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Batteries, Volume 5, Issue 1

2019 March - 36 articles

Cover Story: Aqueous zinc ion batteries (AZIBs), a type of multivalent ion battery, have received attention because of their potential applications in large-scale energy storage systems. Here, we present a prototype of a rocking-chair AZIB system (zinc-dendrite-free) that employs Zn2Mo6S8 and K0.02(H2O)0.22Zn2.94[Fe(CN)6]2 as an anode and cathode, respectively. View this paper.
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Articles (36)

  • Article
  • Open Access
33 Citations
11,464 Views
16 Pages

Reliable development of LIBs requires that they be correlated with accurate aging studies. The present project focuses on the implementation of a weighted ampere-hour throughput model, taking into account the operating parameters, and modulating the...

  • Article
  • Open Access
32 Citations
11,682 Views
13 Pages

Recycling of Alkaline Batteries via a Carbothermal Reduction Process

  • Selçuk Yeşiltepe,
  • Mehmet Buğdaycı,
  • Onuralp Yücel and
  • Mustafa Kelami Şeşen

Primary battery recycling has important environmental and economic benefits. According to battery sales worldwide, the most used battery type is alkaline batteries with 75% of market share due to having a higher performance than other primary batteri...

  • Review
  • Open Access
20 Citations
15,178 Views
11 Pages

To ensure sufficient thermal performance within electric vehicle (EV) batteries, thermal interface materials (TIMs), such as pastes or adhesives, are widely used to fill thermally insulating voids between cells and cooling components. However, TIMs a...

  • Article
  • Open Access
9 Citations
9,855 Views
12 Pages

Corrosion and discharge behavior of battery-grade zinc particles coated with a silica layer doped with bismuth was investigated and compared with untreated zinc powder. Electrochemical investigations were carried out in half-cell configuration. The e...

  • Article
  • Open Access
40 Citations
12,591 Views
18 Pages

This paper focuses on the fast characterization of automotive second life lithium-ion batteries that have been recently re-used in many projects to create battery storages for stationary applications and sporadically for embedded applications. Specif...

  • Article
  • Open Access
117 Citations
14,318 Views
14 Pages

An Electrical Equivalent Circuit Model of a Lithium Titanate Oxide Battery

  • Seyed Saeed Madani,
  • Erik Schaltz and
  • Søren Knudsen Kær

A precise lithium-ion battery model is required to specify their appropriateness for different applications and to study their dynamic behavior. In addition, it is important to design an efficient battery system for power applications. In this invest...

  • Article
  • Open Access
35 Citations
12,533 Views
20 Pages

Refractive Index Measurement of Lithium Ion Battery Electrolyte with Etched Surface Cladding Waveguide Bragg Gratings and Cell Electrode State Monitoring by Optical Strain Sensors

  • Antonio Nedjalkov,
  • Jan Meyer,
  • Alexander Gräfenstein,
  • Benjamin Schramm,
  • Martin Angelmahr,
  • Julian Schwenzel and
  • Wolfgang Schade

In this scientific publication, a new sensor approach for status monitoring, such as state of charge and state of health, of lithium ion batteries by using special Bragg gratings inscribed into standard optical glass fibers is presented. In addition...

  • Article
  • Open Access
15 Citations
7,532 Views
17 Pages

Devices operating in complete energy autonomy are multiplying: small fixed signaling applications or sensors often operating in a network. To ensure operation for a substantial period, for applications with difficult physical access, a means of stori...

  • Article
  • Open Access
15 Citations
9,730 Views
11 Pages

Lithium-ion Capacitors (LiCs) that have intermediate properties between lithium-ion batteries and supercapacitors are still considered as a new technology whose aging is not well studied in the literature. This paper presents the results of accelerat...

  • Article
  • Open Access
13 Citations
8,564 Views
10 Pages

27 February 2019

The pores in silicon particles can accommodate the volume expansion of silicon during the charging–discharging process. However, pores in silicon particles are easily occupied by carbon during the preparation of silicon/carbon composites. In th...

