Table of Contents
Inorganics, Volume 6, Issue 4 (December 2018)
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Cover Story (view full-size image) The interaction between surfactants and zirconium-containing Keggin-type polyoxometalate, which [...] Read more. The interaction between surfactants and zirconium-containing Keggin-type polyoxometalate, which acts as a catalyst for the hydrolysis of peptides and proteins, was studied on the basis of fluorescence spectroscopy and diffusion-ordered NMR spectroscopy (DOSY). Critical micellar concentrations revealed that the dimeric polyanion [Zr(α-PW11O39)2]10− retained its structure in the presence of CHAPS surfactant, but its dissociation to the catalytically active monomeric species occurred in the presence of Zw3-12-type surfactant. By Tatjana N. Parac-Vogt. View Paper here.