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Volume 11
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Batteries, Volume 11, Issue 7 (July 2025) – 45 articles

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20 pages, 4023 KiB  
Article
Numerical Study on the Thermal Behavior of Lithium-Ion Batteries Based on an Electrochemical–Thermal Coupling Model
by Xing Hu, Hu Xu, Chenglin Ding, Yupeng Tian and Kuo Yang
Batteries 2025, 11(7), 280; https://doi.org/10.3390/batteries11070280 - 21 Jul 2025
Viewed by 328
Abstract
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics [...] Read more.
The escalating demand for efficient thermal management in lithium-ion batteries necessitates precise characterization of their thermal behavior under diverse operating conditions. This study develops a three-dimensional (3D) electrochemical–thermal coupling model grounded in porous electrode theory and energy conservation principles. The model solves multi-physics equations such as Fick’s law, Ohm’s law, and the Butler–Volmer equation, to resolve coupled electrochemical and thermal dynamics, with temperature-dependent parameters calibrated via the Arrhenius equation. Simulations under varying discharge rates reveal that high-rate discharges exacerbate internal heat accumulation. Low ambient temperatures amplify polarization effects. Forced convection cooling reduces surface temperatures but exacerbates core-to-surface thermal gradients. Structural optimization strategies demonstrate that enhancing through-thickness thermal conductivity reduces temperature differences. These findings underscore the necessity of balancing energy density and thermal management in lithium-ion battery design, proposing actionable insights such as preheating protocols for low-temperature operation, optimized cooling systems for high-rate scenarios, and material-level enhancements for improved thermal uniformity. Full article
(This article belongs to the Special Issue High-Performance Secondary Batteries: Recent Processes and Future Challenges)
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16 pages, 5057 KiB  
Article
Control and Management of Multi-Agent Systems Using Fuzzy Logic for Microgrids
by Zineb Cabrane, Mohammed Ouassaid, Donghee Choi and Soo Hyoung Lee
Batteries 2025, 11(7), 279; https://doi.org/10.3390/batteries11070279 - 21 Jul 2025
Viewed by 215
Abstract
The existing standalone microgrids (MGs) require good energy management systems (EMSs) to respond to energy needs. The EMS presented in this paper is used for an MG based on PV and wind energy sources. The energy storage system is implemented using three packs [...] Read more.
The existing standalone microgrids (MGs) require good energy management systems (EMSs) to respond to energy needs. The EMS presented in this paper is used for an MG based on PV and wind energy sources. The energy storage system is implemented using three packs of batteries. Power smoothing is carried out via the introduction of supercapacitors (SCs) in parallel to the loads and sources. The distribution of energy of the presented MG is focused on the multi-agent system (MAS) using Fuzzy Logic Supervisor control. The MAS is used in order to leverage autonomous and interacting agents to optimize operations and achieve system objectives. To reduce the stress on batteries and avoid damaging all the batteries together by the charge and discharge cycles, one pack of batteries can usually be used. When this pack of batteries is fully discharged and there is a need for energy, it can be taken from another pack of batteries. The same analysis applies to the charge; when batteries of the first pack are fully charged and there is a surplus of energy, it can be stored in other packs of batteries. Two simulation results are used to demonstrate the efficiency of the EMS control used. These simulation tests are proposed with and without SCs. Full article
(This article belongs to the Section Battery Modelling, Simulation, Management and Application)
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15 pages, 2596 KiB  
Article
Comprehensive Experimental Investigation of Operational Parameter Sensitivity in Proton Exchange Membrane Fuel Cell Performance
by Renhua Feng, Zhanye Hua, Jing Yu, Shaoyang Wang, Laihua Shi, Xing Shu, Ziyi Yan and Jiayi Guo
Batteries 2025, 11(7), 278; https://doi.org/10.3390/batteries11070278 - 21 Jul 2025
Viewed by 253
Abstract
In this study, the sensitivity of operating parameters such as the hydrogen and air excess coefficient, cathode inlet pressure, intake relative humidity, and coolant inlet temperature and their effects on the performance of single proton exchange membrane fuel cells (PEMFCs) are experimentally assessed. [...] Read more.
In this study, the sensitivity of operating parameters such as the hydrogen and air excess coefficient, cathode inlet pressure, intake relative humidity, and coolant inlet temperature and their effects on the performance of single proton exchange membrane fuel cells (PEMFCs) are experimentally assessed. The results revealed that the fuel cell node voltage increases as the hydrogen and air excess coefficient increases, and the impact of the hydrogen and air excess coefficient on the fuel cell node voltage gradually increases as the current density increases. However, a higher hydrogen and air excess coefficient is not always better. The node voltage increases as the intake pressure increases. However, it is not that a higher intake pressure is always better, but rather that there is an optimal intake pressure value to achieve the best overall performance of the fuel cell. The node voltage increases as the coolant inlet temperature increases at most fuel cell current densities. However, the optimum fuel cell operating inlet temperature is not necessarily higher, as the coolant inlet temperature may have a strong coupling relationship with other operating conditions that will also affect the fuel cell performance. The fuel cell operating inlet temperature may have a strong coupling relationship with the intake relative humidity, and both of these parameters must be well-matched to achieve better fuel cell performance. Full article
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20 pages, 2939 KiB  
Article
Investigations of Dongyue Series Perfluorosulfonic Acid Membranes for Applications in Proton Exchange Membrane Fuel Cells (PEMFCs)
by Ge Meng, Xiang Li, Mengjie Liu, Sergey A. Grigoriev, Ivan Tolj, Jiaqi Shen, Chaonan Yue and Chuanyu Sun
Batteries 2025, 11(7), 277; https://doi.org/10.3390/batteries11070277 - 20 Jul 2025
Viewed by 342
Abstract
This study systematically investigated the physicochemical properties and proton exchange membrane fuel cell (PEMFC) performance of perfluorosulfonic acid (PFSA) membranes with different thicknesses, which were prepared based on the resins produced by Dongyue (China) in comparison with commercial Nafion membranes. It was found [...] Read more.
This study systematically investigated the physicochemical properties and proton exchange membrane fuel cell (PEMFC) performance of perfluorosulfonic acid (PFSA) membranes with different thicknesses, which were prepared based on the resins produced by Dongyue (China) in comparison with commercial Nafion membranes. It was found that the water uptake of Dongyue membranes is significantly higher than that of Nafion, showing a significant upward trend with the thickness increase. The ion exchange capacity (IEC) of these membranes is ca. 1 mmol·g−1. Moreover, the tensile strength of the Dongyue membrane was positively correlated with the thickness and was significantly higher than that of recast Nafion. Under 80 °C, all Dongyue membranes with various thicknesses (15~45 μm) exhibited PEMFC single-cell performance superior to that of Nafion. The maximum power density is observed with a thickness of 25 μm, reaching 851.76 mW·cm−2, which is higher than that of Nafion (635.99 mW·cm−2). However, the oxidative stability of the prepared Dongyue PFSA series membranes exhibits a slight deficit compared to commercial Nafion membranes. Subsequently, the modification and optimization of preparation processes can be employed to improve the mechanical and chemical stability of Dongyue PFSA membranes. Full article
(This article belongs to the Special Issue Batteries: 10th Anniversary)
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21 pages, 2547 KiB  
Article
Remaining Available Energy Prediction for Energy Storage Batteries Based on Interpretable Generalized Additive Neural Network
by Ji Qi, Pengrui Li, Yifan Dong, Zhicheng Fu, Zhanguo Wang, Yong Yi and Jie Tian
Batteries 2025, 11(7), 276; https://doi.org/10.3390/batteries11070276 - 20 Jul 2025
Viewed by 222
Abstract
Precise estimation of the remaining available energy in batteries is not only key to improving energy management efficiency, but also serves as a critical safeguard for ensuring the safe operation of battery systems. To address the challenges associated with energy state estimation under [...] Read more.
