Coatings

15 pages, 1391 KiB

Open AccessArticle

A Simple Method to Prepare Superhydrophobic Surfaces Based on Bamboo Cellulose, and an Investigation of Surface Properties

by Yu Wang, Junting Li, JingHai Guo, Tiancheng Yuan and Yanjun Li

Coatings 2025, 15(7), 740; https://doi.org/10.3390/coatings15070740 - 20 Jun 2025

Abstract

The present work introduces a sustainable, low-carbon method to fabricate durable, non-toxic superhydrophobic surfaces using bamboo-derived cellulose. Uniform TEMPO-carboxylated cellulose particles (TOC-Ps), approximately 2 μm in diameter, were synthesized through thermal polymerization and spray drying. These particles, featuring a nano-scale convex structure formed [...] Read more.

The present work introduces a sustainable, low-carbon method to fabricate durable, non-toxic superhydrophobic surfaces using bamboo-derived cellulose. Uniform TEMPO-carboxylated cellulose particles (TOC-Ps), approximately 2 μm in diameter, were synthesized through thermal polymerization and spray drying. These particles, featuring a nano-scale convex structure formed by intertwined TOC nanofibers, were applied to substrates and modified with low-surface-energy materials to achieve superhydrophobicity. At an optimal TOC-P mass ratio of 6%, the surface displayed a water contact angle of 156.2° and a sliding angle of 7°. The coating maintained superhydrophobicity after extensive mechanical testing—120 cm of abrasion, 100 bending cycles, and continuous trampling—and exhibited robust chemical stability across harsh conditions, including subjection to high temperatures, UV irradiation, and corrosive solutions (pH 2–12). The hierarchical micro–nano structure was found to enhance both hydrophobicity and durability, offering an environmentally friendly alternative for self-cleaning surfaces, textiles, and building applications. Full article

(This article belongs to the Section Functional Polymer Coatings and Films)

15 pages, 3321 KiB

Open AccessArticle

Preparation and Characterization of Boron–Magnesium–Titanium Ternary Composite Powders

by Yanjun Wang and Yueguang Yu

Coatings 2025, 15(7), 739; https://doi.org/10.3390/coatings15070739 - 20 Jun 2025

Abstract

To improve the combustion performance of boron powder, a method was developed for synthesizing boron–magnesium–titanium (B-Mg-Ti) ternary composite powders with controlled metal content. Boron–magnesium (B-Mg) base materials were first prepared via electrical explosion, followed by the incorporation of titanium powder at varying mass [...] Read more.

To improve the combustion performance of boron powder, a method was developed for synthesizing boron–magnesium–titanium (B-Mg-Ti) ternary composite powders with controlled metal content. Boron–magnesium (B-Mg) base materials were first prepared via electrical explosion, followed by the incorporation of titanium powder at varying mass fractions (1 wt.%, 3 wt.%, 5 wt.%, and 7 wt.%) through mechanical ball milling. Field emission scanning electron microscopy (FE-SEM) revealed that the addition of titanium promoted a more uniform dispersion of magnesium within the boron agglomerates. Moreover, nanoscale titanium particles were observed to be embedded on the particle surfaces, confirming successful microscale composite formation. Particle size distribution was measured using a Malvern 3000 laser particle size analyzer, and results showed that the particle size of the ternary composites decreased gradually with increasing titanium content. Specific surface area was determined via the Brunauer–Emmett–Teller (BET) method, with all samples exhibiting values greater than 15 m²/g, indicating good surface reactivity. Furthermore, the rheological behavior of the B-Mg-Ti composite powders, when combined with terminal hydroxyl polybutadiene (HTPB)—a typical binder in solid propellants—was evaluated. Viscosity measurements were conducted using a rotational rheometer at constant temperatures of 20 °C and 70 °C. The results demonstrated a marked decrease in viscosity with increasing titanium content, suggesting that titanium incorporation enhances the flowability of the composite powders. This study systematically evaluated the influence of titanium content on the structural and physicochemical properties of B-Mg-Ti composite powders, thereby providing a valuable experimental foundation for the optimized design of boron-based combustion systems and the enhancement of their processing and application performance. Full article

(This article belongs to the Section Surface Characterization, Deposition and Modification)

15 pages, 4154 KiB

Open AccessArticle

Femtosecond Laser-Modulated Oxygen Vacancies in LiFePO₄ Thick Electrodes for Rapid Ion Transport

by Xiaowei Han, Lu Chen, Hongshui Wang, Ban Chen, Tai Yang, Donghui Wang and Chunyong Liang

Coatings 2025, 15(7), 738; https://doi.org/10.3390/coatings15070738 - 20 Jun 2025

Abstract

Although thick electrodes hold significant potential for enhancing battery energy density, their practical application is limited by restricted ion transport kinetics. Constructing porous structures within thick electrodes is a widely adopted strategy to address this limitation, but it often compromises mass retention and [...] Read more.

