Gels, Volume 8, Issue 10
2022 October - 85 articles
Cover Story: Fiber-forming bisurea bolaamphiphiles were provided with photo-responsive coumarin units to create reversibly photocrosslinkable supramolecular hydrogels. Two different wavelengths of UV light were used to induce photo-reversible dimerization and de-dimerization of the coumarin units. Irradiation with 365 nm UV light in solutions of the amphiphiles induced a sol-to-gel transition through dimerization of coumarin, while de-dimerization occurred with 254 nm UV light to provide a weaker gel. In this system, the mechanical strength of supramolecular hydrogels can be tuned by irradiation time, providing precise control of gelation in a supramolecular hydrogelator. View this paper - Issues are regarded as officially published after their release is announced to the table of contents alert mailing list .
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