  • Article
  • Open Access
18 Citations
12,408 Views
13 Pages

Correlation of Mechanical and Electrical Behavior of Polyethylene Oxide-Based Solid Electrolytes for All-Solid State Lithium-Ion Batteries

  • Fabian Peters,
  • Frederieke Langer,
  • Nikolai Hillen,
  • Katharina Koschek,
  • Ingo Bardenhagen,
  • Julian Schwenzel and
  • Matthias Busse

24 February 2019

Mechanical and electrochemical stability are key issues for large-scale production of solid state Li-ion batteries. Polymer electrolytes can provide good ionic conductivity, but mechanical strength needs to be improved. In this study, we investigate...

  • Article
  • Open Access
46 Citations
14,859 Views
25 Pages

22 February 2019

Current redox flow battery (RFB) stack models are not particularly conducive to accurate yet high-throughput studies of stack operation and design. To facilitate system-level analysis, we have developed a one-dimensional RFB stack model through the c...

  • Article
  • Open Access
122 Citations
30,394 Views
17 Pages

19 February 2019

Lithium-ion battery packs inside electric vehicles represents a high share of the final price. Nevertheless, with technology advances and the growth of the market, the price of the battery is getting more competitive. The greenhouse gas emissions and...

  • Article
  • Open Access
25 Citations
15,040 Views
19 Pages

Vanadium Oxygen Fuel Cell Utilising High Concentration Electrolyte

  • Mandar Risbud,
  • Chris Menictas,
  • Maria Skyllas-Kazacos and
  • Jens Noack

19 February 2019

A vanadium oxygen fuel cell is a modified form of a conventional vanadium redox flow battery (VRFB) where the positive electrolyte (VO2+/VO2+ couple) is replaced by the oxygen reduction (ORR) process. This potentially allows for a significant improve...

  • Article
  • Open Access
58 Citations
39,664 Views
20 Pages

18 February 2019

Batteries have been extensively used in many applications; however, very little is explored regarding the possible environmental impacts for their whole life cycle, even though a lot of studies have been carried out for augmenting performance in many...

  • Article
  • Open Access
6 Citations
11,521 Views
11 Pages

12 February 2019

In this work, we use ultrasonication and chemical etching agents to assist preparation of metal current collectors with nano-scale pores on the surface. Four different current collectors (copper foil, copper foam, aluminum foil, and aluminum foam) ar...

  • Article
  • Open Access
38 Citations
16,171 Views
16 Pages

Optimal Charging of Vanadium Redox Flow Battery with Time-Varying Input Power

  • Md. Parvez Akter,
  • Yifeng Li,
  • Jie Bao,
  • Maria Skyllas-Kazacos and
  • Muhammed Fazlur Rahman

10 February 2019

The battery energy storage system has become an indispensable part of the current electricity network due to the vast integration of renewable energy sources (RESs). This paper proposes an optimal charging method of a vanadium redox flow battery (VRB...

  • Review
  • Open Access
155 Citations
35,860 Views
25 Pages

1 February 2019

Lithium-ion batteries are the most commonly used source of power for modern electronic devices. However, their safety became a topic of concern after reports of the devices catching fire due to battery failure. Making safer batteries is of utmost imp...

  • Article
  • Open Access
2 Citations
9,370 Views
11 Pages

Low Reversible Capacity of Nitridated Titanium Electrical Terminals

  • David Klein,
  • Yaolin Xu,
  • Robert Schlögl and
  • Sébastien Cap

29 January 2019

The currently preferred manufacturing method for Lithium-ion battery (LIB) electrodes is via the slurry route. While such an approach is appealing, the complexity of the electrode layers containing the active materials, conductivity helpers, and bind...