Although thick electrodes hold significant potential for enhancing battery energy density, their practical application is limited by restricted ion transport kinetics. Constructing porous structures within thick electrodes is a widely adopted strategy to address this limitation, but it often compromises mass retention and mechanical integrity. In this study, a microchannel structure that balances the electrochemical and mechanical properties of the electrode was identified through simulation and precisely fabricated using femtosecond laser technology. Furthermore, the ultra-short pulse duration and high pulse energy of femtosecond lasers introduce oxygen vacancies into the electrode material, thereby enhancing its electrical conductivity. The obtained electrode exhibited excellent electrochemical performance under high-rate charging and discharging conditions, achieving significantly enhanced cycling stability and capacity retention, with a capacity 1.99 times greater than that of the unstructured electrode after 100 cycles. Meanwhile, the mechanical stability of the laser-processed electrode was maintained. This study provides new insights into the structural design and processing of the thick electrode and contributes to advancements in the field of energy storage. Full article

(This article belongs to the Special Issue Electrodes and Coatings for Energy Storage Applications: Batteries and Supercapacitors)

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27 pages, 4541 KiB

Open AccessReview

From Molecular Design to Scenario Adaptation: Cutting-Edge Exploration of Silicone-Modified Polyurethane in Smart Sports Fields

by Guobao Yan, Guoyuan Huang, Huibin Wu, Yang Chen, Jiaxun Wu and Yangxian Hu

Coatings 2025, 15(7), 737; https://doi.org/10.3390/coatings15070737 - 20 Jun 2025

Abstract

To overcome the shortcomings of traditional polyurethane, such as poor weather resistance and susceptibility to hydrolysis, this study systematically explores the preparation techniques of organic silicon-modified polyurethane and its application in intelligent sports fields. By introducing siloxane into the polyurethane matrix through copolymerization, [...] Read more.

To overcome the shortcomings of traditional polyurethane, such as poor weather resistance and susceptibility to hydrolysis, this study systematically explores the preparation techniques of organic silicon-modified polyurethane and its application in intelligent sports fields. By introducing siloxane into the polyurethane matrix through copolymerization, physical blending, and grafting techniques, the microphase separation structure and interfacial properties of the material are effectively optimized. In terms of synthesis processes, the one-step method achieves efficient preparation by controlling the isocyanate/hydroxyl molar ratio (1.05–1.15), while the prepolymer chain extension method optimizes the crosslinked network through dual reactions. The modified material exhibits significant performance improvements: tensile strength reaches 60 MPa, tear resistance reaches 80 kN/m, and the elastic recovery rate ranges from 85% to 92%, demonstrating outstanding weather resistance. In sports field applications, the 48% impact absorption rate meets the requirements for athletic tracks, wear resistance of <15 mg suits gym floors, and the impact resistance for skate parks reaches 55%–65%. Its environmental benefits are notable, with volatile organic compounds (VOC) <50 g/L and a recycling rate >85%, complying with green building material standards. However, its development is still constrained by multiple factors: insufficient material interface compatibility, a comprehensive cost of 435 RMB/m², and the lack of a quality evaluation system. Future research priorities include constructing dynamic covalent crosslinked networks (e.g., self-healing systems), adopting bio-based raw materials to reduce carbon footprint by 30%–50%, and integrating flexible sensing technologies for intelligent responsiveness. Through multidimensional innovation, this material is expected to evolve toward multifunctionality and environmental friendliness, providing core material support for the intelligent upgrading of sports fields. Full article

(This article belongs to the Special Issue Synthesis and Application of Functional Polymer Coatings)

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15 pages, 3089 KiB

Open AccessArticle

Influence of Carbonized Garbage Fly Ash on the Performance of Foam Concrete

by Di Wang, Zhiqiang Xu, Yehan Yu, Na Xu, Chuanqi Li, Xu Tian, Hui Wang, Feiting Shi and Kangshuo Xia

Coatings 2025, 15(7), 736; https://doi.org/10.3390/coatings15070736 - 20 Jun 2025

Abstract

To utilize garbage fly ash (GFA) as a resource, this research proposes a method for preparing GFA with higher reactivity through carbonation and applies it to the production of foamed concrete. The effects of CO₂-cured GFA substitution rate and foam volume [...] Read more.

To utilize garbage fly ash (GFA) as a resource, this research proposes a method for preparing GFA with higher reactivity through carbonation and applies it to the production of foamed concrete. The effects of CO₂-cured GFA substitution rate and foam volume on slump flow, rheological properties, mechanical strength, thermal conductivity, water absorption rate, and water resistance coefficient of foam concrete are clarified. The results show that an increase in the CO₂-cured GFA substitution rate from 0 to 100% improves the slump flow by 10.8%~34.5% and decreases the plastic viscosity by 4.8%~36.4% and yield stress by 5.6%~28.1%. The higher carbonized GFA substitution rate can prolong the initial setting time with the largest amplitude of 30.4%. In addition, increasing the CO₂-cured GFA substitution rate improves the mechanical strengths, water resistance, thermal conductivity, and solidification of heavy metals. When the CO₂-cured GFA substitution rate is 100%, the 28-day compressive strength, 28-day flexural strength, water absorption rate, water resistance coefficient, thermal conductivity, leached Zn, and leached Cr of foam concrete are 18 MPa, 3.6 MPa, 20.7%, 0.46, 0.69 W·m⁻¹·K⁻¹, 9.4 × 10⁻⁵ mg/mL, and 8.6 × 10⁻⁵ mg/mL, respectively. Moreover, more foam volume improves the fresh-mixed performance of foam concrete while reducing the mechanical strength, water resistance property, thermal conductivity, and solidification of heavy metals. It is found that the technical approach for preparing foamed concrete containing CO₂-cured GFA with 40% foam volume can achieve its large-scale use. Full article