Precise estimation of the remaining available energy in batteries is not only key to improving energy management efficiency, but also serves as a critical safeguard for ensuring the safe operation of battery systems. To address the challenges associated with energy state estimation under dynamic operating conditions, this study proposes a method for predicting the remaining available energy of energy storage batteries based on an interpretable generalized additive neural network (IGANN). First, considering the variability in battery operating conditions, the study designs a battery working voltage threshold that accounts for safety margins and proposes an available energy state assessment metric, which enhances prediction consistency under different discharge conditions. Subsequently, 12 features are selected from both direct observation and statistical characteristics to capture the operating condition information of the battery, and a dataset is constructed using actual operational data from an energy storage station. Finally, the model is trained and validated on the feature dataset. The validation results show that the model achieves an average absolute error of 2.39%, indicating that it effectively captures the energy variation characteristics within the 0.2 C to 0.6 C dynamic current range. Furthermore, the contribution of each feature is analyzed based on the model’s interpretability, and the model is optimized by utilizing high-contribution features. This optimization improves both the accuracy and runtime efficiency of the model. Finally, a dynamic prediction is conducted for a discharge cycle, comparing the predictions of the IGANN model with those of three other machine learning methods. The IGANN model demonstrates the best performance, with the average absolute error consistently controlled within 3%, proving the model’s accuracy and robustness under complex conditions. Full article
(This article belongs to the Special Issue Advances in Lithium-Ion Battery Safety and Fire: 2nd Edition)
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49 pages, 15060 KiB  
Review
A Comprehensive Review of Thermal Management Challenges and Safety Considerations in Lithium-Ion Batteries for Electric Vehicles
by Ali Alawi, Ahmed Saeed, Mostafa H. Sharqawy and Mohammad Al Janaideh
Batteries 2025, 11(7), 275; https://doi.org/10.3390/batteries11070275 - 19 Jul 2025
Viewed by 1010
Abstract
The transition to electric vehicles (EVs) is accelerating due to global efforts to reduce greenhouse gas emissions and reliance on fossil fuels. Lithium-ion batteries (LIBs) are the predominant energy storage solution in EVs, offering high energy density, efficiency, and long lifespan. However, their [...] Read more.
The transition to electric vehicles (EVs) is accelerating due to global efforts to reduce greenhouse gas emissions and reliance on fossil fuels. Lithium-ion batteries (LIBs) are the predominant energy storage solution in EVs, offering high energy density, efficiency, and long lifespan. However, their adoption is overly involved with critical safety concerns, including thermal runaway and overheating. This review systematically focuses on the critical role of battery thermal management systems (BTMSs), such as active, passive, and hybrid cooling systems, in maintaining LIBs within their optimal operating temperature range, ensuring temperature homogeneity, safety, and efficiency. Additionally, the study explores the impact of integrating artificial intelligence (AI) and machine learning (ML) into BTMS on thermal performance prediction and energy-efficient cooling, focusing on optimizing the operating parameters of cooling systems. This review provides insights into enhancing LIB safety and performance for widespread EV adoption by addressing these challenges. Full article
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16 pages, 2291 KiB  
Article
State of Charge Estimation for Sodium-Ion Batteries Based on LSTM Network and Unscented Kalman Filter
by Xiangang Zuo, Xiaoheng Fu, Xu Han, Meng Sun and Yuqian Fan
Batteries 2025, 11(7), 274; https://doi.org/10.3390/batteries11070274 - 18 Jul 2025
Viewed by 299
Abstract
With the increasing application of sodium-ion batteries in energy storage systems, accurate state of charge (SOC) estimation plays a vital role in ensuring both available battery capacity and operational safety. Traditional Kalman-filter-based methods often suffer from limited model expressiveness or oversimplified physical assumptions, [...] Read more.
With the increasing application of sodium-ion batteries in energy storage systems, accurate state of charge (SOC) estimation plays a vital role in ensuring both available battery capacity and operational safety. Traditional Kalman-filter-based methods often suffer from limited model expressiveness or oversimplified physical assumptions, making it difficult to balance accuracy and robustness under complex operating conditions, which may lead to unreliable estimation results. To address these challenges, this paper proposes a hybrid framework that combines an unscented Kalman filter (UKF) with a long short-term memory (LSTM) neural network for SOC estimation. Under various driving conditions, the UKF—based on a second-order equivalent circuit model with online parameter identification—provides physically interpretable estimates, while LSTM effectively captures complex temporal dependencies. Experimental results under CLTC, NEDC, and WLTC cycles demonstrate that the proposed LSTM-UKF approach reduces the mean absolute error (MAE) by an average of 2% and the root mean square error (RMSE) by an average of 3% compared to standalone methods. The proposed framework exhibits excellent adaptability across different scenarios, offering a precise, stable, and robust solution for SOC estimation in sodium-ion batteries. Full article
(This article belongs to the Section Battery Modelling, Simulation, Management and Application)
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15 pages, 1845 KiB  
Article
Comparing the SEI Formation on Copper and Amorphous Carbon: A Study with Combined Operando Methods
by Michael Stich, Christian Leppin, Falk Thorsten Krauss, Jesus Eduardo Valdes Landa, Isabel Pantenburg, Bernhard Roling and Andreas Bund
Batteries 2025, 11(7), 273; https://doi.org/10.3390/batteries11070273 - 18 Jul 2025
Viewed by 240
Abstract
The solid electrolyte interphase (SEI) on the anode of lithium-ion batteries (LIBs) has been studied thoroughly due to its crucial importance to the battery’s long-term performance. At the same time, most studies of the SEI apply ex situ characterization methods, which may introduce [...] Read more.
