures, stable water isotopes values and calculated apparent mean residence times, which suggest minor water-rock interaction within a hydraulically active flow system of the Northeastern and Southeastern Central Molasse Basin. This thermal groundwater have been most likely subglacially recharged in the south of the SGMB in close proximity to the Bavarian Alps with a delineated northwards flow direction. Highly mineralised groundwater of water type 3 (Na-Cl-HCO${}_3$ and Na-Cl) occurs in the Eastern Central Molasse Basin. In contrast to water types 1 and 2, this water type shows substantial water-rock interaction with terrestrial sediments and increasing ${}^{40}$Ar/${}^{36}$Ar ratios, which may also imply a hydraulic exchange with fossil formation waters of overlying Tertiary sediments. Full article

This study reviews the monsoonal Yangtze and the arid Nile deltas with the objective of understanding how the process–response between river-basin modifications and delta-estuary ecological degradation are interrelated under contrasting hydroclimate dynamics. Our analysis shows that the Yangtze River had a long-term stepwise reduction in sediment and silicate fluxes to estuary due to dam construction since the 1960s, especially after the Three Gorges Dam (TGD) closed in 2003. By contrast, the Nile had a drastic reduction of sediment, freshwater, and silicate fluxes immediately after the construction of the Aswan High Dam (AHD) in 1964. Seasonal rainfall in the mid-lower Yangtze basin (below TGD) complemented riverine materials to its estuary, but little was available to the Nile coast below the AHD in the hyper-arid climate setting. Nitrogen (N) and phosphate (P) fluxes in both river basins have increased because of the overuse of N- and P-fertilizer, land-use changes, urbanization, and industrialization. Nutrient ratios (N:P:Si) in both delta-estuaries was greatly altered, i.e., Yangtze case: 75:1:946 (1960s–1970s), 86:1:272 (1980s–1990s) and 102:1:75 (2000s–2010s); and Nile case: 6:1:32 (1960s–1970s), 8:1:9 (1980s–1990s), and 45:1:22 (2013), in the context of the optimum of Redfield ratio (N:P:Si = 16:1:16). This led to an ecological regime shift evidenced by a long-term change in phytoplankton communities in the Yangtze estuary, where silicious algae tended to lose dominance since the end of the 1990s, when more toxic dinoflagellates began to emerge. In the Nile estuary, such a regime shift was indicated by the post-dam dramatic reduction in zooplankton standing crop and fish landings until the early 2000s when biological recovery occurred due to nutrient inputs from anthropogenic sources. Although the Yangtze had higher human impacts than the Nile in terms of population, industrialization, and fertilizer application, N concentrations in the Nile estuarine waters surpassed the Yangtze in recent decades. However, eutrophication in the Yangtze estuary is much more intensive than in the Nile, leading to the likelihood of its estuarine water becoming more acidic than ever before. Therefore, ecological degradation in both delta-estuaries does not follow a linear trajectory, due not only to different climate dynamics but also to human forcings. The comparative insights of this study should be incorporated into future integrated coastal management of these two important systems. Full article

Resource reuse has become an important aspect of wastewater management. At present, use of sludge in agriculture is one of the major reuse routes. Conventional municipal wastewater treatment does not involve any designated process for removal of heavy metals, and these distribute mainly between effluent and sludge. Enhanced removal of heavy metals during primary treatment may decrease the heavy metal concentrations in both effluent and sludge from secondary treatment and promote long-term reuse of secondary sludge. This review considers heavy metal occurrence and removal during primary settling, together with possible treatment technologies for heavy metal removal in primary settlers and their theoretical performance. The variation in total heavy metal concentrations and dissolved fraction in raw municipal wastewater points to a need for site-specific assessments of appropriate technologies for improved heavy metal removal. Studies examining the heavy metal speciation beyond dissolved/particulate are few. Missing or disparate information on process parameters such as hydraulic retention time, pH and composition of return flows makes it hard to generalize the findings from studies concerning heavy metal removal in primary settlers. Coagulation/flocculation and use of low-cost sorbents were identified as the most promising methods for enhancing heavy metal removal during primary settling. Based on the available data on heavy metal speciation and removal during primary settling, sorption technologies may be most effective for enhancing the removal of Cu and Ni, while coagulation may be efficient for Cd, Cr, Cu, Pb, Zn and Hg removal (but not as efficient for Ni removal). Full article

Water, energy, and food are essential resources for humanity. The growing shortages of these resources and serious deterioration of river environments are having a big impact on the sustainable development of the economy and society in China. Water, energy, and food support human life and yet coexist in different ways, and therefore it is critical to find a way for all three key elements to be secured in order to support high standards of sustainable development in China. We used the criteria of stability, coordination, and sustainability of symbiotic systems to select 33 indexes that were then used to establish an index system. The weight of index was determined by using the entropy weight method combined with Analytic Hierarchy Process. The fuzzy comprehensive evaluation method was used to calculate the collaborative security index, which was the basis of our evaluation of the collaborative water–energy–food security of China in time and space. The results show that North China and Northwest China are at high water–food–energy security risk, while East, Central, and South China are at moderate risk. With the exception of Southwest China and South China, risk in most parts of the country has risen over the past decades, while it has fallen in Shandong, Henan, Sichuan, and Yunnan provinces. Full article

Water is an essential necessity for human beings; however, South Africa has a long history of inequalities dating back to apartheid politics and legislation which denied access to water to disadvantaged black populations mostly residing in rural areas. Although apartheid has officially ended, whether the lack of access to water by such populations who still cannot afford it exists and aligns with international human rights principles of equality and non-discrimination merits an examination. To redress the injustices of the apartheid regime, the right to have access to sufficient water is entrenched in section 27(1)(b) of the 1996 South African Constitution. In addition to embracing equality and non-discrimination, the Constitution informs other instruments and measures such as free basic water policy and pre-paid meters meant to ensure access to water. However, the plight of these populations persists in post-apartheid South Africa, but it is rarely a subject of academic scrutiny how the notion of affirmative action as grounded in the principles of equality and non-discrimination under human rights law can be deployed as a response. Using a doctrinal research approach, this article argues that the continuing struggle of disadvantaged communities with access to water does not only constitute water apartheid, it negates the human rights principles of equality and non-discrimination. The principle of affirmative action is useful in responding to inadequate access to sufficient water by disadvantaged populations in post-apartheid South Africa. Full article