(This article belongs to the Special Issue Surface Treatment and Mechanical Properties of Sustainable Pavement Materials)

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11 pages, 3551 KiB

Open AccessArticle

The Influence of Surface Texture Orientation on the Current-Carrying Friction Performance of Elastic Pairs

by Zhenghai Yang, Wenbo Li, Xiaowei Wang, Kaifeng Hu, Xiaojun Tian, Mengfeng Zhao and Yongzhen Zhang

Coatings 2025, 15(7), 735; https://doi.org/10.3390/coatings15070735 - 20 Jun 2025

Abstract

To improve the performance of elastic current-carrying friction pairs, this study employs a wire–plate friction pair and investigates the effect of surface texture orientation on current-carrying friction performance using a self-made micro-sliding current-carrying friction wear tester. The following conclusions were drawn: The angle [...] Read more.

To improve the performance of elastic current-carrying friction pairs, this study employs a wire–plate friction pair and investigates the effect of surface texture orientation on current-carrying friction performance using a self-made micro-sliding current-carrying friction wear tester. The following conclusions were drawn: The angle between texture orientation and friction direction primarily influences the friction pair’s lifespan. At 0°, the lifespan is the longest, exceeding 500 cycles, followed by 90° with a lifespan of 394 cycles, and the shortest lifespan is observed with multi-directional textures. The primary wear mechanisms during the lifespan are furrowing, adhesive tearing, arc erosion, oxidation, and material transfer. At 0°, the width of mechanical damage is confined to the furrows, and the arc erosion is minimal. At 90°, the mechanical damage width and arc erosion are moderate, while at 45°, 135°, and multi-directional orientations, the mechanical wear width and arc erosion are more severe, with the multi-directional texture having the widest mechanical wear. The texture orientation has a significant impact on the performance and running process of current-carrying friction pairs. An appropriate texture orientation can suppress wear, thereby enhance performance and extending service life. Full article

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31 pages, 7823 KiB

Open AccessArticle

Influence of Alkaline Activator Properties on Corrosion Mechanisms and Durability of Steel Reinforcement in Geopolymer Binders

by Mihail Chira, Adrian-Victor Lăzărescu, Andreea Hegyi, Horatiu Vermesan, Alexandra Csapai, Bradut Alexandru Ionescu, Tudor Panfil Toader and Carmen Florean

Coatings 2025, 15(6), 734; https://doi.org/10.3390/coatings15060734 - 19 Jun 2025

Abstract

The durability of steel reinforcement in geopolymer composites is significantly influenced by the chemical characteristics of the alkaline medium in which they are embedded. This research offers detailed insights into the corrosion kinetics and mechanisms of geopolymers derived from various fly ash and [...] Read more.

The durability of steel reinforcement in geopolymer composites is significantly influenced by the chemical characteristics of the alkaline medium in which they are embedded. This research offers detailed insights into the corrosion kinetics and mechanisms of geopolymers derived from various fly ash and alkaline activator formulations, considering their inherent microstructural and chemical heterogeneity. This study investigates the effect of the molarity of sodium hydroxide (NaOH) solution and the ratio of sodium silicate to sodium hydroxide (Na₂SiO₃/NaOH) on the corrosion behavior of steel reinforcement in geopolymer matrix under the action of chloride ions. Corrosion of steel reinforcement embedded in geopolymer binder prepared by alkaline activation of fly ash with alkaline activator prepared with different Na₂SiO₃/NaOH ratios (1:1, 1:2, 2:1) and different molar concentrations of NaOH solution (6 M, 8 M and 10 M) was analyzed in terms of process kinetics using Open Circuit Potential (OCP) and Linear Polarization (LP) and mechanism by Electrochemical Impedance Spectroscopy (EIS). The study demonstrates that a Na₂SiO₃:NaOH ratio of 1:2 and an 8 M NaOH solution yield the most favorable combination of physical and mechanical properties and corrosion resistance, confirmed by the highest apparent density, lowest water absorption, and significantly reduced corrosion current densities (as low as 0.72 μA/cm²), as well as highlighting porosity and pH as key factors influencing steel protection in geopolymer matrices. Full article

(This article belongs to the Special Issue Alloy/Metal/Steel Surface: Fabrication, Structure, Friction and Service Life)

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13 pages, 2792 KiB

Open AccessArticle

Engineering C–S–H Sorbents via Hydrothermal Synthesis of PV Glass and Carbide Sludge for Chromium(III) Removal

by Tran Ngo Quan, Le Phan Hoang Chieu and Pham Trung Kien

Coatings 2025, 15(6), 733; https://doi.org/10.3390/coatings15060733 (registering DOI) - 19 Jun 2025

Abstract

This study investigates the hydrothermal synthesis of calcium silicate hydrate (C-S-H) from photovoltaic (PV) waste glass and carbide sludge as a strategy for resource recovery and sustainable chromium removal from wastewater. Waste-derived precursors were co-ground, blended at controlled Ca/Si molar ratios (0.8, 1.0, [...] Read more.