The solid electrolyte interphase (SEI) on the anode of lithium-ion batteries (LIBs) has been studied thoroughly due to its crucial importance to the battery’s long-term performance. At the same time, most studies of the SEI apply ex situ characterization methods, which may introduce artifacts or misinterpretations as they do not investigate the SEI in its unaltered state immersed in liquid battery electrolyte. Thus, in this work, we focus on using the non-destructive combination of electrochemical quartz crystal microbalance with dissipation monitoring (EQCM-D) and impedance spectroscopy (EIS) in the same electrochemical cell. EQCM-D can not only probe the solidified products of the SEI but also allows for the monitoring of viscoelastic layers and viscosity changes of the electrolyte at the interphase during the SEI formation. EIS complements those results by providing electrochemical properties of the formed interphase. Our results highlight substantial differences in the physical and electrochemical properties between the SEI formed on copper and on amorphous carbon and show how formation parameters and the additive vinylene carbonate (VC) influence their growth. The EQCM-D results show consistently that much thicker SEIs are formed on carbon substrates in comparison to copper substrates. Full article
(This article belongs to the Special Issue Electrocrystallization in Rechargeable Batteries)
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23 pages, 7016 KiB  
Article
SOC Estimation of Lithium-Ion Batteries Utilizing EIS Technology with SHAP–ASO–LightGBM
by Panpan Hu, Chun Yin Li and Chi Chung Lee
Batteries 2025, 11(7), 272; https://doi.org/10.3390/batteries11070272 - 17 Jul 2025
Viewed by 622
Abstract
Accurate State of Charge (SOC) estimation is critical for optimizing the performance and longevity of lithium-ion batteries (LIBs), which are widely used in applications ranging from electric vehicles to renewable energy storage. Traditional SOC estimation methods, such as Coulomb counting and open-circuit voltage [...] Read more.
Accurate State of Charge (SOC) estimation is critical for optimizing the performance and longevity of lithium-ion batteries (LIBs), which are widely used in applications ranging from electric vehicles to renewable energy storage. Traditional SOC estimation methods, such as Coulomb counting and open-circuit voltage measurement, suffer from cumulative errors and slow response times. This paper proposes a novel machine learning-based approach for SOC estimation by integrating Electrochemical Impedance Spectroscopy (EIS) with the SHapley Additive exPlanations (SHAP) method, Atom Search Optimization (ASO), and Light Gradient Boosting Machine (LightGBM). This study focuses on large-capacity lithium iron phosphate (LFP) batteries (3.2 V, 104 Ah), addressing a gap in existing research. EIS data collected at various SOC levels and temperatures were processed using SHAP for feature extraction (FE), and the ASO–LightGBM model was employed for SOC prediction. Experimental results demonstrate that the proposed SHAP–ASO–LightGBM method significantly improves estimation accuracy, achieving an RMSE of 3.3%, MAE of 1.86%, and R2 of 0.99, outperforming traditional methods like LSTM and DNN. The findings highlight the potential of EIS and machine learning (ML) for robust SOC estimation in large-capacity LIBs. Full article
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19 pages, 15854 KiB  
Article
Failure Analysis of Fire in Lithium-Ion Battery-Powered Heating Insoles: Case Study
by Rong Yuan, Sylvia Jin and Glen Stevick
Batteries 2025, 11(7), 271; https://doi.org/10.3390/batteries11070271 - 17 Jul 2025
Viewed by 354
Abstract
This study investigates a lithium-ion battery failure in heating insoles that ignited during normal walking while powered off. Through comprehensive material characterization, electrical testing, thermal analysis, and mechanical gait simulation, we systematically excluded electrical or thermal abuse as failure causes. X-ray/CT imaging localized [...] Read more.
This study investigates a lithium-ion battery failure in heating insoles that ignited during normal walking while powered off. Through comprehensive material characterization, electrical testing, thermal analysis, and mechanical gait simulation, we systematically excluded electrical or thermal abuse as failure causes. X-ray/CT imaging localized the ignition source to the lateral heel edge of the pouch cell, correlating precisely with peak mechanical stress identified through gait analysis. Remarkably, the cyclic load was less than 10% of the single crush load threshold specified in safety standards. Key findings reveal multiple contributing factors as follows: the uncoated polyethylene separator’s inability to prevent stress-induced internal short circuits, the circuit design’s lack of battery health monitoring functionality that permitted undetected degradation, and the hazardous placement inside clothing that exacerbated burn injuries. These findings necessitate a multi-level safety framework for lithium-ion battery products, encompassing enhanced cell design to prevent internal short circuit, improved circuit protection with health monitoring capabilities, optimized product integration to mitigate mechanical and environmental impact, and effective post-failure containment measures. This case study exposes a critical need for product-specific safety standards that address the unique demands of wearable lithium-ion batteries, where existing certification requirements fail to prevent real-use failure scenarios. Full article
(This article belongs to the Section Battery Performance, Ageing, Reliability and Safety)
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17 pages, 4099 KiB  
Article
Tetramethylene Sulfone (TMS) as an Electrolyte Additive for High-Power Lithium-Ion Batteries
by Wenting Liu, Gangxin Chen, Ningfeng Wang, Xianzhong Sun, Chen Li, Yanan Xu, Xiaohu Zhang, Xiong Zhang and Kai Wang
Batteries 2025, 11(7), 270; https://doi.org/10.3390/batteries11070270 - 17 Jul 2025
Viewed by 341
Abstract
High-power lithium-ion batteries impose stringent requirements on output power. Tetramethylene sulfone (TMS), serving as a novel electrolyte additive, effectively enhances the stability of electrolytes under high-voltage conditions due to its high flash point and high dielectric constant, thereby boosting the output performance of [...] Read more.
High-power lithium-ion batteries impose stringent requirements on output power. Tetramethylene sulfone (TMS), serving as a novel electrolyte additive, effectively enhances the stability of electrolytes under high-voltage conditions due to its high flash point and high dielectric constant, thereby boosting the output performance of lithium-ion batteries. In this work, we selected lithium hexafluorophosphate (LiPF6) as the lithium salt, using a solvent carrier consisting of a mixture of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC). TMS was added as an additive to create a novel high-power electrolyte system. We prepared five electrolytes with different TMS concentrations and conducted in-depth investigations into their impacts on the performance of lithium-ion batteries. The findings indicate that the electrolytes with TMS ratios of 2 wt% and 5 wt% demonstrated good synergistic cathode–anode stability in the NCM//soft carbon system, and the electrolyte with a 5 wt% TMS ratio demonstrated the most significant improvement in the overall performance of the full battery. Full article
(This article belongs to the Special Issue Lithium-Ion Batteries and Li-Ion Capacitors: From Fundamentals to Practical Applications: 2nd Edition)
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24 pages, 2152 KiB  
Review
A Concise Overview of the Use of Low-Dimensional Molybdenum Disulfide as an Electrode Material for Li-Ion Batteries and Beyond
by Mattia Bartoli, Meltem Babayiğit Cinali, Özlem Duyar Coşkun, Silvia Porporato, Diego Pugliese, Erik Piatti, Francesco Geobaldo, Giuseppe A. Elia, Claudio Gerbaldi, Giuseppina Meligrana and Alessandro Piovano
Batteries 2025, 11(7), 269; https://doi.org/10.3390/batteries11070269 - 16 Jul 2025
Viewed by 432
Abstract
The urgent demand for sustainable energy solutions in the face of climate change and resource depletion has catalyzed a global shift toward cleaner energy production and more efficient storage technologies. Lithium-ion batteries (LIBs), as the cornerstone of modern portable electronics, electric vehicles, and [...] Read more.
