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Crystals, Volume 7, Issue 12

December 2017 - 33 articles

Cover Story: Our results demonstrate the important role of liquid in directing the mechanochemical synthesis toward the intended solid product. Grinding of the CoCl2(phenantroline)2 complex and 1,4-diiodotetrafluorobenzene with a small amount of water gives a cocrystal product in which the dominant supramolecular interactions are I···Cl halogen bonds. Grinding solid reactants with a small amount of methanol gives an ionic structure, the four-component solid, in which the dominant supramolecular interactions are I···Cl- charge-assisted halogen bonds as well as O-H···Cl- hydrogen bonds. View this paper
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Articles (33)

  • Article
  • Open Access
16 Citations
6,998 Views
8 Pages

20 December 2017

We study computer-generated geometric-phase holograms (GPHs) realized by photo-aligned liquid crystals, in both simulation and experiment. We demonstrate both far-field and Fresnel holograms capable of producing far-field and near-field images with p...

  • Article
  • Open Access
15 Citations
4,938 Views
12 Pages

20 December 2017

Polyamide 66 (PA66) was chosen as the representative of hydrophilic polymers, to investigate the influence of epitaxial crystals in semi-crystalline polymers/reduced graphene oxide nanocomposite injection-molding bars. A differential scanning calorim...

  • Review
  • Open Access
9 Citations
7,445 Views
21 Pages

Chemical Crystallography at the Advanced Light Source

  • Laura J. McCormick,
  • Nico Giordano,
  • Simon J. Teat and
  • Christine M. Beavers

18 December 2017

Chemical crystallography at synchrotrons was pioneered at the Daresbury SRS station 9.8. The chemical crystallography beamlines at the Advanced Light Source seek to follow that example, with orders of magnitude more flux than a lab source, and variou...

  • Article
  • Open Access
3 Citations
3,636 Views
8 Pages

15 December 2017

A series of new Ge-substituted skutterudite compounds with the general composition of LnxCo4Sb12−yGey, where Ln = La, Ce, Pr, and Nd, is prepared by high-pressure and high-temperature reactions at 7 GPa and 800 °C. They have a cubic unit cell and the...

  • Review
  • Open Access
13 Citations
8,204 Views
15 Pages

14 December 2017

This review is focused on the dimerization and dissociation of aromatic C-nitroso compounds and their dimers, the reactions that could be used as a convenient model for studying the thermal organic solid-state reaction mechanisms. This molecular mode...

  • Article
  • Open Access
3 Citations
4,607 Views
11 Pages

Thermal Stability of Epitaxial Graphene Electrodes for Conductive Polymer Nanofiber Devices

  • Kyung Ho Kim,
  • Samuel Lara-Avila,
  • Hans He,
  • Hojin Kang,
  • Yung Woo Park,
  • Rositsa Yakimova and
  • Sergey Kubatkin

14 December 2017

We used large area, monolayer graphene epitaxially grown on SiC (0001) as contact electrodes for polymer nanofiber devices. Our fabrication process, which avoids polymer resist residues on the graphene surface, results in graphene-polyaniline nanofib...

  • Article
  • Open Access
9 Citations
5,334 Views
11 Pages

Influence of Alkali Metal Substitution on the Phase Transition Behavior of CsGaQ2 (Q = S, Se)

  • Daniel Friedrich,
  • Marc Schlosser,
  • Martin Etter and
  • Arno Pfitzner

14 December 2017

The formation of solid solution series Cs1−xMxGaQ2-mC64 (M = K, Rb; Q = S, Se; x = 0–1) was studied by X-ray diffraction and spectroscopic methods, revealing a complete miscibility of CsGaQ2-mC64 with RbGaQ2 and KGaSe2, and a large miscibility gap wi...

  • Article
  • Open Access
8 Citations
12,316 Views
12 Pages

14 December 2017

In this contribution, we present the first crystal structure of iron(III) salicylate without additional counterions. The octahedral complex contains two salicylate and two water molecules as ligands. One salicylate is mono-anionic while the other is...

  • Article
  • Open Access
2 Citations
4,421 Views
14 Pages

14 December 2017

In order to study the effect of the angle of wedged indenters during nanoindentation, indenters with half vertex angles of 60°, 70° and 80° are used for the simulations of nanoindentation on FCC aluminum (Al) bulk material by the multiscale quasicont...

  • Review
  • Open Access
1 Citations
3,875 Views
23 Pages

14 December 2017

A review on mathematical elasticity of quasicrystals is given. In this review, the focus is on various defects of quasicrystals. Dislocation and crack are two classes of typical topological defects, while their existence has great influence on the me...

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Crystals - ISSN 2073-4352