This study investigates the hydrothermal synthesis of calcium silicate hydrate (C-S-H) from photovoltaic (PV) waste glass and carbide sludge as a strategy for resource recovery and sustainable chromium removal from wastewater. Waste-derived precursors were co-ground, blended at controlled Ca/Si molar ratios (0.8, 1.0, 1.2), and hydrothermally treated at 180 °C for 96 h to yield C-S-H with tunable morphology and crystallinity. Comprehensive characterization using XRD, FT-IR, SEM-EDX, and UV-Vis spectroscopy revealed that a Ca/Si ratio of 1.0 produced a well-ordered tobermorite/xonotlite structure with a high surface area and fibrous network, which is optimal for adsorption. Batch adsorption experiments showed that this material achieved rapid and efficient Cr(III) removal, exceeding 90% uptake within 9 h through a combination of surface complexation, ion exchange (Ca²⁺/Na⁺ ↔ Cr³⁺), and precipitation of CaCrO₄ phases. Morphological and structural evolution during adsorption was confirmed by SEM, FT-IR, and XRD, while EDX mapping established the progressive incorporation of Cr into the C-S-H matrix. These findings highlight the viability of upcycling industrial waste into advanced C-S-H sorbents for heavy metal remediation. Further work is recommended to address sorbent regeneration, long-term stability, and application to other contaminants, providing a foundation for circular approaches in advanced wastewater treatment. Full article

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15 pages, 2310 KiB

Open AccessArticle

Fucoidan and Hyaluronic Acid Modified ZE21B Magnesium Alloy for Better Hemocompatibility and Vascular Cell Response

by Haoran Wang, Yunwei Gu, Qi Wang, Lingchuang Bai and Shaokang Guan

Coatings 2025, 15(6), 732; https://doi.org/10.3390/coatings15060732 - 19 Jun 2025

Abstract

Magnesium alloy stents exhibit significant potential in the treatment of cardiovascular and cerebrovascular diseases due to their remarkable mechanical support and biodegradability. However, bare magnesium alloy stents often degrade too quickly and exhibit inadequate biocompatibility, which severely restricts their clinical applicability. Herein, a [...] Read more.

Magnesium alloy stents exhibit significant potential in the treatment of cardiovascular and cerebrovascular diseases due to their remarkable mechanical support and biodegradability. However, bare magnesium alloy stents often degrade too quickly and exhibit inadequate biocompatibility, which severely restricts their clinical applicability. Herein, a composite coating consisting of an MgF₂ conversion layer, a polydopamine (PDA) layer, fucoidan, and hyaluronic acid was prepared to enhance the corrosion resistance and biocompatibility of ZE21B alloy for a vascular stent application. The modified ZE21B alloy exhibited relatively high surface roughness, moderate wettability, and better corrosion resistance. Moreover, the modified ZE21B alloy with a low hemolysis rate and fibrinogen adsorption level confirmed improved hemocompatibility for medical requirements. Furthermore, the ZE21B alloy modified with fucoidan and hyaluronic acid enhanced the adhesion, proliferation, and NO release of endothelial cells (ECs). Simultaneously, it inhibits the adhesion and proliferation of smooth muscle cells (SMCs), promoting a competitive advantage for ECs over SMCs due to the synergistic effects of fucoidan and hyaluronic acid. The incorporation of fucoidan and hyaluronic acid markedly improved the corrosion resistance and biocompatibility of the ZE21B magnesium alloy. This development presents a straightforward and effective strategy for the advancement of biodegradable vascular stents. Full article

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11 pages, 2583 KiB

Open AccessArticle

Annealing Treatment of Al₂CoCrFeNi High-Entropy Alloys: Synergistic Effect of Microstructure Modulation on Mechanical and Thermoelectric Properties

by Jiayi Xu, Lequn Kan, Hao Li, Xiaoke Gao, Wei Zhang, Wei Wei, Xiangkui Liu, Wenfeng Yang, Wenwen Sun and Xulong An

Coatings 2025, 15(6), 731; https://doi.org/10.3390/coatings15060731 - 19 Jun 2025

Abstract

This study synthesized Al₂CoCrFeNi high-entropy alloy (HEA) using spark plasma sintering (SPS) followed by annealing treatment. The effects of heat treatment on the microstructure, mechanical properties, wear resistance, and thermoelectric properties were systematically investigated. The annealed alloy exhibited a microhardness increase [...] Read more.

