Next Issue
Volume 19, August-1
Previous Issue
Volume 19, July-1
 
 
materials-logo

Journal Browser

Journal Browser

Materials, Volume 19, Issue 14 (July-2 2026) – 223 articles

Cover Story (view full-size image): Nano bioinks represent a transformative platform at the interface of nanotechnology, biomaterials, and 3D bioprinting, enabling the development of next-generation constructs for regenerative medicine, drug delivery, and biosensing. By integrating functional nanomaterials into polymeric and hydrogel matrices, nano bioinks achieve enhanced mechanical strength, bioactivity, printability, and structural stability, while preserving biological functionality. This review highlights recent advances in nano bioink design, fabrication strategies, and biomedical applications, while addressing critical challenges including reproducibility, biocompatibility, regulatory considerations, and clinical translation. The insights presented provide a roadmap toward safe, reliable, and multifunctional nano-enabled biofabrication technologies. View this paper
  • Issues are regarded as officially published after their release is announced to the table of contents alert mailing list.
  • You may sign up for e-mail alerts to receive table of contents of newly released issues.
  • PDF is the official format for papers published in both, html and pdf forms. To view the papers in pdf format, click on the "PDF Full-text" link, and use the free Adobe Reader to open them.
Order results
Result details
Section
Select all
Export citation of selected articles as:
59 pages, 2166 KB  
Review
Waste Material Utilization in Civil Engineering Applications: Advances, Challenges, and Future Directions—A Scoping Review
by Chathurika Dassanayake, Nuha S. Mashaan and Ridmi Galagedara
Materials 2026, 19(14), 3154; https://doi.org/10.3390/ma19143154 - 22 Jul 2026
Cited by 1 | Viewed by 1047
Abstract
This PRISMA-guided scoping review examines the use of waste materials in civil engineering as a sustainable approach to reducing environmental impacts, conserving natural resources, and supporting circular economy principles. The rapid growth of urbanization, industrialization, mining, and agricultural activities generates large amounts of [...] Read more.
This PRISMA-guided scoping review examines the use of waste materials in civil engineering as a sustainable approach to reducing environmental impacts, conserving natural resources, and supporting circular economy principles. The rapid growth of urbanization, industrialization, mining, and agricultural activities generates large amounts of waste materials, including fly ash, ground granulated blast-furnace slag, bauxite residue, mining tailings, waste rock, acid-mine drainage sludge, waste plastics, post-consumer vulcanized rubber, recycled construction materials, and agricultural ashes. The disposal of these materials often creates serious environmental and land-use problems, making their reuse increasingly important. In this context, civil engineering is one of the most promising sectors for large-scale waste valorization because of its high material demand and its ability to use different waste streams into practical applications such as concrete and cementitious systems, pavement and asphalt engineering, geotechnical works, and other infrastructure sectors. This review critically evaluates the global availability, material characteristics, engineering applications, environmental and economic benefits, recent advances, and key challenges related to major industrial, mining, agricultural, polymeric, and construction-derived wastes. Although significant progress has been made in this field, wider implementation is still limited by variations in material properties, technical and environmental challenges, economic constraints, and limited field validation of long-term performance. By bringing together current knowledge from different waste streams and civil engineering sectors, this review highlights important research gaps and future directions to support more sustainable, resilient, and resource-efficient infrastructure development. The effective use of waste materials in civil engineering can play an important role in reducing carbon emissions, improving resource efficiency, and supporting global sustainability. Full article
Show Figures

Figure 1

52 pages, 17895 KB  
Review
From Wide- to Low-Bandgap Semiconductors for Transient Photocurrent THz Emission: A Review
by Sanjit Varma, Tsuneyuki Ozaki and My Ali El Khakani
Materials 2026, 19(14), 3153; https://doi.org/10.3390/ma19143153 - 22 Jul 2026
Cited by 1 | Viewed by 770
Abstract
Terahertz (THz) radiation generated through ultrafast transient photocurrent mechanisms has become a cornerstone of modern THz photonics, enabling broadband coherent emission with sub-picosecond temporal resolution. This review provides a comprehensive and mechanism-driven analysis of THz pulse generation via photo-Dember diffusion currents, surface depletion [...] Read more.
Terahertz (THz) radiation generated through ultrafast transient photocurrent mechanisms has become a cornerstone of modern THz photonics, enabling broadband coherent emission with sub-picosecond temporal resolution. This review provides a comprehensive and mechanism-driven analysis of THz pulse generation via photo-Dember diffusion currents, surface depletion field acceleration, and biased photoconductive antenna architectures. We present a comprehensive comparative analysis of wide- and low-bandgap material platforms, including III–V, II–VI, and group IV semiconductors, as well as two-dimensional materials, topological insulators, and Weyl semimetals, highlighting how their intrinsic properties, such as band structure, carrier mobility, recombination dynamics, doping, and dielectric response, govern their THz emission efficiency, bandwidth, and spectral tunability. Special emphasis is placed on germanium (Ge), which has re-emerged as a highly promising THz source material owing to its high carrier mobility, long diffusion lengths, strain-tunable band structure, and CMOS compatibility. We highlight the roles of doping, strain-induced direct transitions, and several fabrication techniques in controlling the nonlinear photoexcited charge-carrier dynamics in Ge, thereby unlocking enhanced broadband THz performance. Finally, we explore the emerging application prospects of THz radiation, ranging from non-invasive security screening to biochemical sensing and archeological preservation. By bridging fundamental material science with scalable device architectures, this review outlines current challenges, highlights evolving opportunities in novel materials, and charts future directions towards integrated THz technologies. Full article
(This article belongs to the Special Issue Emerging Photonic and Electromagnetic Materials and Devices)
Show Figures

Figure 1

32 pages, 37654 KB  
Article
Cross-Scale Correlation Analysis Between Forming Quality and Microstructural Response During SPIF of the Al 1060 Based on PEEQ-Based SSD Density Inference and EBSD Characterization
by Xinyue Zhang, Xiaojing Zhu, Yuhuai Wang, Yaokun Ye, Mingyan Zhao, Teng Zhou and Wenxun Li
Materials 2026, 19(14), 3152; https://doi.org/10.3390/ma19143152 - 22 Jul 2026
Viewed by 507
Abstract
Single-point incremental forming (SPIF) produces localized plastic deformation, resulting in thickness reduction, geometrical deviation, and microstructural evolution. To establish the relationship between forming quality and microstructural response, this study develops a cross-scale analysis framework integrating finite element simulation, Kocks–Mecking (K–M)-based statistically stored dislocation [...] Read more.
Single-point incremental forming (SPIF) produces localized plastic deformation, resulting in thickness reduction, geometrical deviation, and microstructural evolution. To establish the relationship between forming quality and microstructural response, this study develops a cross-scale analysis framework integrating finite element simulation, Kocks–Mecking (K–M)-based statistically stored dislocation (SSD) density inference, metallographic observation and electron backscatter diffraction (EBSD) characterization. Applied to an Al 1060 truncated-cone part, the framework converts the simulated equivalent plastic strain (PEEQ) into SSD density via the K–M model calibrated using the Voce hardening model and the Taylor relation. The inferred SSD density distribution is then spatially correlated with thinning rate, geometrical deviation, grain size, grain-boundary misorientation, kernel average misorientation (KAM), and geometrically necessary dislocation (GND) density across different forming regions. The inferred SSD density rapidly approached a saturation level of 1.55 × 1013 m−2, while the high-SSD density region progressively expanded during forming. This regional evolution was qualitatively consistent with the EBSD observations. The average grain size decreased from 30.4 μm to 21.9 μm, and the medium-angle grain-boundary fraction increased from 10.3% to 34.5%. Regionally, thickness reduction correlates strongly with PEEQ accumulation, SSD storage, and grain refinement, whereas geometrical deviation is more closely related to early-stage deformation heterogeneity. These findings provide a physically based route for predicting and controlling SPIF accuracy. Full article
(This article belongs to the Special Issue Latest Developments in Advanced Machining Technologies for Materials)
Show Figures

