Photo-Crosslinked Coumarin-Containing Bis-Urea Amphiphile Hydrogels
Abstract
:1. Introduction
2. Results and Discussion
2.1. Model Reaction
2.2. Solution Preparation and UV-Vis Absorption Measurements
2.3. Mass Spectroscopy
2.4. Dynamic Light Scattering
2.5. SAXS and Cryo-TEM Determine Size Change upon Irradiation
2.6. Photo-Induced Gelation and Its Reversibility
3. Conclusions
4. Materials and Methods
4.1. Materials
4.2. Experimental Methods
4.2.1. Synthetic Procedures
4.2.2. Sample Preparation Method
4.2.3. Cryogenic Transmission Electron Microscopy (Cryo-TEM)
4.2.4. Small-Angle X-ray Scattering (SAXS)
4.2.5. Rheology
- without UV irradiation.
- irradiated by 365 nm UV light for 30 min.
- initially irradiated by 365 nm UV light for 30 min, followed by irradiation of 254 nm UV light for 30 min.
Supplementary Materials
Author Contributions
Funding
Institutional Review Board Statement
Informed Consent Statement
Data Availability Statement
Acknowledgments
Conflicts of Interest
References
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Liu, J.; Lou, X.; Schotman, M.J.G.; Marín San Román, P.P.; Sijbesma, R.P. Photo-Crosslinked Coumarin-Containing Bis-Urea Amphiphile Hydrogels. Gels 2022, 8, 615. https://doi.org/10.3390/gels8100615
Liu J, Lou X, Schotman MJG, Marín San Román PP, Sijbesma RP. Photo-Crosslinked Coumarin-Containing Bis-Urea Amphiphile Hydrogels. Gels. 2022; 8(10):615. https://doi.org/10.3390/gels8100615
Chicago/Turabian StyleLiu, Jie, Xianwen Lou, Maaike J. G. Schotman, Patricia P. Marín San Román, and Rint P. Sijbesma. 2022. "Photo-Crosslinked Coumarin-Containing Bis-Urea Amphiphile Hydrogels" Gels 8, no. 10: 615. https://doi.org/10.3390/gels8100615