This study synthesized Al₂CoCrFeNi high-entropy alloy (HEA) using spark plasma sintering (SPS) followed by annealing treatment. The effects of heat treatment on the microstructure, mechanical properties, wear resistance, and thermoelectric properties were systematically investigated. The annealed alloy exhibited a microhardness increase from 538.5 HV to 550.9 HV and a significant improvement in ultimate compressive strength from 1540.74 MPa to 2563.67 MPa, attributed to grain homogenization and reduced dislocation density. Wear resistance tests revealed a decrease in wear rate from 7.15 × 10⁻⁵ mm³/(N·m) to 4.74 × 10⁻⁵ mm³/(N·m), with wear morphology analysis confirming enhanced resistance to plastic deformation. Thermoelectric characterization demonstrated that thermal diffusivity increased from 2.98 mm²/s to 3.11 mm²/s at room temperature, while the absolute Seebeck coefficient reached 8.0 μV/K at 200 °C, indicating improved electron transport efficiency due to lattice ordering. This combination of high hardness, high thermal conductivity, and excellent wear resistance presents unique application value in extreme tribological fields involving thermal management and simultaneous surface wear resistance and heat dissipation. Full article

(This article belongs to the Special Issue Advanced High Entropy Alloy Materials and Films: Properties and Applications)

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19 pages, 4071 KiB

Open AccessArticle

Surface Characteristics of TiO₂ Coatings Formed by Micro-Arc Oxidation in Ti-25Ta-xNb Alloys: The Influence of Microstructure and Applied Voltage

by Fernanda de Freitas Quadros, Diego Rafael Nespeque Corrêa, Marco Fosca, Marco Ortenzi, Olga N. Plakhotnaia, Carlos Roberto Grandini and Julietta V. Rau

Coatings 2025, 15(6), 730; https://doi.org/10.3390/coatings15060730 - 19 Jun 2025

Abstract

Due to their excellent mechanical properties and good biocompatibility, titanium (Ti) and its alloys are widely used as biomaterials. However, when implanted in the body, metallic materials may cause serious complications such as wear and infection, leading to patient discomfort and, in some [...] Read more.

Due to their excellent mechanical properties and good biocompatibility, titanium (Ti) and its alloys are widely used as biomaterials. However, when implanted in the body, metallic materials may cause serious complications such as wear and infection, leading to patient discomfort and, in some cases, the need for revision surgery. Micro-arc oxidation (MAO) is a surface modification technique that offers a promising strategy to overcome these challenges. This study investigated the impact of the microstructure of Ti-25 Ta-xNb alloys (x = 10, 20, and 30 wt%) and the variation in applied voltage during the MAO process on the characteristics of the TiO₂ oxide coatings formed. The alloys were treated by MAO at 200, 250, and 300 V using a bioactive electrolyte containing Ca, P, Mg, and Ag. EDS, SEM, XRD, Raman spectroscopy, and adhesion tests performed characterization. Results indicated that Nb addition stabilized the β phase and anticipated the potentiostatic regime. Increasing the voltage supplied to the system provides greater energy, prolonging the galvanostatic regime and promoting the formation of larger and more uniform pores. The oxide coating thickness ranged from approximately 3 to 10 μm, with a tendency to decrease at higher voltages. The coatings exhibited low c, with anatase and rutile phases predominating, the applied voltage and Nb concentration influencing their relative proportions. Even in small amounts, all electrolyte elements (P, Mg, and Ag) were successfully incorporated into the coatings under all conditions. Raman and XRD analyses confirmed a decrease in anatase and an increase in rutile phases with increasing voltage and Nb content. Mechanical testing revealed good adhesion of the coatings in all samples, with the best results obtained at 200 V. The findings demonstrate that the developed coatings exhibit promising characteristics for future surface engineering strategies aimed at improving the performance of metallic biomaterials. Full article

(This article belongs to the Special Issue Films and Coatings with Biomedical Applications)

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14 pages, 3453 KiB

Open AccessArticle

Enhanced Corrosion Resistance and Cytocompatibility of Magnesium Alloys with Mg(OH)₂/Polydopamine Composite Coatings for Orthopedic Applications

by Chunlin Li, Boqiong Li and Wenxia Yan

Coatings 2025, 15(6), 729; https://doi.org/10.3390/coatings15060729 - 18 Jun 2025

Abstract

A critical barrier to the clinical translation of biodegradable magnesium (Mg)-based materials lies in their rapid degradation rate in physiological environment, which leads to premature structural failure and compromised cytocompatibility. Micro-arc oxidation (MAO) coatings offer preliminary corrosion mitigation for Mg alloys, while their [...] Read more.

A critical barrier to the clinical translation of biodegradable magnesium (Mg)-based materials lies in their rapid degradation rate in physiological environment, which leads to premature structural failure and compromised cytocompatibility. Micro-arc oxidation (MAO) coatings offer preliminary corrosion mitigation for Mg alloys, while their inherent structural porosity compromises long-term durability in physiological environment. To address this limitation, we developed a hierarchical coating system consisting of a dense Mg(OH)₂ interlayer (MAO/HT) superimposed on the MAO-treated substrate, followed by a functional polydopamine (PDA) topcoat to create a MAO/HT/PDA composite architecture. The surface characteristics and crystalline structures of these coatings were systematically characterized using field-emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD). The corrosion resistance and interfacsial stability in physiological environment were quantitatively assessed through electrochemical analyses and long-term immersion tests in simulated body fluid (SBF). The cytocompatibility of the coatings was assessed by directly culturing osteoblast on the coated samples. The results reveal that the Mg(OH)₂ film possesses a bulk-like structure and effectively seals the micro-pores of the MAO coating. The current density of MAO/HT/PDA sample decreases by two orders of magnitude compared to that of MAO sample, indicating excellent corrosion resistance. The PDA layer not only acts as a strong barrier to improve the corrosion performance of the coating but also helps maintain the stability of the coating, thus delaying coating destruction in SBF. Moreover, the osteoblast culture results suggest that the MAO/HT/PDA coating promotes cell spread and proliferation noticeably compared to both the MAO and MAO/HT coatings. This study provides compelling evidence that the Mg(OH)₂/PDA composite coating is biodegradable and offers outstanding protection for micro-arc oxidized magnesium. As a result, it holds great promise for significant applications in the field of orthopedic medicine. Full article