Graphical abstract

20 pages, 12561 KB  
Article
Investigation on the Structural Integrity of Solid Propellant Grains with Different-Sized Void Defects
by Jianru Wang, Kai Liu, Tuanwei Xu, Jinkang Du, Yuanzhe Liang, Wenjing Li and Peng Cao
Materials 2026, 19(14), 3151; https://doi.org/10.3390/ma19143151 - 22 Jul 2026
Viewed by 405
Abstract
During the service of solid rocket motors, propellant grains need to bear various loads such as curing cooling, gravity, and combustion internal pressure. The internal pore defects will seriously affect the structural integrity. In this paper, a three-dimensional finite element model of propellant–insulation [...] Read more.
During the service of solid rocket motors, propellant grains need to bear various loads such as curing cooling, gravity, and combustion internal pressure. The internal pore defects will seriously affect the structural integrity. In this paper, a three-dimensional finite element model of propellant–insulation layer–mold is established to study the structural responses of pore defects with different sizes (30–100 mm) under three typical working conditions: curing cooling, curing cooling coupled with gravity, and internal pressure loading. It is found that under the curing cooling condition, compared with the non-porous propellant grain structure, the structure with pores will raise the overall mechanical response of the propellant grain, and the maximum stress and strain are mainly concentrated in the front end of the core hole and the wing groove area. The pore size has a limited impact on the overall stress distribution, but will change the local stress concentration degree. Among them, the 80 mm pore reduces the stress in the wing groove area through stress field interference. Moreover, large-size pores will significantly weaken the structural bearing capacity and increase the contact pressure between the propellant and the core mold. Under the condition of curing cooling coupled with gravity, the stress and strain are mainly distributed at the edge of the pores, and the values increase with the increase of pore size. Under the action of internal pressure load, the stress and strain in the middle section of the propellant grain have no obvious change, but stress concentration occurs in the transition area between the core hole and the wing groove and at the end of the wing groove. The results of this study provide a reference for the integrity evaluation and structural optimization of propellant grains with pore defects. Full article
Show Figures

Figure 1

32 pages, 10997 KB  
Article
CTGAN-Based Data Augmentation and XGBoost–LSTM Strength Prediction of CSG
by Guanghui Li, Yupeng Zhang, Qingqing Tian, Lei Guo and Qihui Chai
Materials 2026, 19(14), 3150; https://doi.org/10.3390/ma19143150 - 22 Jul 2026
Viewed by 614
Abstract
Cementitious sand and gravel (CSG) is commonly used in construction engineering; however, its mix proportion design is complex, and traditional physical experiments face limitations such as long cycles, high costs, and susceptibility to external factors when obtaining high-quality sample data. In this study, [...] Read more.
Cementitious sand and gravel (CSG) is commonly used in construction engineering; however, its mix proportion design is complex, and traditional physical experiments face limitations such as long cycles, high costs, and susceptibility to external factors when obtaining high-quality sample data. In this study, a foundational dataset was first acquired through physical experiments: 100 sets of CSG specimens with different mix proportions (cement content 40, 50, 60, 70 kg/m3; water-to-binder ratio 1.0, 1.2, 1.4; sand ratio 0.1, 0.2, 0.3, 0.4; fly ash content 20, 30, 40, 50 kg/m3) were prepared. After 28 days of standard curing, compressive strength and splitting tensile strength tests were conducted using a WAW-1000 electro-hydraulic servo universal testing machine, yielding 100 sets of real mechanical property data. The coefficients of variation for all test groups were below 10%, confirming the reliability and repeatability of the experimental data. On this basis, a data augmentation method based on Conditional Tabular Generative Adversarial Networks (CTGAN) is proposed. Through adversarial training between the generator and the discriminator, the model learns the multi-dimensional distribution characteristics of the original CSG data and generates 100 synthetic samples, which are then merged with the original data to expand the dataset to 200 samples. The quality of the synthetic data is evaluated using Wasserstein distance and correlation matrix heatmaps. Furthermore, a hybrid XGBoost–LSTM prediction model is proposed—XGBoost is used for feature construction to capture nonlinear interactions among mix proportion variables, and the constructed features are then fed into an LSTM network for sequential learning and regression prediction. The results show that the CTGAN-generated data are highly consistent with the original data in terms of kernel density distributions and variable correlations, with Wasserstein distance significantly superior to four comparative methods: Bootstrap, SMOTE, GaussianCopula, and TVAE. After augmentation, the XGBoost–LSTM model achieves a coefficient of determination (R2) of 0.9897 for compressive strength prediction (vs. 0.9793 before augmentation) and 0.9801 for splitting tensile strength (vs. 0.9882 before augmentation, a slight decrease). The mean absolute percentage errors (MAPE) are 4.49% and 4.11%, and the root mean square errors (RMSE) are 0.201 and 0.049, respectively; both error metrics are reduced compared with those before augmentation. Compared with baseline models including XGBoost, LSTM, Random Forest (RF), and Support Vector Regression (SVR), the XGBoost–LSTM model exhibits the best performance across all evaluation metrics, and Wilcoxon signed-rank tests confirm that the performance differences are statistically significant (p < 0.05). The proposed method of CTGAN-based data augmentation combined with the XGBoost-LSTM hybrid model provides an effective solution to the problem of insufficient CSG sample data and offers a reference for data enhancement and performance prediction of other small-sample materials. Full article
(This article belongs to the Section Construction and Building Materials)
Show Figures

Graphical abstract

15 pages, 9080 KB  
Communication
Effect of Carbonated Steel Slag Powder on the Rheological Properties and Printability of 3D Printed Cement Composites
by Yilin Wang, Xingyu Qu, Junyu Wang, Xingang Xu, Yan Zheng, Heyang Wu and Mingxu Chen
Materials 2026, 19(14), 3149; https://doi.org/10.3390/ma19143149 - 22 Jul 2026
Viewed by 336
Abstract
The insufficient shape stability and uncontrollable rheological behavior of 3D printed cement composites (3DPCCs) still limit their wider application in construction. In this study, graded carbonated steel slag powder (CSS1 and CSS2) was used to adjust the rheological properties of 3DPCCs based on [...] Read more.
The insufficient shape stability and uncontrollable rheological behavior of 3D printed cement composites (3DPCCs) still limit their wider application in construction. In this study, graded carbonated steel slag powder (CSS1 and CSS2) was used to adjust the rheological properties of 3DPCCs based on the oscillation shear and controlled shear-rate protocols, providing a sustainable and novel strategy for improved printability and mechanical properties. The results showed that the incorporation of carbonated steel slag into 3DPCCs effectively improved the viscoelasticity and yield behavior. As the carbonation time increased from 0 d to 21 d, the dynamic yield stresses of 3DPCCs with CSS1 and CSS2 increased from 126.08 Pa and 116.38 Pa to 707.29 Pa and 509.29 Pa, respectively. In addition, the structural deformation of 3DPCCs with CSS1 and CSS2 decreased from 20.35% and 21.61% to 9.83% and 11.29%, respectively, while the 3-day compressive strength increased from 8.5 MPa and 6.0 MPa to 14.2 MPa and 13.2 MPa, respectively. In conclusion, the carbonated steel slag shows great application potential in improving the rheological behavior and printability of 3D-printed cement composites. Full article
Show Figures