The urgent demand for sustainable energy solutions in the face of climate change and resource depletion has catalyzed a global shift toward cleaner energy production and more efficient storage technologies. Lithium-ion batteries (LIBs), as the cornerstone of modern portable electronics, electric vehicles, and grid-scale storage systems, are continually evolving to meet the growing performance requirements. In this dynamic context, two-dimensional (2D) materials have emerged as highly promising candidates for use in electrodes due to their layered structure, tunable electronic properties, and high theoretical capacity. Among 2D materials, molybdenum disulfide (MoS2) has gained increasing attention as a promising low-dimensional candidate for LIB anode applications. This review provides a comprehensive yet concise overview of recent advances in the application of MoS2 in LIB electrodes, with particular attention to its unique electrochemical behavior at the nanoscale. We critically examine the interplay between structural features, charge-storage mechanisms, and performance metrics—chiefly the specific capacity, rate capability, and cycling stability. Furthermore, we discuss current challenges, primarily poor intrinsic conductivity and volume fluctuations, and highlight innovative strategies aimed at overcoming these limitations, such as through nanostructuring, composite formation, and surface engineering. By shedding light on the opportunities and hurdles in this rapidly progressing field, this work offers a forward-looking perspective on the role of MoS2 in the next generation of high-performance LIBs. Full article
(This article belongs to the Section Battery Mechanisms and Fundamental Electrochemistry Aspects)
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15 pages, 4059 KiB  
Article
Surface Fluorination for the Stabilization in Air of Garnet-Type Oxide Solid Electrolyte for Lithium Ion Battery
by Michael Herraiz, Saida Moumen, Kevin Lemoine, Laurent Jouffret, Katia Guérin, Elodie Petit, Nathalie Gaillard, Laure Bertry, Reka Toth, Thierry Le Mercier, Valérie Buissette and Marc Dubois
Batteries 2025, 11(7), 268; https://doi.org/10.3390/batteries11070268 - 16 Jul 2025
Viewed by 252
Abstract
After reviewing the state of the art of the fluorination of inorganic solid electrolytes, an application of gas/solid fluorination is given and how it can be processed. Garnet-type oxide has been chosen. These oxides with an ideal structure of chemical formula A3 [...] Read more.
After reviewing the state of the art of the fluorination of inorganic solid electrolytes, an application of gas/solid fluorination is given and how it can be processed. Garnet-type oxide has been chosen. These oxides with an ideal structure of chemical formula A3B2(XO4)3 are mainly known for their magnetic and dielectric properties. Certain garnets may have a high enough Li+ ionic conductivity to be used as solid electrolyte of lithium ion battery. The surface of LLZO may be changed in contact with the moisture and CO2 present in the atmosphere that results in a change of the conductivity at the interface of the solid. LiOH and/or lithium carbonate are formed at the surface of the garnet particles. In order to allow for handling and storage under normal conditions of this solid electrolyte, surface fluorination was performed using elemental fluorine. When controlled using mild conditions (temperature lower or equal to 200 °C, either in static or dynamic mode), the addition of fluorine atoms to LLZO with Li6,4Al0,2La3Zr2O12 composition is limited to the surface, forming a covering layer of lithium fluoride LiF. The effect of the fluorination was evidenced by IR, Raman, and NMR spectroscopies. If present in the pristine LLZO powder, then the carbonate groups disappear. More interestingly, contrary to the pristine LLZO, the contents of these groups are drastically reduced even after storage in air up to 45 days when the powder is covered with the LiF layer. Surface fluorination could be applied to other solid electrolytes that are air sensitive. Full article
(This article belongs to the Special Issue Electrolyte and Electrode Design for Next-Generation Rechargeable Batteries)
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18 pages, 4053 KiB  
Article
Comprehensive Study of the Gas Volume and Composition Produced by Different 3–230 Ah Lithium Iron Phosphate (LFP) Cells Failed Using External Heat, Overcharge and Nail Penetration Under Air and Inert Atmospheres
by Gemma E. Howard, Jonathan E. H. Buston, Jason Gill, Steven L. Goddard, Jack W. Mellor and Philip A. P. Reeve
Batteries 2025, 11(7), 267; https://doi.org/10.3390/batteries11070267 - 16 Jul 2025
Viewed by 499
Abstract
This paper reports on the failure of cells with lithium iron phosphate (LFP) chemistry tested under a range of conditions to understand their effect on the volume and composition of gas generated. Cells of the following formats, 26,650, pouch, and prismatic, and capacities [...] Read more.
This paper reports on the failure of cells with lithium iron phosphate (LFP) chemistry tested under a range of conditions to understand their effect on the volume and composition of gas generated. Cells of the following formats, 26,650, pouch, and prismatic, and capacities ranging from 3 to 230 Ah, were subjected to external heat, overcharge, and nail penetration tests. Gas volume was calculated, and the following gases analysed: H2, CO2, CO, CH4, C2H4, C2H6, C3H6, and C3H8. Cells that failed via external heating under inert conditions (N2 or Ar atmosphere) at 100% state of charge (SoC) typically generated 0.7 L/Ah of gas; overcharged cells, 0.11–0.68 L/Ah; and nail penetration between 0.3 and 0.5 L/Ah. In general, for all test configurations, regardless of atmosphere, the total gas volume contained a 40% concentration of H2, 15% of CO2, and the remaining gas consisted of varying concentrations of CO and flammable hydrocarbons. This demonstrates that despite differences in gas volume, the failure gas composition of LFP cells remains similar. Full article
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20 pages, 1818 KiB  
Article
Interfacial Layer (“Interlayer”) Addition to Improve Active Material Utilisation in Lithium–Sulfur Batteries: Use of a Phenylsulfonated MWCNT Film
by Luke D. J. Barter, Steven J. Hinder, John F. Watts, Robert C. T. Slade and Carol Crean
Batteries 2025, 11(7), 266; https://doi.org/10.3390/batteries11070266 - 16 Jul 2025
Viewed by 469
Abstract
Films of functionalised multiwalled carbon nanotubes (MWCNTs) were fabricated as interlayers (interfacial layers between the cathode and separator) in a lithium–sulfur battery (LSB). Phenylsulfonate functionalisation of commercial MWCNTs was achieved via diazotisation to attach lithium phenylsulfonate groups and was characterised by IR and [...] Read more.