(This article belongs to the Special Issue Deposition-Based Coating Solutions for Enhanced Surface Properties)

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21 pages, 8141 KiB

Open AccessArticle

Octahedral Fe₃O₄ Nanozymes Penetrate and Remove Biofilms on Implants via Photomagnetic Response

by Xingpu Yin, Bo Zhao, Lu Chen, Xuan Di, Baoe Li, Hongshui Wang, Donghui Wang and Chunyong Liang

Coatings 2025, 15(6), 728; https://doi.org/10.3390/coatings15060728 - 18 Jun 2025

Abstract

Dental implant papilla (DIP) is susceptible to bacterial adhesion and biofilm formation, and oral pathogenic biofilms can cause persistent oral infections. Enrichment of bacterial biofilms on implants can lead to soft tissue irritation and adjacent bone resorption, severely compromising dental health and potentially [...] Read more.

Dental implant papilla (DIP) is susceptible to bacterial adhesion and biofilm formation, and oral pathogenic biofilms can cause persistent oral infections. Enrichment of bacterial biofilms on implants can lead to soft tissue irritation and adjacent bone resorption, severely compromising dental health and potentially leading to periodontitis, implant loss and costly follow-up care. Nanozymes (NZs) are recently used in biofilm removal as they can induce the production of reactive oxygen species (ROS), which can kill bacteria. However, the short lifespan of ROS limits their diffusion distance, and affects their therapeutic efficacy. In this study, we prepared Fe₃O₄ nanoparticles (NZs) with different morphologies: flower-like (F-Fe₃O₄), hollow spherical (M-Fe₃O₄), octahedral (O-Fe₃O₄), and conventional nanoparticles (N-Fe₃O₄). The ferromagnetic properties of Fe₃O₄ NZs allow them to move and penetrate the biofilm under the action of a magnetic field. The saturation magnetic intensities of the four samples were as follows: F-Fe₃O₄ (23.1 emu g⁻¹), M-Fe₃O₄ (73.34 emu g⁻¹), O-Fe₃O₄ (96.06 emu g⁻¹), and N-Fe₃O₄ (52.15 emu g⁻¹). The synergistic combination of photothermal action and catalytic sterilization can effectively remove the biofilm. In addition, the prepared Fe₃O₄ nanozymes were able to maintain high biological activity on the implant surface with some osteogenic effect. Full article

(This article belongs to the Special Issue Bioactive Coatings on Elements Used in the Oral Cavity Environment)

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11 pages, 7908 KiB

Open AccessArticle

Poly(Methyl Methacrylate)-Based Core-Shell Electrospun Fibers: Structural and Morphological Analysis

by Ivana Stajcic, Vesna Radojevic, Zorica Lazarevic, Milica Curcic, Branka Hadzic, Aleksandar Kojovic and Aleksandar Stajcic

Coatings 2025, 15(6), 727; https://doi.org/10.3390/coatings15060727 - 18 Jun 2025

Abstract

Dicyclopentadiene (DCPD)–poly(methyl methacrylate) (PMMA) core–shell fibers were fabricated via coaxial electrospinning to develop a self-healing polymer composite. A PMMA shell containing a first-generation Grubbs catalyst was co-spun with a DCPD core at 0.5 mL h⁻¹ and 28 kV, yielding smooth, cylindrical fibers. [...] Read more.

Dicyclopentadiene (DCPD)–poly(methyl methacrylate) (PMMA) core–shell fibers were fabricated via coaxial electrospinning to develop a self-healing polymer composite. A PMMA shell containing a first-generation Grubbs catalyst was co-spun with a DCPD core at 0.5 mL h⁻¹ and 28 kV, yielding smooth, cylindrical fibers. The diameter range of nanofibers was 300–900 nm, with 95% below 800 nm, as confirmed by FESEM image analysis. FTIR spectroscopy monitored shell integrity via the PMMA C=O stretch and core polymerization via the trans-C=C bands. The high presence of the 970 cm⁻¹ band in the healed nanofiber mat and the minor appearance in the uncut core–shell mat demonstrated successful DCPD polymerization mostly where the intended damage was. The optical clarity of PMMA enabled the direct monitoring of healing progress via optical microscopy. The presented findings demonstrate that PMMA can retain a liquid active core and catalyst to form a polymer layer on a damaged site and could be used as a model material for other self-healing systems that require healing monitoring. Full article

(This article belongs to the Special Issue Advances in Optical Coatings and Thin Films)

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14 pages, 1479 KiB

Open AccessArticle

Innovative Preservation of Fresh-Cut Potatoes: Synergistic Effects of Antimicrobial Edible Coatings, Ohmic Heating–Osmotic Dehydration, and MAP on Quality and Shelf Life

by Alexandra Mari, Christina Drosou, Konstantina Theodora Laina, Christoforos Vasileiou and Magdalini Krokida

Coatings 2025, 15(6), 726; https://doi.org/10.3390/coatings15060726 - 18 Jun 2025

Abstract

Fresh-cut potatoes are highly perishable, requiring effective preservation strategies to maintain quality and extend shelf life. This study evaluated the use of edible coatings and the combination of osmotic dehydration and ohmic heating (OH-OD), both integrated with modified atmosphere packaging (MAP), to enhance [...] Read more.

