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Batteries, Volume 5, Issue 1

2019 March - 36 articles

Cover Story: Aqueous zinc ion batteries (AZIBs), a type of multivalent ion battery, have received attention because of their potential applications in large-scale energy storage systems. Here, we present a prototype of a rocking-chair AZIB system (zinc-dendrite-free) that employs Zn2Mo6S8 and K0.02(H2O)0.22Zn2.94[Fe(CN)6]2 as an anode and cathode, respectively. View this paper.
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Articles (36)

  • Article
  • Open Access
37 Citations
12,606 Views
16 Pages

Reliable development of LIBs requires that they be correlated with accurate aging studies. The present project focuses on the implementation of a weighted ampere-hour throughput model, taking into account the operating parameters, and modulating the...

(This article belongs to the Special Issue Batteries and Supercapacitors Aging)
  • Article
  • Open Access
33 Citations
12,809 Views
13 Pages

Recycling of Alkaline Batteries via a Carbothermal Reduction Process

  • Selçuk Yeşiltepe,
  • Mehmet Buğdaycı,
  • Onuralp Yücel and
  • Mustafa Kelami Şeşen

Primary battery recycling has important environmental and economic benefits. According to battery sales worldwide, the most used battery type is alkaline batteries with 75% of market share due to having a higher performance than other primary batteri...

(This article belongs to the Special Issue Circular Economy of Batteries Production and Recycling)
  • Review
  • Open Access
20 Citations
16,757 Views
11 Pages

To ensure sufficient thermal performance within electric vehicle (EV) batteries, thermal interface materials (TIMs), such as pastes or adhesives, are widely used to fill thermally insulating voids between cells and cooling components. However, TIMs a...

(This article belongs to the Special Issue Thermal and Safety Properties of Materials, Cells and Batteries)
  • Article
  • Open Access
10 Citations
10,325 Views
12 Pages

Corrosion and discharge behavior of battery-grade zinc particles coated with a silica layer doped with bismuth was investigated and compared with untreated zinc powder. Electrochemical investigations were carried out in half-cell configuration. The e...

  • Article
  • Open Access
42 Citations
13,185 Views
18 Pages

This paper focuses on the fast characterization of automotive second life lithium-ion batteries that have been recently re-used in many projects to create battery storages for stationary applications and sporadically for embedded applications. Specif...

(This article belongs to the Special Issue Batteries and Supercapacitors Aging)
  • Article
  • Open Access
125 Citations
15,466 Views
14 Pages

An Electrical Equivalent Circuit Model of a Lithium Titanate Oxide Battery

  • Seyed Saeed Madani,
  • Erik Schaltz and
  • Søren Knudsen Kær

A precise lithium-ion battery model is required to specify their appropriateness for different applications and to study their dynamic behavior. In addition, it is important to design an efficient battery system for power applications. In this invest...

  • Article
  • Open Access
42 Citations
13,685 Views
20 Pages

Refractive Index Measurement of Lithium Ion Battery Electrolyte with Etched Surface Cladding Waveguide Bragg Gratings and Cell Electrode State Monitoring by Optical Strain Sensors

  • Antonio Nedjalkov,
  • Jan Meyer,
  • Alexander Gräfenstein,
  • Benjamin Schramm,
  • Martin Angelmahr,
  • Julian Schwenzel and
  • Wolfgang Schade

In this scientific publication, a new sensor approach for status monitoring, such as state of charge and state of health, of lithium ion batteries by using special Bragg gratings inscribed into standard optical glass fibers is presented. In addition...

  • Article
  • Open Access
16 Citations
7,867 Views
17 Pages

Devices operating in complete energy autonomy are multiplying: small fixed signaling applications or sensors often operating in a network. To ensure operation for a substantial period, for applications with difficult physical access, a means of stori...

(This article belongs to the Special Issue Batteries and Supercapacitors Aging)
  • Article
  • Open Access
17 Citations
10,544 Views
11 Pages

Lithium-ion Capacitors (LiCs) that have intermediate properties between lithium-ion batteries and supercapacitors are still considered as a new technology whose aging is not well studied in the literature. This paper presents the results of accelerat...