Graphical abstract

17 pages, 11489 KB  
Article
Boosting Reaction Kinetics in Co3O4/ZnCo2O4 Frameworks with Heterostructures for High-Performance Lithium-Ion Batteries
by Qibei Tu and Zhifeng Wang
Materials 2026, 19(14), 3148; https://doi.org/10.3390/ma19143148 - 22 Jul 2026
Viewed by 327
Abstract
When metal oxides are employed as anodes in lithium-ion batteries, their practical application is often constrained by sluggish reaction kinetics. Structure optimization and heterointerface regulation are effective strategies for improving the aforementioned issue. Herein, a series of Co3O4/ZnCo2 [...] Read more.
When metal oxides are employed as anodes in lithium-ion batteries, their practical application is often constrained by sluggish reaction kinetics. Structure optimization and heterointerface regulation are effective strategies for improving the aforementioned issue. Herein, a series of Co3O4/ZnCo2O4 heterostructured materials with hollow structures is prepared. The effects of the two-phase ratio on the interfacial activity and electrochemical performance are systematically investigated. Among them, the optimized Co3O4/ZnCo2O4-2 material exhibits enhanced interfacial interactions and abundant oxygen vacancies, which optimize the local electronic environment and facilitate charge transfer. Electrochemical test results indicate that the Co3O4/ZnCo2O4-2 anode maintains a reversible capacity of 582.4 mAh g−1 after 1000 cycles at 1 A g−1, demonstrating good cycling stability. Furthermore, the full cell assembled with a LiFePO4 cathode maintains a discharge capacity of 115.9 mAh g−1 after 100 cycles at 0.2 C, validating the practical application potential of the material. This work reveals the key role of interface regulation in boosting Li+ diffusion kinetics of transition metal oxides, providing new insights for the rational design of heterostructured anodes. Full article
(This article belongs to the Special Issue Materials for Electrochemical Energy Storage)
Show Figures

Graphical abstract

37 pages, 6327 KB  
Review
A Comparative Review of Multi-Walled Carbon Nanotube-Reinforced Thermoplastic Petroleum-Based (PET, PBT) and Bio-Based (PLA, PBS) Polyester Systems
by Kashif Ullah Khan, Ferenc Ronkay and Andrea Ádámné Major
Materials 2026, 19(14), 3147; https://doi.org/10.3390/ma19143147 - 22 Jul 2026
Viewed by 404
Abstract
This review comparatively analyzed MWCNT-reinforced thermoplastic polyester nanocomposites based on petroleum-derived (PET, PBT) and bio-based (PLA, PBS) matrices, focusing on processing methods, mechanical performance, thermal stability, electrical behavior, and recyclability. Optimal MWCNT loadings typically ranged from 0.3 to 3 wt.%; higher loadings induced [...] Read more.
This review comparatively analyzed MWCNT-reinforced thermoplastic polyester nanocomposites based on petroleum-derived (PET, PBT) and bio-based (PLA, PBS) matrices, focusing on processing methods, mechanical performance, thermal stability, electrical behavior, and recyclability. Optimal MWCNT loadings typically ranged from 0.3 to 3 wt.%; higher loadings induced nanotube agglomeration and deteriorated properties due to poor dispersion and stress concentration. Melt mixing, solution blending, direct compounding, and in situ polymerization were evaluated, and their influence on dispersion quality, interfacial bonding, and scalable manufacturability was discussed. PET exhibited the largest improvements in mechanical and thermal performance (tensile strength and modulus increases >300% in optimized systems); acid or compatibilizer functionalization of MWCNT improved PET thermal stability by approximately 20–50 °C and promoted heterogeneous nucleation. PBT reached optimal reinforcement at 0.3–1 wt.% MWCNT, yielding tensile strength increases up to ~57% alongside increased crystallinity and faster crystallization kinetics. PLA generally showed reduced tensile strength after MWCNT addition unless compatibilized (e.g., via plasticizers or grafting), whereas PBS consistently gained strength, modulus, and crystallinity but experienced reductions in ductility. Electrical percolation thresholds varied widely (0.25–14 wt.%), demonstrating that dispersion quality, nanotube functionalization, and processing route governed conductivity and percolation behavior more than matrix chemistry. Recyclability and circular economy aspects were assessed: while PET/MWCNT systems showed promise for mechanical recycling and property recovery, data on repeated reprocessing, CNT structural integrity, and long-term electrical performance were scarce; PBT recycling studies were limited, and PBS/PLA recycling with retained conductive networks remained underexplored. Based on the comparative analysis, key limitations, critical research gaps, and practical recommendations for processing, compatibilization, and end-of-life evaluation were identified to guide future work aimed at enhancing both performance and sustainability of polyester/MWCNT nanocomposites. Full article
(This article belongs to the Special Issue Innovations in Carbon Nanomaterials and Composites)
Show Figures

Graphical abstract

13 pages, 28928 KB  
Article
Understanding the Tensile Deformation Behavior of a Serviced 304 Stainless Steel Based on Quasi In Situ EBSD Measurement
by Daicun Ding, Zhijin Ji, Yan Jing, Shilong Xing, Guanghua Yan, Shuo Wu and Lingkun Zhang
Materials 2026, 19(14), 3146; https://doi.org/10.3390/ma19143146 - 22 Jul 2026
Viewed by 296
Abstract
The microstructural evolution and strain-hardening mechanisms of a serviced 304 stainless steel during tensile deformation are investigated using quasi in situ EBSD measurements. This steel exhibits a high ultimate tensile strength of about 652 MPa alongside an exceptional fracture elongation of 83.4%. Its [...] Read more.
The microstructural evolution and strain-hardening mechanisms of a serviced 304 stainless steel during tensile deformation are investigated using quasi in situ EBSD measurements. This steel exhibits a high ultimate tensile strength of about 652 MPa alongside an exceptional fracture elongation of 83.4%. Its strain hardening behavior can be divided into three distinct stages. Deformation induces heterogeneous lattice rotation, which is dominated by the preferential activation of slip systems with the top two Schmid factors. With increasing strain, the deformation mechanism evolves sequentially from dislocation slip to mechanical twinning and then strain-induced martensite transformation. Mechanical twins act as the preferential nucleation sites for strain-induced martensite. In the latter two deformation stages, mechanical twinning serves as the primary driver of strain hardening, while strain-induced martensite merely contributes auxiliary hardening due to its limited volume fraction. This work elucidates the full-chain deformation mechanism of serviced 304 stainless steel. It provides experimental fundamentals for evaluating the residual ductility and failure risk of serviced austenitic stainless steel components. Full article
(This article belongs to the Section Metals and Alloys)
Show Figures

Figure 1

11 pages, 9374 KB  
Article
Integration of LASER Diodes Emitting at Eight Different Wavelengths from Blue to Infrared on a 4H-SiC-Based Optical Integration Platform
by Xiaoshan Wang, Xiaoxuan Li, Ruyan Kang, Wenqi Jia, Xueyi Duan, Rongpeng Yang, Zhinuo Fan, Zechao Li, Jian Zhou and Zhiyuan Zuo
Materials 2026, 19(14), 3145; https://doi.org/10.3390/ma19143145 - 22 Jul 2026
Viewed by 327
Abstract
We demonstrate an integrated eight-wavelength high-power laser source on a 4H-silicon carbide (SiC)-based optical integration platform. Eight discrete Fabry–Perot laser diodes emitting at 445 nm, 637 nm, 789 nm, 806 nm, 846 nm, 978 nm, 1316 nm, and 1552 nm are integrated on [...] Read more.
We demonstrate an integrated eight-wavelength high-power laser source on a 4H-silicon carbide (SiC)-based optical integration platform. Eight discrete Fabry–Perot laser diodes emitting at 445 nm, 637 nm, 789 nm, 806 nm, 846 nm, 978 nm, 1316 nm, and 1552 nm are integrated on a single SiC chip, each delivering ≥100 mW continuous-wave output power. A complete fabrication process is developed, including lift-off metallization (Ni/Ti/Pt/Au), surface hydrophilic activation bonding, and multi-step blade dicing to form SiC waveguides with a width of 500 μm and a thickness defined by the ~510 μm dicing depth, matching the output aperture of the multimode laser diodes. The resulting waveguides exhibit a facet misorientation of <1° and an approximate facet mean surface roughness of ~2 nm. The laser diodes are directly butted against the waveguide facets for edge coupling, and fixed using In52Sn48 solder bonding with pulse temperature control. Under controlled temperature, all eight channels operate stably with measured peak wavelengths matching the design targets. This work provides a scalable and practical solution for multi-wavelength, high-power on-chip light source integration on the SiC platform, addressing critical thermal and integration challenges for dense wavelength division multiplexing. Full article
(This article belongs to the Section Optical and Photonic Materials)
Show Figures