Films of functionalised multiwalled carbon nanotubes (MWCNTs) were fabricated as interlayers (interfacial layers between the cathode and separator) in a lithium–sulfur battery (LSB). Phenylsulfonate functionalisation of commercial MWCNTs was achieved via diazotisation to attach lithium phenylsulfonate groups and was characterised by IR and XPS spectroscopies. SEM-EDX showed sulfur and oxygen colocations due to the sulfonate groups on the interlayer surface. However, CHNS elemental microstudies showed a low degree of functionalisation. Without an interlayer, the LSB produced stable cycling at a capacity of 600 mA h g−1sulfur at 0.05 C for 40 cycles. Using an unfunctionalised interlayer as a control gave a capacity of 1400 mA h g−1sulfur for the first cycle but rapidly decayed to the same 600 mA h g−1sulfur at the 40th cycle at 0.05 C, suggesting a high degree of polysulfide shuttling. Adding a lithium phenylsulfonated interlayer gave an initial capacity increase to 1100 mA h g−1sulfur that lowered to 800 mA h g−1sulfur at 0.05 C by the 40th cycle, showing an increase in charge storage (33%) relative to the other cells. This performance increase has been attributed to lessened polysulfide shuttling due to repulsion by the phenylsulfonate groups, increased conductivity at the separator-cathode interface and an increase in surface area. Full article
(This article belongs to the Special Issue Advanced Carbon-Based Materials for Next-Generation Batteries and Supercapacitors)
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16 pages, 2528 KiB  
Article
An Adaptable Capacity Estimation Method for Lithium-Ion Batteries Based on a Constructed Open Circuit Voltage Curve
by Linjing Zhang, Xiaoqian Su, Caiping Zhang, Yubin Wang, Yao Wang, Tao Zhu and Xinyuan Fan
Batteries 2025, 11(7), 265; https://doi.org/10.3390/batteries11070265 - 14 Jul 2025
Viewed by 266
Abstract
The inevitable decline in battery performance presents a major barrier to its widespread industrial application. Adaptive and accurate estimation of battery capacity is paramount for battery operation, maintenance, and residual value evaluation. In this paper, we propose a novel battery capacity estimation method [...] Read more.
The inevitable decline in battery performance presents a major barrier to its widespread industrial application. Adaptive and accurate estimation of battery capacity is paramount for battery operation, maintenance, and residual value evaluation. In this paper, we propose a novel battery capacity estimation method based on an approximate open circuit voltage curve. The proposed method is rigorously tested using both lithium–iron–phosphate (LFP) and nickel–cobalt–manganese (NCM) battery packs at multiple charging rates under varied aging conditions. To further enhance capacity estimation accuracy, a voltage correction strategy is implemented utilizing the incremental capacity (IC) curve. This strategy also verifies the potential benefits of increasing the charging rate to shorten the overall test duration. Eventually, the capacity estimation error is consistently controlled within 2%. With optimal state of charge (SOC) interval selection, the estimation error can be further reduced to 1%. Clearly, our proposed method exhibits excellent compatibility across diverse battery materials and degradation states. This adaptability holds substantial scientific value and practical importance. It contributes to the safe and economic utilization of Li-ion batteries throughout their entire lifespan. Full article
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22 pages, 3348 KiB  
Article
Integrated Machine Learning Framework Combining Electrical Cycling and Material Features for Supercapacitor Health Forecasting
by Mojtaba Khakpour Komarsofla, Kavian Khosravinia and Amirkianoosh Kiani
Batteries 2025, 11(7), 264; https://doi.org/10.3390/batteries11070264 - 14 Jul 2025
Viewed by 214
Abstract
The ability to predict capacity retention is critical for ensuring the long-term reliability of supercapacitors in energy storage systems. This study presents a comprehensive machine learning framework that integrates both electrical cycling data and experimentally derived material and structural features to forecast the [...] Read more.
The ability to predict capacity retention is critical for ensuring the long-term reliability of supercapacitors in energy storage systems. This study presents a comprehensive machine learning framework that integrates both electrical cycling data and experimentally derived material and structural features to forecast the degradation behavior of commercial supercapacitors. A total of seven supercapacitor samples were tested under various current and voltage conditions, resulting in over 70,000 charge–discharge cycles across three case studies. In addition to electrical measurements, detailed physical and material characterizations were performed, including electrode dimension analysis, Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS), and Thermogravimetric Analysis (TGA). Three machine learning models, Linear Regression (LR), Random Forest (RF), and Multi-Layer Perceptron (MLP), were trained using both cycler-only and combined cycler + material features. Results show that incorporating material features consistently improved prediction accuracy across all models. The MLP model exhibited the highest performance, achieving an R2 of 0.976 on the training set and 0.941 on unseen data. Feature importance analysis confirmed that material descriptors such as porosity, thermal stability, and electrode thickness significantly contributed to model performance. This study demonstrates that combining electrical and material data offers a more holistic and physically informed approach to supercapacitor health prediction. The framework developed here provides a practical foundation for accurate and robust lifetime forecasting of commercial energy storage devices, highlighting the critical role of material-level insights in enhancing model generalization and reliability. Full article
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30 pages, 4926 KiB  
Article
Impact Testing of Aging Li-Ion Batteries from Light Electric Vehicles (LEVs)
by Miguel Antonio Cardoso-Palomares, Juan Carlos Paredes-Rojas, Juan Alejandro Flores-Campos, Armando Oropeza-Osornio and Christopher René Torres-SanMiguel
Batteries 2025, 11(7), 263; https://doi.org/10.3390/batteries11070263 - 13 Jul 2025
Viewed by 362
Abstract
The increasing adoption of Light Electric Vehicles (LEVs) in urban areas, driven by the micromobility wave, raises significant safety concerns, particularly regarding battery fire incidents. This research investigates the electromechanical performance of aged 18650 lithium-ion batteries (LIBs) from LEVs under mechanical impact conditions. [...] Read more.
The increasing adoption of Light Electric Vehicles (LEVs) in urban areas, driven by the micromobility wave, raises significant safety concerns, particularly regarding battery fire incidents. This research investigates the electromechanical performance of aged 18650 lithium-ion batteries (LIBs) from LEVs under mechanical impact conditions. For this study, a battery module from a used e-scooter was disassembled, and its constituent cells were reconfigured into compact modules for testing. To characterize their initial condition, the cells underwent cycling tests to evaluate their state of health (SOH). Although a slight majority of the cells retained an SOH greater than 80%, a notable increase in their internal resistance (IR) was also observed, indicating degradation due to aging. The mechanical impact tests were conducted in adherence to the UL 2271:2018 standard, employing a semi-sinusoidal acceleration pulse. During these tests, linear kinematics were analyzed using videogrammetry, while key electrical and thermal parameters were monitored. Additionally, strain gauges were installed on the central cells to measure stress and deformation. The results from the mechanical shock tests revealed characteristic acceleration and velocity patterns. These findings clarify the electromechanical behavior of aged LIBs under impact, providing critical data to enhance the safety and reliability of these vehicles. Full article
(This article belongs to the Topic Batteries, Supercapacitors, Fuel Cells and Combined Energy/Power Supply Systems, 2nd Edition)
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23 pages, 2707 KiB  
Article
Performance Analysis of Battery State Prediction Based on Improved Transformer and Time Delay Second Estimation Algorithm
by Bo Gao, Xiangjun Li, Fang Guo and Xiping Wang
Batteries 2025, 11(7), 262; https://doi.org/10.3390/batteries11070262 - 13 Jul 2025
Viewed by 400
Abstract
As energy storage technology advances rapidly, the power industry demands accurate state estimation of lithium batteries in energy storage power stations. This study aimed to improve such estimations. An improved Transformer structure was employed to estimate the battery’s state of charge (SOC). The [...] Read more.