Although plot-scale erosion experiments are numerous, there are few studies on constructed landforms. This limits the understanding of their long-term stability, which is especially important for planning mined land rehabilitation. The objective of this study was to gain insight into the erosion processes in a 30 × 30 m trial plot on a mine waste rock dump in tropical northern Australia. The relationships between rainfall, runoff and suspended and bedload sediment export were assessed at annual, seasonal, inter-event and intra-event timescales. During a five-year study period, 231 rainfall–runoff–sediment export events were examined. The measured bedload and suspended sediments (mainly represented in nephelometric turbidity units (NTU)) showed the dominance of the wet season and heavy rainfall events. The bedload dominated the total mass, although the annual bedload diminished by approximately 75% over the five years, with greater flow energy required over time to mobilise the same bedload. The suspended load was more sustained, though it also exhibited an exhaustion process, with equal rainfall and runoff volumes and intensities, leading to lower NTU values over time. Intra-event NTU dynamics, including runoff-NTU time lags and hysteretic behaviours, were somewhat random from one event to the next, indicating the influence of the antecedent distribution of mobilisable sediments. The value of the results for supporting predictive modelling is discussed. Full article

An experimental investigation of flexural-gravity waves was performed in the Hamburg Ship Model Basin HSVA ice tank. Physical characteristics of the water-ice system were measured in several locations of the tank with a few sensors deployed in the water and on the ice during the tests. The three-dimensional motion of ice was measured with the optical system Qualisys; water pressure was measured by several pressure sensors mounted on the tank wall, in-plane deformations of the ice and the temperatures of the ice and water were measured by fiber optic sensors; and acoustic emissions were recorded with compressional crystal sensors. The experimental setup and selected results of the tests are discussed in this paper. Viscous-elastic model (Burgers material) is adopted to describe the dispersion and attenuation of waves propagating below the ice. The elastic modulus and the coefficient of viscosity are calculated using the experimental data. The results of the measurements demonstrated the dependence of wave characteristics from the variability of ice properties during the experiment caused by the brine drainage. We showed that the cyclic motion of the ice along the tank, imitating ice drift, and the generation of under ice turbulence cause an increase of wave damping. Recorded acoustic emissions demonstrated cyclic microcracking occurring with wave frequencies and accompanying bending deformations of the ice. This explains the viscous and anelastic rheology of the model ice. Full article

Pakistan is among the countries that have already crossed the water scarcity line, and the situation is worsened due to the recent pandemic. This is because the major budget of the country is shifted to primary healthcare activities from other development projects that included water treatment and transportation infrastructure. Consequently, water-borne diseases have increased drastically in the past few months. Therefore, there is a dire need to address this issue on a priority basis to ameliorate the worsening situation. One possible solution is to shift the focus/load from mega-projects that require a plethora of resources, money, and time to small domestic-scale systems for water treatment. For this purpose, domestic-scale solar stills are designed, fabricated, and tested in one of the harshest climatic condition areas of Pakistan, Rahim Yar Khan. A comprehensive overview of the regional climatology, including wind speed, solar potential, and ambient temperature is presented for the whole year. The analysis shows that the proposed system can adequately resolve the drinking water problems of deprived areas of Pakistan. The average water productivity of 1.5 L/d/m² is achieved with a total investment of PKR 3000 (<$20). This real site testing data will serve as a guideline for similar system design in other arid areas globally. Full article

In drought years, most residents fail to improve water use efficiency due to residential water supply normally being prioritized in many regions, which makes other low-priority industrial water users suffer more from water shortage. This paper proposes a Pricing Strategy for Residential Water (PSRW), a water tariff that changes on annual time scale, based on the scarcity value of water resources, aiming to promote residential water conservation and reallocate water resources across the residential and industrial sectors during droughts. An optimization model to maximize the total benefit of residents and industrial sectors is introduced based on marginal benefit and price elasticity. The water shortage of industrial sectors is used to reflect the scarcity of water resources, and the lowest water supply standard for households and the maximum proportion of household water fee expenditure (HWFE) to household disposable income (HDI) are used to ensure the residents’ acceptability to price raising. It shows an “S-type” relationship between the optimal price raising coefficient and industrial water shortage, and two turning points are found in the curve, which are the starting and stopping points of price raising. The appearance of starting point depends on the non-negative net benefit, and the stopping point is affected by the factors that represent the residents’ acceptability to price raising. The application to Tianjin, a city in northern China with the rapid growth of population and economy but scarce water resources, shows PSRW is a potential means to improve water efficiency and optimize water resource allocation in water scarcity situations. Full article

Multi-objective evolutionary algorithms (MOEAs) are widely used to optimize multi-purpose reservoir operations. Considering that most outcomes of MOEAs are Pareto optimal sets with a large number of incomparable solutions, it is not a trivial task for decision-makers (DMs) to select a compromise solution for application purposes. Due to the increasing popularity of data-driven decision-making, we introduce a clustering-based decision-making method into the multi-objective reservoir operation optimization problem. Traditionally, solution selection has been conducted based on trade-off ranking in objective space, and solution characteristics in decision space have been ignored. In our work, reservoir operation processes were innovatively clustered into groups with unique properties in decision space, and the trade-off surfaces were analyzed via clustering in objective space. To attain a suitable performance, a new similarity measure, referred to as the Mei–Wang fluctuation similarity measure (MWFSM), was tailored to reservoir operation processes. This method describes time series in terms of both their shape and quantitative variation. Then, a compromise solution was selected via the joint use of two clustering results. A case study of the Three Gorges cascade reservoirs system under small and medium floods was investigated to verify the applicability of the proposed method. The results revealed that the MWFSM effectively distinguishes reservoir operation processes. Two more operation patterns with similar positions but different shapes were identified via MWFSM when compared with Euclidean distance and the dynamic time warping method. Furthermore, the proposed method decreased the selection range from the whole Pareto optimal set to a set containing relatively few solutions. Finally, a compromise solution was selected. Full article