Fresh-cut potatoes are highly perishable, requiring effective preservation strategies to maintain quality and extend shelf life. This study evaluated the use of edible coatings and the combination of osmotic dehydration and ohmic heating (OH-OD), both integrated with modified atmosphere packaging (MAP), to enhance microbial stability and reduce quality deterioration. Key quality parameters—including color stability, browning index, weight loss, microbial activity, and sensory attributes—were assessed. Results showed that coated samples (E-FP) had the lowest browning index (59.71) by day 8, compared to a value of 62.69 in control samples (C-FP). OH-OD-treated samples exhibited the least weight loss (6.73%) versus 17.75% in C-FP. Microbial analysis showed that E-FP samples maintained the lowest total viable count by day 8 (3.98 ± 0.02 log CFU/g), compared to OH-OD-FP (4.43 ± 0.13 log CFU/g) and C-FP (4.79 ± 0.06 log CFU/g), confirming the antimicrobial efficacy of the edible coating enriched with rosemary essential oil and ascorbic acid. Sensory evaluation further confirmed that coated samples retained superior sensory qualities, receiving the highest overall acceptance score of 8.86 ± 0.80, compared to values of 7.80 ± 0.98 for control samples (C-FP) and 2.80 ± 0.69 for OH-OD-FP samples, highlighting their enhanced consumer appeal. These findings highlight that combining advanced preservation techniques with MAP can significantly reduce moisture loss and microbial spoilage while maintaining freshness and sensory appeal. This integrated approach offers a promising solution for extending shelf life, reducing food waste, and supporting sustainability in response to consumer demand for minimally processed, high-quality fresh products. Full article

(This article belongs to the Special Issue Advanced Materials for Safe and Smart Food Packaging)

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23 pages, 5461 KiB

Open AccessArticle

Classification and Prediction of Unknown Thermal Barrier Coating Thickness Based on Hybrid Machine Learning and Terahertz Nondestructive Characterization

by Zhou Xu, Jianfei Xu, Yiwen Wu, Changdong Yin, Suqin Chen, Qiang Liu, Xin Ge, Luanfei Wan and Dongdong Ye

Coatings 2025, 15(6), 725; https://doi.org/10.3390/coatings15060725 - 17 Jun 2025

Abstract

Thickness inspection of thermal barrier coatings is crucial to safeguard the reliability of high-temperature components of aero-engines, but traditional destructive inspection methods are difficult to meet the demand for rapid assessment in the field. In this study, a new non-destructive testing method integrating [...] Read more.

Thickness inspection of thermal barrier coatings is crucial to safeguard the reliability of high-temperature components of aero-engines, but traditional destructive inspection methods are difficult to meet the demand for rapid assessment in the field. In this study, a new non-destructive testing method integrating terahertz time-domain spectroscopy and machine learning algorithms is proposed to systematically study the thickness inspection of 8YSZ coatings prepared by two processes, namely atmospheric plasma spraying (APS) and electron beam physical vapor deposition (EB-PVD). By optimizing the preparation process parameters, 620 sets of specimens with thicknesses of 100–400 μm are prepared, and three types of characteristic parameters, namely, time delay Δt, frequency shift Δf, and energy decay η, are extracted by combining wavelet threshold denoising and time-frequency joint analysis. A CNN-RF cascade model is constructed to realize coating process classification, and an attention-LSTM and SVR weighted fusion model is developed for thickness regression prediction. The results show that the multimodal feature fusion reduces the root-mean-square error of thickness prediction to 8.9 μm, which further improves the accuracy over the single feature model. The classification accuracy reaches 96.8%, of which the feature importance of time delay Δt accounts for 62%. The hierarchical modeling strategy reduces the detection mean absolute error from 6.2 μm to 4.1 μm. the method provides a high-precision solution for intelligent quality assessment of thermal barrier coatings, which is of great significance in promoting the progress of intelligent manufacturing technology for high-end equipment. Full article

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10 pages, 2683 KiB

Open AccessArticle

Effects of Synthesis Process on the Properties of La_1−xSr_xMnO₃ Materials for Thermal Control Coatings

by Fang Jia, Xin Zhang, Xiaoliang Lu, Haoran Peng, Tianjie Shi, Kang Yuan, Xiaoxiao Pang and Rifei Han

Coatings 2025, 15(6), 724; https://doi.org/10.3390/coatings15060724 - 17 Jun 2025

Abstract

Lanthanum strontium manganate (La_1−xSr_xMnO₃) is considered a highly promising material for the development of intelligent thermal control coatings due to its exceptional properties. Recent studies on this material have primarily utilized solid-state synthesis as the main preparation [...] Read more.