Graphical abstract

16 pages, 12596 KB  
Article
Exploring the Role of Superplasticizers in Tailoring the Aqueous Dispersions of Graphene Nanoplatelets
by Maria-Evangelia Stogia, George Maistros, Philippe Poulin and Nikolaos D. Alexopoulos
Materials 2026, 19(14), 3144; https://doi.org/10.3390/ma19143144 - 22 Jul 2026
Viewed by 400
Abstract
Graphene nanoplatelets (GnPs) exhibit exceptional properties for advanced functional applications; nevertheless, their effective utilization is critically limited by agglomeration and poor dispersion. The incorporation of polycarboxylate-based superplasticizers (SPs) enables improved dispersion yet simultaneously introduces insulating effects that hinder conductive network formation. In the [...] Read more.
Graphene nanoplatelets (GnPs) exhibit exceptional properties for advanced functional applications; nevertheless, their effective utilization is critically limited by agglomeration and poor dispersion. The incorporation of polycarboxylate-based superplasticizers (SPs) enables improved dispersion yet simultaneously introduces insulating effects that hinder conductive network formation. In the present article, we systematically investigate the interplay between GnPs and an SP under varying ultrasonic energy inputs to optimize dispersion and electrical performance through low-cost suspension processing. Dielectric measurements identify the key parameters governing conductive network formation and reveal the dual role of the SP as both dispersant and electrical barrier. Electrochemical impedance spectroscopy, combined with optical microscopy, provides further insights into the state of dispersion and charge-transport behaviour of the suspensions. For the first time, a wide range of SP and GnP concentrations were systematically analysed in terms of electrical properties. The proposed methodology provides a robust and facile approach for on-site characterization of aqueous suspensions with varying GnPs and SP concentrations. Furthermore, an equivalent circuit model is developed to quantitatively validate the experimental results, offering deeper insights into the underlying conduction mechanisms. GnP concentrations of 0.15, 0.50 and 1.00 wt.% were investigated at varying ratios of SP to GnP (0, 1, 2, 4, and 8). Dispersions without SP addition require ultrasonication up to 80 kJ for the GnP agglomerates to break. SP addition at a quantity equal to GnPs (SP1) reduces the amount of appropriate ultrasonic energy for creating a conductive network up to 65 kJ and even more (SP2) at 45 kJ. The fourfold (SP4) and eightfold (SP8) ratio of SP to GnP require higher ultrasonic energy, up to 82 kJ and 70 kJ, accordingly. Full article
Show Figures

Graphical abstract

22 pages, 24675 KB  
Article
Fabrication of Li/In Double-Sided Diffusion Contacts in Planar High-Purity Germanium Detectors and Their Low-Temperature X-Ray Response
by Meng Cao, Zexin Wang, Yanggang Jia, Qingzhi Hu, Zhaoran Guan, Haofei Huang, Linjun Wang and Jian Huang
Materials 2026, 19(14), 3143; https://doi.org/10.3390/ma19143143 - 22 Jul 2026
Viewed by 356
Abstract
Li n+ and In p+ diffusion contacts were fabricated on p-type 12N high-purity germanium (HPGe) single crystals by vacuum evaporation of thin-film sources followed by solid-state thermal diffusion. The effects of diffusion temperature on the near-surface structure, morphology, impurity distribution, and [...] Read more.
Li n+ and In p+ diffusion contacts were fabricated on p-type 12N high-purity germanium (HPGe) single crystals by vacuum evaporation of thin-film sources followed by solid-state thermal diffusion. The effects of diffusion temperature on the near-surface structure, morphology, impurity distribution, and device response were systematically investigated. XRD and Raman analyses show that Li diffusion at 100–300 °C and In diffusion at 600–800 °C preserve the bulk Ge crystal structure, whereas higher diffusion temperatures induce surface roughening, near-surface disordering, and interfacial reactions. SIMS depth profiles combined with diffusion simulations confirm effective inward diffusion of both Li and In, with low-concentration tailing that is consistent with defect-assisted diffusion or interfacial trapping. The sample diffused with Li at 200 °C exhibits the lowest dark current, 8.07 × 10−8 A at −10 V. The final HPGe device with Li/In diffusion contacts shows a stable synchrotron X-ray photoconductive response, and the net response current increases from 4.48 × 10−7 to 1.15 × 10−6 A as the incident photon flux increases. These results demonstrate that low-leakage HPGe diffusion contacts require a balance between diffusion-layer formation and near-surface/interface stability, rather than a simple increase in thermal budget. Full article
Show Figures

Figure 1

25 pages, 3144 KB  
Article
Environmental and Mechanical Performance of Green Concrete Utilizing Coarse Copper Slag Aggregate
by Sandra Guševac, Vesna Marjanović, Olivera Đokić, Aleksandar Radević, Sandra Milutinović, Jelena Đorđević and Dragana Adamović Marković
Materials 2026, 19(14), 3142; https://doi.org/10.3390/ma19143142 - 22 Jul 2026
Viewed by 454
Abstract
This study investigates the environmental potential and viability of replacing natural river aggregates (RAs) with copper slag aggregates (CSAs) in concrete production. The primary objective was to assess the structural performance of these eco-concrete mixtures and determine the optimum copper slag content for [...] Read more.
This study investigates the environmental potential and viability of replacing natural river aggregates (RAs) with copper slag aggregates (CSAs) in concrete production. The primary objective was to assess the structural performance of these eco-concrete mixtures and determine the optimum copper slag content for structural applications. The experimental program evaluated concrete mixtures with natural river aggregate replacement levels of 20% + 20% and 50% + 100% for the 8/16 mm and 16/32 mm fractions, respectively, using coarse copper slag aggregate (CCA). The results indicate that incorporating CCA increases concrete compressive strength, successfully meeting the requirements for strength class C25/30. The petrographic assessment indicated a shift towards an aggregate mixture, in which the dominant quartzite and a constant quartz-mineral fraction of 16.5% provide a stable structure alongside the CSA grains. However, a significant increase in water penetration depth (up to 22%) was observed, highlighting the enhanced water penetration depth of these concretes. SEM microstructural analysis attributed the improved bond between the cement matrix and CCA grains to a compact interfacial transition zone. Additionally, leaching tests confirmed that heavy metals are effectively immobilized in the cement paste for mixtures with lower replacement levels (up to 20%), thereby meeting environmental standards. The study concludes that copper slag at these controlled replacement levels represents a sustainable, high-quality alternative for construction materials in drainage infrastructure. Incremental analysis in accordance with NEN 7375 showed that the tested material behaves as an insoluble matrix, with no evidence of diffusion-controlled leaching. The cumulative leaching values obtained after 64 days of testing in accordance with NEN 7375 were significantly below the regulatory limits for all components analyzed. These findings indicate a low potential for contaminant release and favorable environmental stability of the 20% replacement mixture, though further leaching evaluation is required for maximum slag contents. Full article
Show Figures