Small streams in urbanized rural areas receive loads of P from various, often episodic, sources. This paper addresses, through a tracer test with ${}^{32}$P, retention and transport of a pulse input of phosphorus in a 2.6 km long stretch of a channelized second-order lowland stream. Tritiated water was introduced alongside the ${}^{32}$P-labelled ortophosphate in order to isolate the influence of the hydrodynamic factors on P behavior. Tracer concentrations in unfiltered water samples were measured by liquid scintillation counting. Four in-stream and five hyporheic breakthrough curves were collected at four points along the stream, two of which encompass a beaver dam impoundment. The overall retention efficiency of ${}^{32}$P along the studied reach was 46%. The transient storage transport model OTIS-P provided reasonable fits for in-stream breakthrough curves (BTCs) but failed at reproducing the hyporheic BTCs. The overall small effect of transient storage on solute transport was higher in the stretch with a more pronounced surface storage. Transient storage and phosphorus retention were not enhanced in the beaver dam impoundment. Full article

Some species of seagrasses (e.g., Zostera marina and Posidonia oceanica) have declined in the Mediterranean, at least locally. Others are progressing, helped by sea warming, such as Cymodocea nodosa and the non-native Halophila stipulacea. The decline of one seagrass can favor another seagrass. All in all, the decline of seagrasses could be less extensive and less general than claimed by some authors. Natural recolonization (cuttings and seedlings) has been more rapid and more widespread than was thought in the 20th century; however, it is sometimes insufficient, which justifies transplanting operations. Many techniques have been proposed to restore Mediterranean seagrass meadows. However, setting aside the short-term failure or half-success of experimental operations, long-term monitoring has usually been lacking, suggesting that possible failures were considered not worthy of a scientific paper. Many transplanting operations (e.g., P. oceanica) have been carried out at sites where the species had never previously been present. Replacing the natural ecosystem (e.g., sandy bottoms, sublittoral reefs) with P. oceanica is obviously inappropriate in most cases. This presupposes ignorance of the fact that the diversity of ecosystems is one of the bases of the biodiversity concept. In order to prevent the possibility of seagrass transplanting from being misused as a pretext for further destruction, a guide for the proper conduct of transplanting is proposed. Full article

Intensity-duration-frequency (IDF) relationships are traditional tools in water infrastructure planning and design. IDFs are developed under a stationarity assumption which may not be realistic, neither in the present nor in the future, under a changing climatic condition. This paper introduces a framework for generating non-stationary IDFs under climate change, assuming that probability of occurrence of quantiles changes over time. Using Extreme Value Theory, eight trend combinations in Generalized Extreme Value (GEV) parameters using time as covariate are compared with a stationary GEV, to identify the best alternative. Additionally, a modified Equidistance Quantile Matching (EQM_NS) method is implemented to develop IDFs for future conditions, introducing non-stationarity where justified, based on the Global Climate Models (GCM). The methodology is applied for Moncton and Shearwater gauges in Northeast Canada. From the results, it is observed that EQM_NS is able to capture the trends in the present and to translate them to estimated future rainfall intensities. Comparison of present and future IDFs strongly suggest that return period can be reduced by more than 50 years in the estimates of future rainfall intensities (e.g., historical 100-yr return period extreme rainfall may have frequency smaller than 50-yr under future conditions), raising attention to emerging risks to water infrastructure systems. Full article

Shifts in winter temperature and precipitation patterns can profoundly affect snow accumulation and melt regimes. These shifts have varying impacts on local to large-scale hydro-ecological systems and freshwater distribution, especially in cold regions with high hydroclimatic heterogeneity. We evaluate winter climate changes in the six ecozones (Mountains, Foothills, Prairie, Parkland, Boreal, and Taiga) in Alberta, Canada, and identify regions of elevated susceptibility to change. Evaluation of historic trends and future changes in winter climate use high-resolution (~10 km) gridded data for 1950–2017 and projections for the 2050s (2041–2070) and 2080s (2071–2100) under medium (RCP 4.5) and high (RCP 8.5) emissions scenarios. Results indicate continued declines in winter duration and earlier onset of spring above-freezing temperatures from historic through future periods, with greater changes in Prairie and Mountain ecozones, and extremely short or nonexistent winter durations in future climatologies. Decreases in November–April precipitation and a shift from snow to rain dominate the historic period. Future scenarios suggest winter precipitation increases are expected to predominantly fall as rain. Additionally, shifts in precipitation distributions are likely to lead to historically-rare, high-precipitation extreme events becoming more common. This study increases our understanding of historic trends and projected future change effects on winter snowpack-related climate and can be used inform adaptive water resource management strategies. Full article

Water resources face an unparalleled confluence of pressures, with agriculture and urban growth as the most relevant human-related stressors. In this context, methodologies using a Nexus framework seem to be suitable to address these challenges. However, the urban sector has been commonly ignored in the Nexus literature. We propose a Nexus framework approach, considering the economic dimensions of the interdependencies and interconnections among agriculture (food production) and the urban sector as water users within a common basin. Then, we assess the responses of both sectors to climatic and demographic stressors. In this setting, the urban sector is represented through an economic water demand at the household level, from which economic welfare is derived. Our results show that the Nexus components here considered (food, water, and welfare) will be negatively affected under the simulated scenarios. However, when these components are decomposed to their particular elements, we found that the less water-intensive sector—the urban sector—will be better off since food production will leave significant amounts of water available. Moreover, when addressing uncertainty related to climate-induced shocks, we could identify the basin resilience threshold. Our approach shows the compatibilities and divergences between food production and the urban sector under the Nexus framework. Full article