  • Article
  • Open Access
11 Citations
11,613 Views
15 Pages

Discharge by Short Circuit Currents of Parallel-Connected Lithium-Ion Cells in Thermal Propagation

  • Sascha Koch,
  • Alexander Fill,
  • Katerina Kelesiadou and
  • Kai Peter Birke

29 January 2019

The increasing need for high capacity batteries in plug-in hybrids and all-electric vehicles gives rise to the question of whether these batteries should be equipped with a few large capacity cells or rather many low capacity cells in parallel. This...

  • Article
  • Open Access
9 Citations
9,429 Views
14 Pages

23 January 2019

The electrochemical oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) and on CNT (carbon nanotube) cathode with a palladium catalyst, palladium-coated CNT (PC-CNT), and palladium-filled CNT (PF-CNT) are assessed in an ether-based el...

  • Article
  • Open Access
29 Citations
10,770 Views
12 Pages

Degradation Phenomena of Bismuth-Modified Felt Electrodes in VRFB Studied by Electrochemical Impedance Spectroscopy

  • Jonathan Schneider,
  • Eduard Bulczak,
  • Gumaa A. El-Nagar,
  • Marcus Gebhard,
  • Paul Kubella,
  • Maike Schnucklake,
  • Abdulmonem Fetyan,
  • Igor Derr and
  • Christina Roth

23 January 2019

The performance of all-V redox flow batteries (VRFB) will decrease when they are exposed to dynamic electrochemical cycling, but also when they are in prolonged contact with the acidic electrolyte. These phenomena are especially severe at the negativ...

  • Article
  • Open Access
25 Citations
13,581 Views
19 Pages

Design and Analysis of the Use of Re-Purposed Electric Vehicle Batteries for Stationary Energy Storage in Canada

  • John W. A. Catton,
  • Sean B. Walker,
  • Paul McInnis,
  • Michael Fowler,
  • Roydon A. Fraser,
  • Steven B. Young and
  • Ben Gaffney

19 January 2019

Vehicle electrification increases the fuel efficiency of the transportation sector while lowering emissions. Eventually, however, electric vehicle batteries will reach their end-of-life (EOL) point, when the capacity of the battery is insufficient fo...

  • Review
  • Open Access
137 Citations
39,512 Views
24 Pages

18 January 2019

Use of a reference electrode (RE) in Li-ion batteries (LIBs) aims to enable quantitative evaluation of various electrochemical aspects of operation such as: (i) the distinct contribution of each cell component to the overall battery performance, (ii)...

  • Article
  • Open Access
57 Citations
24,342 Views
16 Pages

Vanadium Electrolyte for All-Vanadium Redox-Flow Batteries: The Effect of the Counter Ion

  • Nataliya Roznyatovskaya,
  • Jens Noack,
  • Heiko Mild,
  • Matthias Fühl,
  • Peter Fischer,
  • Karsten Pinkwart,
  • Jens Tübke and
  • Maria Skyllas-Kazacos

18 January 2019

In this study, 1.6 M vanadium electrolytes in the oxidation forms V(III) and V(V) were prepared from V(IV) in sulfuric (4.7 M total sulphate), V(IV) in hydrochloric (6.1 M total chloride) acids, as well as from 1:1 mol mixture of V(III) and V(IV) (de...

  • Article
  • Open Access
197 Citations
44,710 Views
15 Pages

Exploring the Economic Potential of Sodium-Ion Batteries

  • Jens F. Peters,
  • Alexandra Peña Cruz and
  • Marcel Weil

16 January 2019

Sodium-ion batteries (SIBs) are a recent development being promoted repeatedly as an economically promising alternative to lithium-ion batteries (LIBs). However, only one detailed study about material costs has yet been published for this battery typ...