Figure 1

21 pages, 5008 KB  
Article
Effect of Sn and Ru in Pt-Based Catalysts for Alcohol Oxidation in Alkaline Media: A Combined Electrochemical and DFT Study
by Diego González-Quijano, Wilian Jesús Pech-Rodríguez, Eduardo Rubio, Gladis Guadalupe Suárez-Velázquez, Jesús Adrián Díaz-Real and Francisco Javier Rodríguez-Varela
Materials 2026, 19(14), 3141; https://doi.org/10.3390/ma19143141 - 22 Jul 2026
Viewed by 297
Abstract
Pt-Sn/C and Pt-Ru/C electrocatalysts were synthesized by a polyol method at nominal atomic ratios of 1:1, 2:1, and 3:1, and evaluated for the ethanol oxidation reaction (EOR) and ethylene glycol oxidation reaction (EGOR) in alkaline media. EDS confirmed compositions close to the nominal [...] Read more.
Pt-Sn/C and Pt-Ru/C electrocatalysts were synthesized by a polyol method at nominal atomic ratios of 1:1, 2:1, and 3:1, and evaluated for the ethanol oxidation reaction (EOR) and ethylene glycol oxidation reaction (EGOR) in alkaline media. EDS confirmed compositions close to the nominal values, XRD evidenced fcc Pt-M alloy formation, and ADF-STEM revealed well-dispersed nanoparticles below 3 nm. Cyclic voltammetry showed that both Sn and Ru enhance activity relative to Pt/C: Pt-Sn1:1 delivered the highest forward current density in the Sn series (1486 mA mg−1Pt for EOR; 2583 mA mg−1Pt for EGOR), whereas Pt-Ru shifted the onset to more negative potentials (down to −539 mV vs. SHE for EOR), with Pt-Ru3:1 reaching 1858 (EOR) and 2434 mA mg−1Pt (EGOR). Chronoamperometry revealed higher current retention during EGOR than EOR for all catalysts, indicating fewer poisoning intermediates from ethylene glycol. DFT calculations of CO adsorption on 1:1 and 3:1 model surfaces rationalize the distinct roles of the two metals: Sn excludes CO from Sn sites at both compositions and weakens the Pt-CO bond by 0.602 eV at 1:1, while Ru weakens it moderately yet binds CO strongly at both compositions; the bifunctional supply of OHads by Ru, inferred from the more negative onset potentials, accounts for its higher activity. PDOS analysis links these trends to distinct Pt d-band modifications. Full article
(This article belongs to the Section Energy Materials)
Show Figures

Graphical abstract

16 pages, 4511 KB  
Article
Experimental Determination of the Relationship Between the Resistance Micro-Drilling Characteristic and the Density of Spruce Wood at Different Moisture Contents
by Věra Heřmánková, Ondřej Anton, Kristýna Hrabová, Petr Cikrle and Dalibor Kocáb
Materials 2026, 19(14), 3140; https://doi.org/10.3390/ma19143140 - 22 Jul 2026
Viewed by 443
Abstract
This study explores the potential of non-destructive methods for diagnosing timber structures, with a primary focus on maximising the capabilities of the resistance-drilling technique. Laboratory tests were performed on spruce wood specimens, the most commonly used construction timber in Central Europe, prepared across [...] Read more.
This study explores the potential of non-destructive methods for diagnosing timber structures, with a primary focus on maximising the capabilities of the resistance-drilling technique. Laboratory tests were performed on spruce wood specimens, the most commonly used construction timber in Central Europe, prepared across a wide range of moisture contents (0–53%) to assess the influence of moisture on resistance-drilling characteristics. The resistance micro-drilling (RM) characteristic was found to be independent of moisture content (coefficient of determination close to zero), confirming that resistance drilling provides stable results under varying in situ moisture conditions. In contrast, wood density and the RM characteristic were strongly correlated, with coefficients of determination of R2 = 0.87 for moisture contents between 0% and 30%, and R2 = 0.90 for the 8–18% moisture range typical of timber in service. Based on these relationships, two linear conversion equations were developed (ρ = 1.685·RM + 183.85 and ρ = 1.982·RM + 135.15, respectively), enabling estimation of spruce wood density directly from RM values. Compressive strength parallel and perpendicular to grain decreased with increasing moisture content up to the fibre saturation point, beyond which the reduction in strength plateaued. Full article
Show Figures

Figure 1

15 pages, 2038 KB  
Article
Phase-Specific Assessment of Corrosion Susceptibility in Inconel 625 and SA508 Low-Alloy Steel Under Molten Chloride Conditions
by Seongwon Ham, Hyung-Ha Jin, Chaewon Kim, Jinsuo Zhang and Sangtae Kim
Materials 2026, 19(14), 3139; https://doi.org/10.3390/ma19143139 - 22 Jul 2026
Viewed by 444
Abstract
Nickel-based alloys are promising structural materials for molten salt systems; however, secondary-phase formation during long-term high-temperature exposure may introduce local corrosion susceptibility because secondary phases have compositions and redox stabilities distinct from the matrix. Here, we combine CALculation of PHAse Diagrams (CALPHAD)-based phase [...] Read more.
Nickel-based alloys are promising structural materials for molten salt systems; however, secondary-phase formation during long-term high-temperature exposure may introduce local corrosion susceptibility because secondary phases have compositions and redox stabilities distinct from the matrix. Here, we combine CALculation of PHAse Diagrams (CALPHAD)-based phase prediction with redox thermodynamic analysis to assess phase-specific corrosion susceptibility in Inconel 625 (IN625) and SA508 low-alloy steel under molten chloride conditions. Equilibrium phase constitutions at 1000 K were predicted using Thermo-Calc, and redox equilibrium potentials were calculated for representative-phase dissolution reactions of major metallic elements in each phase. The dominant α and γ phases in SA508 exhibited similar Fe-ionization potentials of −1.728 and −1.768 V vs. Cl2/Cl, respectively. In IN625, the γ matrix exhibited a Cr-ionization potential of −1.964 V vs. Cl2/Cl, whereas the P phase showed the most negative potential of −2.132 V vs. Cl2/Cl, 0.168 V more negative than the matrix, identifying the P phase as the primary local thermodynamic weak point. These results show that phase-specific metal-ionization susceptibility cannot be inferred solely from nominal alloy composition or matrix behavior. The proposed framework provides a thermodynamic screening approach for identifying susceptible secondary phases in multicomponent alloys under molten-salt conditions. Full article
Show Figures

Graphical abstract

17 pages, 2229 KB  
Article
Interfacial Microstructure Evolution and High-Speed Ball Shear Fracture of SAC305/Cu-20wt%Zn Solder Joints Under Isothermal Aging
by Jae-Yong Park and Sehoon Yoo
Materials 2026, 19(14), 3138; https://doi.org/10.3390/ma19143138 - 22 Jul 2026
Viewed by 280
Abstract
The interfacial microstructure evolution and high-speed ball shear reliability of SAC305 (Sn-3.0Ag-0.5Cu)/Cu-20wt%Zn solder joints were systematically investigated after isothermal aging at 180 °C for up to 250 h. SAC305/electroless nickel immersion gold (ENIG) joints were used as a comparative reference. Unlike prior studies [...] Read more.
The interfacial microstructure evolution and high-speed ball shear reliability of SAC305 (Sn-3.0Ag-0.5Cu)/Cu-20wt%Zn solder joints were systematically investigated after isothermal aging at 180 °C for up to 250 h. SAC305/electroless nickel immersion gold (ENIG) joints were used as a comparative reference. Unlike prior studies that benchmarked Cu-Zn against bare Cu, this work directly compares the two systems, establishing ENIG as the industrially relevant reference. Cu6(Sn,Zn)5 was identified as the dominant intermetallic compound (IMC) phase at the SAC305/Cu-Zn interface by SEM/EDS analysis. At the SAC305/ENIG interface, (Cu,Ni)6Sn5 formed as the dominant IMC phase, accompanied by a P-rich layer at the (Cu,Ni)6Sn5/Ni(P) boundary. The IMC thickness of SAC305/Cu-Zn joints increased from approximately 2.50 μm in the as-reflowed condition to 3.41 μm at 250 h, consistently exceeding that of SAC305/ENIG joints (1.94–2.25 μm) throughout aging. Despite this, the high-speed ball shear strength of SAC305/Cu-Zn joints was equivalent or superior to that of SAC305/ENIG joints at all aging durations. Fractographic analysis confirmed that the P-rich layer in ENIG joints acted as a preferential crack propagation path under impact loading, driving the brittle fracture ratio to approximately 75% at 250 h—compared to approximately 47% in SAC305/Cu-Zn joints. These results demonstrate that Cu-Zn electroplated from a neutral pyrophosphate-based bath constitutes a highly reliable wetting layer, offering impact reliability equivalent or superior to that of the conventional ENIG surface finish. Full article
(This article belongs to the Special Issue Progress and Challenges of Advanced Metallic Materials and Composites)
Show Figures