(This article belongs to the Special Issue Batteries and Supercapacitors Aging)
  • Article
  • Open Access
14 Citations
8,938 Views
10 Pages

27 February 2019

The pores in silicon particles can accommodate the volume expansion of silicon during the charging–discharging process. However, pores in silicon particles are easily occupied by carbon during the preparation of silicon/carbon composites. In th...

  • Article
  • Open Access
19 Citations
13,052 Views
13 Pages

Correlation of Mechanical and Electrical Behavior of Polyethylene Oxide-Based Solid Electrolytes for All-Solid State Lithium-Ion Batteries

  • Fabian Peters,
  • Frederieke Langer,
  • Nikolai Hillen,
  • Katharina Koschek,
  • Ingo Bardenhagen,
  • Julian Schwenzel and
  • Matthias Busse

24 February 2019

Mechanical and electrochemical stability are key issues for large-scale production of solid state Li-ion batteries. Polymer electrolytes can provide good ionic conductivity, but mechanical strength needs to be improved. In this study, we investigate...

  • Article
  • Open Access
48 Citations
16,333 Views
25 Pages

22 February 2019

Current redox flow battery (RFB) stack models are not particularly conducive to accurate yet high-throughput studies of stack operation and design. To facilitate system-level analysis, we have developed a one-dimensional RFB stack model through the c...

(This article belongs to the Special Issue Vanadium Redox Flow Battery and Its Applications)
  • Article
  • Open Access
130 Citations
31,895 Views
17 Pages

19 February 2019

Lithium-ion battery packs inside electric vehicles represents a high share of the final price. Nevertheless, with technology advances and the growth of the market, the price of the battery is getting more competitive. The greenhouse gas emissions and...

(This article belongs to the Special Issue Sustainable Lithium Ion Batteries: From Production to Recycling)
  • Article
  • Open Access
28 Citations
16,234 Views
19 Pages

Vanadium Oxygen Fuel Cell Utilising High Concentration Electrolyte

  • Mandar Risbud,
  • Chris Menictas,
  • Maria Skyllas-Kazacos and
  • Jens Noack

19 February 2019

A vanadium oxygen fuel cell is a modified form of a conventional vanadium redox flow battery (VRFB) where the positive electrolyte (VO2+/VO2+ couple) is replaced by the oxygen reduction (ORR) process. This potentially allows for a significant improve...

(This article belongs to the Special Issue Vanadium Redox Flow Battery and Its Applications)
  • Article
  • Open Access
66 Citations
41,520 Views
20 Pages

18 February 2019

Batteries have been extensively used in many applications; however, very little is explored regarding the possible environmental impacts for their whole life cycle, even though a lot of studies have been carried out for augmenting performance in many...

  • Article
  • Open Access
6 Citations
12,190 Views
11 Pages

12 February 2019

In this work, we use ultrasonication and chemical etching agents to assist preparation of metal current collectors with nano-scale pores on the surface. Four different current collectors (copper foil, copper foam, aluminum foil, and aluminum foam) ar...

  • Article
  • Open Access
38 Citations
17,399 Views
16 Pages

Optimal Charging of Vanadium Redox Flow Battery with Time-Varying Input Power

  • Md. Parvez Akter,
  • Yifeng Li,
  • Jie Bao,
  • Maria Skyllas-Kazacos and
  • Muhammed Fazlur Rahman

10 February 2019

The battery energy storage system has become an indispensable part of the current electricity network due to the vast integration of renewable energy sources (RESs). This paper proposes an optimal charging method of a vanadium redox flow battery (VRB...

(This article belongs to the Special Issue Vanadium Redox Flow Battery and Its Applications)
  • Review
  • Open Access
163 Citations
37,658 Views
25 Pages

1 February 2019

Lithium-ion batteries are the most commonly used source of power for modern electronic devices. However, their safety became a topic of concern after reports of the devices catching fire due to battery failure. Making safer batteries is of utmost imp...

  • Article
  • Open Access
2 Citations
9,736 Views
11 Pages

Low Reversible Capacity of Nitridated Titanium Electrical Terminals

  • David Klein,
  • Yaolin Xu,
  • Robert Schlögl and
  • Sébastien Cap

29 January 2019

The currently preferred manufacturing method for Lithium-ion battery (LIB) electrodes is via the slurry route. While such an approach is appealing, the complexity of the electrode layers containing the active materials, conductivity helpers, and bind...