As energy storage technology advances rapidly, the power industry demands accurate state estimation of lithium batteries in energy storage power stations. This study aimed to improve such estimations. An improved Transformer structure was employed to estimate the battery’s state of charge (SOC). The Time Delay Second Estimation (TDSE) algorithm optimized the improved Transformer model to overcome traditional models’ limitations in extracting long-term dependency. Innovative particle filter algorithms were proposed to handle the nonlinearity, uncertainty, and dynamic changes in predicting remaining battery life. Results showed that for LiNiMnCoO2 positive electrode datasets, the model’s max SOC estimation error was 2.68% at 10 °C and 2.15% at 30 °C. For LiFePO4 positive electrode datasets, the max error was 2.79% at 10 °C (average 1.25%) and 2.35% at 30 °C (average 0.94%). In full lifecycle calculations, the particle filter algorithm predicted battery capacity with 98.34% accuracy and an RMSE of 0.82%. In conclusion, the improved Transformer and TDSE algorithm enable advanced battery state prediction, and the particle filter algorithm effectively predicts remaining battery life, enhancing the adaptability and robustness of lithium battery state analysis and offering technical support for energy storage station management. Full article
(This article belongs to the Topic Advanced Battery Thermal Management Solution for Electric Vehicles, 2nd Edition)
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23 pages, 5743 KiB  
Article
Impact of Low-Pressure in High-Altitude Area on the Aging Characteristics of NCM523/Graphite Pouch Cells
by Xiantao Chen, Zhi Wang, Jian Wang, Yichao Lin and Jian Li
Batteries 2025, 11(7), 261; https://doi.org/10.3390/batteries11070261 - 13 Jul 2025
Viewed by 340
Abstract
With the development and application of electric vehicles powered by lithium-ion batteries (LIBs) at high altitude, the lack of research on the aging laws and mechanisms of LIBs under a low-pressure aviation environment has become an important obstacle to their safe application. Herein, [...] Read more.
With the development and application of electric vehicles powered by lithium-ion batteries (LIBs) at high altitude, the lack of research on the aging laws and mechanisms of LIBs under a low-pressure aviation environment has become an important obstacle to their safe application. Herein, the influences and mechanisms of high-altitude and low-pressure environment (50 kPa) on the cycling performance of commercial pouch LIBs were systematically studied. The results showed that low air pressure caused a sharp decrease in battery capacity to 46.6% after 200 cycles, with a significant increase in charge transfer impedance by 70%, and the contribution rate of active lithium loss reached 74%. Low air pressure led to irreversible deformation of the battery, resulting in the expansion of the gap between the electrodes, poor electrolyte infiltration, and reduction of the effective lithium insertion area, which in turn induced multiple synergistic accelerated decay mechanisms, including obstructed lithium-ion transmission, reduced interfacial reaction efficiency, increased active lithium consumption, changes in heat generation structure, and a significant increase in heat generation. After applying external force, the deformation of the electrode was effectively suppressed, and the cycle capacity retention rate increased to 87.6%, which significantly alleviated the performance degradation of LIBs in low pressure environment. This work provides a key theoretical basis and engineering solutions for the design of power batteries in high-altitude areas. Full article
(This article belongs to the Special Issue Advances in Lithium-Ion Battery Safety and Fire: 2nd Edition)
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28 pages, 47946 KiB  
Article
Artificial Neural Networks for Residual Capacity Estimation of Cycle-Aged Cylindric LFP Batteries
by Pasquale Franzese, Diego Iannuzzi, Roberta Merolla, Mattia Ribera and Ivan Spina
Batteries 2025, 11(7), 260; https://doi.org/10.3390/batteries11070260 - 10 Jul 2025
Viewed by 272
Abstract
This paper introduces a data-driven methodology for accurately estimating the residual capacity (RC) of lithium iron phosphate (LFP) batteries through a tailored artificial neural network (ANN) architecture. The proposed model integrates a long short-term memory (LSTM) layer with a fully connected layer, leveraging [...] Read more.
This paper introduces a data-driven methodology for accurately estimating the residual capacity (RC) of lithium iron phosphate (LFP) batteries through a tailored artificial neural network (ANN) architecture. The proposed model integrates a long short-term memory (LSTM) layer with a fully connected layer, leveraging their combined strengths to achieve precise RC predictions. A distinguishing feature of this study is its ability to deliver highly accurate estimates using a limited dataset that was derived from a single cylindrical LFP battery with a 40 Ah capacity and collected during a controlled experimental campaign. Despite the constraints imposed by the dataset size, the ANN demonstrates remarkable performance, underscoring the model’s capability to operate effectively with minimal data. The dataset is partitioned into the training and testing subsets to ensure a rigorous evaluation. Additionally, the robustness of the approach is validated by testing the trained ANN on data from a second battery cell subjected to a distinct aging process, which was entirely unseen during training. This critical aspect underscores the method’s applicability in estimating RC for batteries with varying aging profiles, a key requirement for real-world deployment. The proposed LSTM-based architecture was also benchmarked against a GRU-based model, yielding significantly lower prediction errors. Furthermore, beyond LFP chemistry, the method was tested on a broader NMC dataset comprising seven cells aged under different C-rates and temperatures, where it maintained high accuracy, confirming its scalability and robustness across chemistries and usage conditions. These results advance battery management systems by offering a robust, efficient modeling framework that optimizes battery utilization across diverse applications, even under data-constrained conditions. Full article
(This article belongs to the Special Issue Artificial Intelligence and Batteries: AI-Powered Innovations in Battery Technology)
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19 pages, 5124 KiB  
Article
Gradient Silica Loading: Performance Analysis of PEMFCs Under Temperature-Humidity Variations
by Qiang Bai, Chuangyu Hsieh, Zhenghong Liu, Qipeng Chen and Fangbor Weng
Batteries 2025, 11(7), 259; https://doi.org/10.3390/batteries11070259 - 10 Jul 2025
Viewed by 277
Abstract
Fuel cells, as one of the most promising alternatives to lithium-ion batteries for portable power systems, still face significant challenges. A critical issue is their substantial performance degradation under low-humidity conditions. To address this, researchers commonly add silica to components. This study employs [...] Read more.
Fuel cells, as one of the most promising alternatives to lithium-ion batteries for portable power systems, still face significant challenges. A critical issue is their substantial performance degradation under low-humidity conditions. To address this, researchers commonly add silica to components. This study employs a control variable method to systematically investigate the impact of four parameters—gas stoichiometry, temperature, humidity, and silica content—on fuel cell performance. Initially, the effects of gas stoichiometry, temperature, and humidity on performance were examined. Subsequently, hydrophilic silica was incorporated into the membrane electrode assembly (MEA) to assess its potential for improving performance in low-humidity environments. Experimental results reveal that under 100% humidification, silica addition had a minimal impact on performance, particularly at high temperatures where performance improved by only 2.5%. This is attributed to increased water production at elevated temperatures, which—when combined with silica’s water retention properties—exacerbates flooding. However, when humidity was reduced to 50%, silica incorporation significantly enhanced performance. At high temperatures, silica addition resulted in a 126.2% performance improvement, demonstrating its efficacy as a rational strategy under low-humidity conditions. Full article
(This article belongs to the Special Issue Challenges, Progress, and Outlook of High-Performance Fuel Cells)
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44 pages, 7563 KiB  
Review
Green Batteries: A Sustainable Approach Towards Next-Generation Batteries
by Annu, Bairi Sri Harisha, Manesh Yewale, Bhargav Akkinepally and Dong Kil Shin
Batteries 2025, 11(7), 258; https://doi.org/10.3390/batteries11070258 - 10 Jul 2025
Viewed by 871
Abstract
The rising demand for sustainable energy storage has fueled the development of green batteries as alternatives to conventional systems. However, a major research gap lies in the unified integration of environmentally friendly materials and processes across all battery components—electrodes, electrolytes, and separators—without compromising [...] Read more.