Graphical abstract

11 pages, 1493 KB  
Article
A Bimaterial Beam Strategy for Suppressing Thermal Deformation of Arc-Shaped CFRP Ribs via Asymmetric Laminate Design
by Yonggang Xue, Xiaofei Ma, Yonggang Fang, Dayu Zhang, Jialong Zhu and Pengbo Su
Materials 2026, 19(14), 3137; https://doi.org/10.3390/ma19143137 - 22 Jul 2026
Viewed by 376
Abstract
Deployable reflector antennas demand high geometric precision; the Ruze equation directly links surface error to RF gain. Arc-shaped CFRP ribs are vulnerable to thermal deformation, as their curvature converts in-plane expansion into out-of-plane displacement, which symmetric laminates cannot suppress. Classical laminate theory (CLT) [...] Read more.
Deployable reflector antennas demand high geometric precision; the Ruze equation directly links surface error to RF gain. Arc-shaped CFRP ribs are vulnerable to thermal deformation, as their curvature converts in-plane expansion into out-of-plane displacement, which symmetric laminates cannot suppress. Classical laminate theory (CLT) underestimates the coefficient of thermal expansion (CTE) of cross-ply laminates by factors of 1.75–2.38 for the laminate configurations investigated in this study, causing up to 79.4% of displacement prediction errors in symmetric designs. Here, we present an asymmetric laminate that overcomes both limitations. The upper skin (nine plies) and lower/web skins (seven plies) from the same prepreg batch create a CTE mismatch (Δα = 6.30 × 10−7 K−1), activating coupling stiffness to generate a thermal moment opposing curvature-driven displacement. Because both skins share identical batch history, CTE prediction errors cancel through common-mode rejection. Compared with the symmetric design, the asymmetric design achieved a 50.4% reduction in thermal deformation (from 210 µm to 104 µm) and improved FEA accuracy from 79.4% error to 4.8% error under experimental schemes. The method uses only conventional 0/90° prepreg and standard autoclave processing, with the upper-surface ply count as the sole design variable for a given section’s geometry, establishing retained coupling stiffness as a practical route to dimensional stability in curved space structures. Full article
(This article belongs to the Special Issue Experimental Testing and Numerical Modelling for Structural Dynamics)
Show Figures

Figure 1

20 pages, 13092 KB  
Article
Thermodynamic Assessment of CaO-Al2O3-Fe2O3 System
by Wenqing Zhao, Lideng Ye, Junfeng Wu, Hong Chen, Ligang Zhang and Libin Liu
Materials 2026, 19(14), 3136; https://doi.org/10.3390/ma19143136 - 21 Jul 2026
Viewed by 321
Abstract
The CaO-Al2O3-Fe2O3 system is widely encountered in cement production, iron ore sintering, metallurgical slags, and refractory materials. A thermodynamic assessment of the CaO-Fe2O3 and CaO-Al2O3-Fe2O3 systems [...] Read more.
The CaO-Al2O3-Fe2O3 system is widely encountered in cement production, iron ore sintering, metallurgical slags, and refractory materials. A thermodynamic assessment of the CaO-Fe2O3 and CaO-Al2O3-Fe2O3 systems was carried out in this study based on the CALculation of PHAse Diagrams (CALPHAD) method. The liquid was modeled using the ionic two-sublattice model, expressed as (Ca+2, Al+3, Fe+2) P (O−2, AlO1.5, FeO1.5, Va, O) Q. The Compound Energy Formalism (CEF) was adopted to describe compounds and solid solutions. A self-consistent thermodynamic assessment of the CaO-Fe2O3 and CaO-Al2O3-Fe2O3 systems was achieved, enabling accurate reproduction of phase equilibrium and thermodynamic data. The obtained thermodynamic description provides a useful foundation for the design, optimization, and processing of refractory materials. Full article
(This article belongs to the Section Metals and Alloys)
Show Figures

Figure 1

14 pages, 4677 KB  
Article
Barkhausen Noise in 100Cr6 Bearing Steel as a Function of Microstructure and Stress State
by Martin Pitoňák, Anna Mičietová, Ján Moravec, Miroslav Neslušan, Štefan Toth and Branislav Mičieta
Materials 2026, 19(14), 3135; https://doi.org/10.3390/ma19143135 - 21 Jul 2026
Viewed by 301
Abstract
This study is focused on the unwrapping contribution of microstructure (mainly expressed in terms of dislocation density) and stress state in the quenched bearing steel 100Cr6. Microstructure as well as residual stress state alterations are developed only as a function of variable infeed [...] Read more.
This study is focused on the unwrapping contribution of microstructure (mainly expressed in terms of dislocation density) and stress state in the quenched bearing steel 100Cr6. Microstructure as well as residual stress state alterations are developed only as a function of variable infeed rates in the flat plunge grinding (other grinding conditions are kept constant). The study is also dealing with the synergistic contribution of residual stress state and the superimposing elastic external stress developed during bending. It was found that the Barkhausen noise after grinding is mostly a function of the thermal softening, whereas the role of residual stress state is only minor. The growing Barkhausen noise emission at the lower infeed rates is connected with the compressive stress, and the tensile stresses are developed at the higher removal rates only. The study also demonstrates good sensitivity of Barkhausen noise when this emission is descending along the compressive external stresses and the ascending evolution along the tensile stresses when the magnetic field is altering along the direction of exerted stress. On the other hand, this evolution is reversed when the altering magnetic field is altered along the transversal direction. Full article
(This article belongs to the Section Advanced Materials Characterization)
Show Figures

Figure 1

23 pages, 17928 KB  
Article
Ageing Analysis of Light-Emitting Diodes Used in Consumer Lighting
by Levente Ákos Ludvig, Bianka Forczek and Gábor Harsányi
Materials 2026, 19(14), 3134; https://doi.org/10.3390/ma19143134 - 21 Jul 2026
Viewed by 362
Abstract
This study investigates the degradation mechanisms of 2835-packaged white LEDs commonly used in residential lighting scenarios under various environmental conditions and explores how standard ageing tests compare to those that better reflect real-world use cases. The samples consist of commercially available LED strips, [...] Read more.
This study investigates the degradation mechanisms of 2835-packaged white LEDs commonly used in residential lighting scenarios under various environmental conditions and explores how standard ageing tests compare to those that better reflect real-world use cases. The samples consist of commercially available LED strips, both cool and warm white. The luminous output of each LED on a strip is spectrally measured individually before ageing, then aged under particular conditions for a certain time and measured individually again. The measurements for a given LED are then analysed from multiple aspects, including material degradation processes during ageing, for example by following changes in phosphor efficiency. Full article
Show Figures

Figure 1

25 pages, 7289 KB  
Article
Synergistic Thermal–Electrical Modulation of Broadband Terahertz Absorption via Asymmetric MoS2/VO2 Hybrid Metasurfaces
by Xiaoyue Lu, Xianbin Zhang, Shihan Zhao and Huiyu Liu
Materials 2026, 19(14), 3133; https://doi.org/10.3390/ma19143133 - 21 Jul 2026
Viewed by 440
Abstract
To address the challenge of simultaneously achieving broadband absorption, multi-mechanism tunability, and angular stability in terahertz multifunctional devices, this paper proposes a MoS2/VO2 composite terahertz metamaterial absorber based on an asymmetric multi-nested C-shaped structure. The device adopts a three-layer configuration [...] Read more.
To address the challenge of simultaneously achieving broadband absorption, multi-mechanism tunability, and angular stability in terahertz multifunctional devices, this paper proposes a MoS2/VO2 composite terahertz metamaterial absorber based on an asymmetric multi-nested C-shaped structure. The device adopts a three-layer configuration consisting of a MoS2/VO2 composite plane–SiO2 dielectric–Au reflector layer. Unlike conventional symmetric structures, which are limited by selection rules and symmetry-protected dark modes that hinder the excitation of higher-order resonances, this design effectively breaks structural symmetry protection through geometric asymmetry. This induces strong mode hybridization between originally orthogonal dark and bright modes, enabling broadband high absorption exceeding 96.7% across the 1.88–3.52 THz frequency range (61% RBW). Notably, the device demonstrates synergistic tuning advantages: the macroscopic on/off switching of broadband absorption characteristics via the phase transition of VO2, combined with fine blind-spot compensation and enhancement in absorption peaks using the electrical tunability of MoS2. Furthermore, thanks to its sub-wavelength unit cell design, the structure maintains excellent performance stability over a wide incident angle range from 0° to 60°. This study reveals a synergistic enhancement mechanism combining the asymmetric unit cell and hybrid materials, providing a systematic physical solution for resolving the trade-off between bandwidth extension and dynamic reconfigurability. Full article
Show Figures