Lanthanum strontium manganate (La_1−xSr_xMnO₃) is considered a highly promising material for the development of intelligent thermal control coatings due to its exceptional properties. Recent studies on this material have primarily utilized solid-state synthesis as the main preparation method. Research efforts have predominantly focused on investigating the effects of material composition, heat treatment processes, and other factors on the properties of the synthesized material. There has been a limited amount of research investigating the influence of chemical precipitation process parameters on the properties of the synthesized La_1−xSr_xMnO₃ material. In this study, the intelligent thermal control coating material La_0.8Sr_0.2MnO₃ was synthesized using the chemical precipitation method. The effects of varying precipitant concentrations on the properties of the synthesized material were investigated. When the precipitant concentration is 12 wt.% or 15 wt.%, the synthesized powder agglomerates predominantly form three-dimensional blocky structures after sintering. At lower concentrations such as 6 wt.% and 9 wt.%, the powder agglomerates predominantly form two-dimensional sheet-like structures after sintering. At precipitant concentrations of 6 wt.% and 9 wt.%, the strontium content in the synthesized powder becomes significantly lower than the designed theoretical value. When the precipitant concentration is relatively high, localized manganese aggregation occurs in the synthesized lanthanum strontium manganate material. The temperature dependence of the emittance test result indicates that the emissivity variation of La_0.8Sr_0.2MnO₃ material synthesized using 12 wt.% ammonia solution as precipitant reaches 0.428 from 173 K to 373 K, demonstrating excellent emissivity modulation performance. Full article

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20 pages, 14981 KiB

Open AccessArticle

Multi-Scale Modelling of Residual Stress on Arbitrary Substrate Geometry in Atmospheric Plasma Spray Process

by Jose Martínez-García, Venancio Martínez-García and Andreas Killinger

Coatings 2025, 15(6), 723; https://doi.org/10.3390/coatings15060723 - 17 Jun 2025

Abstract

This work presents an exhaustive parametric study of the multi-scale residual stress analysis on arbitrary substrate geometry based on a one-way-coupled thermo-mechanical model in an Atmospheric Plasma Spray process. It was carried out by modifying key process parameters, such as substrate surface geometry, [...] Read more.

This work presents an exhaustive parametric study of the multi-scale residual stress analysis on arbitrary substrate geometry based on a one-way-coupled thermo-mechanical model in an Atmospheric Plasma Spray process. It was carried out by modifying key process parameters, such as substrate surface geometry, substrate pre-heating temperature, and coating thickness, in an Al₂O₃ coating process on an aluminium substrate. The relationship of these parameters to the generation of quenching stress, thermal stress and residual stress was analysed at three different sub-modelling scales, from the macroscopic dimension of the substrate to the microscopic dimension of the splats. The thermo-mechanical phenomena occurring during the deposition process at the microscopic level were discussed in the proposed cases. Understanding these phenomena helps to optimise the parameters of the coating process by identifying the underlying mechanisms responsible for the generation of residual stresses. The simulated residual stresses of the 200 μm Al₂O₃ outer coated aluminium cylinder were experimental validated using the incremental high-speed micro-hole drilling and milling method. Full article

(This article belongs to the Special Issue Advances in Surface Coatings for Wear and Corrosion Protection)

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15 pages, 4658 KiB

Open AccessArticle

Hydrothermal Preparation of Calcium Aluminum Corrosion-Resistant Coatings on AZ91D Magnesium Alloy

by Qingrong Tan, Ying Zhang, Min Jiang and Jiyuan Zhu

Coatings 2025, 15(6), 722; https://doi.org/10.3390/coatings15060722 - 17 Jun 2025

Abstract

Magnesium alloys are widely used in all kinds of fields because of their excellent mechanical properties, but their application has been prevented by poor corrosion resistance. In this paper, Mg(OH)₂-Ca(OH)₂/Al(OH)₃/Al₂O₃ composite coatings with long-term [...] Read more.

Magnesium alloys are widely used in all kinds of fields because of their excellent mechanical properties, but their application has been prevented by poor corrosion resistance. In this paper, Mg(OH)₂-Ca(OH)₂/Al(OH)₃/Al₂O₃ composite coatings with long-term corrosion resistance were fabricated on the surface of Mg alloys using the hydrothermal method. Among them, the calcium hydroxide/calcium nitrate–alumina coating successfully filled the cracks in the magnesium hydroxide coating. Meanwhile, we explored the influences of different heating times and temperatures on the coating and analyzed its composition. After immersing the coating in a 3.5% NaCl solution for 168 h, only a small portion of the surface dissolved. Electrochemical test results indicated that the corrosion potential and corrosion current density of the coating increased by three orders of magnitude, significantly improving corrosion resistance in comparison to bare samples. Adhesion tests showed that the coating exhibited good bonding performance to the substrate. This method features a simple, pollution-free preparation process and does not require complex instrumentation, thereby enhancing the longevity of the magnesium alloy. Full article

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