The rising demand for sustainable energy storage has fueled the development of green batteries as alternatives to conventional systems. However, a major research gap lies in the unified integration of environmentally friendly materials and processes across all battery components—electrodes, electrolytes, and separators—without compromising performance or scalability. This review addresses this gap by highlighting recent advances in eco-conscious battery technologies, focusing on green electrode fabrication using water-based methods, electrophoretic deposition, solvent-free dry-press coating, 3D printing, and biomass-derived materials. It also examines the shift toward safer electrolytes, including ionic liquids, deep eutectic solvents, water-based systems, and solid biopolymer matrices, which improve both environmental compatibility and safety. Additionally, biodegradable separators made from natural polymers such as cellulose and chitosan offer enhanced thermal stability and ecological benefits. The review emphasizes the importance of lifecycle considerations like recyclability and biodegradability, aligning battery design with circular economy principles. While significant progress has been made, challenges such as standardization, long-term stability, and industrial scalability remain. By identifying key strategies and future directions, this article contributes to the foundation for next-generation green batteries, promoting their adoption in environmentally sensitive applications ranging from wearable electronics to grid storage. Full article
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26 pages, 8831 KiB  
Article
Coupling Performance of Cored and Coreless Circular Coils for WPTS: Experimental Validation Under Misalignment Scenarios
by Ahmed M. Ibrahim and Osama A. Mohammed
Batteries 2025, 11(7), 257; https://doi.org/10.3390/batteries11070257 - 10 Jul 2025
Viewed by 264
Abstract
Wireless power transfer systems (WPTSs) are critical for efficient and reliable electric vehicle (EV) charging, but challenges such as misalignment and coupling variations limit their performance. This paper addresses a proposed design approach for WPTSs by optimizing the following two widely used coil [...] Read more.
Wireless power transfer systems (WPTSs) are critical for efficient and reliable electric vehicle (EV) charging, but challenges such as misalignment and coupling variations limit their performance. This paper addresses a proposed design approach for WPTSs by optimizing the following two widely used coil types: ring and spiral circular coils. An analytical estimation of inductive characteristics is conducted to establish a foundation for system optimization. The study framework focuses on coil geometrical parameters and relative placements, accounting for horizontal, vertical, and angular misalignments to ensure a consistent performance under varying coupling conditions. COMSOL simulations accurately determine inductive parameters, validating the theoretical analysis for a 200 W charging coil prototype. Experimental investigations of coupling coefficients for coreless and cored charging pads highlight the superior performance of the Square I-Core-based spiral winding configuration in enhancing the coupling coefficient while ensuring that it remains below the critical value required for stable system operation. The agreement between the analytical results, simulation data, and experimental findings underscores the reliability of the proposed design approach. Full article
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11 pages, 1302 KiB  
Article
Design of a Transformer-GRU-Based Satellite Power System Status Detection Algorithm
by Guoqi Xie, Xinhao Yang, Jiayu Zhao and Zhou Huang
Batteries 2025, 11(7), 256; https://doi.org/10.3390/batteries11070256 - 8 Jul 2025
Viewed by 288
Abstract
The health state of satellite power systems plays a critical role in ensuring the normal operation of satellite platforms. This paper proposes an improved Transformer-GRU-based algorithm for satellite power status detection, which characterizes the operational condition of power systems by utilizing voltage and [...] Read more.
The health state of satellite power systems plays a critical role in ensuring the normal operation of satellite platforms. This paper proposes an improved Transformer-GRU-based algorithm for satellite power status detection, which characterizes the operational condition of power systems by utilizing voltage and temperature data from battery packs. The proposed method enhances the original Transformer architecture through an integrated attention network mechanism that dynamically adjusts attention weights to strengthen feature spatial correlations. A gated recurrent unit (GRU) network with cyclic structures is innovatively adopted to replace the conventional Transformer decoder, enabling efficient computation while maintaining temporal dependencies. Experimental results on satellite power system status detection demonstrate that the modified Transformer-GRU model achieves superior detection performance compared to baseline approaches. This research provides an effective solution for enhancing the reliability of satellite power management systems and opens new research directions for future advancements in space power system monitoring technologies. Full article
(This article belongs to the Section Battery Modelling, Simulation, Management and Application)
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32 pages, 4753 KiB  
Review
Prospective Obstacles and Improvement Strategies of Manganese-Based Materials in Achieving High-Performance Rechargeable Zinc–Air Batteries
by Zhangli Ye, Tianjing Wu, Lanhua Yi and Mingjun Jing
Batteries 2025, 11(7), 255; https://doi.org/10.3390/batteries11070255 - 8 Jul 2025
Viewed by 610
Abstract
Zinc–air batteries (ZABs) are crucial for renewable energy conversion and storage due to their cost-effectiveness, excellent safety, and superior cycling stability. However, developing efficient and affordable bifunctional electrocatalysts for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) at the air [...] Read more.
Zinc–air batteries (ZABs) are crucial for renewable energy conversion and storage due to their cost-effectiveness, excellent safety, and superior cycling stability. However, developing efficient and affordable bifunctional electrocatalysts for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER) at the air cathode remains a significant challenge. Manganese (Mn)-based materials, known for their tunable oxidation states, adaptable crystal structures, and environmental friendliness, are regarded as the most promising candidates. This review systematically summarizes recent advances in Mn-based bifunctional catalysts, concentrating on four primary categories: Mn–N–C electrocatalysts, manganese oxides, manganates, and other Mn-based compounds. By examining the intrinsic merits and limitations of each category, we provide a comprehensive discussion of optimization strategies, which include morphological modulation, structural engineering, carbon hybridization, heterointerface construction, heteroatom doping, and defect engineering, aimed at enhancing catalytic performance. Additionally, we critically address existing challenges and propose future research directions for Mn-based materials in rechargeable ZABs, offering theoretical insights and design principles to advance the development of next-generation energy storage systems. Full article
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117 pages, 10736 KiB  
Review
Design Principles and Engineering Strategies for Stabilizing Ni-Rich Layered Oxides in Lithium-Ion Batteries
by Alain Mauger and Christian M. Julien
Batteries 2025, 11(7), 254; https://doi.org/10.3390/batteries11070254 - 4 Jul 2025
Viewed by 830
Abstract
Nickel-rich layered oxides such as LiNixMnyCozO2 (NMC), LiNixCoyAlzO2 (NCA), and LiNixMnyCozAl(1–x–y–z)O2 (NMCA), where x [...] Read more.