Graphical abstract

55 pages, 2392 KB  
Article
Safe Curing Limits of Thick Composite Shells
by Rikard Gebart
Materials 2026, 19(14), 3132; https://doi.org/10.3390/ma19143132 - 21 Jul 2026
Viewed by 338
Abstract
Thermal runaway during cure limits robust process design for thick composite laminates, especially when shell curvature and non-uniform heat transfer alter local heat removal. We present a semi-analytical framework for estimating safe curing limits in curved composite shells by reducing the three-dimensional thermo-kinetic [...] Read more.
Thermal runaway during cure limits robust process design for thick composite laminates, especially when shell curvature and non-uniform heat transfer alter local heat removal. We present a semi-analytical framework for estimating safe curing limits in curved composite shells by reducing the three-dimensional thermo-kinetic problem to a locally one-dimensional through-thickness stability problem evaluated pointwise over the mid-surface. The resulting criterion is expressed in terms of a critical Damköhler number and separates geometry and boundary heat transfer, represented by a stability factor depending on principal curvatures and Biot numbers, from chemistry and processing temperature, represented by Arrhenius scaling and an effective kinetic factor. The geometry-dependent stability factor is obtained from a nonlinear boundary-value problem and represented by compact differentiable response surfaces for symmetric and asymmetric boundary conditions. Validation against fully coupled transient simulations confirms the predicted separation over the investigated parameter range. A complementary analytical and quasi-three-dimensional flux-ratio assessment shows that lateral heat transport remains small for the representative smooth shell geometries studied, with strongly anticlastic regions providing the most restrictive cases. The framework enables rapid curvature-based stability sweeps, identification of critical locations, estimation of safe thickness limits, and practical screening of cure-cycle modifications without full three-dimensional simulation. Full article
(This article belongs to the Special Issue Thick Composites: Materials and Structures)
Show Figures

Graphical abstract

19 pages, 6160 KB  
Article
Deterioration Mechanism and Health Diagnosis Methods of Deep Anchoring Structures
by Shucan Lu, Saisai Wu, Moxuan Zhu, Krzysztof Skrzypkowski, Krzysztof Zagórski and Anna Zagórska
Materials 2026, 19(14), 3131; https://doi.org/10.3390/ma19143131 - 21 Jul 2026
Viewed by 286
Abstract
As mineral resource extraction progressively extends to greater depths, the complex deep underground environment poses severe corrosion-induced deterioration risks to anchoring structures such as rock bolts. Anchorage failure has thus become a critical safety concern constraining the stability of deep roadways. To address [...] Read more.
As mineral resource extraction progressively extends to greater depths, the complex deep underground environment poses severe corrosion-induced deterioration risks to anchoring structures such as rock bolts. Anchorage failure has thus become a critical safety concern constraining the stability of deep roadways. To address the failure mechanisms of anchoring systems under multi-physical field coupling effects, this study conducts numerical simulations of multi-field corrosion processes and ultrasonic nondestructive testing (NDT) based on a numerical modeling platform. The influence of temperature on corrosion rate and current density is systematically analyzed, and interface response characteristics are extracted and interpreted for defects of varying dimensions. A spatial complementary mechanism under different corrosion defect configurations is revealed, and a health diagnosis system incorporating multiple critical indicators is established. The results indicate that elevated temperature significantly accelerates bolt corrosion: the rise in temperature shifts the equilibrium potential negatively and exponentially increases the reaction rate constant, both of which synergistically promote anodic dissolution. In ultrasonic testing, monitoring points along the main axis are positioned within the transmission-focused zone, where defects induce acoustic wave diffraction and superposition such that even minor defects cause a multiplication of the dominant frequency. Lateral monitoring points lie in the reflection–interference zone, where small defects preferentially attenuate energy, while larger defects manifest as amplitude reduction and first-arrival wave lag; all characteristic indices increase monotonically with defect size. Based on the numerical simulation outcomes, a four-level grading diagnosis standard and a “bottom–lateral” detection scheme are proposed as simulation-based reference indicators. The model effectively reproduces both corrosion deterioration and acoustic wave propagation characteristics, thereby providing a quantitative basis for the assessment of anchoring structures in high-temperature deep underground environments. Full article
Show Figures

Figure 1

22 pages, 6565 KB  
Article
Comparison of Destructive Strength Testing with Non-Destructive Ultrasonic Pulse Velocity Testing for Waste Marble Aggregate Concrete: An Experimental and Statistical Investigation
by Esra Tuğrul Tunç
Materials 2026, 19(14), 3130; https://doi.org/10.3390/ma19143130 - 21 Jul 2026
Viewed by 395
Abstract
In this study, the performance of eco-friendly concrete produced by utilizing waste marble as a total aggregate replacement was evaluated. The experimental findings indicated that the developed waste marble aggregate concrete (WMC) specimens successfully met the standardized strength requirements for structural applications. The [...] Read more.
In this study, the performance of eco-friendly concrete produced by utilizing waste marble as a total aggregate replacement was evaluated. The experimental findings indicated that the developed waste marble aggregate concrete (WMC) specimens successfully met the standardized strength requirements for structural applications. The main objective of this investigation was to determine the experimental and statistical correlation between destructive strength tests and the non-destructive ultrasonic pulse velocity (UPV) test, taking into account the content ratios of concrete. This study presents an experimental and statistical investigation to correlate destructive strength properties with non-destructive UPV measurements in eco-friendly concrete. A total of 300 concrete cubic specimens were produced by fully substituting conventional aggregates with waste marble aggregates across five distinct water-to-cement ratios (W/C = 0.20 to 0.40) and ten aggregate-to-cement ratios (WMA/C = 1.1 to 2.0). Compressive strength (fc), splitting tensile strength (ft), and UPV tests were conducted on the 28th day. The experimental results showed that fc ranged from 19.2 to 37.5 MPa, ft from 2.3 to 4.4 MPa, and UPV from 3580 to 4386 m/s, confirming the high structural quality of the waste marble aggregate concrete. Non-linear regression analyses were performed using IBM SPSS Statistics 22 to develop empirical models predicting destructive strengths based on mix design parameters and UPV data. The proposed statistical models demonstrated high accuracy with determination coefficients (R2) of 0.98 for fc and 0.97 for ft, backed by low mean absolute relative deviations (6% and 8%, respectively). The findings indicate that the developed empirical formulations can reliably evaluate the strength of WMC in a practical and non-destructive manner. Full article
(This article belongs to the Section Construction and Building Materials)
Show Figures