Cadmium is one of the most hazardous metals in the environment, even when present at very low concentrations. This study reports the systematic development of Kenaf fiber biochar as an adsorbent for the removal of cadmium (Cd) (II) ions from water. The adsorbent development was aided by an optimization tool. Activated biochar was prepared using the physicochemical activation method, consisting of pre-impregnation with NaOH and nitrogen (N₂) pyrolysis. The influence of the preparation parameters—namely, chemical impregnation (NaOH: KF), pyrolysis temperature, and pyrolysis time on biochar yield, removal rate, and the adsorption capacity of Cd (II) ions—was investigated. From the experimental data, some quadratic correlation models were developed according to the central composite design. All models demonstrated a good fit with the experimental data. The experimental results revealed that the pyrolysis temperature and heating time were the main factors that affected the yield of biochar and had a positive effect on the Cd (II) ions’ removal rate and adsorption capacity. The impregnation ratio also showed a positive effect on the specific surface area of the biochar, removal rate, and adsorption capacity of cadmium, with a negligible effect on the biochar yield. The optimal biochar-based adsorbent was obtained under the following conditions: 550 °C of pyrolysis temperature, 180 min of heating time, and a 1:1 NaOH impregnation ratio. The optimum adsorbent showed 28.60% biochar yield, 69.82% Cd (II) ions removal, 23.48 mg/g of adsorption capacity, and 160.44 m²/g of biochar-specific area. Full article

In this paper, the different possibilities and innovations related to sustainable aquaculture in the Mediterranean area are discussed, while different maricultural methods, and the role of Integrated Multi-Trophic Aquaculture (IMTA) in supporting the exploitation of the ocean’s resources, are also reviewed. IMTA, and mariculture in general, when carefully planned, can be suitable for environmental restoration and conservation purposes. Aquaculture, especially mariculture, is a sector that is progressively increasing in parallel with the increase in human needs; however, several problems still affect its development, mainly in relation to the choice of suitable sites, fodder production, and the impact on the surrounding environment. A current challenge that requires suitable solutions is the implementation of IMTA. Unfortunately, some criticisms still affect this approach, mostly concerning the commercialization of new products such as invertebrates and seaweeds, notwithstanding their environmentally friendly character. Regarding the location of a suitable site, mariculture plans are currently displaced from inshore to offshore, with the aim of reducing the competition for space with other human activities carried out within coastal waters. Moreover, in open water, waste loading does not appear to be a problem, but high-energy waters increase maintenance costs. Some suggestions are given for developing sustainable mariculture in the Mediterranean area, where IMTA is in its infancy and where the scarce nutrients that characterize offshore waters are not suitable for the farming of both filter feeder invertebrates and macroalgae. From the perspective of coupling mariculture activity with restoration ecology, the practices suggested in this review concern the implementation of inshore IMTA, creating artificially controlled gardens, as well as offshore mussel farming coupled with artificial reefs, while also hypothesizing the possibility of the use of artificially eutrophized areas. Full article

Groundwater contamination due to saltwater intrusion (SWI) has an extreme effect on freshwater quality. Analytical and numerical models could be used to investigate SWI. This study aims to develop an analytical solution to investigate SWI into coastal aquifers which was applied to a real case study at the Middle Nile Delta aquifer (MNDA). The study presented a new formula to predict the difference in depth of freshwater to seawater interface due to a change in boundary conditions. A Computer Program for Simulation of Three-Dimensional Variable-Density Ground-Water Flow and Transport (SEAWAT) is used for groundwater flow simulation and SWI and the results compared with the developed analytical solution. Four scenarios are considered in the study, including; the sea-level rise (SLR), reduction in recharge, over abstraction, and combination after 50 years (2070). The analytical solution gave good results compared to the numerical one where Equiline 1 intruded to 103 and 101.66 km respectively at the base case. The results also gave a good agreement between numerical and the analytical solution for SLR due to climate changes by 52.80 cm where the Equiline 1 reached to 105 and 103.45 km. However, the reduction in aquifer recharge by 18.50% resulted in an intrusion for the Equiline-1 to 111 and 108.25 km from the shoreline. Over pumping due to the increase in population by 89% has increased the SWI to reach 121,110.31 km, while it reached 131 and 111.32 km at a combination of the three scenarios, which represents the highest threatening scenario. Also, the difference between the two solutions reached 1.30%, 1.48%, 2.48%, 8.84%, and 15.02%, respectively for the base case and four scenarios. For the current case study, the analytical model gave good results compared to the numerical one, so that the analytical solution is recommended for similar studies, which could save the time and capabilities of computer required for the numerical solutions. Full article

Precipitation is the main source for replenishing groundwater stored in aquifers for a myriad of beneficial purposes, especially in arid and semi-arid regions. A significant portion of the municipal and agricultural water demand is satisfied through groundwater withdrawals in Texas. These withdrawals have to be monitored and regulated to be in balance with the recharge amount from precipitation in order to ensure water security. The main goal of this study is to understand the spatio-temporal variability of precipitation in the 21st century using high spatial resolution stage-IV radar data over the state of Texas and examine some climatic controls behind this variability. The results will shed light on the trends of precipitation and hence will contribute to improving water resources management strategies and policies. Pettit’s test and Standard Normal Homogeneity Test (SNHT), tools for detecting change-point in the monthly precipitation, suggested change-points have occurred across the state around the years 2013 and 2014. The test for the homogeneity of the data before and after 2013 revealed that, in over 64% of the state, the precipitation means were significantly different. The Panhandle region (northern part) is the only part of the state that did not show a significant difference in the mean precipitation before and after 2013. Theil-Sen’s slope test, Correlated Seasonal Mann-Kendall Test, and Cox and Stuart Trend Test all indicated that there were no significant trends in the monthly precipitation after 2013 in over 98% of the area of the state. Texas precipitation was found to be influenced significantly by the El Niño-Southern Oscillation (ENSO) and the Pacific Decadal Oscillation (PDO). A significant correlation in more than 82% and 60% of the state was found with ENSO at two-month and with PDO at four-month lag, respectively. Full article