  • Article
  • Open Access
15 Citations
12,819 Views
15 Pages

Discharge by Short Circuit Currents of Parallel-Connected Lithium-Ion Cells in Thermal Propagation

  • Sascha Koch,
  • Alexander Fill,
  • Katerina Kelesiadou and
  • Kai Peter Birke

29 January 2019

The increasing need for high capacity batteries in plug-in hybrids and all-electric vehicles gives rise to the question of whether these batteries should be equipped with a few large capacity cells or rather many low capacity cells in parallel. This...

  • Article
  • Open Access
9 Citations
9,721 Views
14 Pages

23 January 2019

The electrochemical oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) and on CNT (carbon nanotube) cathode with a palladium catalyst, palladium-coated CNT (PC-CNT), and palladium-filled CNT (PF-CNT) are assessed in an ether-based el...

(This article belongs to the Special Issue Recent Advances in Post-Lithium Ion Batteries)
  • Article
  • Open Access
33 Citations
11,233 Views
12 Pages

Degradation Phenomena of Bismuth-Modified Felt Electrodes in VRFB Studied by Electrochemical Impedance Spectroscopy

  • Jonathan Schneider,
  • Eduard Bulczak,
  • Gumaa A. El-Nagar,
  • Marcus Gebhard,
  • Paul Kubella,
  • Maike Schnucklake,
  • Abdulmonem Fetyan,
  • Igor Derr and
  • Christina Roth

23 January 2019

The performance of all-V redox flow batteries (VRFB) will decrease when they are exposed to dynamic electrochemical cycling, but also when they are in prolonged contact with the acidic electrolyte. These phenomena are especially severe at the negativ...

(This article belongs to the Special Issue Vanadium Redox Flow Battery and Its Applications)
  • Article
  • Open Access
27 Citations
14,709 Views
19 Pages

Design and Analysis of the Use of Re-Purposed Electric Vehicle Batteries for Stationary Energy Storage in Canada

  • John W. A. Catton,
  • Sean B. Walker,
  • Paul McInnis,
  • Michael Fowler,
  • Roydon A. Fraser,
  • Steven B. Young and
  • Ben Gaffney

19 January 2019

Vehicle electrification increases the fuel efficiency of the transportation sector while lowering emissions. Eventually, however, electric vehicle batteries will reach their end-of-life (EOL) point, when the capacity of the battery is insufficient fo...

  • Review
  • Open Access
157 Citations
42,138 Views
24 Pages

18 January 2019

Use of a reference electrode (RE) in Li-ion batteries (LIBs) aims to enable quantitative evaluation of various electrochemical aspects of operation such as: (i) the distinct contribution of each cell component to the overall battery performance, (ii)...

  • Article
  • Open Access
65 Citations
26,679 Views
16 Pages

Vanadium Electrolyte for All-Vanadium Redox-Flow Batteries: The Effect of the Counter Ion

  • Nataliya Roznyatovskaya,
  • Jens Noack,
  • Heiko Mild,
  • Matthias Fühl,
  • Peter Fischer,
  • Karsten Pinkwart,
  • Jens Tübke and
  • Maria Skyllas-Kazacos

18 January 2019

In this study, 1.6 M vanadium electrolytes in the oxidation forms V(III) and V(V) were prepared from V(IV) in sulfuric (4.7 M total sulphate), V(IV) in hydrochloric (6.1 M total chloride) acids, as well as from 1:1 mol mixture of V(III) and V(IV) (de...

(This article belongs to the Special Issue Redox Flow Batteries for Large-Scale Energy Storage)
  • Article
  • Open Access
219 Citations
47,023 Views
15 Pages

Exploring the Economic Potential of Sodium-Ion Batteries

  • Jens F. Peters,
  • Alexandra Peña Cruz and
  • Marcel Weil

16 January 2019

Sodium-ion batteries (SIBs) are a recent development being promoted repeatedly as an economically promising alternative to lithium-ion batteries (LIBs). However, only one detailed study about material costs has yet been published for this battery typ...