  • Article
  • Open Access
5 Citations
8,813 Views
12 Pages

Silicon/Mesoporous Carbon (Si/MC) Derived from Phenolic Resin for High Energy Anode Materials for Li-ion Batteries: Role of HF Etching and Vinylene Carbonate (VC) Additive

  • Arlavinda Rezqita,
  • Hristina Vasilchina,
  • Raad Hamid,
  • Markus Sauer,
  • Annette Foelske,
  • Corina Täubert and
  • Hermann Kronberger

16 January 2019

Silicon/mesoporous carbon (Si/MC) composites with optimum Si content, in which the volumetric energy density would be maximized, while volume changes would be minimized, have been developed. The composites were prepared by dispersing Si nanoparticles...

  • Article
  • Open Access
11 Citations
8,624 Views
14 Pages

This study describes a novel approach for real-time energy harvesting and performance diagnostics of a solid anolyte microbial fuel cell (SA-MFC) representing a prototype smart biobattery. The biobattery power output was maximized in real time by com...

  • Article
  • Open Access
16 Citations
9,901 Views
17 Pages

Lithium ion battery modules have significant capacity left after their useful life in transportation applications. This empirical study successfully tested the used modules in secondary grid applications in laboratory conditions. The selection of the...

  • Article
  • Open Access
23 Citations
8,988 Views
11 Pages

Vanadium redox-flow batteries are a promising energy storage technology due to their safety, long-term stability, and independent adjustability of power and capacity. However, the vanadium crossover through the membrane causes a self-discharge, which...

  • Article
  • Open Access
11 Citations
8,915 Views
24 Pages

Investigations on a Mesoporous Glass Membrane as Ion Separator for a Redox Flow Battery

  • Ioannis Michos,
  • Zishu Cao,
  • Zhi Xu,
  • Wenheng Jing and
  • Junhang Dong

This article reports extensive studies of a Vycor® porous glass (VPG) membrane as an ion separator for an all-vanadium redox flow battery (VRFB). The VPG membrane had an average pore size of 4 nm and porosity of ~28%. The VPG ion separator exhibi...

  • Article
  • Open Access
23 Citations
9,198 Views
17 Pages

With the ever-increasing usage of lithium-ion batteries, especially in transportation applications, accurate estimation of battery state of charge (SOC) is of paramount importance. A majority of the current SOC estimation methods rely on data collect...

  • Article
  • Open Access
71 Citations
13,557 Views
13 Pages

Zinc-ion batteries (ZIBs) have received attention as one type of multivalent-ion batteries due to their potential applications in large-scale energy storage systems. Here we report a prototype of rocking-chair ZIB system employing Zn2Mo6S8 (zinc Chev...

  • Article
  • Open Access
7 Citations
7,506 Views
11 Pages

Investigation of Reactant Conversion in the Vanadium Redox Flow Battery Using Spatially Resolved State of Charge Mapping

  • Purna C. Ghimire,
  • Arjun Bhattarai,
  • Rüdiger Schweiss,
  • Günther G. Scherer,
  • Nyunt Wai,
  • Tuti M. Lim and
  • Qingyu Yan

Segmented cells enable real time visualization of the flow distribution in vanadium redox flow batteries by local current or voltage mapping. The lateral flow of current within thick porous electrodes, however, impairs the local resolution of the det...

  • Article
  • Open Access
3 Citations
7,047 Views
15 Pages

Electrochemical Performance and in Operando Charge Efficiency Measurements of Cu/Sn-Doped Nano Iron Electrodes

  • Alagar Raj Paulraj,
  • Yohannes Kiros,
  • Mylad Chamoun,
  • Henrik Svengren,
  • Dag Noréus,
  • Mats Göthelid,
  • Björn Skårman,
  • Hilmar Vidarsson and
  • Malin B. Johansson

21 December 2018

Fe-air or Ni-Fe cells can offer low-cost and large-scale sustainable energy storage. At present, they are limited by low coulombic efficiency, low active material use, and poor rate capability. To overcome these challenges, two types of nanostructure...

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Batteries - ISSN 2313-0105