Industrial developments in the oil and gas, petrochemical, pharmaceutical and food sector have contributed to the large production of oily wastewater worldwide. Oily wastewater pollution affects drinking water and groundwater resources, endangers aquatic life and human health, causes atmospheric pollution, and affects crop production. Several traditional and conventional methods were widely reported, and the advantages and limitations were discussed. However, with the technology innovation, new trends of coupling between techniques, use of new materials, optimization of the cleaning process, and multiphysical approach present new paths for improvement. Despite these trends of improvement and the encouraging laboratory results of modern and green methods, many challenges remain to be raised, particularly the commercialization and the global aspect of these solutions and the reliability to reduce the system’s maintenance and operational cost. In this review, the well-known oily wastewater cleaning methods and approaches are being highlighted, and the obstacles faced in the practical use of these technologies are discussed. A critical review on the technologies and future direction as the road to commercialization is also presented to persevere water resources for the benefit of mankind and all living things. Full article

A variety of hydrological models is currently available. Many of those employ physically based formulations to account for the complexity and spatial heterogeneity of natural processes. In turn, they require a substantial amount of spatial data, which may not always be available at sufficient quality. Recently, a top-down approach for distributed rainfall-runoff modelling has been developed, which aims at combining accuracy and simplicity. Essentially, a distributed model with uniform model parameters (base model) is derived from a calibrated lumped conceptual model. Subsequently, selected parameters are disaggregated based on links with the available spatially variable catchment properties. The disaggregation concept is now adjusted to better account for non-linearities and extended to incorporate more model parameters (and, thus, larger catchment heterogeneity). The modelling approach is tested for a catchment including several flow gauging stations. The disaggregated model is shown to outperform the base model with respect to internal catchment dynamics, while performing similarly at the catchment outlet. Moreover, it manages to bridge on average 44% of the Nash–Sutcliffe efficiency difference between the base model and the lumped models calibrated for the internal gauging stations. Nevertheless, the aforementioned improvement is not necessarily sufficient for reliable model results. Full article

Microplastics (MP) have recently been considered as emerging contaminants in the water environment. In the last number of years, the number of studies on MP has grown quickly due to the increasing consciousness of the potential risks for human health related to MP exposure. The present review article discusses scientific literature regarding MP occurrence and accumulation on the aquatic compartment (river, lake, wastewater, seafood), the analytical methods used to assess their concentration, their fate and transport to humans, and delineates the urgent areas for future research. To better analogize literature data regarding MP occurrence in the aquatic compartment we subdivided papers based on sampling, analytical methods, and concentration units with the aim to help the reader identify the similarities and differences of the considered research papers, thus making the comparison of literature data easier and the individuation of the most relevant articles for the reader’s interests faster. Furthermore, we argued about several ways for MP transport to humans, highlighting some gaps in analytical methods based on the reviewed publications. We suggest improving studies on developing standardized protocols to collect, process, and analyze samples. Full article

The main landfill in the city of Rabat (Morocco) is based on sandy material containing the shallow Mio-Pliocene aquifer. The presence of a pollution plume is likely, but its extent is not known. Measurements of spontaneous potential (SP) from the soil surface were cross-referenced with direct measurements of the water table and leachates (pH, redox potential, electrical conductivity) according to the available accesses, as well as with an analysis of the landscape and the water table flows. With a few precautions during data acquisition on this resistive terrain, the results made it possible to separate the electrokinetic (~30%) and electrochemical (~70%) components responsible for the range of potentials observed (70 mV). The plume is detected in the hydrogeological downstream of the discharge, but is captured by the natural drainage network and does not extend further under the hills. Full article

Extreme streamflow nonstationarity has probably attracted more attention than mean streamflow nonstationarity in the assessment of the impacts of climate change on the water cycle. Nonetheless, a significant decrease in mean streamflow could lead to conditions of scarcity of freshwater in the long-term period, seriously compromising the sustainability of the demand for civil, agricultural, and industrial uses. Regional analyses are useful to better characterize an area’s nonstationarity, since a clear trend at a global scale has not been detected yet. In this article, long-term and high-quality series of streamflow discharges observed in five rivers in the Central Italian Alps, including two multicentury series and two new precipitation and streamflow series not analyzed before, are investigated to statistically characterize individual trends of mean annual runoff volumes. Nonparametric pooled statistics are also introduced to assess the regional trend. Additional climatic and nonclimatic factors, namely, precipitation trends and land cover transformations, have also been considered as potential change drivers. Unlike precipitation, runoff volumes show a marked and statistically significant decrease of −1.45 mm/year, which appears to be homogeneous in the region. The land cover transformation analysis presented here revealed extensive woodland expansions of 510 km² in 2018 out of the 2650 km² area measured in 1954, representing 38% of the area investigated in this study: this anthropic driver of enhanced hydrologic losses can be recognized as an additional likely cause for the regional runoff volume decrease. Full article