Graphical abstract

17 pages, 3765 KB  
Article
Experimental Study on Crack Evolution Law of a Full-Scale Prestressed Concrete Beam Based on Fractal Theory
by Zhenyu Jiang, Bo Wang, Hongyi Liu, Jinquan Zhang, Jianting Zhou, Haifang He, Han Wei and Jingyan Zou
Materials 2026, 19(14), 3129; https://doi.org/10.3390/ma19143129 - 21 Jul 2026
Viewed by 307
Abstract
There are different degrees of cracks in prestressed concrete (PC) beams, especially the transverse cracks in the bottom plate and the vertical cracks in the web of prestressed concrete box girders, which will reduce the bearing capacity of the structure. In order to [...] Read more.
There are different degrees of cracks in prestressed concrete (PC) beams, especially the transverse cracks in the bottom plate and the vertical cracks in the web of prestressed concrete box girders, which will reduce the bearing capacity of the structure. In order to clarify the evolution law of cracks in prestressed concrete box girders after cracking, a 25 m prestressed concrete box girder was poured and a full-scale model test was carried out. At the 1/4 span position of the test beam, the test beam was cracked in 19 steps to 1900 kN. Then at the 3/4 span position, the test beam was cracked in 18 steps to 1800 kN, and after that the bending load test was carried out in 17 steps to analyze the influence of existing cracks on the bending cracks of the test beam. Combined with fractal theory, the evolution law of cracks, the development law of fractal dimensions, and their relationship under different loading conditions were analyzed. The results showed that the crack distribution of the test beam satisfies self-similarity and had fractal characteristics in a statistical sense, which could reflect the process of crack occurrence, propagation and damage, and could quantify the crack shape. The fractal dimension of cracks gradually increased with the increase in concentrated load on the test beam, and the fractal dimension of cracks had a linear relationship with the concentrated load. The crack propagation process of the concrete beam reflected the fractal dimension increasing process; that is, the crack damage evolution process of test beam was a dimension increasing process, and the fractal dimension of crack distribution increased linearly with the applied load. The functional relationship between prestressed concrete crack width and fractal dimension was constructed, which provided a new path for bridge safety evaluation. The research results provide engineering reference for the cause analysis and maintenance treatment of similar bridge cracks. Full article
(This article belongs to the Special Issue Reinforced Concrete: Mechanical Properties and Materials Design)
Show Figures

Figure 1

23 pages, 3241 KB  
Article
Analysis of Some Empirical Equations for Modeling Sound Absorption of Porous Absorbers
by Valentín Gómez Escobar and Celia Moreno González
Materials 2026, 19(14), 3128; https://doi.org/10.3390/ma19143128 - 21 Jul 2026
Viewed by 298
Abstract
The empirical Delany–Bazley model and several of its subsequent modifications were evaluated to determine their ability to predict the sound absorption coefficient spectra of porous materials. The study considered three porous materials (foam, mineral wool and samples made from recycled cigarette butt) with [...] Read more.
The empirical Delany–Bazley model and several of its subsequent modifications were evaluated to determine their ability to predict the sound absorption coefficient spectra of porous materials. The study considered three porous materials (foam, mineral wool and samples made from recycled cigarette butt) with different thicknesses. Model performance was assessed by comparing theoretical predictions with impedance tube measurements using the root mean square error (RMSE). Although some models yielded lower prediction errors for specific materials and thicknesses, the results showed that sample thickness—and the associated changes in the shape of the sound absorption spectrum—have a greater influence on model performance than the material itself. No single empirical model consistently provided the best agreement over the entire thickness range. These findings suggest that the applicability of Delany–Bazley-type empirical models appears to be more closely related to the shape of the sound absorption spectrum than to the material for which they were originally developed. These findings provide practical guidance for selecting suitable models for both conventional and recycled porous sound absorbers. Full article
(This article belongs to the Section Advanced Materials Characterization)
Show Figures

Figure 1

27 pages, 21277 KB  
Article
Investigation of Multi-Factor Coupled Aging Mechanisms and Rheological Performance Prediction of Asphalt in Diverse Climatic Regions
by Hong Xu, Shanglin Song, Fangxia Wang, Xiaolei Wu, Yang Luo, Xiaoyan Ma, Ningyuan Meng and Tianyu Wu
Materials 2026, 19(14), 3127; https://doi.org/10.3390/ma19143127 - 21 Jul 2026
Viewed by 310
Abstract
Aging of asphalt pavements is a complex, multi-scale degradative process driven by the synergistic effects of various environmental stressors. Traditional laboratory-accelerated aging protocols often employ static parameters that fail to accurately replicate dynamic, region-specific climatic conditions. To bridge the gap between laboratory simulations [...] Read more.
Aging of asphalt pavements is a complex, multi-scale degradative process driven by the synergistic effects of various environmental stressors. Traditional laboratory-accelerated aging protocols often employ static parameters that fail to accurately replicate dynamic, region-specific climatic conditions. To bridge the gap between laboratory simulations and actual field performance, this study investigates the aging behaviors of base binder and SBS-modified binder under multi-factor coupled environmental conditions. Field observations were conducted across six distinct climatic regions in Gansu Province, alongside an indoor second-order orthogonal regression composite design that evaluated the interactive effects of temperature, ultraviolet (UV) radiation, humidity, and aging time. Rheological evaluations revealed that for the base binder, the synergistic coupling of UV radiation, elevated temperatures, and high humidity significantly accelerates oxidative hardening and embrittlement far beyond the impact of any single factor. Conversely, SBS-modified binder demonstrated a non-linear, U-shaped rheological response governed by a competitive mechanism between UV/thermal-induced polymer scission and moisture/time-driven matrix oxidation. Fourier Transform Infrared (FT-IR) spectroscopy corroborated these macroscopic findings at the molecular level, tracking the simultaneous evolution of carbonyl and sulfoxide indices alongside the degradation of the polybutadiene segments in the modified binder. Ultimately, a quadratic polynomial regression model was established to precisely correlate natural field aging with equivalent indoor accelerated aging times based on specific regional climatic data. Full article
Show Figures

Figure 1

3 pages, 1170 KB  
Correction
Correction: Wu et al. Nano-Silicon@Exfoliated Graphite@Pyrolytic Polyaniline Composite of a High-Performance Anode for Lithium Storage. Materials 2023, 16, 1584
by Qian Wu, Yinghong Zhu, Haojie Duan, Lin Zhu, Yuting Zhang, Hongqiang Xu, Ishioma Laurene Egun and Haiyong He
Materials 2026, 19(14), 3126; https://doi.org/10.3390/ma19143126 - 21 Jul 2026
Viewed by 246
Abstract
In the original publication [...] Full article
Show Figures

Figure 2

30 pages, 13758 KB  
Article
Influence of Construction Material Type on the Dynamic Response of Low-Rise Buildings
by Maciej Zajac, Krystyna Kuzniar and Tadeusz Tatara
Materials 2026, 19(14), 3125; https://doi.org/10.3390/ma19143125 - 21 Jul 2026
Viewed by 323
Abstract
This study presents a numerical investigation of the dynamic response of a typical low-rise building subjected to recorded mine-induced vibrations, with particular emphasis on the role of construction material type. Several structural variants consistent with the real building configuration were analysed using a [...] Read more.
This study presents a numerical investigation of the dynamic response of a typical low-rise building subjected to recorded mine-induced vibrations, with particular emphasis on the role of construction material type. Several structural variants consistent with the real building configuration were analysed using a validated three-dimensional finite element (3D FEM) model. Seven load-bearing wall materials were considered, including reinforced concrete, lightweight concrete, cellular concrete, standard brick, and selected sand–lime bricks. Dynamic responses were evaluated in terms of displacements and accelerations, including time histories along the building axis, peak component values, resultant responses, and Fourier spectra. The results clearly demonstrate that material properties—especially stiffness—govern the dynamic behaviour of the structure. Low-stiffness materials, such as cellular concrete, significantly amplify both acceleration and displacement responses, increasing susceptibility to vibration-induced effects. Moreover, the dominant vibration frequencies were found to vary depending on the wall material, which directly affects resonance conditions and potential damage risk. A notable sensitivity of the calculated response to the choice of numerical evaluation point within the structure was also observed. The findings highlight the critical importance of material selection in controlling the dynamic performance of low-rise buildings exposed to mining-induced vibrations and provide practical guidance for mitigating paraseismic effects in engineering design. Full article
Show Figures

Graphical abstract

Previous Issue
Next Issue
Back to TopTop