Nickel-rich layered oxides such as LiNixMnyCozO2 (NMC), LiNixCoyAlzO2 (NCA), and LiNixMnyCozAl(1–x–y–z)O2 (NMCA), where x ≥ 0.6, have emerged as key cathode materials in lithium-ion batteries due to their high operating voltage and superior energy density. These materials, characterized by low cobalt content, offer a promising path toward sustainable and cost-effective energy storage solutions. However, their electrochemical performance remains below theoretical expectations, primarily due to challenges related to structural instability, limited thermal safety, and suboptimal cycle life. Intensive research efforts have been devoted to addressing these issues, resulting in substantial performance improvements and enabling the development of next-generation lithium-ion batteries with higher nickel content and reduced cobalt dependency. In this review, we present recent advances in material design and engineering strategies to overcome the problems limiting their electrochemical performance (cation mixing, phase stability, oxygen release, microcracks during cycling). These strategies include synthesis methods to optimize the morphology (size of the particles, core–shell and gradient structures), surface modifications of the Ni-rich particles, and doping. A detailed comparison between these strategies and the synergetic effects of their combination is presented. We also highlight the synergistic role of compatible lithium salts and electrolytes in achieving state-of-the-art nickel-rich lithium-ion batteries. Full article
(This article belongs to the Special Issue Batteries: 10th Anniversary)
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15 pages, 2182 KiB  
Article
Investigating the Thermal Runaway Characteristics of the Prismatic Lithium Iron Phosphate Battery Under a Coupled Charge Rate and Ambient Temperature
by Jikai Tian, Zhenxiong Wang, Lingrui Kong, Fengyang Xu, Xin Dong and Jun Shen
Batteries 2025, 11(7), 253; https://doi.org/10.3390/batteries11070253 - 4 Jul 2025
Viewed by 578
Abstract
Optimizing the charging rate is crucial for enhancing lithium iron phosphate (LFP) battery performance. The substantial heat generation during high C-rate charging poses a significant risk of thermal runaway, necessitating advanced thermal management strategies. This study systematically investigates the coupling mechanism between charging [...] Read more.
Optimizing the charging rate is crucial for enhancing lithium iron phosphate (LFP) battery performance. The substantial heat generation during high C-rate charging poses a significant risk of thermal runaway, necessitating advanced thermal management strategies. This study systematically investigates the coupling mechanism between charging rates and ambient temperatures in overcharge-induced thermal runaway, filling the knowledge gaps associated with multi-indicator thermal management approaches. Through experiments on prismatic LFP cells across five operational conditions (1C/35 °C, 1.5C/5 °C, 1.5C/15 °C, 1.5C/25 °C, and 1.5C/35 °C), synchronized infrared thermography and electrochemical monitoring quantitatively characterize the thermal–electric coupling dynamics throughout overcharge-to-runaway transitions. The experimental findings reveal three key observations: (1) Charge rate and temperature have synergistic amplification effects on triggering thermal runaway. (2) Contrary to intuition, while low-current/high-temperature charging enhances safety versus high-current/high-temperature conditions, low-temperature/high-current charging triggers thermal runaway faster than high-temperature/high-current scenarios. (3) Staged multi-indicator lithium battery thermal runaway warning signals would be more accurate (first peaks > 0.5 °C/s temperature rise rate + >10 V/s voltage drop rate). These findings collectively demonstrate the imperative for next-generation battery management systems integrating real-time ambient temperature compensation with adaptive C-rate control, fundamentally advancing beyond conventional single-variable thermal regulation strategies. Intelligent adaptation is critical for mitigating thermal runaway risks in LFP battery operations. Full article
(This article belongs to the Special Issue Thermal Management System for Lithium-Ion Batteries: 2nd Edition)
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21 pages, 13514 KiB  
Article
Comparative Analysis via CFD Simulation on the Impact of Graphite Anode Morphologies on the Discharge of a Lithium-Ion Battery
by Alessio Lombardo Pontillo, Agnese Marcato, Daniele Versaci, Daniele Marchisio and Gianluca Boccardo
Batteries 2025, 11(7), 252; https://doi.org/10.3390/batteries11070252 - 2 Jul 2025
Viewed by 433
Abstract
The morphology of electrode materials plays a crucial role in determining the performance of lithium-ion batteries. Traditional computational models often simplify graphite flakes as uniformly sized spheres, which limits their predictive accuracy. In this study, we present a computational workflow that overcomes these [...] Read more.
The morphology of electrode materials plays a crucial role in determining the performance of lithium-ion batteries. Traditional computational models often simplify graphite flakes as uniformly sized spheres, which limits their predictive accuracy. In this study, we present a computational workflow that overcomes these limitations by incorporating a more realistic representation of graphite morphologies. This workflow is designed to be flexible and reproducible, enabling efficient evaluation of electrochemical performance across diverse material structures. By exploring different graphite morphologies, our approach accelerates the optimization of material preparation techniques and processing conditions. Our findings reveal that incorporating greater morphological complexity leads to significant deviations from classical model predictions. Instead, our refined model offers a more accurate representation of battery discharge behavior, closely aligning with experimental data. This improvement underscores the importance of detailed morphological descriptions in advancing battery design and performance assessments. To promote accessibility and reproducibility, we provide the developed code for seamless integration with the COMSOL API, allowing researchers to implement and adapt it easily. This computational framework serves as a valuable tool for investigating the impact of graphite morphology on battery performance, bridging the gap between theoretical modeling and experimental validation to enhance lithium-ion battery technology. Full article
(This article belongs to the Special Issue Batteries: 10th Anniversary)
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15 pages, 508 KiB  
Article
Demand-Adapting Charging Strategy for Battery-Swapping Stations
by Benjamín Pla, Pau Bares, Andre Aronis and Augusto Perin
Batteries 2025, 11(7), 251; https://doi.org/10.3390/batteries11070251 - 2 Jul 2025
Viewed by 265
Abstract
This paper analyzes the control strategy for urban battery-swapping stations by optimizing the charging policy based on real-time battery demand and the time required for a full charge. The energy stored in available batteries serves as an electricity buffer, allowing energy to be [...] Read more.
This paper analyzes the control strategy for urban battery-swapping stations by optimizing the charging policy based on real-time battery demand and the time required for a full charge. The energy stored in available batteries serves as an electricity buffer, allowing energy to be drawn from the grid when costs or equivalent CO2 emissions are low. An optimized charging policy is derived using dynamic programming (DP), assuming average battery demand and accounting for both the costs and emissions associated with electricity consumption. The proposed algorithm uses a prediction of the expected traffic in the area as well as the expected cost of electricity on the net. Battery tests were conducted to assess charging time variability, and traffic density measurements were collected in the city of Valencia across multiple days to provide a realistic scenario, while real-time data of the electricity cost is integrated into the control proposal. The results show that incorporating traffic and electricity price forecasts into the control algorithm can reduce electricity costs by up to 11% and decrease associated CO2 emissions by more than 26%. Full article
(This article belongs to the Special Issue Control, Modelling, and Management of Batteries)
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