In shallow alluvial aquifers characterized by coarse sediments, the evapotranspiration rates from groundwater are often not accounted for due to their low capillarity. Nevertheless, this assumption can lead to errors in the hydrogeological balance estimation. To quantify such impacts, a numerical flow model using MODFLOW was set up for the Tronto river alluvial aquifer (Italy). Different estimates of evapotranspiration rates were retrieved from the online Moderate Resolution Imaging Spectroradiometer (MODIS) database and used as input values. The numerical model was calibrated against piezometric heads collected in two snapshots (mid-January 2007 and mid-June 2007) in monitoring wells distributed along the whole alluvial aquifer. The model performance was excellent, with all the statistical parameters indicating very good agreement between calculated and observed heads. The model validation was performed using baseflow data of the Tronto river compared with the calculated aquifer–river exchanges in both of the simulated periods. Then, a series of numerical scenarios indicated that, although the model performance did not vary appreciably regardless of whether it included evapotranspiration from groundwater, the aquifer–river exchanges were influenced significantly. This study showed that evapotranspiration from shallow groundwater accounts for up to 21% of the hydrogeological balance at the aquifer scale and that baseflow observations are pivotal in quantifying the evapotranspiration impact. Full article

This article describes the features and migration patterns of natural long-lived heavy radionuclides ²³⁸U and ²²⁶Ra in the major components of the environment including rocks, river waters, soils, and vegetation of permafrost taiga landscapes of Southern Yakutia, which helped us to understand the scale and levels of their radioactive contamination. Different methods have been used in this study to determine the content of ²³⁸U and ²²⁶Ra in various samples, including gamma-ray spectrometry, X-ray spectroscopy, laser excited luminescence, and emanation method. It was determined that the main source of radioactive pollution of soil and vegetation cover, as well as surface waters in these technogenic landscapes, are the dumps of radioactive rock that were formed here as the result of geological exploration carried out in this area during the last third of the 20th century. The rocks studied were initially characterized by a coarse, mainly stony gravelly composition and contrasting radiation parameters, where the gamma radiation exposure rate varied between 1.71 and 16.7 µSv/h, and the contents of ²³⁸U and ²²⁶Ra were within the range 126–1620 mg/kg and 428–5508 × 10⁻⁷ mg/kg, respectively, and the ²²⁶Ra: ²³⁸U ratio was 1.0. This ratio shifted later on from the equilibrium state towards the excess of either ²³⁸U or ²²⁶Ra, due to the processes of air, water, and biogenic migration. Two types of ²³⁸U and ²²⁶Ra radionuclides migration were observed in studied soils, namely aerotechnogenic and hydrotechnogenic, each of which results in a different intraprofile radionuclide distribution and different levels of radioactive contamination. In this study, we also identified plants capable of selective accumulation of certain radionuclides, including Siberian mountain ash (Sorbus sibiricus), which selectively absorbs ²²⁶Ra, and terrestrial green and aquatic mosses, which accumulate significant amounts of ²³⁸U. Full article

Many calibrated hydrological models are inconsistent with the behavioral functions of catchments and do not fully represent the catchments’ underlying processes despite their seemingly adequate performance, if measured by traditional statistical error metrics. Using such metrics for calibration is hindered if only short-term data are available. This study investigated the influence of varying lengths of streamflow observation records on model calibration and evaluated the usefulness of a signature-based calibration approach in conceptual rainfall-runoff model calibration. Scenarios of continuous short-period observations were used to emulate poorly gauged catchments. Two approaches were employed to calibrate the HBV model for the Brue catchment in the UK. The first approach used single-objective optimization to maximize Nash–Sutcliffe efficiency (NSE) as a goodness-of-fit measure. The second approach involved multiobjective optimization based on maximizing the scores of 11 signature indices, as well as maximizing NSE. In addition, a diagnostic model evaluation approach was used to evaluate both model performance and behavioral consistency. The results showed that the HBV model was successfully calibrated using short-term datasets with a lower limit of approximately four months of data (10% FRD model). One formulation of the multiobjective signature-based optimization approach yielded the highest performance and hydrological consistency among all parameterization algorithms. The diagnostic model evaluation enabled the selection of consistent models reflecting catchment behavior and allowed an accurate detection of deficiencies in other models. It can be argued that signature-based calibration can be employed for building adequate models even in data-poor situations. Full article

In the stepped spillway, the steps, by providing an artificial roughening bed, dissipate the flow of energy more than other types of spillways, so the construction costs for stilling basin are reduced. However, what is important in this type of spillway is increasing the effectiveness of steps in the rate of energy dissipation. The present study deals with experimental and numerical simulations regarding the influence of geometric appendance elements on the steps and its impact on the energy dissipation performances, flow patterns properties, turbulent kinetic energy, flow resistance and the Darcy roughness. The localization of inception point of air entrainment is also assessed. To this aim, different configurations are taken into account. The computational procedure is validated with experimental results and then used to test the hydraulic behavior of different geometric configurations. The results showed that the appendance elements on the steps increased the turbulent kinetic energy (TKE) values and Darcy–Weisbach friction and the energy dissipation increased significantly. By reducing the height of the elements, energy dissipation and the TKE value increase more significantly. With the appendance elements on step, the air entrainment inception locations a positioning further upstream than the flat step stepped spillway. Full article

Defining natural background levels (NBL) of geochemical parameters in groundwater is a key element for establishing threshold values and assessing the environmental state of groundwater bodies (GWBs). In the Apulia region (Italy), carbonate sequences and clastic sediments host the 29 regional GWBs. In this study, we applied the Italian guidelines for the assessment of the NBLs, implementing the EU Water Framework Directive, in a south-European region characterized by the typical Mediterranean climatic and hydrologic features. Inorganic compounds were analyzed at GWB scale using groundwater quality data measured half-yearly from 1995 to 2018 in the regional groundwater monitoring network (341 wells and 20 springs). Nitrates, chloride, sulfate, boron, iron, manganese and sporadically fluorides, boron, selenium, arsenic, exceed the national standards, likely due to salt contamination along the coast, agricultural practices or natural reasons. Monitoring sites impacted by evident anthropic activities were excluded from the dataset prior to NBL calculation using a web-based software tool implemented to automate the procedure. The NBLs resulted larger than the law limits for iron, manganese, chlorides, and sulfates. This methodology is suitable to be applied in Mediterranean coastal areas with high anthropic impact and overexploitation of groundwater for agricultural needs. The NBL definition can be considered one of the pillars for sustainable and long-term groundwater management by tracing a clear boundary between natural and anthropic impacts. Full article