  • Article
  • Open Access
6 Citations
9,122 Views
12 Pages

Silicon/Mesoporous Carbon (Si/MC) Derived from Phenolic Resin for High Energy Anode Materials for Li-ion Batteries: Role of HF Etching and Vinylene Carbonate (VC) Additive

  • Arlavinda Rezqita,
  • Hristina Vasilchina,
  • Raad Hamid,
  • Markus Sauer,
  • Annette Foelske,
  • Corina Täubert and
  • Hermann Kronberger

16 January 2019

Silicon/mesoporous carbon (Si/MC) composites with optimum Si content, in which the volumetric energy density would be maximized, while volume changes would be minimized, have been developed. The composites were prepared by dispersing Si nanoparticles...

  • Article
  • Open Access
12 Citations
9,081 Views
14 Pages

This study describes a novel approach for real-time energy harvesting and performance diagnostics of a solid anolyte microbial fuel cell (SA-MFC) representing a prototype smart biobattery. The biobattery power output was maximized in real time by com...

  • Article
  • Open Access
17 Citations
10,380 Views
17 Pages

Lithium ion battery modules have significant capacity left after their useful life in transportation applications. This empirical study successfully tested the used modules in secondary grid applications in laboratory conditions. The selection of the...

(This article belongs to the Special Issue Sustainable Lithium Ion Batteries: From Production to Recycling)
  • Article
  • Open Access
25 Citations
9,348 Views
11 Pages

Vanadium redox-flow batteries are a promising energy storage technology due to their safety, long-term stability, and independent adjustability of power and capacity. However, the vanadium crossover through the membrane causes a self-discharge, which...

(This article belongs to the Special Issue Vanadium Redox Flow Battery and Its Applications)
  • Article
  • Open Access
12 Citations
9,544 Views
24 Pages

Investigations on a Mesoporous Glass Membrane as Ion Separator for a Redox Flow Battery

  • Ioannis Michos,
  • Zishu Cao,
  • Zhi Xu,
  • Wenheng Jing and
  • Junhang Dong

This article reports extensive studies of a Vycor® porous glass (VPG) membrane as an ion separator for an all-vanadium redox flow battery (VRFB). The VPG membrane had an average pore size of 4 nm and porosity of ~28%. The VPG ion separator exhibi...

(This article belongs to the Special Issue Vanadium Redox Flow Battery and Its Applications)
  • Article
  • Open Access
23 Citations
9,571 Views
17 Pages

With the ever-increasing usage of lithium-ion batteries, especially in transportation applications, accurate estimation of battery state of charge (SOC) is of paramount importance. A majority of the current SOC estimation methods rely on data collect...

  • Article
  • Open Access
72 Citations
14,212 Views
13 Pages

Zinc-ion batteries (ZIBs) have received attention as one type of multivalent-ion batteries due to their potential applications in large-scale energy storage systems. Here we report a prototype of rocking-chair ZIB system employing Zn2Mo6S8 (zinc Chev...

  • Article
  • Open Access
8 Citations
7,802 Views
11 Pages

Investigation of Reactant Conversion in the Vanadium Redox Flow Battery Using Spatially Resolved State of Charge Mapping

  • Purna C. Ghimire,
  • Arjun Bhattarai,
  • Rüdiger Schweiss,
  • Günther G. Scherer,
  • Nyunt Wai,
  • Tuti M. Lim and
  • Qingyu Yan

Segmented cells enable real time visualization of the flow distribution in vanadium redox flow batteries by local current or voltage mapping. The lateral flow of current within thick porous electrodes, however, impairs the local resolution of the det...

(This article belongs to the Special Issue Redox Flow Batteries for Large-Scale Energy Storage)
  • Article
  • Open Access
3 Citations
7,373 Views
15 Pages

Electrochemical Performance and in Operando Charge Efficiency Measurements of Cu/Sn-Doped Nano Iron Electrodes

  • Alagar Raj Paulraj,
  • Yohannes Kiros,
  • Mylad Chamoun,
  • Henrik Svengren,
  • Dag Noréus,
  • Mats Göthelid,
  • Björn Skårman,
  • Hilmar Vidarsson and
  • Malin B. Johansson

21 December 2018

Fe-air or Ni-Fe cells can offer low-cost and large-scale sustainable energy storage. At present, they are limited by low coulombic efficiency, low active material use, and poor rate capability. To overcome these challenges, two types of nanostructure...

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Batteries - ISSN 2313-0105