Nourishment has shown to be an effective method for short-term storm protection along barrier islands and sandy beaches by reducing flooding, wave attack and erosion. However, the ability of nourishment to mitigate the effects of storms and sea level rise (SLR) and improve coastal resilience over decadal time scales is not well understood. This study uses integrated models of storm-driven hydrodynamics, morphodynamics and post-storm dune recovery to assess the effectiveness of beach and dune nourishment on barrier island morphological resilience over a 30-year period, accounting for storms and a moderate amount of SLR. Results show that at the end of the 30 years, nourishment contributes to maintaining island volumes by increasing barrier height and width compared with a no-action scenario (i.e., no nourishment, only natural recovery). During storms where the collision regime was dominant, higher volumes of sand were lost from the wider beach in the nourishment scenario than in the no-action scenario. During stronger storms, nourishment reduced dune overtopping compared with the no-action scenario, allowing the island to maintain height and width. Additionally, nourishment was particularly effective in reducing breaching during back-to-back storms occurring in the same year. Full article

This study aimed to evaluate the installation of a system that combines rainwater to wash clothes and greywater to flush toilets in a house located in Florianópolis, southern Brazil. The evaluation consisted of determining the potable water savings, performing a financial analysis, and verifying the possibility of using rainwater and reusing greywater according to the local legislation. The reduction in potable water consumption was determined by comparing the monthly water and sewage bill, before and after installing the system, combining rainwater and greywater. The financial analysis was performed considering the financial benefits, operational costs, costs for installing the system, and local water tariffs. After installing the system, there was a decrease of 38.0% in the monthly potable water consumption, which represents a decrease of 7.00 m³ in the monthly potable water consumption. The payback periods for the old and new water tariffs were equivalent to, respectively, ten years and seven months, and eight years and five months. Both rainwater and greywater had parameters with concentrations higher than the limits established by the legislation. Therefore, the rainwater had to go through a device for discarding the first flush and needed disinfection; and the greywater needed to go through a treatment process. The results indicated that the system combining rainwater and greywater shows significant potential for potable water savings, which can be a good alternative to the preservation of potable water resources. It is important to note that current studies on rainwater use and greywater reuse are mainly related to non-potable purposes, but it was shown herein that rainwater can be used for washing clothes. Full article

In the urban drainage sector, the problem of polluting discharges in sewers may act on the proper functioning of the sewer system, on the wastewater treatment plant reliability and on the receiving water body preservation. Therefore, the implementation of a chemical monitoring network is necessary to promptly detect and contain the event of contamination. Sensor location is usually an optimization exercise that is based on probabilistic or black-box methods and their efficiency is usually dependent on the initial assumption made on possible eligibility of nodes to become a monitoring point. It is a common practice to establish an initial non-informative assumption by considering all network nodes to have equal possibilities to allocate a sensor. In the present study, such a common approach is compared with different initial strategies to pre-screen eligible nodes as a function of topological and hydraulic information, and non-formal ‘grey’ information on the most probable locations of the contamination source. Such strategies were previously compared for conservative xenobiotic contaminations and now they are compared for a more difficult identification exercise: the detection of nonconservative immanent contaminants. The strategies are applied to a Bayesian optimization approach that demonstrated to be efficient in contamination source location. The case study is the literature network of the Storm Water Management Model (SWMM) manual, Example 8. The results show that the pre-screening and ‘grey’ information are able to reduce the computational effort needed to obtain the optimal solution or, with equal computational effort, to improve location efficiency. The nature of the contamination is highly relevant, affecting monitoring efficiency, sensor location and computational efforts to reach optimality. Full article

This paper presents a spatial interpolation of the hydrological and socioeconomic processes impacting groundwater systems to predict the sustainability of the Modder river catchment of South Africa. These processes are grouped as climatic (factor A), aquifer sustainability (factor D), social-economic and land use (factor B), and the human-induced parameters of rights and equity (factor C). The parameters evaluated for factors A and D included climatic zones, precipitation, sunshine, evapotranspiration, slope, topography, recharge, yields, storativity, aquifer types, and lithology/rock types. Factors B and C included population in the catchment, use per capita, water uses, tariffs and duration of the permits, pump rate per year, number of issued permits per year in the catchment, and number of boreholes in the sub-catchment. This paper, therefore, looks at the impact of the average values of the chosen set of parameters within the given factors A, B, C and D on groundwater in the C52 catchment of the Modder River, as modelled in a sustainability index. C52 is an Upper Orange catchment in South Africa. The results are presented in sustainability maps predicting areas in the catchment with differing groundwater dynamics. The Modder River groundwater sustainability ranged between low and moderate sustainability. The sustainability maps were validated with actual field groundwater recharge and surface water, a comparison between storativity and licensed volume, and a comparison of sustainability scores and storativity. The key finding in this paper will assist groundwater managers and users to adequately plan groundwater resources, especially on licensing and over pumping. Full article

The concept of water–energy–food (WEF) nexus is gaining favor as a means to highlight the functions of the three individual nexus elements as interrelated components of a single complex system. In practice, the nexus approach projects forward from the present, seeking to maximize future WEF synergies and avoid undesirable tradeoffs. A complementary approach was employed here to gain insights into how the ancients dealt with WEF relationships, whether currently relevant nexus principles were practiced long ago, and how past WEF dynamics compare to those of today. Two examples, both dating to before the common era (BCE), are considered in detail. The qanats of ancient Persia brought groundwater to the surface and directed it to clusters of agricultural fields in arid areas where crop production was not otherwise feasible. In contrast, the Dujiangyan irrigation scheme of ancient China harnessed previously destructive surface water flows to stabilize food production across a vast agricultural plain. Designed and constructed under highly uncertain conditions and with a long-term perspective, both relied on local resources and expertise to exploit the tight coupling of water and the intrinsic energy from its flows to produce food. Ingenious infrastructure combined with sound governance allowed both to achieve remarkable synergies among the WEF components with minimal apparent tradeoffs. Although both are now challenged by climate change and the increasing complexity of modern WEF relationships, qanat systems and the Dujiangyan irrigation scheme have survived for millennia and still exist in recognizable form. This is due in large part to the persistence of governance systems that devolved significant decision-making authority to those who used water and energy for food production. Although it is not feasible to roll back technology to that of an earlier time, the successful attributes of earlier WEF governance systems warrant more attention in the future. Full article

Using Estimating the Circulation and Climate of the Ocean (phase 2, ECCO2) reanalysis products from 1997 to 2019, this study analyzes the spatiotemporal features of the eddy available gravitational potential energy (EAPE) in the South China Sea (SCS). The results indicate that the EAPE accounts for 64% of the total APE in the SCS with the climatological mean. The 2D EAPE distribution images manifest show high-value regions which are generally consistent with the eddy distributions. One region is located around 21° N and west of the Luzon Strait, the second around 17° N and near Luzon Island, and the third off the Vietnam coast. In the region around 21° N and 17° N, both the seasonal variability and the interannual variability associated with the El Niño–Southern Oscillation (ENSO) are significant. Off the Vietnam coast, the EAPE is closely associated with coastal processes which heavily depend on the seasonal monsoon, the El Nino/La Nina events, and the Indian Ocean Dipole (IOD). The results provide new insights into SCS dynamics from the point of view of ocean energy sources. Full article

Two laboratory tests were carried out to verify the suitability of an Italian commercial biochar as an adsorbing material. The chosen contaminant, considered dissolved in groundwater, was As. The circular economic concept demands the use of such waste material. Its use has been studied in recent years on several contaminants. The possibility of using an efficient material at low cost could help the use of low-impact technologies like permeable reactive barriers (PRBs). A numerical model was used to derive the kinetic constant for two of the most used isotherms. The results are aligned with others derived from the literature, but they also indicate that the use of a large amount of biochar does not improve the efficiency of the removal. The particular origin of the biochar, together with its grain size, causes a decrease in contact time required for the adsorption. Furthermore, it is possible that a strong local decrease in the hydraulic conductibility does not allow for a correct dispersion of the flow, thereby limiting its efficiency. Full article

In many parts of the world, the impact of open landfills on soils, biosphere, and groundwater has become a major concern. These landfills frequently generate pollution plumes, the contours of which can be delineated by non-intrusive geophysical measurements, but in arid environments, the high soils resistivity is usually an obstacle, which results in the low number of studies that have been carried out there. In addition, such prospecting using geophysical techniques do not provide information on the intensity of the processes occurring in the water table. This study was carried out on an uncontrolled landfill in the arid Tadla plain, Morocco’s main agricultural region. A survey based on geo-referenced spontaneous potential measurements was combined with measurements of anoxic conditions (Eh-pH and O₂ equilibrating partial pressure) in the groundwater and leachates, in order to highlight a pollution plume and its geometry. The range of spontaneous potential measurement is wide, reaching 155 mV. Ponds of leachate with high electrical conductivity (20 to 40 mS cm⁻¹) form within the landfill, and present very reducing conditions down to sulphate reduction and methanisation. The plume is slowly but continuously supplied with these highly reducing and organic carbon-rich leachates from the landfill. Its direction is towards N-NW, stable throughout the season, and consistent with local knowledge of groundwater flow. The fast flow of the water table suggests pollution over long distances that should be monitored in the future. The results obtained are spatially contrasting and stable, and show that such techniques can be used on a resistive medium of arid environments. Full article

Canada, like other high latitude cold regions on Earth, is experiencing some of the most accelerated and intense warming resulting from global climate change. In the northern regions, Arctic amplification has resulted in warming two to three times greater than global mean temperature trends. Unprecedented warming is matched by intensification of wet and dry regions and hydroclimatic cycles, which is altering the spatial and seasonal distribution of surface waters in Canada. Diagnosing and tracking hydrologic change across Canada requires the implementation of continental-scale prediction models owing the size of Canada’s drainage basins, their distribution across multiple eco- and climatic zones, and the scarcity and paucity of observational networks. This review examines the current state of continental-scale climate change across Canada and the anticipated impacts to freshwater availability, including the role of anthropogenic regulation. The review focuses on continental and regional-scale prediction that underpins operational design and long-term resource planning and management in Canada. While there are significant process-based changes being experienced within Canadian catchments that are equally—if not more so—critical for community water availability, the focus of this review is on the cumulative effects of climate change and anthropogenic regulation for the Canadian freshwater supply. Full article

Human activities continue to affect our water quality; it remains a major problem worldwide (particularly concerning freshwater and human consumption). A critical water quality index (WQI) method has been used to determine the overall water quality status of surface water and groundwater systems globally since the 1960s. WQI follows four steps: parameter selection, sub-indices, establishing weights, and final index aggregation, which are addressed in this review. However, the WQI method is a prolonged process and applied to specific water quality parameters, i.e., water consumption (particular area and time) and other purposes. Therefore, this review discusses the WQI method in simple steps, for water quality assessment, based on two multi-criteria decision-making (MCDM) methods: (1) analytical hierarchical process (AHP); and (2) measuring attractiveness by a categorically based evaluation technique (MACBETH). MCDM methods can facilitate easy calculations, with less effort and great accuracy. Moreover, the uncertainty and eclipsing problems are also discussed—a challenge at every step of WQI development, particularly for parameter selection and establishing weights. This review will help provide water management authorities with useful knowledge pertaining to water usage or modification of existing indicators globally, and contribute to future WQI planning and studies for drinking, irrigation, domestic, and industrial purposes. Full article